• 제목/요약/키워드: Gold film

검색결과 277건 처리시간 0.03초

금도금을 위한 AISI 304 스테인레스강 표면의 세정 (A Study on the Cleaning of AISI 304 Stainless Steel Surface for Gold Plating)

  • 한범석;장현구
    • 한국표면공학회지
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    • 제28권1호
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    • pp.23-33
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    • 1995
  • AISI 304 stainless steel has high resistance to corrosion due to the presence of a self-healing chromium oxide film on the surface, which also accounts for the difficulty in plating. Surface cleaning of this alloy is of fundamental importance in gold plating since its effectiveness puts an upper limit on the quality of the final coating. The cleaning of AISI 304 stainless steel was investigated with elimination of artificial passive oxide film and degreasing of remaining buffing wax as stearic acid. The familiar cleaning methods i.e. ultrasonic cleaning, electro-cleaning and activation treatment were fabricated in this study. Activation treatment showed best cleaning efficiency for elimination of passive oxide film among these methods, which was also confirmed by AES (Auger electron spectrometer) analysis. However, the best condition of cleaning was obtained by combining these methods. Electrocleaning time, for degreasing the stearic acid layer, was decreased with increasing amount of added KCN.

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Directional Radiation of Surface Plasmon Polaritons at Visible Wavelengths through a Nanohole Dimer Optical Antenna Milled in a Gold Film

  • Janipour, Mohsen;Hodjat-Kashani, Farrokh
    • Journal of the Optical Society of Korea
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    • 제18권6호
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    • pp.799-808
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    • 2014
  • The mechanism of optical interaction of two nanoholes, milled in an opaque gold film, by means of surface plasmon polariton (SPP) propagation is investigated. The interaction depends on the polarization direction of the incident light when the nanohole pair is illuminated through uniform single antenna excitations. It is shown that by illuminating one of the nanoholes, under single antenna excitation, the other nanohole can be excited indirectly via propagated SPPs from the excited nanohole. In addition, it is found that the spectrum of electromagnetic power above the surface of the metallic film at an arbitrary point along the axis of the nanohole pair presents two resonant peaks. These peaks are due to the optical interaction between nanoholes, where the short- and long-wavelength peaks can be assigned to in-phase and antiphase interactions of magnetic dipoles relative to each nanohole, respectively. The magnetic coupled dipole approximation (MCDA) method confirms the simulation results.

Charged Cluster Model as a New Paradigm of Crystal Growth

  • Nong-M. Hwang;In-D. Jeon;Kim, Doh-Y.
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 2000년도 Proceedings of 2000 International Nano Crystals/Ceramics Forum and International Symposium on Intermaterials
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    • pp.87-125
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    • 2000
  • A new paradigm of crystal growth was suggested in a charged cluster model, where charged clusters of nanometer size are suspended in the gas phase in most thin film processes and are a major flux for thin film growth. The existence of these hypothetical clusters was experimentally confirmed in the diamond and silicon CVD processes as well as in gold and tungsten evaporation. These results imply new insights as to the low pressure diamond synthesis without hydrogen, epitaxial growth, selective deposition and fabrication of quantum dots, nanometer-sized powders and nanowires or nanotubes. Based on this concept, we produced such quantum dot structures of carbon, silicon, gold and tungsten. Charged clusters land preferably on conducting substrates over on insulating substrates, resulting in selective deposition. if the behavior of selective deposition is properly controlled, charged clusters can make highly anisotropic growth, leading to nanowires or nanotubes.

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YBCO film을 이용한 저항형 초전도 한류기의 전류제한 특성 (Current limiting characteristics of the resistive SFCL using YBCO film)

  • 최효삼;김혜림;황시돌;현옥배;김상준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 A
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    • pp.277-280
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    • 1999
  • We fabricated a resistive superconducting fault current limiter of two stripe meander type based on a YBCO film, and performed current limitation experiments. In order to disperse the heat generated at hot spots in the YBCO film the film was coated with a gold shunt layer. At $0^{\circ}$ fault angle the minimum quench current was $9.6 A_{peak}$(meander line cross section: $5{\times}10^{-6}cm^2$) and the fast quench time was 0.63 msec. The resistance of the limiter continued to increase for three cycles due to heat generation in the gold layer and was stabilized afterwards. At $45^{\circ}$ and $90^{\circ}$ the fast quench time were 0.56 msec and 0.26 msec, respectively. The quench time is believed to be reduced because faults occurred when the current was increasing or was at the peak value. With the limiter we could effectively limit the fault current about 1/5 times right after the fault and about 1/8.5 times three cycles after.

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논시안 금도금층의 조직과 경도에 미치는 Tl+ 과 Pd2+ 이온첨가의 영향 (Effect of addition of Tl+ and Pd2+ on the texture and hardness of the non-cyanide gold plating layer)

  • 허원영;손인준
    • 한국표면공학회지
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    • 제55권6호
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    • pp.460-468
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    • 2022
  • Due to its high electrical conductivity, low contact resistance, good weldability and high corrosion resi-stance, gold is widely used in electronic components such as connectors and printed circuit boards (PCB). Gold ion salts currently used in gold plating are largely cyan-based salts and non-cyanic salts. The cya-nide bath can be used for both high and low hardness, but the non-cyanide bath can be used for low hardness plating. Potassium gold cyanide (KAu(CN)2) as a cyanide type and sodium gold sulfite (Na3[Au(SO)3]2) salt as a non-cyanide type are most widely used. Although the cyan bath has excellent performance in plating, potassium gold cyanide (KAu(CN)2) used in the cyan bath is classified as a poison and a toxic substance and has strong toxicity, which tends to damage the positive photoresist film and make it difficult to form a straight side-wall. There is a need to supplement this. Therefore, it is intended to supplement this with an eco-friendly process using sodium sulfite sodium salt that does not contain cyan. Therefore, the main goal is to form a gold plating layer with a controllable hardness using a non-cyanide gold plating solution. In this study, the composition of a non-cyanide gold plating solution that maintains hardness even after annealing is generated through gold-palladium alloying by adding thallium, a crystal regulator among electrolysis factors affecting the structure and hardness, and changes in plating layer structure and crystallinity before and after annealing the correlation with the hardness.

고대신라의 금속기술 연구 (A Study of Metal Technology in Ancient Silla Dynasity)

  • 강성군;조종수
    • 한국표면공학회지
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    • 제8권1호
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    • pp.1-9
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    • 1975
  • The crorosion film of gilt bronz, silver and iron objects, which were excaved from Ancient Tomb of Silla Dynasty, was removed by the electrolytic reduction process. These metallic objects were mainly investigated for microstructure, designs and gilting film etc. Most iron objects might be made by hot forging process. The cold extrusion technique might be used for gold and silver objects, in addition to an amalgam method might be applied for the gilting Au film on Cu-alloy surface. For the gilting on glass surface, first, a Cu alloy was cladded on glass , next, Au-film was obtained on the Cu-ally by the amagum method.

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Voltammetric Behaviors of Chemically Modified Electrodes Based on Zirconium Phosphonate Film

  • 홍훈기
    • Bulletin of the Korean Chemical Society
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    • 제16권9호
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    • pp.886-891
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    • 1995
  • Electroactive monolayers based on zirconium(Ⅳ) phosphonate film were prepared on gold and tin oxide electrodes by sequential layer-by-layer depostion technique. High transfer coefficient values and surface coverages of surface bound redox molecules were obtained from the electrochemical measurements of heterogeneous electron transfer rates for monolayer modified electrodes. 1,10-Decanediylbis(phosphonic acid) (DBPA) monolayer as insulating barrier was effective in blocking electron transfer. However, these film modified oxide electrode shows voltammetric behavior of diffusion/permeation process taking place at very small exposed area of modified electrode through channels due to structural defects within film when a very fast redox couple such as Ru(NH3)63+ is hired.

Surface Plasmon Resonance Imaging Analysis of Hexahistidine-tagged Protein on the Gold Thin Film Coated with a Calix Crown Derivative

  • Chung, Bong-Hyun;Baek, Seung-Hak;Shin, Yong-Beom;Kim, Min-Gon;Ro, Hyeon-Su;Kim, Eun-Ki
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제9권2호
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    • pp.143-146
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    • 2004
  • A surface plasmon resonance (SPR) imaging system was constructed and used to detect the hexahistidine-ubiquitin-tagged human parathyroid hormone fragment (His$\sub$6/-Ub-hPTHF(1-34)) expressed in Escherichia coli. The hexahistidine-specific antibody was immobilized on a thin gold film coated with ProLinker$\^$TM/ B, a novel calixcrown derivative with a bifunctional coupling property that permits efficient immobilizaton of capture proteins on solid matrices. The soluble and insoluble fractions of an E. coli cell lysate were spotted onto the antibody-coated gold chip, which was then washed with buffer (pH 7.4) solution and dried. SPR imaging measurements were carried out to detect the expressed His$\sub$6/-Ub-hPTHF(1-34). There was no discernible protein image in the uninduced cell lysate, indicating that non-specific binding of contaminant proteins did not occur on the gold chip surface. It is expected that the approach used here to detect affinity-tagged recombinant proteins using an SPR imaging technique could be used as a powerful tool for the analyses of a number of proteins in a high-throughput mode.