• Title/Summary/Keyword: Green dopant

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The Study on the Improved Quantum Efficiency of the PVK:Bu-PBD:C6 Single Layer Green Light Emitting Devices (PVK:Bu-PBD:C6 단일층 녹색발광소자의 양자효율 개선에 관한 연구)

  • 조재영;노병규;오환술
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.11
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    • pp.922-927
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    • 2001
  • Single-layer green ELs was fabricated with using molecularly-dispersed Bu-PBD into poly-N-vinylcarbazole(PVK) which has low operating voltage and high quantum efficiency. A EL cell structure of glass substrate/indium-tin-oxide/PVK:Bu-PBD:C6(∼ 100nm)/Ca(20nm)/Al(20nm) was employed with variable doping concentration. The keys to obtain high quantum efficiency was excellent film forming capability of molecularly dispersed into PVK and appropriate combination of cathode for avoiding exciplex. We obtained the turn-on voltage of 4.2V and quantum efficiency of 0.52% at 0.lmol% of C6 concentration which has been improved about a factor of 50 in comparison with the undoped cell. The PL peak wavelengths wouldn\`t be turned by changing the concentration of the C6 dopant. Green EL emission peak and FWHM were 520nm and 70nm respectively. PL emission peak was obtained at 495nm.

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Effect of nitrogen doping and hydrogen confinement on the electronic properties of a single walled carbon nanotube

  • Bhat, Bashir Mohi Ud Din;Dar, Jehangir Rashid;Sen, Pratima
    • Carbon letters
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    • v.17 no.1
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    • pp.29-32
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    • 2016
  • This paper addresses the effect of dopants on the electronic properties of zigzag (8, 0) semiconducting single walled carbon nanotubes (SWCNTs), using extended Hückel theory combined with nonequilibrium Green’s function formalism. Through appropriate dopant concentrations, the electronic properties of SWCNTs can be modified. Within this context, we present our ongoing investigation on (8, 0) SWCNTs doped with nitrogen. Quantum confinement effects on the electronic properties of the SWCNTs have also been investigated. The obtained results reveal that the electronic properties of SWCNTs are strongly dependent on the dopant concentration and modification of electronic structures by hydrogen confinement.

Preparation and Luminescence Properties of $Zn_2$$SiO_4$:Mn,Al Green Phosphors by Sol-gel Technique (졸-겔법에 의한 $Zn_2$$SiO_4$:Mn, Al 녹색 형광체의 제조 및 발광 특성)

  • 박희동;성부용;한정화;김대수
    • Journal of the Korean Ceramic Society
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    • v.38 no.4
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    • pp.337-342
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    • 2001
  • PDP(Plasma Display Panel)용 녹색 형광체인 Zn$_2$SiO$_4$:Mn에 채-dopant로 Al을 첨가하여 졸-겔법으로 합성하였다. 졸-겔법으로 제조한 형광체는 기존의 고상 반응에 의해 합성된 경우보다 낮은 온도(1000-110$0^{\circ}C$)에서 Zn$_2$SiO$_4$단일상을 형성하였으며, 300-500nm의 비교적 균일한 입자를 얻을 수 있었다. 또한, co-dopant인 Al을 첨가함으로써 발광휘도를 향상시키고, 전광시간을 줄일 수 있었다. 한편, TEOS의 가수분해시 $H_2O$/TEOS 비율을 조절하여 발광의 최적 조건을 조사하였다.

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Intramolecular Energy Transfer in Heteroleptic Red Phosphorescent Organic Light Emitting Diodes

  • Lee, Jun-Yeob;Kim, Sung-Hyun;Jang, Jyong-Sik
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.232-232
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    • 2006
  • Intramolecular energy transfer in heteroleptic red phosphorescent dopant materials with mixed ligand units in one molecule was studied. 1-phenylisoquinoline(piq) and phenylpyridine(ppy) moieties were introduced as ligands for Ir based phosphorescent dopants and light emission mechanism was investigated. Intramolecular energy transfer from ppy ligand to piq ligand resulted in pure red emission without any green emission from ppy. Current efficiency of red devices was improved from 4 cd/A to 4.8 cd/A by using mixed ligand structures and deposition temperature of red dopant could be lowered by introducing ppy ligand.

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Effect of Co-dopant (Cr, Ti) in Zn2Si04:Mn Green Phosphors by Sol-Gel technique.

  • Ahn, Joong-In;Han, Cheong-Hwa;Park, Hee-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.840-844
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    • 2003
  • The main objective of this investigation is to improve the photoluminescent of $Zn_{2}SiO_{4}:Mn$ phosphors prepared by the sol-gel technique. We try to use adding a new co-dopan such as Cr and Ti. The calcination temperature of sol-gel technique(1100 $^{\circ}C$) was lower than that of the solid state reaction (1300 $^{\circ}C$). Under 147nm excitation, the maximum emission intensity was obtained when the concentration of Cr and Ti was 0.1mol% with respect to $Zn_{2}SiO_{4}:Mn$. In order to study the effect of co-dopant, the content of Mn and the ratio of water to TEOS were fixed at 2mol% and 36:1, respectively.

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Highly efficient phosphorescent polymer OLEDs fabricated by screen printing

  • Lee, D.H.;Choi, J.S.;Cho, S.M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.694-697
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    • 2007
  • We demonstrate the use of screen printing in the fabrication of highly efficient phosphorescent polymer organic-light-emitting devices (OLEDs) based on a green-emitting $Ir(ppy)_3$ and a host polymer PVK. We incorporate PBD in the polymer host as an electron-transporting dopant and ${\alpha}-NPD$ as a hole transporting dopant. The best screen printed single-layer device exhibits very high peak luminous efficiency of 63 cd/A at a relatively high operating voltage of 17.1 V at the luminance of $650\;cd/m^2$. We observed the highest luminance of $21,000\;Cd/m^2$ at 35V. Due to the high operating voltage, despite of the high peak luminous efficiency the peak power efficiency was found to be 12.2 lm/W at the luminance of $470\;cd/m^2$ (15.9 V).

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Characteristic of transparent OLED using transparent metal cathode with green phosphorescent dopant (투명 금속 음극을 이용한 녹색 인광 OLED의 특성)

  • Yoon, Do-Yeol;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.154-154
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    • 2010
  • We have developed transparent OLED with green phosphorescent doped layer using transparent metal cathode deposited by thermal evaporation technique. Phosphorescent guest molecule, $Ir(ppy)_3$, was doped in host mCP for the green phosphorescent emission. Ca/Ag double layers were used as a cathode material of transparent OLED. The turn-on voltage of OLED was 5.2 V. The highest efficiency of the device reachs to 31 cd/A at 2 mA/$cm^2$.

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Enhancing Lifetime of White OLED Device by Minimizing Operating Voltage Increase

  • Lee, Sung-Soo;Choi, Jun-Ho;Ha, Jae-Kook;Lee, Sang-Pil;Kim, Seong-Min;Choi, Ji-Hye;Lee, Soo-Yeon;Kim, Hyo-Seok;Chu, Chang-Woong;Shin, Sung-Tae;Kim, Chi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1658-1660
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    • 2007
  • We fabricate green device having unique life time characteristics of operating voltage reduction with time, ${\Delta}V_{op}$ <0. A green device needs lower voltage than initial voltage for sustaining constant current as life time goes on. It means there are two possible reasons; one is interface modification between anode and HIL due to oxygen plasma treatment and the other is bulk property modification due to combination of new green host and new green dopant. From these materials and oxygen plasma treatment, we can make white OLED device having the characteristics of low ${\Delta}V_{op}$ increasing.

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Doping and Annealing Effect on Luminescent Characteristics of $_2$ Phosphor Thin Films (ZnGa$_2$O$_4$형광박막의 발광특성에 미치는 도핑 및 어닐리의 효과)

  • 정영호;정승묵;김석범;김영진
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.619-625
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    • 1998
  • Mn doped {{{{ {Zn {Ga }_{2 }O }_{4 } }} thin film phosphors were prepared on Si(100) wafers and ITO coated glass substrates by rf magnetron sputtering technique and the effects of the substrates dopant and the sputtering paramet-ers were analyzed, Changes of the oreintation were observed after annealine tratment. The grain size of {{{{ {Zn {Ga }_{2 }O }_{4 } }} : Mn thin film deposited on Si wafer was smaller than that on ITO/glass substrate which resulted in higher PL intensity. The PL spectra of Mn doped {{{{ {Zn {Ga }_{2 }O }_{4 } }} thin films showed sharp green luminescence spec-trum. According to CL spectrum it could be concluded that Mn ions acted as an actuator for green emission by substituting Zn atom sites.

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