• 한국군사과학기술학회지
• /
• 제18권2호
• /
• pp.160-166
• /
• 2015

On board hydrogen generation from the hydrolysis of an active metal is very attractive due to its economical, convenient, and safe reasons. A Mg-graphite pellet has been designed as a hydrogen source for portable fuel cell. Mg (1 g) + 0.10 g graphite pellet showed an excellent hydrogen generation rate that is equivalent to 15.8 ml/g.min from its hydrolysis. The hydrogen generation rate of the pellet is significantly increased due to the galvanic corrosion by galvanic cells between Mg anode and graphite cathode in a 10.wt. % NaCl solution at a room temperature.

• 한국환경보건학회지
• /
• 제34권2호
• /
• pp.175-182
• /
• 2008

This study investigates the optimal conditions for electrogenerated hydrogen peroxide production and the application of the electro-Fenton process using DSA electrodes. The influences of parameters for the hydrogen peroxide generation such as electrode materials, electrolyte concentration, current, pH, air flow rate and electrode distance were investigated using a laboratory scale batch reactor. The relative performance for hydrogen peroxide generation of each of the six electrodes is : Ru-Sn-Ti > Ru-Sn-Sb > Ru > Ir > Pt > Sn-Sb. Optimum NaCl dosage, current and air flow rate were 2.0 g/l, 12.5 A and 2 l/min, respectively. When the pH is low, hydrogen peroxide concentration was high. Electrode distance dos not effect to a hydrogen peroxide generation. A complete color removal was obtained for RhB (200 mg/l) at the 8 min mark of the electro-Fenton process under optimum operation conditions of $Fe^{2+}$ 0.105 g/l and 5.0 A. The electro-Fenton process increased initial reaction and decreased final reaction time. However the effect was not high.

• 한국기계가공학회지
• /
• 제2권3호
• /
• pp.26-33
• /
• 2003

The term 'High Speed Machining' has been used for many years to describe end milling with small diameter tools at high rotational speeds, typically 10,000-100,000rpm. The process was applied in the aerospace industry for the machining of light alloys, notably aluminum. In recent year, however, the mold and die industry has begun to use the technology for the production of components, including those manufactured from hardened tool steels. With increasing cutting speed used in modern machining operation, the thermal aspects of cutting become more and mole Important. It not only directly influences in rate of tool weal, but also affects machining precision recognized as thermal expansion and the roughness of the surface finish. Hence, one needs to accurately evaluate the rate of cutting heat generation and temperature distributions on the machining surface. To overcome the heat generation, we used to cutting fluid. Cutting fluid plays a roles in metal cutting process. Mechanically coupled effectiveness of cutting fluids affect to friction coefficient at tool-workpiece interface and cutting temperature and chip control, surface finish, tool wear and form accuracy. Through this study, we examined the behavior of heat generation in high-speed machining and the cooling performance of various cooling methods.

• 한국환경보건학회지
• /
• 제34권6호
• /
• pp.414-422
• /
• 2008

Methane is a potent greenhouse gas and methane emissions from landfill sites have been linked to global warming. In this study, LandGEM (Landfill Gas Emission Model) was applied to predict landfill gas quantity over time, and then this result was compared with the data surveyed on the site, Cheongju Megalo Landfill. LandGEM allows the input of site-specific values for methane generation rate (k) and potential methane generation capacity $L_o$, but in this study, k value of 0.04/yr and $L_o$ value of $100\;m^3$/ton were considered to be most appropriate for reflecting non-arid temperate region conventional landfilling like Cheongju Megalo Landfill. Relatively high discrepancies between the surveyed data and the predicted data about landfill gas seems to be derived from insufficient compaction of daily soil-cover, inefficient recovery of landfill gas and banning of direct landfilling of food waste in 2005. This study can be used for dissemination of information and increasing awareness about the benefits of recovering and utilizing LFG (landfill gas) and mitigating greenhouse gas emissions.

• 한국수소및신에너지학회논문집
• /
• 제16권4호
• /
• pp.379-385
• /
• 2005

Effects of Co and Co-P catalysts on the hydrolysis of alkaline $NaBH_4$ solution were investigated. Co and Co-P catalysts were prepared on Cu substrate by electroplating. Hydrogen generation rate of Co-P catalyst was much faster than that of Co catalyst, demonstrating that Co-P had higher intrinsic catalytic activity for the hydrolysis of $NaBH_4$ than Co. Hydrogen generation properties of Co-P catalysts largely depended on cathodic current density and electroplating time because they influenced on the P concentration of the Co-P catalysts. Maximum hydrogen generation rate of Co-P catalyst was 1066 ml/min.g-catalyst in 1 wt.% NaOH + 10 wt.% $NaBH_4$ solution at $20^{\circ}C$, which was obtained at cathodic current density of $0.01\;A/cm^2$ for 130 s.

• 소성∙가공
• /
• 제32권4호
• /
• pp.215-220
• /
• 2023

In this study, the correction process of stress-strain curves obtained from hot compression test is introduced since the barreling induced by friction and adiabatic heat generation induced by plastic work occur under high strain rate. A shear friction factor was quantitatively estimated by measuring the dimension of barreling and temperature rise due to adiabatic heat generation was directly measured during compression test. Thereafter, the stress-strain curves were re-evaluated by introducing several equations to correct the effects of the friction and temperature rise. It was found that adiabatic factor at strain rate of 10/s is in the range of about 0.5 to 0.75 for Nimonic 80A and decreases as the assigned temperature increases.

• Journal of Electrochemical Science and Technology
• /
• 제8권4호
• /
• pp.344-355
• /
• 2017

In this study, a numerical approach is adopted to investigate the effectiveness factors for distributed electrochemical reactions in thin active reaction layers of solid oxide fuel cells (SOFCs), taking into account the Butler-Volmer reaction kinetics. The mathematical equations for the electrochemical reaction and charge conduction process were formulated by assuming that the active reaction layer has a small thickness, homogeneous microstructure, and high effective electronic conductivity. The effectiveness factor is defined as the ratio of the actual reaction rate (or equivalently, current generation rate) in the active reaction layer to the nominal reaction rate. From extensive numerical calculations, the effectiveness factors were obtained for various charge transfer coefficients of 0.3-0.8. These effectiveness data were then fitted to simple correlation equations, and the resulting correlation coefficients are presented along with estimated magnitude of error.

• Nuclear Engineering and Technology
• /
• 제29권2호
• /
• pp.99-109
• /
• 1997

A dynamic model for hydrogen generation by Fuel-Coolant Interactions(FCI) is developed with separate models for each FCI stage, coarse mixing and stratification. The model includes the physical concept of FCI, semi-empirical heat and mass transfer correlation and the concentration diffusion equation with the general non-zero boundary condition. The calculated amount of hydrogen, which is mainly generated in stratification, is compared with the FITS experiments. The model developed in this study shows a good agreement within a range of 10 % fuel oxidation rate and predicts the controlled mechanism of the chemical reaction very well. And this model predicts more accurately than the previous works. It is shown from the sensitivity study that the higher initial temperature of fuel particle is, the larger the reaction rate is. Up to 2700 K of temperature of the particle, the reaction rate increases rapid, which can lead to metal ignition.

• Journal of Mechanical Science and Technology
• /
• 제18권5호
• /
• pp.753-761
• /
• 2004

In this paper, an efficient method for generating 5-axis cutting data for a turbine blade is presented. The interference elimination of 5-axis cutting currently is very complicated, and it takes up a lot of time. The proposed method can generate an interference-free tool path, within an allowance range. Generating the cutting data just point to the cutting process and using it to obtain NC data by calculating the feed rate, allows us to maintain the proper feed rate of the 5-axis machine. This paper includes the algorithms for: (1) CL data generation by detecting an interference-free heel angle, (2) finding the optimal tool path interval considering the cusp-height, (3) finding the adaptive feed rate values for each cutter path, and (4) the inverse kinematics depending on the structure of the 5-axis machine, for generating the NC data.

• 한국대기환경학회지
• /
• 제7권1호
• /
• pp.31-40
• /
• 1991

This study shows the correlation between $NO_x$ emission in the exhaust gas and various operation factors of dual fuel engine for Co-generation system. General tendency was shown that the thermal efficiency was lowered by the change of operation factors. However these were not confirmed on this experiment. Increasing T4 temperature (exhaust gas temperature at turbo-charger inlet) reduces $NO_x$ emission rate. The higher T4 temperature requires lower excess air as the excess air ratio is controlled by T4 temperature on gas mode operation. Another tendency was that $NO_x$ emission rate is reduced in case of increasing boost air temperature, quantity of pilot oil or bypassing flue gas through the exhaust gas boiler. The diameter of the fuel injection nozzle was changed smaller than design value and the injection timing was readjusted. Thus $NO_x$ emission rate could be reduced as retarding injection timing and changing hole diameter of fuel injection nozzle, however maxium engine out-put was decreased by changing fuel nozzle on the diesel mode operation.