• 한국세라믹학회지
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• 제40권11호
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• pp.1132-1137
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• 2003

환경친화적인 유리비료로서의 응용을 위해 인산염계 유리의 용출특성에 대한 연구를 진행하였다. 0.1K₂O-0.1SiO₂-0.6P₂O/sub 5/계 유리를 기본조성으로 하고, CaO와 MgO의 함량변화를 준 다양한 유리조성에 대한 유리 형성 조건을 확인하고자 하였다. 또한 CaO 및 MgO의 함량변화에 따른 열적특성 및 용출 특성 변화를 확인하였다. MgO 함량의 증가에 따라 유리 전이온도 및 연화온도는 증가하였으며, CaO 및 MgO의 함량변화에 따라 용출특성에 큰 영향을 미치는 것을 확인하였다.

• Nuclear Engineering and Technology
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• 제54권3호
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• pp.997-1002
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• 2022

Oxyapatite[Ca₂Nd₈(SiO₄)₆O₂] glass-ceramics have been suggested as wasteforms for the immobilisation of rare-earth radioactive nuclides because of their high waste-loading capability and good chemical durability. In particular, a partitioning effect is predicted to contribute to an enhancement of corrosion resistance in glass-ceramics compared with that of conjugate glasses of the same composition. Because rare-earths are inherently insoluble nuclides, detection of changes in corrosion behavior between glass-ceramics and conjugate glasses under normal conditions is not easy. In this study, therefore, we revealed the partitioning effect by exposing glass-ceramics and glasses to solution of pH 2, 7 and 10 at 90 ℃ for 20 d. In addition, we proposed the corrosion mechanism for oxyapatite glass-ceramics under various corrosion conditions. Especially, the glassy phase dissolved first, followed by the oxyapatite phase during pH 7 corrosion.

• 반도체디스플레이기술학회지
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• 제22권1호
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• pp.64-71
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• 2023

In this study, we investigated the effects of BiAlSiO glass composition on its glass forming range, thermal properties, and plasma resistance. The results showed that increasing the Al2O3 content suppressed the tendency for crystallization and hindered glass formation beyond a certain threshold. Bi2O3 was found to increase the content of non-bridging oxygen, resulting in a decrease in glass transition temperature and an increase in thermal expansion coefficient. Furthermore, the etching rate was found to improve with increasing Al2O3 content but decrease with increasing SiO2 content. It was concluded that the boiling point of fluorinated compounds should be considered to 900℃. Therefore, this study is expected to contribute to the understanding of the properties of BiAlSiO glass and its application to low temperature melting PRG compositions.

• 헤리티지:역사와 과학
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• 제49권2호
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• pp.158-171
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• 2016

동남아시아 고대 항시국가 푸난의 외항인 베트남 옥 에오 유적에서 채집한 9점의 유리구슬에 대한 관찰 및 분석결과 형태는 환옥, 색상은 적갈색, 벽색, 녹색, 흑색 및 감청색, 화학조성은 소다유리군으로 고대 한반도에서 출토되는 유리구슬과 형태, 색상, 화학 조성이 유사함을 확인할 수 있었다. 발굴조사가 아니라 지표채집으로 확보한 9점의 유리구슬이므로 자료적인 한계가 있기는 하지만 옥 에오유적 채집 유리구슬이 기본적으로 한반도의 유리구슬과 유사한 제작기법과 화학조성을 보인다는 점을 확인한 점에 의미가 크다. "일본서기(日本書紀)" "흠명기(欽明紀)"에 543년 백제 성왕이 푸난의 물품과 노예 2명을 일본에 보낸 점을 고려할 때 백제와 푸난 사이에 직접, 혹은 간접적인 교섭이 이루어졌음이 확실하며 그 물품 중에 유리구슬이 포함되었을 가능성이 높아졌다.

• 한국주조공학회지
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• 제26권2호
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• pp.77-84
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• 2006

The effect of alloy composition on the glass forming ability (GFA) of the Ca-rich Ca-Mg-Zn alloys has been investigated in $Ca_{65}Mg_{5+x}Zn_{30-x}$ and $Ca_{55+x}Mg_{15}Zn_{30-x}$ (x=0, 5, 10, 15, 20) alloys. In a wide composition range of 15-25% Zn and 10-20% Mg bulk metallic glass (BMG) samples with the diameter larger than 6 mm are fabricated by conventional copper mold casting method in air atmosphere. Among the alloys investigated, the $Ca_{65}Mg_{15}Zn_{20}$ alloy exhibits the highest GFA enabling to form BMG sample with the diameter of at least 15 mm. The crystalline phase formed during solidification of $Ca_{65}Mg_{15}Zn_{20}$ ($D_{max}=15\;mm$) could be identified as a mixture of $Ca_3Zn$ and $CaMg_2$ cause by the redistribution of the constituent elements on long-range scale. The compressive fracture strength and fracture elongation of the $Ca_{65}Mg_{15}Zn_{20}$ BMG are 602 MPa and 2.08% respectively. The ${\sigma}$ parameter which has been recently proposed for evaluating GFA exhibits better correlation with GFA of Ca-Mg-Zn alloys than other parameters suggested so far such as ${\Delta}T_x$, $T_{rg}$, K, ${\gamma}$, and ${\Delta}T^*$ parameters.

• Current Optics and Photonics
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• 제8권3호
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• pp.230-238
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• 2024

The refractive index is a key material-design parameter, especially for high-refractive-index glasses, which are used for precision optics and devices. Increased demand for high-precision optical lenses produced by the glass-mold-press (GMP) process has spurred extensive studies of proper glass materials. B₂O₃, SiO₂, and multiple heavy-metal oxides such as Ta₂O₅, Nb₂O₅, La₂O₃, and Gd₂O₃ mostly compose the high-refractive-index glasses for GMP. However, due to many oxides including up to 10 components, it is hard to predict the refractivity solely from the composition of the glass. In this study, the refractive index of optical glasses based on the B₂O₃-La₂O₃-Ta₂O₅-SiO₂ system is predicted using machine learning (ML) and compared to experimental data. A dataset comprising up to 271 glasses with 10 components is collected and used for training. Various ML algorithms (linear-regression, Bayesian-ridge-regression, nearest-neighbor, and random-forest models) are employed to train the data. Along with composition, the polarizability and density of the glasses are also considered independent parameters to predict the refractive index. After obtaining the best-fitting model by R² value, the trained model is examined alongside the experimentally obtained refractive indices of B₂O₃-La₂O₃-Ta₂O₅-SiO₂ quaternary glasses.

• 한국주조공학회지
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• 제12권4호
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• pp.317-325
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• 1992

Diamond is the hardest material known to humans, also possesses the highest thermal conductivity and a very low thermal expansion coefficient. Therefore, these properties of diamond make them logical choices for many difficult grinding application. Bonding material is a very important factor to performance of a grinding wheel. Grinding glass constitutes one of the major application areas of diamond grinding wheels, and Cu-Sn tin bronze matrix is widely used as a metal bond of diamond wheel in grinding glass but these studies are rarely reported. The bronze test pieces excluding diamond are sintered by the method of hot sizing respectively at $600^{\circ}C$, $650^{\circ}C$, $700^{\circ}C$, with a composition(Cu-10wt%Sn) on ${\alpha}$ phase and two compositions(Cu-20wt%Sn and Cu-23wt%Sn) on ${\alpha}+{\beta}$ phase. The rupture strength of Cu-10wt%Sn is highest. The bronze bonded diamond wheels are manufactured by same conditions as the bronze test pieces. The results of grinding ratio of wheels are highest in case of Cu-10wt%Sn bonded wheel sintered at $650^{\circ}C$ and grinding power is highest in same composition sintered at $700^{\circ}C$.

• 임산에너지
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• 제18권2호
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• pp.55-61
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• 1999

본 실험에서는 화학조성이 다른 일련의 에틸렌/초산비닐 공중합체의 점탄성(또는 화학조성)이 목재/고분자/목재 샌드위치 복합체의 진동·충격음 흡수성능에 미치는 영향을 검토하였다. 그 결과는 다음과 같다. 복합체의 진동·충격음 흡수성능은 고분자의 분자 운동상태에 민감하다. 즉, 복합체의 진동·충격음 흡수성능 고분자가 시험온도에 있어서 유리전이 상태일 때(대략 초산 비닐 55∼75%) 가장 크며, 고분자가 고무상태(초산비닐 47∼20%) 또는 유리상태(초산비닐 100∼87%)일 때는 작다. 또한 유리전이상태의 고분자 적층재는 약 6∼12dB의 충격음 저감효과가 있었다.

• 한국세라믹학회지
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• 제30권6호
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• pp.441-448
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• 1993

The Ba1-xSrxTiO3 thin films deposited on ITO-coated glass substrate at 55$0^{\circ}C$ by rf magnetron sputtering method have individual preferential orientations as a function of composition (X=0, 0.25, 0.5, 0.75, 1) due to the stress relief interactions among the intrinsic compressive stress, thermal tensile stress adn extrinsic compressive stress (compressive stress in case of BaTiO3(Tc=12$0^{\circ}C$) and Ba0.75Sr0.25TiO3(Tc=57$^{\circ}C$)). This behavior also appears on the (BaSr)TiO3 thin films (X=0.5) deposited on ITO-coated glass substrate at deposition temperature between 35$0^{\circ}C$ and 55$0^{\circ}C$. The composition of Ba1-xSrxTiO3 thin films deposited on ITO-coated glass substrate at 55$0^{\circ}C$ is close to stoichiometry (1.009~1.089 in A/B ratio), but the compositional deviation from a stoichiometry is larger as SrTiO3 is added. The morphology of Ba1-xSrxTiO3 thin films is very similar for over all substrate temperatures, and the roughness due to the differences of cluster size is the smallest at X=0.25.

• 대한기계학회논문집A
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• 제29권6호
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• pp.876-888
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• 2005

Tensile properties and fracture toughness of monolithic aluminum, fiber reinforced plastics and glass fiber/aluminum hybrid laminates under tensile loads have been investigated using plain coupon and single-edge-notched specimens. Elastic modulus and ultimate tensile strength of GFMLs showed different characteristic behaviors according to the Al kind, fiber orientation and composition ratio. Fracture, toughness of A-GFML-UD which was determined by the evaluation of $K_{IC}$ and $G_{IC}$ based on critical load was similar to that of GFRP-UD and was much higher than monolithic Al. Therefore, A-GFML-UD presented superior fracture toughness as well as prominent damage tolerance in comparison to its constituent Al. By separating Al sheet from GFMLs after the test, optical microscope observation of fracture zone of GFRP layer in the vicinity of crack tip revealed that crack advance of GFMLs depended on the orientation of fiber layer as well as Al/fiber composition ratio.