• Title/Summary/Keyword: Glass melting

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Thermal Properties of Semiconductive Materials(Shield) by Sonic Impurities in Carbon Black (카본블랙내 이온성 불순물들에 따른 반도전 재료(층)의 열적특성)

  • Lee Yong-Sung;Choi Yong-Sung;Park Dae-Hee;Lee Kyoung-Yong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.4
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    • pp.149-153
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    • 2005
  • We have investigated thermal properties showed by changing the content of carbon black which is the component parts of semiconductive shield in underground power transmission cable. Specimens were made of sheet with the nine of those for measurement. Heat capacity (${\Delta}$H), glass transition temperature (Tg) and melting temperature (Tm) were measured by DSC (Differential Scanning Calorimetry). The ranges of measurement temperature were from -100($^{\circ}C$) to 100($^{\circ}C$), and heating rate was 4($^{\circ}C$/min). And then thermal diffusivity was measured by LFA 447. The dimension of measurement temperature was 25[$^{\circ}C$]. Glass transition temperature of specimens was showed near -25[$^{\circ}C$] and the heat capacity and the melting temperature from the DSC results were simultaneously decreased according to increasing the content of carbon black, while thermal diffusivity was increased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

Property of Carboxylic Polyester Powder Coatings with Different Hardeners (경화제에 따른 열경화성 분체도료의 물성 비교)

  • Choi, Seung-Ok;Kim, Eun-Mi;Yoo, Jung-Hee;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.351-358
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    • 2011
  • It was researched to be alternative of TGIC type hardener with human hazard element as PT 910 mix powder paint with hardener. Generally PT 910 was compared with TGIC & Epoxy resin of hardener to be used at thermosetting powder paint. We inquired a property of matter for paint through Gel time, glass transition temperature, melting point and a property of matter for film through a property of adhesion, a property of tolerance, softness, gloss, acid-resistant, alkali-resistant, salt water spray-resistant, facilitation climatic. When PT 910 is used of hardener, it was shown the excellent results in gel time, softness, salt water spray-resistant, fracilitation climatic and the similar results in melting point, a property of tolerance, a property of adhesion, gloss, acid-resistant, alkali-resistant, as compared with the powder paint used by TGIC hardener. The glass transition temperature was little low. But there was slightly different results. After the study results, we reached the conclusion that thermosetting powder used by PT 910 is alterative to by TGIC hardener.

Effect of the Melting atmospheres for the $SnO_2-(1-x)P_2O_5-xR_2O_3$ Glass System (SnO-(1-x)$P_2O_5-xR_2O_3$ 계 유리에서 $R_2O_3$ 치환 및 용융분위기의 영향)

  • Lee, Young-Hun;Ji, Mi-Jung;Lee, Hong-Lim
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.206-207
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    • 2005
  • Display 소재로서 유전체나 격벽재 실링재로 사용되고 있는 frit는 PbO를 주성분으로 갖는 유리가 사용되고 있다. PbO 성분이 함유된(50$\sim$85%) 구성소재는 최근 RoHS 나 WEEE 등의 환경규제 실행에 직면해 있으며, 대체재료의 개발을 위한 많은 연구가 진행되고 있다 PbO 성분을 대체할 성분으로는 $Bi_2O_3$ 계, BaO-ZnO 계, $P_2O_5$ 계 등의 성분이 주요성분으로 이루어져 있으며, PbO 성분을 함유한 유리의 저융점, 저유전율, 고 투과율, 내산성, 내전압, 팽창계수 matching 등의 특성들에 부합되는 재료를 개발하기 위해 많은 노력을 기울이고 있다. 본 연구에서는 SnO-$P_2O_5$ 계 유리 조성을 선택하여 $R_2O_3$의 치환 및 용융분위기의 조절에 따른 저융점 유리로서의 특성과 효과에 대하여 고찰하였다.

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Behavior of Ag+ and Sn2+ After Reaction Between the Transparent Dielectric PbO-B2O3-SiO2-Al2O3 and Ag Electrodes (투명 유전체 (PbO-B2O3-SiO2-Al2O3 계)와 Ag 전극과의 반응에 의한 Ag+과 Sn2+의 거동)

  • Hong, Gyeong-Jun;Park, Jun-Hyeon;Heo, Jeung-Su;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.347-352
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    • 2002
  • A transparent dielectric of the $PbO-B_2O_3-SiO_2-A1_2O_3$ system which was a low melting glass has been used for PDP (Plasma Display Panel), but it has a problem which is a reaction to be occurred between a transparent dielectric layer and electrodes (Ag, ITO) after firing. This research was conducted for ion migration of $Ag^+\$ and $Sn^ {2+}$ during firing three different frits of low melting glass. The result showed that yellowing phenomena occurred through a chemical reaction between $Ag^+\$and $Sn^ {2+}$ at 550~58$0^{\circ}C$ for 20~60 min. In addition, it was confirmed that the migration of $Sn^{2+}$ from ITO electrode made a strong effect on the yellowing phenomena.

Thermal Properties of Semiconducting Materials for Power Cable by Carbon Nanotube Content (CNT 함량에 따른 전력케이블용 반도전층 재료의 열적 특성)

  • Yang, Jong-Seok;Lee, Kyoung-Yong;Shin, Dong-Hoon;Park, Bae-Hee
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.12
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    • pp.570-575
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    • 2006
  • In this paper, we have investigated thermal properties by changing the content of carbon nanotube, which is component part of semiconductive shield in underground power transmission cable. Heat capacity (${\Delta}H$), glass transition temperature (Tg) and melting temperature (Tm) were measured with the samples of eight, through DSC (Differential Scanning Calorimetry), and the measurement ranges of temperature selected from $-100[^{\circ}C]\;to\;100[^{\circ}C]$ with heating temperature selected per $4[^{\circ}C/min]$ Also, high temperature, heat degradation initiation temperature, and heat weight loss were measured by TGA (Thermogravimetric Analysis) in the temperature from $0[^{\circ}C]\;to\;700[^{\circ}C]$ with rising temperature of $10[^{\circ}C/min]$. As a result, the Glass transition temperatures of the sample were showed near $-20[^{\circ}C]{\sim}25[^{\circ}C]$, and the heat capacity and melting temperature from the DSC was increased according to increasing the content of carbon nanotube, while, thermal diffusivity was increased according to increasing the content of carbon nanotube. Also, heat degradation initiation temperature from the TGA results was increasing according to increasing the content of carbon nanotube with CNT/EEA. Therefore, heat stabilities of EVA, which contained the we VA (vinyl acetate), showed the lowest.

Microstructure Evolution of Cu-based BMG Coating during APS Process and Phase Analysis by Nano-indentation Test (대기 플라즈마 용사공정을 이용한 Cu계 벌크 비정질 금속 코팅의 미세조직 분석과 나노 압입시험을 이용한 상 분석)

  • Kim, Jung-Hwan;Kang, Ki-Cheol;Yoon, Sang-Hoon;Na, Hyun-Taek;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.27 no.6
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    • pp.43-48
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    • 2009
  • In this study, Cu-based bulk metallic glass (BMG) coatings were deposited by atmospheric plasma spraying (APS) process with different process conditions (with- and without hydrogen gas). As adding the hydrogen gas, thermal energy in the plasma flame increased and induced difference in the melting state of the Cu-based BMG particles. The microstructure and mechanical properties of the coatings were analyzed using a scanning electron microscope (SEM) with an energy dispersive spectroscopy (EDS) and nano-indentation tester in the light of phase analysis. It was elucidated by the nano-indentation tests that un-melted region was a mainly amorphous phase which showed discrete plasticity observed as the flow serrations on the load.displacement (P - h) curves, and the curves of solidified region showed lower flow serrations as amorphous phase mingled with crystalline phase. Oxides produced during the spraying process had the highest hardness value among the phases and were well mixed with other phases resulted from the increase in melting degree.

The Study of Low Temperature Firing Glass-Ceramics Substrate in Lithium Fluorhectorite

  • Choi, J-H;Park, D-H;Kim, B-I;Kang, W-H
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 1999.11a
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    • pp.111-115
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    • 1999
  • The $Li_2O-MgO-MgF_2-SiO_2$glasses with addition of $B_2O_3$ were investigated in order to make glass-ceramics for low temperature firing substrate. Glasses were made by melting at $1450^{\circ}C$ in the electronic furnace and crystallized at $750^{\circ}C$. After the crystallization, crystal phases and microstructure were observed. The crystal phases were polycrystalline of lithium boron fluorphlogopite and lithium fluorhectorite. The crystal shape was changed to grande type from needle type with the increase in $B_2O_3$ contents. Average particle size of the glass-ceramics aftar water swelling was $3.77{\mu}{\textrm}{m}$. The optimum sintering temperature and sintering shrinkage of the substrate were $900^{\circ}C$ and 13.4vol%, respectively.

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A Study on the Pelletized Batch for $Na_2O-BaO-SiO_2$ System Glass ($Na_2O-BaO-SiO_2$ 계 유리조합물의 조립화에 관한 연구)

  • 박영원;강원호
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.147-152
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    • 1983
  • For $Na_2O-BaO-SiO_2$ system glass the pelletizing conditions of the disk type equipment were investigated. The effects of the pelletized batch on melting were also examined. Through the experiment the optimum conditions for pelletizing the batch were found as follows. Revolving speed of the pan 30rpm pan angle 40-35 degree Water content 12-13% Drying temperature $200^{\circ}C$ Preheating temperature $650^{\circ}C$ The molten glass of the pelletized batch was refined better than that of the loose batch.

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Thermal effects on the mechanical properties of cement mortars reinforced with aramid, glass, basalt and polypropylene fibers

  • Mazloom, Moosa;Mirzamohammadi, Sajjad
    • Advances in materials Research
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    • v.8 no.2
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    • pp.137-154
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    • 2019
  • In this study, thermal effects on the mechanical properties of cement mortars with some types of fibers is investigated. The replaced fibers were made of polypropylene (PP), aramid, glass and basalt. In other words, the main goal of this paper is to study the effects of different fibers on the mechanical properties of cement mortars after subjecting to normal and sub-elevated temperatures. The experimental tests used for investigating these effects were compressive, splitting tensile, and four-point bending tests at 20, 100 and $300^{\circ}C$, respectively. Moreover, the microstructures of the specimens in different temperatures were investigated using scanning electron microscope (SEM). Based on the experimental results, the negative effects of sub-elevated temperatures on four-point bending tests were much more than the others. Moreover, using the fibers with higher melting points could not improve the qualities of the samples in sub-elevated temperatures.

Effects of waste glass aggregate on thermal behavior of fly ash alkali activated mortar

  • Sasui, Sasui;Kim, Gyu Yong;Pyeon, Su Jeong;Eu, Ha Min;Lee, Yae Chan;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.115-116
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    • 2022
  • This study incorporates fine waste glass (GS) as a replacement for natural sand (NS) in fly ash (FA) based alkali activated mortar (AAm). AAms were heated at elevated temperature of 200℃, 400℃, 600℃, and 800℃ to explore the residual mass, compressive strength, thermal expansion and change in microstructure of matrix. Results showed greater resistance of AAms with increasing GS content to 50% at each temperature. Owing to the melting of GS at 800℃, the greater matrix bond was observed for AAm incorporating 75% and 100% GS as a result, the residual compressive strength was increased.

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