• Fibers and Polymers
• /
• v.5 no.3
• /
• pp.245-251
• /
• 2004

Poly(trimethylene terephthalate-co-trimethylene 2,6-naphthalate)s (P(TT-co-TN)s) with various copolymer composition were synthesized, and their chain structure, thermal property and crystalline structure were investigated by using $^1$H-NMR spectroscopy, differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD), respectively. It was found from sequence analysis that all the P(TT-co-TN) copolymers synthesized have a statistical random distribution of TT and TN units. It was also observed from DSC thermograms that the glass transition temperature increases linearly with increasing the TN comonomer content, whereas the melting temperature of copolymer decreases with increasing the corresponding comonomer content in respective PTT- and PTN-based copolymer, showing pseudo-eutectic melting behavior. All the samples melt-crystallized isothermally except for P(TT-co-66 mol % TN) exhibit multiple melting endotherms and clear X-ray diffraction patterns. The multiple melting behavior originates from the dual lamellar population and/or the melting-recrystallization-remelting. The X-ray diffraction patterns are largely divided into two classes depending on the copolymer composition, i.e., PTT and PTN $\beta$-form diffraction patterns, without exhibiting cocrystallization.

• Journal of Advanced Marine Engineering and Technology
• /
• v.38 no.5
• /
• pp.533-540
• /
• 2014

Recently, latent heat thermal energy storage system (LHTES) has gained attention in order to utilize middle temperature (373~573 K) waste heat from biomass gasification. This paper has investigated thermo-physical properties of erythritol [$CH_2OHCHOH$ $CHOHCH_2OH$], mannitol [$CH_2OH$ $(CHOH)_4CH_2OH$] and their compounds as phase change materials (PCMs). The differential scanning calorimetry (DSC) was applied to measure the melting point and latent heat of these PCMs. Also the melting and solidification characteristics of these PCMs were observed in a glass tube with a digital camera. In the DSC measurement, when the amount of mannitol content was more than 40 mass%, the melting point of these compounds show two melting points. The experimental results showed that the velocity of melting and solidification were different for every mixture ratio of compounds. These compounds had the super-cooling phenomenon during the solidification process.

• Journal of Technologic Dentistry
• /
• v.31 no.4
• /
• pp.25-30
• /
• 2009

Zirconia($ZrO_2$) has attracted much attention in science and technology because of its high refractive index, high melting temperature, hardness, low thermal conductivity and corrosion barrier properties. And it is widely used as the dental restoration material because of its esthetic appearance. In this research, we analyzed the particle size and composition of the imported dental porcelain for zirconia. And the glass frit was produced. To decrease the glass transition temperature and softening temperature of the glass frit, $Li_2O$ was added into it and the effect of $Li_2O$ on the firing temperature was researched. Then the glass which contains leucite crystal with a high coefficient of thermal expansion(CTE) was manufactured and it was mixed with the glass frit to control the CTE. The phase composition were analyzed using the X-ray diffraction. The morphologies of the samples were observed by the scanning electron microscope. The 4wt% $Li_2O$-added glass frit has the optimal glass transition temperature and softening temperature. And 6 wt% leucite crystal was mixed with the glass frit to control the CTE. From the experimental results of crystallization, the crystal phase was found only leucite crystal.

• Korean Journal of Materials Research
• /
• v.19 no.2
• /
• pp.95-101
• /
• 2009

Glass ceramics were made from coal bottom ash by adding CaO and $Li_2O$ as glass modifiers and $TiO_2$ as a nucleating agent in a process of melting and quenching followed by a thermal treatment. The surface of the glass ceramics has 1.6 times more $Li_2O$ compared to the inner matrix. When $TiO_2$ was not added or when only 2 wt% was added, the surface parts of the glass ceramics were crystalline with a thickness close to $130{\mu}m$. In addition, the matrixes showed only the glass phase and not the crystalline phase. However, doping of $TiO_2$ from 4 wt% to 10 wt% began to create small crystalline phases in the matrix with an increase in the quantity of the crystalline. The matrix microstructure of glass ceramics containing $TiO_2$ in excess of 8 wt% was a mixture of dark-gray crystalline and white crystalline parts. These two parts had no considerable difference in terms of composition. It was thought that the crystallization mechanism affects the crystal growth, direction and shape and rather than the existence of two types of crystals.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.11b
• /
• pp.550-553
• /
• 2001

$Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ glass containing glass former, $P_{2}O_{5}$ and $Bi_{2}O_{3}$ was prepard by melting the glass batch in pt. erucible followed by guenching on the copper plate. We found that $Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ glass-ceramics obtained from the crystallization of glass showed signifieantly higher capacity and longer cycle life tham $LiV_{3}O_{8}$ made from powder synthesis. In this paper, we described crystallization process and $LiV_{3}O_{8}$ crystal growth in glass matrix by increasing temperature. The electrochemical properties were strongly affected by $LiV_{3}O_{8}$ crystal growth in matrix

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.14 no.8
• /
• pp.652-657
• /
• 2001

Vanadate glasses containing 10~20mol% glass former, P$_2$O$_{5}$ were prepared by melting the batch in platinum crucible and quenching on the copper plate. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics having LiV$_3$O$_{8}$ were obtained by heat-treatment of this glass in crystallization temperature. The glass-ceramics showed singnificantly good capacity and long cycles life according to heating condition. In this paper, we described electrochemical properties during crystallization process and found the best crystallizaton condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass as cathode material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics heat-treated at 233$^{\circ}C$ for 3 hors showed good rechargeable capacity of 220mAh/g in the cycling range between 2.0 and 3.9V.en 2.0 and 3.9V.

• Journal of the Semiconductor & Display Technology
• /
• v.21 no.1
• /
• pp.119-126
• /
• 2022

MAS-based glass, which has been studied to replace the ceramic material used in the plasma etching chamber, has problems such as forming and processing due to its high melting temperature. To solve this problem, in this study, fluoride was added to the existing MAS-based glass to increase the workability in the glass manufacturing and to improve the chemical resistance to CF₄/Ar/O₂ plasma gas. Through RAMAN analysis, the structural change of the glass according to the addition of fluoride was observed. In addition, it was confirmed that high-temperature viscosity and thermal properties decreased as the fluoride content increased and plasma resistance was maintained, it showed an excellent etching rate of up to 11 times compared to quartz glass.

• Korean Journal of Materials Research
• /
• v.20 no.10
• /
• pp.524-534
• /
• 2010

Glass was fabricated using refused coal ore obtained from the Dogye coal mine in Samcheok. We additionally used soda ash and calcium carbonate to make a glass with the chemical composition of soda-lime glass, and we also used white, brown, and green glass cullet to make various kinds of colored glass. Transparent glass was fabricated by melting batch materials including refused coal ore at $1550^{\circ}C$ for 1 hr in an electrical furnace. The light transmittance and color chromaticity were measured by a UV/VIS/NIR spectrometer. Transparent glass with a light transmittance of over 80% was fabricated using normal refused coal ore and white glass cullet. Various kinds of colored glass with a light transmittance of 30-80% were fabricated using refused coal ore and brown or green glass cullet. The light transmittance of the mixed color glass samples, fabricated using normal refused coal ore and brown glass cullet and green glass cullet, indicated 30-47%, a relatively low value, in the condition of a cullet ratio of 20-50%. The characteristics of the color chromaticity of the glass samples were indicated in a chromaticity diagram by x-coordinates, y-coordinates, Y (lightness). The values of x-coordinates and y-coordinates were moved with a regular directional property according to the kind and amount of glass cullet. Therefore, we concluded that refused coal ore can be used for raw materials of color glass products like art glass and glass tile.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2004.08a
• /
• pp.1095-1098
• /
• 2004

In this study, $Bi_2O_3-B_2O_3-ZnO$ glass system, which was expected to have similar properties with PbO containing glass system, was selected as a PbO replaceable potential composition because the atomic weight and ionic radius of Bi is similar to those of Pb. Glasses with different modifier/former ratio were prepared by melting the raw ingredient mixtures in $Bi_2O_3-B_2O_3-ZnO$ system, and the thermal and electrical properties of the sintered samples were examined. The glass transition temperatures and the dielectric constant of the glass pellets were between 350 $^{\circ}C{\sim}$500 $^{\circ}C$ and 15-35, respectively.

• Journal of the Korean Ceramic Society
• /
• v.42 no.6 s.277
• /
• pp.371-376
• /
• 2005

Phosphate glasses were prepared by melting quenching process, and glass formation and dissolution properties were studied. The glass forming region in the $K_2O-CaO-P_2O_5$ system is quietly agreed with the report by Mazurin OV et al. with $M_2O-M'O-P_2O_5$ system (M : monovalent cation, M'divalent cation). Conditionally these glasses have solubility from absorbing the moisture or water and then release elements with trace elements, and the thermal and chemical properties were controllable by the $CaO,\;K_2O,\;P_2O_5$ contents. In the abnormal glass properties, this paper showed the possibility the present glasses can be a good candidate for one component of the slow released agriculture fertilizer.