• Title/Summary/Keyword: Green Materials

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Process Design and Economic Evaluation of Condensate Recycling Process for Steam Consumption Reduction (스팀 사용 저감을 위한 응축수 재활용 공정설계 및 경제성 평가)

  • Kim, Jinuk;Choi, Yeongryeol;Cho, Hyungtae;Kim, Junghwan
    • Applied Chemistry for Engineering
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    • v.31 no.6
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    • pp.660-667
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    • 2020
  • This study focused on the epoxy resin production process, which uses the steam of 155 ℃ or higher as a heat source, and discards all condensate generated. A part of the process is operated at low temperatures of 70 ℃ or below, thus there are opportunities to reduce the steam consumption by recycling wasted condensate as a heat source for the low temperature section of process. In this study, we developed process models that can reduce steam by recovering waste heat through recycling condensate and conducted a case study to find an optimal condensate recycling system. Three different process designs were proposed and economic evaluations were performed by comparing annual capital costs and steam savings in each case. Finally, an annual steam consumption of the low-temperature section could be reduced by up to 67.6%, which could also bring an additional economic benefit of 522.1 million won/yr.

Molecular and Phenotypic Investigation on Antibacterial Activities of Limonene Isomers and Its Oxidation Derivative against Xanthomonas oryzae pv. oryzae

  • Hyeonbin Kim;Mi Hee Kim;Ui-Lim Choi;Moon-Soo Chung;Chul-Ho Yun;Youngkun Shim;Jaejun Oh;Sungbeom Lee;Gun Woong Lee
    • Journal of Microbiology and Biotechnology
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    • v.34 no.3
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    • pp.562-569
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    • 2024
  • Xanthomonas oryzae pv. oryzae (Xoo) causes a devastating bacterial leaf blight in rice. Here, the antimicrobial effects of ᴰ-limonene, ᴸ-limonene, and its oxidative derivative carveol against Xoo were investigated. We revealed that carveol treatment at ≥ 0.1 mM in liquid culture resulted in significant decrease in Xoo growth rate (> 40%) in a concentration-dependent manner, and over 1 mM, no growth was observed. The treatment with ᴰ-limonene and ᴸ-limonene also inhibited the Xoo growth but to a lesser extent compared to carveol. These results were further elaborated with the assays of motility, biofilm formation and xanthomonadin production. The carveol treatment over 1 mM caused no motilities, basal level of biofilm formation (< 10%), and significantly reduced xanthomonadin production. The biofilm formation after the treatment with two limonene isomers was decreased in a concentration-dependent manner, but the degree of the effect was not comparable to carveol. In addition, there was negligible effect on the xanthomonadin production mediated by the treatment of two limonene isomers. Field emission-scanning electron microscope (FE-SEM) unveiled that all three compounds used in this study cause severe ultrastructural morphological changes in Xoo cells, showing shrinking, shriveling, and holes on their surface. Moreover, quantitative real-time PCR revealed that carveol and ᴰ-limonene treatment significantly down-regulated the expression levels of genes involved in virulence and biofilm formation of Xoo, but not with ᴸ-limonene. Together, we suggest that limonenes and carveol will be the candidates of interest in the development of biological pesticides.

Fracture properties and tensile strength of three typical sandstone materials under static and impact loads

  • Zhou, Lei;Niu, Caoyuan;Zhu, Zheming;Ying, Peng;Dong, Yuqing;Deng, Shuai
    • Geomechanics and Engineering
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    • v.23 no.5
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    • pp.467-480
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    • 2020
  • The failure behavior and tensile strength of sandstone materials under different strain rates are greatly different, especially under static loads and impact loads. In order to clearly investigate the failure mechanism of sandstone materials under static and impact loads, a series of Brazilian disc samples were used by employing green sandstone, red sandstone and black sandstone to carry out static and impact loading splitting tensile tests, and the failure properties subjected to two different loading conditions were analyzed and discussed. Subsequently, the failure behavior of sandstone materials also were simulated by finite element code. The good agreement between simulation results and experimental results can obtain the following significantly conclusions: (1) The relationship of the tensile strength among sandstone materials is that green sandstone < red sandstone < black sandstone, and the variation of the tensile sensitivity of sandstone materials is that green sandstone > red sandstone > black sandstone; (2) The mainly cause for the difference of dynamic tensile strength of sandstone materials is that the strength of crystal particles in sandstone material, and the tensile strength of sandstone is proportional to the fractal dimension; (3) The dynamic failure behavior of sandstone is greatly different from that of static failure behavior, and the dynamic tensile failure rate in dynamic failure behavior is about 54.92%.

Blue Luminescent Center in Undoped ZnO Thin Films Grown by Plasma-assisted Molecular Beam Epitaxy (플라즈마 보조 분자선 적층 성장법으로 성장한 ZnO 박막의 청색 발광 중심)

  • Kim, Jong-Bin;No, Young-Soo;Byun, Dong-Jin;Park, Dong-Hee;Choi, Won-Kook
    • Korean Journal of Materials Research
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    • v.19 no.5
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    • pp.281-287
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    • 2009
  • ZnO thin film was grown on a sapphire single crystal substrate by plasma assisted molecular beam epitaxy. In addition to near band edge (NBE) emissions, both blue and green luminescences are also observed together. The PL intensity of the blue luminescence (BL) range from 2.7 to 2.9 eV increased as the amount of activated oxygen increased, but green luminescence (GL) was weakly observed at about 2.4 eV without much change in intensity. This result is quite unlike previous studies in which BL and GL were regarded as the transition between shallow donor levels such as oxygen vacancy and interstitial zinc. Based on the transition level and formation energy of the ZnO intrinsic defects predicted through the first principle calculation, which employs density functional approximation (DFA) revised by local density approximation (LDA) and the LDA+U approach, the green and blue luminescence are nearly coincident with the transition from the conduction band to zinc vacancies of $V^{2-}_{Zn}$ and $V^-_{Zn}$, respectively.

Effect of Temperature/Humidity Treatment Conditions on Interfacial Adhesion of Electroless-plated Ni on Polyimide (고온다습처리 조건이 무전해 니켈 도금 박막과 폴리이미드 사이의 계면 접착력에 미치는 영향)

  • Min, Kyoung-Jin;Jeong, Myeong-Hyeok;Lee, Kyu-Hwan;Jeong, Yong-Soo;Park, Young-Bae
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.675-680
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    • 2009
  • Effects of $85^{\circ}C/85%$ Temperature/Humidity (T/H) treatment conditions on the peel strength of an electroless-plated Ni/polyimide system were investigated from a $180^{\circ}$ peel test. Peel strength between electroless-plated Ni and polyimide monotonically decreased from $37.4{\pm}5.6g/mm$ to $22.0{\pm}2.7g/mm$ for variation of T/H treatment time from 0 to 1000 hrs. The interfacial bonding mechanism between Ni and polyimide appears to be closely related to Ni-O bonding at the Ni/polyimide interface. The decrease in peel strength due to T/H treatment appears to be related to polyimide degradation due to moisture penetration through the interface and the bulk polyimide itself.

A Study on the Effect of Air Temperature and Ground Temperature Mitigation from Several Arrangements of Urban Green (도시녹지의 기온 및 지온 완화효과에 관한 연구)

  • 이은엽;문석기;심상렬
    • Journal of the Korean Institute of Landscape Architecture
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    • v.24 no.1
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    • pp.65-78
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    • 1996
  • To study the temperature mitigation effects from urban green, several arrangements of green spaces were selected and air/ground temperatures were measured in Chongju city area. The results of this study can be summarized as follows; 1. It was found that the natural ground materials effect more affirmatively on the air and ground temperature than artificial ones do. The best results were recorded from the grass surface presenting highest mitigation effect and lowest daily temperature deviation. 2. Temperature mitigation effects of Tree-Shade on ground are different from season, ground material, and crown-size. Them most effects were found in interlocking block, the least in grass surface among recorded 2 seasons and 3 materials. In case of air temperature, the effects were more or less decreased in most cases. 3. From the survey, it was confirmed that the smaller urban greens can do its role of temperature mitigation as larger ones does. In case of this study, the effect was recorded about 2.3$^{\circ}C$.

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Renewable green polymers

  • Albertsson, Ann-Christine;Edlund, Ulrica;Hakkarainen, Minna;Sjoberg, John
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.121-122
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    • 2006
  • Paralleled with the development of new materials we need to develop methods and techniques to reveal the environmental interaction and impact of the new materials. Small changes in the chemical structure or product formulation may render the product less environmentally adaptable. Degradation products formed from PLLA were identified after aging in different environments and their assimilation in the biotic environment was shown. Green and degradable hydrogels could be designed from renewable hemicelluloses and lactic acid. Hemicelluloses are a renewable and highly interesting raw material source for new green polymers.

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Mechanical Properties of Green Strain-Hardening Cement-based Composites with Recycled Materials (순환재료를 사용한 그린 변형 경화형 시멘트 복합체의 역학적 특성)

  • Yun, Hyun-Do;Kim, Sun-Woo;Lee, Young-Oh;Nam, Sang-Hyun;Cha, Jun-Ho;Kim, Yun-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.399-400
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    • 2010
  • This paper presents results of an experimental program for evaluating the mechanical properties of green strain-hardening cementitious composite (SHCC) using recycled material. Recycled poly ethylene terephthalate (PET) fiber, fly ash, and recycled sand from waste concrete are used as materials for green SHCC. Test results indicated that average tensile strength of five dumbbell-shaped specimen is 4.76MPa and average compressive and flexural strength of three specimens are 38MPa and 7.40MPa, respectively.

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Dispersant Effect on Thermal Performance of SG (증기발생기 열성능에 미치는 분산제 첨가효과)

  • Lee, Jae-Keun;Moon, Jeon-Soo;Yoon, Seok-Won;Maeng, Wan-Young
    • Journal of Hydrogen and New Energy
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    • v.22 no.4
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    • pp.546-551
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    • 2011
  • The corrosion on steam generator tubes of the secondary side of pressurized water reactor inhibits heat transfer. One of the most efficient techniques improving the heat transfer performance of a nuclear electric generation is a corrosion control. The environmental parameters mostly affecting corrosion are materials and chemical additives. It seems that no further corrosion occurs in steels with Polyacrylic acid polymer dispersant treatment. Polyacrylic acid forms a protective coating with uniform thickness on metal surface. Polyacrylic treatment appears to be the most convenient way to enhance the thermal performance by the thermal conductivity improvement in steam generators.

Synthesis and Optical Characteristics of Green-Emitting (Mg,Zn)$Al_2O_4:Mn^{2+}$ Phosphor for 3D- PDP Applications

  • Han, Bo-Yong;Yoo, Jae-Soo;Heo, Eun-Gi;Yoo, Young-Gil
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.272-275
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    • 2009
  • A new green phosphor, ($Mg_{1-x-yZnx)$)$Al_2O_4:Mn^{2+}{_y}$ (0 x 0.6, 0.001 y 0.01), was synthesized by a flux-assisted solid reaction and its vacuum ultraviolet (VUV) excitation and emission characteristics were examined in this study. The chromaticity and peak intensity of the $(Mg_{0.79}Zn_{0.2})Al_2O_4:Mn^{2+}{_{0.01}}$ (x = 0.177, y = 0.745) phosphor were found to be more desirable than that of $Zn_2SiO_4:Mn^{2+}$ (x = 0.216, y = 0.72) phosphor as a green primary color.

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