• 제목/요약/키워드: Gibb's free energy

검색결과 21건 처리시간 0.028초

ELECTROMAGNETIC MEANING OF GIBB'S FREE ENERGY, ELECTOLYSIS, CELL REACTION AND BROWN GAS

  • Oh, Hung-Kuk
    • 한국감성과학회:학술대회논문집
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    • 한국감성과학회 2001년도 춘계학술대회 논문집
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    • pp.10-14
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    • 2001
  • Physical chemistry states that electric potential is due to Gibb's free energy from chemical reaction of the electric cell. However we have not the electromagnetic meaning of Gibb's free energy. the free energy is discovered to be a kinetic energy part of the rotating electromagnetic wave ($\pi$-ray), which is different from conventional Coulomb attraction energy and can anticipate that there is a current difference between before and after the electric load. This paper manipulates the relationship between $\pi$-rays (Gibb's free energy) and electrolysis, cell reaction and brown gas reaction.

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기존의 적산전력계측 개념의 새로운 평가 (A CRITICAL NOTE ON THE CONCEPT OF THE CONVENTIONAL INTEGRAL ELECTRIC POWER METERING)

  • 오흥국
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.171-173
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    • 2001
  • Conventional potential concept does not allow different currents before and after the electric load. Experimental examples in case of bioloads show a lot of different currents before and after the bioload, which means that the true potential concept is not the conventional concept from Coulomb attraction energy but the new concept from Gibb's free energy. Gibb's free energy is a kind of potential heat energies and also they are rotating electromagnetic waves. We might think that electric current is not a flow of electrons but a flow of rotating electromagnetic waves, which induces electrons' vibrations. A new measuring method for integral electrical power is suggested for the new Gibb's free energy concept.

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ELEMENTAL TRANSMUTATION BY ENER(OR BROWN) GAS TREATMENT

  • Guk, O-Heung
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2001년도 추계학술대회 논문집
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    • pp.219-220
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    • 2001
  • Each atom is enclosed with $\pi$-rays, which were produced by the alternating magnetic field that is made by the electron's going and returning between atoms. If some resonant $\pi$-rays are supplied to and suppress the fencing $\pi$-rays, the bonding will be broken because the equilibrium distance for the electron moving between atoms can not be maintained. Electrolysis process supplies $\pi$-rays of Gibb's free energy to the reactant atoms and then the component atoms are divided into and are induced to both electric poles. (omitted)

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RESOLUTION OF AIR POLLUTIONAL GASES BY ENER(or BROWN) GAS

  • Guk, O-Heung
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2001년도 추계학술대회 논문집
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    • pp.217-218
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    • 2001
  • Each atom is enclosed with $\pi$-rays, which were produced by the alternating magnetic field that is made by the electron's going and returning between atoms. If some resonant $\pi$-rays are supplied to and suppress the fencing $\pi$-rays, the bonding will be broken because the equilibrium distance for the electron moving between atoms can not be maintained. Electrolysis process supplies $\pi$-rays of Gibb's free energy to the reactant atoms and then the component atoms are divided into and are induced to both electric poles. (omitted)

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비틀림 변환기용 압전 원판의 진동 해석 (Vibration Analysis of a Piezoelectric Disc for a Torsional Transducer)

  • 이정현;김진오
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2005년도 추계학술대회논문집
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    • pp.911-914
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    • 2005
  • The vibrational characteristics of the piezoelectric disc for a torsional vibration transducer is theoretically studied in this paper. The characteristic equation of the piezoelectric annular disc has been derived from Newton's End law and Gibb's free energy equations. With an anisotropic material property of the disc, the characteristic equation has yielded resonance frequencies. Numerically-calculated results were compared with the values obtained by finite element analysis and experiments

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지구 핵에 수산화물의 존재에 관한 연구 (A Study of the Oxyhydroxide Presence at the Earth Core)

  • 김영호;도재기;황길찬
    • 한국광물학회지
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    • 제21권4호
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    • pp.415-423
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    • 2008
  • 외핵은 대부분 철로 이루어져 있으나 외핵의 밀도를 10% 정도 줄일 수 있는 희석 원소가 존재해야 한다. 외핵에서 존재할 가능성이 있는 가벼운 희석원소가 수소와 산소라는 가정 하에, 고압 하에서 수소의 열역학적 안정성을 적철석($Fe_2O_3$) + 수소($H_2$) $\to$ 괴타이트(FeOOH) + 철(Fe) 반응관계식을 이용하여 계산하였다. 열역학적 해석 결과, 상온 및 상압에서 이러한 화학반응의 깁스자유에너지는 12.62 kJ/mol로 계산되었다. 상온에서 압력이 증가함에 따라 깁스자유에너지 값은 감소하여 0.068 GPa에서 '0 kJ/mol'을 나타내었다. 압력이 증가함에 따라 깁스자유에너지 값은 일정한 비율로 점차적으로 감소하여 200 GPa에서는 -208.26 kJ/mol을 나타내었다. 이러한 열역학적 분석 결과로 볼 때 고압 하에서 수소와 철산화물이 반응하여 철원소와 철 수산화물을 생성하는 환원반응이 선호되며, 수소와 산소가 철수산화물의 형태로 원시지구 핵 내에 존재하게 되었을 가능성을 배제할 수 없다.

Thermodynamic Investigation of the Formation of Complexes between Norfloxacin and Various Mononucleotides

  • Kwon, Yong-Jun;Lee, Hyun-Mee;Han, Sung-Wook;Lee, Dong-Jin;Cho, Tae-Sub
    • Bulletin of the Korean Chemical Society
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    • 제32권9호
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    • pp.3233-3238
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    • 2011
  • The fluorescence of norfloxacin was quenched by various nucleotides. The ratio of the fluorescence intensities in the absence and presence of nucleotide was linearly dependent on nucleotide concentration, suggesting that quenching occurred through the formation of nonfluorescent norfloxacin-nucleotide complexes. The gradient of the linear relationship represented the equilibrium constant of complex formation; it decreased with increasing temperature. The slopes of van't Hoff plots constructed from the temperature-dependent equilibrium constants were positive in all cases, indicating that complex formation was energetically favorable - i.e., exothermic, with negative Gibb's free energy. The equilibrium constant increased when triphosphate was used instead of monophosphate. It also increased when the oxygen at the $C'_2$ position of the nucleotide was removed. Both enhancements were due to entropic effects: entropy decreased when complexes with AMP or GMP formed, while it increased when norfloxacin complexed with ATP, GTP, dAMP and dGMP.

제철소내 발전소에서의 대기오염 물질 배출 패턴 모델링 (Development of predictive model for pollutants emission from the power plant in a steel plant)

  • 김민석;이창형;양대륙;장근수
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1993년도 한국자동제어학술회의논문집(국내학술편); Seoul National University, Seoul; 20-22 Oct. 1993
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    • pp.601-606
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    • 1993
  • From the power plants in a steel plant, environment pollutants such as SOx, NOx, CO are emitted by the combustion reaction between the fuels those are by-product gases and oil. To reduce the amounts of the pollutants, it must be important that build the predictive models for the emission of the pollutants. In this paper, the model that predict the amount of future fuel consumption and the model that predict the amount of generated pollutants for the used fuel amounts is developed by using Gibb's free energy minimization method with the temperature correction techniques and neural network back propagation method. For some data set, the calculation results from this models are compared with the real emission amounts of SOx, NOx and result of the calculation by the ASPEN plus which is a commercial software. The result from this model is better than the result by ASPEN plus for this problem.

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Bioproduct 분리를 위한 결정화 연구 동향 (Technological Trend of Crystallization Research for Bioproduct Separation)

  • 김우식;이은규
    • KSBB Journal
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    • 제20권3호
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    • pp.164-176
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    • 2005
  • In bioengineering field, current academic trends and informations on crystallization technology for bioproduct separation were summarized. It is essential for utilizing the crystallization technology to understand the fundamental phenomena of crystallization of crystal nucleation, crystal growth, crystal agglomeration and population balance for the design of crystallizers. In general, the crystal nucleation that the crystalline solids occur from the solution is analyzed by Gibb's free energy change in the aspect of thermodynamics and in the present paper the crystal nucleation models based on the above thermodynamics are summarized by their key characteristics. The crystal growth and agglomeration, which have been studied over 50 years and are essential phenomena for separation technology, are reviewed from their basic concept to most leading edge trend of researches. In the material and population balances for the designs of crystallization separation process, the analysis of crystallizers is summarized. Thereon, the present review paper will academically contribute the understanding the crystallization phenomena and the design of the crystallization separation process.

燃燒氣體의 熱力學的 平衡組成計算에 관한 硏究 (Calculation of thermodynamical equilibrium composition of combustion gases)

  • 허병기;이청종
    • 대한기계학회논문집
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    • 제11권1호
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    • pp.177-188
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    • 1987
  • 본 논문에서는 연소기체의 열력학적 평형조성 계산을 위한 수식을 Gibbs의 자 유에너지 최소화법에 의하여 유도하고 이를 컴퓨터 프로그램화하여, Table 1의 특성을 지닌 연료에 대하여 ⅰ) 연소공기량에 따른 평형조성 및 단열불꽃온도, ⅱ) 연소온도 변화에 따른 평형조성의 변화를 계산함으로써 연소기체의 생성기구를 열력학적으로 해 석하였다.