• 한국재료학회지
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• 제31권3호
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• pp.139-149
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• 2021

In this study, three kinds of bainitic steels are fabricated by controlling the contents of vanadium and boron. High vanadium steel has a lot of carbides and nitrides, and so, during the cooling process, acicular ferrite is well formed. Carbides and nitrides develop fine grains by inhibiting grain growth. As a result, the low temperature Charpy absorbed energy of high vanadium steel is higher than that of low vanadium steel. In boron added steel, boron segregates at the prior austenite grain boundary, so that acicular ferrite formation occurs well during the cooling process. However, the granular bainite packet size of the boron added steel is larger than that of high vanadium steel because boron cannot effectively suppress grain growth. Therefore, the low temperature Charpy absorbed energy of the boron added steel is lower than that of the low vanadium steel. HAZ (heat affected zone) microstructure formation affects not only vanadium and boron but also the prior austenite grain size. In the HAZ specimen having large prior austenite grain size, acicular ferrite is formed inside the austenite, and granular bainite, bainitic ferrite, and martensite are also formed in a complex, resulting in a mixed acicular ferrite region with a high volume fraction. On the other hand, in the HAZ specimen having small prior austenite grain size, the volume fraction of the mixed acicular ferrite region is low because granular bainite and bainitic ferrite are coarse due to the large number of prior austenite grain boundaries.

• 한국토양비료학회지
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• 제6권2호
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• pp.107-113
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• 1973

인산(燐酸), 가리(加里) 및 규산시용(珪酸施用)과 출수후(出穗後)의 생육온도(生育溫度)가 벼의 수량(收量) 및 양분흡수(養分吸收)에 미치는 영향(影響)을 구명(究明)하기 위(爲)하여 실시(實施)한 Pot시험결과(試驗結果)를 요약(要約)하면 다음과 같다. 1. 수량(收量)은 출수후(出穗後) 생육온도(生育溫度)에 크게 영향(影響)을 받아 $25^{\circ}C$ 수량(收量) 100에 대(對)하여 $20^{\circ}C$에서는 62.3%, $15^{\circ}C$에서는 37.2%로 감수(減收)되였으며 출수후(出穗後) 생육온도(生育溫度)가 낮은 $15^{\circ}C$에서는 인산(燐酸), 가리(加里) 및 규산(珪酸)의 시용(施用)이 수량(收量)을 크게 증가(增加)시켰다. 2. 등숙율(登熟率)과 천립중(千粒重)도 출수후(出穗後) 생육온도(生育溫度)가 낮을수록 떨어지며 저온(低溫)인 $15^{\circ}C$에서는 인산(燐酸), 가리(加里) 및 규산(珪酸)의 시용(施用)은 등숙율(登熟率)과 천립중(千粒重)을 크게 증가(增加)시켰다. 3. 출수후(出穗後) 생육온도(生育溫度)가 높아짐에 따라 립중증가(粒重增加)의 속도(速度)가 빠르고 그 정지(停止)도 빠르며 저온(低溫)인 $15^{\circ}C$에서는 이와 반대(反對)로 그 속도(速度)가 완만하고 등숙후기(登熟後期)로 갈수록 빠르다. 저온(低溫)에 의(依)한 등숙장해(登熟障害)는 등숙초기(登熟初期)에 크다. 4. 출수후(出穗後) 생육온도(生育溫度)가 낮을수록 립중(粒中)의 탄수화물(炭水化物) 축적(蓄積)이 적고 인산(憐酸), 가리(加里) 및 규산(珪酸)을 시용(施用)함으로서 그 함량(含量)을 크게 증가(增加)시켰다. 5. 수확기(收穫期) 식물체중(植物體中)의 T-N 및 $P_2O_5$ 함량(含量)은 출수후(出穗後) 생육온도(生育溫度)가 낮을수록 높고 $K_2O$와 $SiO_2$는 이와 반대(反對)로 적으며 가리(加里)나 규산(珪酸)이 시용(施用)됨에 따라 그 함량(含量)도 증가(增加)되었다. 6. 수량(收量)과 등숙율(登熟率), 천립중(千粒重) 및 수확기(收穫期) 식물체중(植物體中)의 $K_2O$, $SiO_2$, $K_2O/N$ 및 $SiO_2/N$ 비율(比率)과는 정(正)의 상관(相關)이 있었고 T-N 및 $P_2O_5$와 부(負)의 상관(相關)이 있었다. 7. 등숙율(登熟率)과 천립중(千粒重)은 수확기(收穫期) 식물체중(植物體中)의 $K_2O$, $SiO_2$, $K_2O/N$ 및 $SiO_2/N$ 비율(比率)과 유의성(有意性) 있는 정상관(正相關)을 보여 주었고 T-N 및 $P_2O_5$는 등숙율(登熟率)과는 부(負), 천립중(千粒重)과는 정(正)의 상관(相關)이 있었다.

• 한국세라믹학회지
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• 제32권2호
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• pp.147-154
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• 1995

Abnormal grain growth behavior of BaTiO3 ceramics with controlling of particle size distribution of calcined powder was investigated. The particle size distribution was controlled by changing the calcining temperature or by using of classification and regrinding process. With broadening of the normallized size distribution in calcined powder, it showeda normal grain growth behavior in sintered body due to an increase of volume fraction of seed grain in the calcined powder. It was supposed that the seed grains could easily contact each other for the rapid grain growth during sintering process and resulted in fast switching-over from abnormal to normal grain growth stage.

• 한국세라믹학회지
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• 제37권6호
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• pp.530-536
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• 2000

During the grain growth of the PZT thin films by selective nucleation method using PZT seed, it was found that the grain size was saturated with the annealing temperature. The saturation of grain size was analyzed by the interfacial energy which appeared during the crystallization. The factors affecting the saturation of grain size were found to be the interfacial energy between perovskite phase and pyrochlore phase, and PZT thin film and the bottom Pt electrode. When the ion damage was introduced to the grain-size saturated PZT thin films, further lateral growth was observed. Pt bottom electrode thickness was changed to control the interfacial energy between the PZT thin film and the Pt bottom electrode. When Pt thickness was increased, the grain size was also increased, because the lattice parameter of Pt films was increased with the thickness of the Pt films. The incubation time of nucleation was increased with the amount of the ion damage on the Pt films.

• 한국초전도ㆍ저온공학회논문지
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• 제24권3호
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• pp.52-56
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• 2022

Single-grain (c-normal or c-parallel) and multi-grain YBCO superconductors were prepared by a melt growth process with/without seeding. The magnetic levitation force and trapped magnetic field at liquid N₂ temperature (77 K) of the YBCO superconductors were investigated. Samples for the levitation force measurement were zero-field cooled (ZFC) to 77 K, and samples for trapped field measurement were field-cooled (FC) using Nd magnets. As for the magnetic levitation force, the c-normal, single grain sample showed the largest value, whereas the multi-grain sample showed the lowest value. The trapped magnetic field of the c-normal and c-parallel single-grain samples was 4-5 times that of the multi-grain sample. In addition, as the external magnetic field (the number of magnets) increased, the both properties increased proportionally. These results were explained in terms of the orientation dependence of the levitation forces and the magnetic field trapping capability of the YBCO superconductor.

• 한국재료학회지
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• 제27권4호
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• pp.184-191
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• 2017

This present study deals with the effect of micro-alloying elements and transformation temperature on the correlation of microstructure and tensile properties of low-carbon steels with ferrite-pearlite microstructure. Six kinds of low-carbon steel specimens were fabricated by adding micro-alloying elements of Nb, Ti and V, and by varying isothermal transformation temperature. Ferrite grain size of the specimens containing mirco-alloying elements was smaller than that of the Base specimens because of pinning effect by the precipitates of carbonitrides at austenite grain boundaries. The pearlite interlamellar spacing and cementite thickness decreased with decreasing transformation temperature, while the pearlite volume fraction was hardly affected by micro-alloying elements and transformation temperature. The room-temperature tensile test results showed that the yield strength increased mostly with decreasing ferrite grain size and elongation was slightly improved as the ferrite grain size and pearlite interlamellar spacing decreased. All the specimens exhibited a discontinuous yielding behavior and the yield point elongation of the Nb4 and TiNbV specimens containing micro-alloying elements was larger than that of the Base specimens, presumably due to repetitive pinning and release of dislocation by the fine precipitates of carbonitrides.

• 한국전기전자재료학회논문지
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• 제35권5호
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• pp.445-451
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• 2022

Ultrasonic sensor is suitable as a next-generation autonomous driving assist device because its lower price compared to that of other sensors and its sensing stability in the external environment. Although Pb(Zr, Ti)O₃ (PZT)-relaxor ferroelectric system has excellent piezoelectric properties, the change in capacitance is large in the daily operating temperature range due to the low phase transition temperature. Recently, many studies have been conducted to improve the temperature stability of ferroelectric ceramics by controlling the grain size and crystal structure, so it is necessary to study the effect of the grain size on the piezoelectric properties and the temperature stability of PZT-relaxor ferroelectric system. In this study, the piezoelectric properties, phase transition temperature, and temperature coefficient of capacitance (TCC) of 0.9 Pb(Zr_1-xTi_x)O₃-0.1 Pb(Zn_1/3Nb_2/3)O₃ (PZT_x-PZN) ceramics with various grain sizes were investigated. PZT_x-PZN ceramics with larger grain size showed higher piezoelectric properties and temperature stability, and are expected to be suitable for ultrasonic devices in the future.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제50권11호
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• pp.539-543
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• 2001

ln this paper, the $Sr_{l-x}Ca_xTiO_3(0\leqx\leq0.2)-based$ grain boundary layer ceramics were fabricated to measure dielectric properties with the sintering temperature and the thermal treatment time. The sintering temperature and time were $1420~15206{\circ}C$, 4hours, and the thermal treatment temperature and time of the specimen were $l150^{\circ}C$, 1, 2, 3hours, respectively. The structural and the dielectric properties were investigated by SEM, X-ray, HP4194A and K6517. The average grain size was increased with increasing the sintering temperature, but it decreased up to 15mo1% with increasing content of Ca. X-ray diffraction analysis results showed that all specimens were the cubic structure, and the main peaks were moved to right and the lattice constant were decreased with increasing content of Ca. The appropriate thermal treatment time and temperature of CuO to obtain dielectric properties of $\varepsilon_r>50000,\; tan \delta<0.05\; and \;\DeltaC<\pm10%$ were 2hrs and $l150^{\circ}C$, respectively.

• Journal of Magnetics
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• 제15권4호
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• pp.155-158
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• 2010

The HDDR (hydrogenation, disproportionation, desorption, and recombination) process can be used as an effective way of converting a no coercivity Nd-Fe-B ingot material, with a coarse $Nd_2Fe_{14}B$ grain structure, to a highly coercive one with a fine grain structure. Careful control of the HDDR process can lead to an anisotropic powder with good $Nd_2Fe_{14}B$ grain texture; the most critical step for inducing texture is disproportionation. The critical conditions (hydrogen pressure and temperature) for the disproportionation reaction of fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ (x = 0 or 0.3, y = 0 or 0.2) alloys, in different atmospheres of pure hydrogen and a mixed gas of hydrogen and argon, was investigated with TPA (thermopiezic analyser). From this, the hydrogen pressure-temperature diagram showing the critical conditions was established. The critical disproportionation temperature of the fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ alloys was slightly increased as the hydrogen pressure decreased in both pure hydrogen and mixed gas. The critical disproportionation temperature of the hydrogenated alloys was higher in the mixed gas than in pure hydrogen. Addition of Ga and Nb increased the critical disproportionation temperature of the fully hydrogenated Nd-Fe-B alloys.

• E2M - 전기 전자와 첨단 소재
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• 제8권5호
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• pp.640-647
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• 1995

In this study, the BaTiO$\sub$3/ capacitor add to MnO$\sub$2/ like depressor and shifter were investigated for temperature or voltage compensation by structural and electrical analysis. The relative density of BCTM, generating poly crystall and formation of lattice defect, has a 90[%] over as the CaTiO$\sub$3/ come out to control grain size. The current density of BCTM2 increased non-ohmic in high-electric field but that BCTM3 and BCTM4 had a few changing. The BCTM3 and BCTM4 unformated grain boundary shown temperature compensation properties, so that the dielectric constant was low value. The curie point was near 140[.deg. C] in BCTM1 and BCTM4, but BCTM3 and BCTM4 not shown the curie point. It is found that the charging energy of BCTM4 was changed 6[%] according to rising temperature from room temperature to 417[K]. The formation of BaMnO$\sub$3/ was low dielectric constant to change frequency and temperature.