• Title/Summary/Keyword: Green emission

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Cathodoluminescence and Longevity Properties of Potential Sr1-xMxGa2S4:Eu (M = Ba or Ca) Green Phosphors for Field Emission Displays

  • Ko, Ki-Young;Huh, Young-Duk;Do, Young-Rag
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.822-826
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    • 2008
  • We report the cathodoluminescence and aging properties of a series of green phosphors of formula $Sr_{1-x}M_xGa_2S_4$:Eu (x = 0.0-1.0, M = Ba or Ca) that have potential applications in field emission displays (FEDs). The series of phosphors was synthesized via NaBr-aided solid-state reactions in a flowing $H_2S$ stream. A low level ($\sim$20%) of Ba or Ca substitution for Sr in $SrGa_2S_4$:Eu maintains the orthorhombic phase of pure $SrGa_2S_4$:Eu phosphors. Further, a low level ($\sim$20%) of Ba or Ca substitution for Sr in $SrGa_2S_4$:Eu provides various green colors and sufficient brightness for FED applications. Substitution of Ba or Ca for Sr in $SrGa_2S_4$:Eu also improved the stability of the phosphor when it was operated under electron-beam irradiation of 5 kV.

Simple Fabrication of Green Emission and Water-Resistant CsPbBr3 Encapsulation Using Commercial Glass Frits (상업용 유리프릿의 소결 공정을 이용한 내수성을 갖는 CsPbBr3/Glass 세라믹 복합체의 제작)

  • Mun, Na-eun;Kim, Sunghoon
    • Korean Journal of Materials Research
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    • v.31 no.1
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    • pp.54-59
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    • 2021
  • In this work, narrow-band green-emitting CsPbBr3 particles are embedded in commercialized glass composites by a facile dry process. By optimizing the method through sintering in glass frit (GF) composites including CsBr and PbBr2, used as precursors, the encapsulation of CsPbBr3 particles made them waterproof with green fluorescence. To improve the fluorescent properties by reducing aggregation of CsPbBr3, fumed silica (FS) is additionally used to help particles avoid bulking up in the glass matrix. The CsPbBr3 perovskite/glass composites are characterized using scanning electron microscopy (SEM) images and energy-dispersive X-ray spectroscopy (EDS) maps, which support the existence of CsPbBr3 particles in the glass matrix. The photoluminescence (PL) properties demonstrate that the emission spectrum peak, full width at half maximum (FWHM), and photoluminescence quantum yield (PLQY) values are 519 nm, 17 nm, and 17.7 %. We also confirm the water-resistant properties. To enhance water/moisture stability, the composite sample is put directly into water, with its PLQY monitored periodically under UV light.

Effects of Yb3+/Er3+ Ratios on the Down- and Up-Conversion Luminescence of YNbO4:Yb3+/Er3+ (Yb3+/Er3+ 비가 YNbO4:Yb3+/Er3+의 하향 및 상향전환 발광 특성에 미치는 영향)

  • Park, Jung Hye;Ahn, Wonsik;Lee, Eun Young;Kim, Young Jin
    • Korean Journal of Materials Research
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    • v.25 no.9
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    • pp.475-479
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    • 2015
  • $YNbO_4:Yb^{3+}/Er^{3+}$ is synthesized using a solid-state reaction process with a LiCl flux. The effects of the Er/(Yb+Er) ratios ($R_{Er}$) on the up-conversion (UC) and down-conversion (DC) spectra are investigated. The XRD data confirm that the $Yb^{3+}$ and $Er^{3+}$ ions are fully substituted for the $Y^{3+}$ sites. The UC emission spectra activated by 980 nm consists of green and red emission bands, which originate from the $Er^{3+}$ ions through an energy transfer (ET) process from $Yb^{3+}$ to $Er^{3+}$. The UC emission intensity depends on the $R_{Er}$ value, and the findings demonstrate that $R_{Er}{\leq}0.14$ is suitable for an effective UC process. The DC emission spectra under 269 nm radiation of the synthesized powders exhibits not only a strong blue emission assigned to the $[NbO_4]^{3-}$ niobates, but also green peaks that originate from the $Er^{3+}$ ions through an ET process between $[NbO_4]^{3-}$ and $Er^{3+}$.

The Effect of Real-time Navigation on the Reduction of Greenhouse Gas Emission (실시간내비게이션의 온실가스 감축 영향력 분석)

  • Kim, Jeong Su;Oh, Junseok;Lee, Bong Gyou
    • KIPS Transactions on Computer and Communication Systems
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    • v.2 no.1
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    • pp.35-42
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    • 2013
  • This paper shows the positivistic approach for analyzing the effect of ICT on the reduction of greenhouse gas (GHG) emission. The real-time navigation was selected for the ICT based service in this research, and the CO2 reduction ratios of the optimized routes in the navigation were compared with the reduction ratios of the shortest routes in existing navigations. The results of experiments showed the driving based on the optimized routes has more reduction effects than the driving on the basis of the shortest routes. Also, new evaluation method for GHG emission was suggested by the quantification and monitoring approaches on the basis of the Clean Development Mechanism (CDM) in this paper. The results of this paper can be used as a preliminary research for the effect of ICT on the reduction of GHG emission. The evaluation method which suggested in this paper will be suggested to CDM as the new standard for the reduction of GHG emission in the transportation field as well.

Al-doping Effects on Structural and Optical Properties of Prism-like ZnO Nanorods

  • Kim, So-A-Ram;Kim, Min-Su;Cho, Min-Young;Nam, Gi-Woong;Lee, Dong-Yul;Kim, Jin-Soo;Kim, Jong-Su;Son, Jeong-Sik;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.420-420
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    • 2012
  • ZnO seed layer were deposited on quartz substrate by sol-gel method and prism-like Al-doped ZnO nanorods (AZO nanorods) were grown on ZnO seed layer by hydrothermal method with various Al concentration ranging from 0 to 2.0 at.%. Structural and optical properties of the AZO nanorods were investigated by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), photoluminescence (PL). The diameter of the AZO nanorods was smaller than undoped ZnO nanorods and its diameter of the AZO nanorods decreased with increasing Al concentration. In XRD spectrum, it was observed that stress and full width at half maximum (FWHM) of the AZO nanorods decreased and the 'c' lattice constant increased as the Al concentration increased. From undoped ZnO nanorods, it was observed that the green-red emission peak of deep-level emission (DLE) in PL spectra. However, after Al doping, not only a broad green emission peak but also a blue emission peak of DLE were observed.

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Optical Properties of ZnO Soccer Ball Structures by Using Vapor Phase Transport

  • Nam, Gi-Woong;Kim, Min-Su;Kim, Do-Yeob;Yim, Kwang-Gug;Kim, So-A-Ram;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.248-248
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    • 2011
  • ZnO was grown on a Au-catalyzed Si(100) substrate by using a simple vapor phase transport (VPT) with a mixture of zinc oxide and graphite powders. The ZnO grown at 800$^{\circ}C$ had a soccer ball structure with diameters of <500 nm. The ZnO soccer ball structure was, for the first time, observed in this work. The optical properties of the ZnO soccer balls were investigated by photoluminescence (PL). In the room-temperature (RT) PL of the ZnO soccer balls, a strong near-band-edge emission (NBE) and a weak deep-level emission were observed at 3.25 and 2.47 eV (green emission), respectively. The weak deep-level emission (DLE) at around 2.47 eV (green emission) is caused by impurities and structural defects. The FWHM of the NBE peak from the ZnO soccer balls was 110 meV. In addition, the PL intensity ratio of the NBE to DLE was about 4. The temperature-dependent PL was also carried out to investigate the mechanism governing the quenching behavior of the PL spectra.

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p" Color Field Emission Displays Using Carbon Nanotube Emitters

  • Lee, N.S.;Park, W.B.;Kim, J.M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.211-211
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    • 2000
  • Carbon nanotubes (CNTs) have been spotlighted as one of promising field emission displays(FEDs). For the first time, to authors knowledge, we have developed the 9" color CNT-FEDs with the resolution of 240x576 lines. The 9" CNT-FEDs with diode-type and triode-type structures are presented. The well-dispersed CNT paste was squeezed onto the metal-patterned cathode glass. For the anode plate, the Y2O2S:Eu, ZnS:Ag,Cl low-voltage phosphors were printed for red, green, and blue colors, respectively. The vacuum-packaged panel maintained the vacuum level of 1x10-7 Torr. The uniform moving images vacuum-packaged panel maintained the vacuum level of 1x10-7 Torr. The uniform moving images were demonstrated at 2 V/um. High brightness of 800, 200, and 150cd/m2 was observed on the green, red, and blue phosphors at V/um, respectively. Field emission characteristics of a triode-type CNT-FED were simulated using a finite element method. the resultant field strength on the cathode was modulated by gate bias and emitted electrons were focused on the anode. A relatively uniform emission image was experimentally achieved at the 800V anode. A relatively uniform emission image was experimentally achieved at the 800V anode and the 50-180 V gate biases. Energy distribution of electrons emitted from CNTs was measured using an energy analyzer. The maximum peak of energy curve corresponded to the Fermi energy level of CNTs. The whole fabrication processed of CNT-FEDs were fully scalable and reproducible. Our CNT-FEDs has demonstrated the high potential of large-area and full-color applications with very low cost fabrication and low power consumption.

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High Efficiency Green Phosphorescent Organic Light Emitting Devices using the Emission Layer of (TCTA/TCTA1/3TAZ2/3/TAZ) : Ir(ppy)3 ((TCTA/TCTA1/3TAZ2/3/TAZ) : Ir(ppy)3 발광층을 이용한 고효율 녹색 인광소자)

  • Jang, Ji-Geun;Shin, Sang-Baie;Shin, Hyun-Kwan;Kim, Won-Ki;Ryu, Sang-Ouk;Chang, Ho-Jung;Gong, Myoung-Seon;Lee, Jun-Yeob
    • Korean Journal of Materials Research
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    • v.18 no.7
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    • pp.347-351
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    • 2008
  • We have fabricated and evaluated newNew high high-efficiency green green-light light-emitting phosphorescent devices with an emission layer of [$TCTA/TCTA_{1/3}TAZ_{2/3}/TAZ$] : $Ir(ppy)_3$ were fabricated and evaluated, and compared the electroluminescence characteristics of these devices were compared with the conventional phosphorescent devices with emission layers of ($TCTA_{1/3}TAZ_{2/3}$) : $Ir(ppy)_3$ and (TCTA/TAZ) : $Ir(ppy)_3$. The current density, luminance, and current efficiency of the a device with an emission layer of ($80{\AA}-TCTA/90^{\circ}{\AA}-TCTA_{1/3}TAZ_{2/3}/130{\AA}-TAZ$) : 10%-$Ir(ppy)_3$ were $95\;mA/cm^2$, $25000\;cd/m^2$, and 27 cd/A at an applied voltage of 10 V, respectively. The maximum current efficiency was 52 cd/A under the a luminance value of $400\;cd/m^2$. The peak wavelength and FWHM (FWHM (full width at half maximum) in the electroluminescence spectral were 513 nm and 65 nm, respectively. The color coordinate was (0.30, 0.62) on the CIE (Commission Internationale de I'Eclairage) chart. Under the a luminance of $15000\;cd/m^2$, the current efficiency of the a device with an emission layer of ($80{\AA}-TCTA/90{\AA}-TCTA_{1/3}TAZ_{2/3}/130{\AA}-TAZ$) : 10%-$Ir(ppy)_3$ was 34 cd/A, which has beenshowed an improvement of improved 1.7 and 1.4 times compared to those of the devices with emission layers of ($300{\AA}-TCTA_{1/3}TAZ_{2/3}$) : 10%-$Ir(ppy)_3$ and ($100{\AA}-TCTA/200{\AA}$-TAZ) : 10%-$Ir(ppy)_3$, respectively.

A Study on Eco-friendly Policy and Current State of Japanese Logistics (일본 물류분야에 대한 친환경정책과 현황에 관한 연구)

  • Yoon, Song-Han
    • Journal of Korea Port Economic Association
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    • v.27 no.4
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    • pp.253-270
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    • 2011
  • The problem of global warming faced a big turning point due to the adoption of "Kyoto protocol"in 1997. Therefore, by enacting "Act on Advancement of Integration and Streamlining of Distribution Business"and "green logistics partnership council"to reduce $CO_2$ emission, fulfillment of distribution work is comprehensively and effectively supported by Japan. In particular, the green management certification system, which promotes green management based on the independent and planned environmental measures of transportation service of harbor employers, warehouse operators, and trucking employers of logistics sector, is promoted. As such, the Japanese government is actively promoting the eco-friendly green logistics policy to reduce $CO_2$ emission in terms of the prevention of global warming by building the comprehensive and efficient logistics system. Therefore, this thesis studied the status of the green logistics policy of Japan where the eco-friendly logistics system is being built ahead of Korea and as a result, it presented the implications on the green logistics strategy which is eco-friendly and can be developed continuously, the development of eco-friendly green logistics industry, the introduction of green logistics certification system, Departmental roles and responsibility of administrative agencies.