• Title/Summary/Keyword: Green Materials

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Effects of Solvent-Based Dilution Condition on CNT Dispersion in CNT/Epoxy Composites (용매를 이용한 에폭시 희석 조건이 CNT 에폭시 복합재료 내 CNT 분산도에 미치는 영향)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Lee, Hyung-Ik;Park, Jong-Kyoo;Park, Joung-Man
    • Composites Research
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    • v.29 no.4
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    • pp.125-131
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    • 2016
  • In case of CNT mixing with epoxy, epoxy matrix needs to be diluted. This work studied the effect of the dilution condition of epoxy on CNT dispersion. The optimum solvent condition using acetone and DMF was found via mechanical and solubility methods which affects, the epoxy performance. The dispersion using acetone was better than the DMF and thus higher mechanical properties. Four mixing types of CNT particle were performed. To verify the effects of each step between dilution and dispersion, the dispersion between epoxy and CNT was evaluated via the electrical resistance and optical methods. The optimum dispersion was obtained via mechanical test and thermal analysis by DSC. Among four types, the best was to disperse CNT after epoxy and hardeners were diluted respectively.

A Study on the Characteristics of Green Design and Construction of Golf Courses in Korea (한국의 골프 코스 그린의 설계 및 시공 특성에 관한 연구)

  • 이상재;허근영
    • Asian Journal of Turfgrass Science
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    • v.13 no.4
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    • pp.181-190
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    • 1999
  • This study was carried out to survey green system, area, green slope, green turfgrass variety, green section, and particle size of green construction materials, and to investigate and evaluate the characteristics of Design and Construction in Korean golf course green for improving the quality of Korean golf course into that of the international golf course held international tournament. The results were as follows. 1. The greens of 129 Korean golf courses consisted of 2(two) green system and 1(one) green system. 2(two) green system was 50.8%, 1(one) green system was 40.7%, and 1+2 green system was 8.5% of them. 2. In 48 Korean golf courses, the green area of 2(two) green system was mostly 400~$600\m^2$(56.5%) and the green area of 1(one) green system was mostly 600~$800\m^2$(47.8%). In 48 Korean golf courses, 1.5~3% green slope appeared the highest frequency(50.0%) and the next was 3~5%(29.4%). 3. Penncross variety was the highest frequency(71.2%). The next was mixed variety (Penncross+Crenshaw, Penn A-1, Pennlinks, or Penneagle/SR 1020+SR 1019) and the frequency of mixed variety was 7.6%. 4. In 48 Korean golf courses, 70~80cm total thickness of green appeared the highest frequency(36.1%), 10~20cm thickness of green mixed sandy layer appeared the highest frequency(43.6%), and 10~20cm thickness of green coarse sandy layer appeared the highest frequency(55.6%). 0~10cm thickness of green gravel layer appeared the highest frequency(67.6%), 20~30cm thickness of green drain layer appeared the highest frequency(52.8%), and 20~30cm width of green drain layer appeared the highest frequency(44.4%). Below 1mm sand diameter used in green mixed sandy layer appeared the highest frequency(46.2%), below 2mm or over 2mm sand diameter used in green coarse sandy layer appeared the highest frequency(31.4%). 20~40mm coarse gravel diameter used in green gravel layer appeared the highest frequency(43.2%) and 0~20mm fine gravel diameter used in green gravel layer appeared the highest frequency(65.8%). 20~40mm gravel diameter used in green drain layer appeared the highest frequency(64.1%).

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Review : Ionic Liquids as Green Solvent (리뷰 : 녹색용매로서의 이온성액체 기술동향)

  • Lee, Junwung
    • Journal of the Korea Institute of Military Science and Technology
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    • v.16 no.5
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    • pp.690-702
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    • 2013
  • Ionic liquids(ILs) have been the most investigated chemicals among green solvents including water, glycerol, supercritical carbon dioxdie($scCO_2$). ILs are attracting organic as well as inorganic chemicals because most ionic liquids' vapor pressures are very low so that ILs are liquids phase at ambient conditions. ILs are composed of various anions and cations, thus chemists can design functionalized solvents and/or catalysts that can be used in specific synthetic reactions by means of combinations of different ions. Many scientists believe ILs being green materials because of its low vapor pressure as well as the flexibility in controlling the chemical and physical properties. In this review the author describes recent development of ILs focused on imidazolium and pyridinium ILs which are being most investigated presently. In order to apply this materials in industrial level, the toxicity matter must be resolved first. In this regard, the author describes recent research trend regarding environmental effects by ILs as well as some meaningful results as well.

Development of Petroleum-Based Carbon Composite Materials Containing Graphite/silicon Particles and Their Application to Lithium Ion Battery Anodes

  • Noh, Soon-Young;Kim, Young-Hoon;Lee, Chul-Wee;Yoon, Song-Hun
    • Journal of Electrochemical Science and Technology
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    • v.2 no.2
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    • pp.116-123
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    • 2011
  • Herein, a novel preparation method of highly homogeneous carbon-silicon composite materials was presented. In contrast to conventional solvent evaporation method, a milled silicon-graphite or its oxidized material were directly reacted with petroleum-derived pitch precursor. After thermal reaction under high pressure, pitch-graphite-silicon composite was prepared. Carbon-graphite-silicon composite were prepared by an air-oxidization and following carbonization. From energy dispersive spectroscopy, it was observed that small Si particles were highly embedded within carbon, which was confirmed by disappearance of Si peaks in Raman spectra. Furthermore, X-ray diffraction and Raman spectra revealed that carbon crystallinity decreased when the strongly oxidized silicon-graphite was added, which was probably due to oxygen-induced cross-linking. From the anode application in lithium ion batteries, carbon-graphite-silicon composite anode displayed a high capacity ($565\;mAh\;g^{-1}$), a good initial efficiency (68%) and an good cyclability (88% retention at 50 cycles), which were attributed to the high dispersion of Si particles within cabon. In case of the strongly oxidized silicongraphite addtion, a decrease of reversible capacity was observed due to its low crystallinity.

Correlation to the Physical Properties of Green and Sintered Body of Artificial Lightweight Aggregate with the Pelletizing Variables (펠레타이저 공정변수와 인공경량골재의 성형체와 소성체 물성과의 상관관계)

  • Wie, Young-Min;Lee, Ki-Gang
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.568-573
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    • 2007
  • For the manufacturing lightweight fine aggregate, clay and waste material was formed by pelletizer. The fine aggregate of 1-5 mm diameter was formed by diameter 76 cm pelletizer disc. Pelletization variables were : (1) pelletizer disc angle, (2) speed of revolution of pelletizer, (3) added pelletization time. Green and sintered aggregate were measured specific gravity, absorption rate and average size. The optimum condition were found that the pelletization variables were angle at $70^{\circ}$, speed of revolution of pelletizer at 23.2 rpm, and water/solid ratio at 1/5. At these conditions, it was formed that fine aggregate green whose average size was $2.0{\sim}3.35mm$. Specific gravity and average size are increased with low angle of disc and fast revolution speed of disc. Specific gravity and average size were not distinctly influenced by added pelletization time. Sintered aggregate was distinctly influenced by properties of green.

Synthesis and Characterization of Al-doped Uvarovite Green Pigments (Al-doped Uvarovite 안료의 합성과 특성)

  • Seo, Sung-Gyu;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.608-612
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    • 2010
  • Uvarovite Garnet is green pigment prepared by using $Cr_2O_3$, CaO and $SiO_2$ which are widely used in ceramic industry. The synthesis of above pigment was carried out by mixing $K_2Cr_2O_7$, $SiO_2$ and $CaCO_3$ as formulated and then firing at $1000{\sim}1200^{\circ}C$. To investigate the optimum synthesis condition of the Uvarovite Garnet. it was prepared by using CaO to replace $CaCO_3$, $CaF_2$ and $CaCl_2$. To get green brighter color, $Al^{3+}$ was substituted for $Cr^{3+}$. They were characterized by X-ray diffraction, UV-Vis spectroscopy, Raman spectroscopy and SEM analysis. When the pigments were applied to lime glazes (6 wt%), color parameters of Uvarovite Garnet showed the $L^*$=40.99, $a^*$=-16.23 and $b^*$=17.04.

Effect of Dispersion on Tape Casted Green Sheet Prepared from Bimodal-Type AlN Powders (Bimodal 입도분포를 보이는 AlN 분말의 테이프캐스팅 성형을 위한 분산효과)

  • Choi, Hong-Soo;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.566-571
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    • 2010
  • Dispersion behavior of the slurries consisted of bimodal-type AlN powders was examined in non-aqueous solvent system. Azotropic solvent system and copolymer acidic dispersant were applied to the slurries. Measurements of the sedimentation height and the viscosity of the each slurry, and the test of particle size distribution of the each powder sample were conducted as examinations for the dispersion behavior at the various dispersant contents. The bimodal-type particle size distribution was continued after addition of the dispersant and small particle portions were increased as the dispersant content increases. The density of the green sheet was also increased as the dispersant content increases and a green density of $2.114\;g/cm^3$ was obtained at the sample prepared from 2.4 wt% dispersant content. The increase of large particle portions resulted in the surface defects of the green sheets.

The optical properties of ZnS/$Na_3AlF_6$/ZnS multi-layered thin film with Co reflection layer (ZnS/$Na_3AlF_6$/ZnS 박막의 Cu 반사층을 이용한 광 특성)

  • Kim, Jun-Sik;Jang, Gun-Ik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.322-323
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    • 2008
  • Multi layered thin films with ZnS/$Na_3AlF_6$/ZnS were deposited on glass substrate by thermal evaporator precess and simulated by using EMP(Essential Macleod Program). EMP is a comprehensive software package to design and analyse the optical characteristics of multi-layered thin film. ZnS and $Na_3AlF_6$ were selected as a high refractive index and low refractive index material respectively. Additionally Cu was chosen as mid reflective material. Optical properties including color effect were systematically studied. in terms of different optical thickness of low refractive index material. The optical thickness of $Na_3AlF_6$ was changed as 0.25, 0.5, 0.75 and $1.0\lambda$. The film with 0.25, 0.5, 0.75 and $1.0\lambda$. of optical thickness showed mixed color range between bluish green and red purple, yellowish green and bluish green, purple and mixed color range of green and purple respectively.

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A Study on Examples of Eco-Friendly School Design - Focusing on School Facilities in USA, Japan and Korea - (학교건축의 친환경적 계획수법에 대한 사례연구 - 미국, 일본, 한국의 학교건축을 중심으로 -)

  • Lee, Ji-Young;Lee, Kyung-Sun
    • Journal of the Korean Institute of Educational Facilities
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    • v.18 no.2
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    • pp.3-14
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    • 2011
  • This study aims to identify differences and lessons in eco-school planning techniques and sustainable design methods by analyzing comparatively green building certification system and the cases of sustainable schools in US, Korea and Japan. As a result of the comparative analysis, green building certification system for school facilities, both domestic and international, is categorized into external environment, energy, materials and resources, and indoor environment. From the case study, it is common that roof garden and biotopes are installed for external environment, while energy saving, passive energy utilization methods for natural lighting and ventilation such as arrangement planning, courtyard, top-light, shading devices, solar panel and insulation by roof garden are most frequently used. Also, storm water uses, water saving equipment and sustainable materials are often introduced for resource savings. Concerns for indoor environment is frequently addressed by introducing natural light and ventilation in the buildings, which makes ultimately a comfortable space.

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Effect of Organic Additives on Microstructure and Green Density of Zirconia Granules Using Water Solvent (유기첨가제가 수계에서 제조된 지르코니아 과립의 미세구조 및 성형밀도에 미치는 영향)

  • Jung, Ji-Hwan;Lee, Sang-Jin
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.147-152
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    • 2017
  • Spherical-type zirconia granules are successfully fabricated by a spray-drying process using a water solvent slurry, and the change in the green density of the granule powder compacts is examined according to the organic polymers used. Two organic binders, polyvinyl alcohol (PVA) and 2-hydroxyethyl methacrylate (HEMA), which are dissolved in a water solvent and have different degrees of polymerization, are applied to the slurry with a plasticizer (polyethylene glycol). The granules employing a binder with a higher degree of polymerization (PVA) are not broken under a uniaxial press; consequently, they exhibit a poor green density of $2.4g/cm^3$. In contrast, the granule powder compacts employing a binder with a lower degree of polymerization (HEMA) show a higher density of $2.6g/cm^3$ with an increase in plasticizer content. The packing behavior of the granule powders for each organic polymer system is studied by examining the microstructure of the fracture surface at different applied pressures.