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A Study on the Prediction of the Octane Number of Gasolines from the Carbon Type Structural Compositions by 13C-Nuclear Magnetic Resonance Spectroscopy (13C-NMR에 의해 결정된 탄소 유형별 구조적 조성으로부터 가솔린 옥탄가의 예측에 관한 연구)

  • Choi, Ju-Hwan;Chun, Yong-Jin;Choi, Ung-Su;Choi, Young-Sang;Kwon, Oh-Kwan
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.753-759
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    • 1993
  • The research and motor octane numbers (RON & MON, respectively) of a gasoline are dynamic measures of its quality of performance as a fuel. ASTM standard engine test methods (RON:ASTM D-2699, MON:ASTM D-2700) have been used for determining the octane numbers (RON,MON)of gasolines. But these methods have been widely criticized because their repeatability and reproducibility of the test method are very poor. In addition to these objections, the cost and operation time involved in measuring by the standard method led to searches for "non -engine" methods (Gas Chromatographic method, Nuclear Magnetic Resonance Spectroscopic method). In this study, we determined the carbon type structural compositions of the gasolines by $^{13}C-NMR$ spectroscopy and predicted the octane number (RON & MON) with good accuracy. we presented an assessment of the effects of molecular structural composition on octane numbers.

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A Study on Transport Characteristics of MTBE(Methyl Tertiary Butyl Ether) in Soil (MTBE(Methyl Tertiary Butyl Ether)의 토양내 이동특성에 관한 연구)

  • Cho, Ki-Chul;Park, Chang-Woong;Choi, Won-Joon;Kang, Seung-Yub;Hwang, Jong-Hyun;Kim, Youn-Soo;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.2
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    • pp.190-198
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    • 2008
  • In this stduy, the column experiments were carried out assuming the soil was contaminated by leakage of gasoline containing MTBE from USTs and pipes around gas stations. Then, characteristics of MTBE transport in the soil were investigated using CXTFIT program. The column experiments with different soil properties, moisture content, organic matter content and flow rate were carried out. Some parameters(D, R, $\beta$, $\omega$) used in two-site non-equilibrium adsorption model were obtained from measuring the MTBE concentration in injection-liquid and in effluent and using CXTFIT program. In addition, The characteristics of MTBE transport in the soil was found using BTCs and obtained parameters. Consequently, the advection decreased as the increase of the content of fine particle and organic, while the MTBE transport by advection was enhanced as increasing flow rate and moisture content.

A Experimental Study on the Effects of the Impingement-wall on the Spray and Combustion Characteristics of Direct-Injection LPG (충돌벽면이 직분식 LPG의 분무 및 연소 특성에 미치는 영향에 관한 실험 연구)

  • Hwang, Seong-Ill;Chung, Sung-Sik;Yeom, Jeong-Kuk
    • Journal of Power System Engineering
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    • v.19 no.2
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    • pp.49-56
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    • 2015
  • As an alternative fuel that can be used in SI engine, LPG is one of clean fuels with larger H/C ratio compared to gasoline, low $CO_2$ emission, and small amount of pollutants such as sulfur compounds. When LPG is used in spark ignition engine, volumetric efficiency of the engine can be improved and pumping loss can be reduced by performing direct injection into the combustion chamber instead of port fuel injection. LPG-DI engine allows for lean combustion and stratified combustion under low load. In case of stratified combustion, air fuel ratio can be greatly increased compared to theoretic mixture ratio combustion. Improved thermal efficiency of the engine and reduced pumping loss can be expected from stratified combustion. Accordingly in this study, an experimental apparatus for visualization was designed and manufactured to study the combustion process of LPG after injection and ignition, intended to examine ignition probability and combustion characteristics of spark ignition direct injection(SIDI) LPG fuel. Ambient pressure, ambient temperature and fuel injection pressure were found as important variables that affect ignition probability and flame propagation characteristics of LPG-air mixture. Also, it was verified that the injected LPG fuel can be directly ignited by spark plug under appropriate ambient conditions.

A Study on the Structural Reform of Urban Transit Vehicle Considering Elevation of Fire Safety (화재안전성을 위한 도시철도 차량의 구조개선)

  • Lee, Keun-Oh;Kim, Kyu-Joong
    • Journal of the Korean Society of Safety
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    • v.21 no.5 s.77
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    • pp.22-27
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    • 2006
  • Even though the interior of urban transit vehicle has been changed as a preventing measure against fire to make it inflammable, there remains a possibility of fire breaking out in case of gasoline etc being brought in the subway. However, there is also the possibility that in case if fire toxic gas is generated and hot air spreads in carriage it will prove very dangerous for people sitting inside. This is a comparative study where we compare simulation results with model examining the time and direction the fire spreads when it breaks out. Also there is vertical distribution of temperature in carriage where the fire spreads out. This study is about demonstrating how to establish smokeless system in urban vehicle, about its necessity, and about vehicle system restructuring. This study also makes an effort to find more advanced method for efficient fire safety in trains. In existing vehicles, in case of fire, the smoke can't go out when doors are closed and hence it spreads in whole train. Even though the method of using ventilation or exhaust established inside the carriage to throw smoke out is much better than the way of opening end doors in each carriage, this study is trying to do research on second way. Through simulation we see that in second case, even though not as good as the first one, smoke can exit through gates. Even though the first method is better, the second can also be uses to let fire out. We can know that in the first case as the smoke can exit out faster, it provides more safety for people. So this system provides better fire safety condition.

Performance Design of Boiler for Waste Heat Recovery of Engine Coolant by Rankine Steam Cycle (엔진 냉각수 폐열 회수를 위한 랭킨 스팀 사이클용 보일러의 성능 설계)

  • Heo, Hyung-Seok;Bae, Suk-Jung;Hwang, Jae-Soon;Lee, Heon-Kyun;Lee, Dong-Hyuk;Park, Jeong-Sang;Lee, Hong-Yeol
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.5
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    • pp.58-66
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    • 2011
  • A 2-loop waste heat recovery system with Rankine steam cycles for the improvement of fuel efficiency of gasoline vehicles has been investigated. A high temperature loop(HT loop) is a system to recover the waste heat from the exhaust gas, a low temperature loop(LT loop) is for heat recovery from the engine coolant cold relatively. This paper has dealt with a layout of a LT loop system, the review of the working fluids, and the design of the cycle. The design point and the target heat recovery of the LT boiler, a core part of a LT loop, has been presented and analytically investigated. Considering the characteristics of the cycle, the basic concept of the LT boiler has been determined as a shell-and tube type counterflow heat exchanger, the performance characteristics for various design parameters were investigated.

A Study on the Characteristics of Vehicle Fuel Economy by Increasing Mileage (주행거리 증가에 따른 자동차 연비 특성 연구)

  • LIM, JAE-HYUK;KIM, KI-HO;LEE, MIN-HO;PARK, JIN-SUNG;LEE, JUNG-MIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.3
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    • pp.299-305
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    • 2018
  • The domestic label fuel economy measurement method is the same as the North American measurement method. The results of two test modes (city [FTP-75 mode], highway [HWFET mode]) are calculated to be equivalent to the final fuel economy value calculated as the result of five test modes reflecting various environmental conditions and driving patterns 5-cycle correction formula is used. In this study, we tried to find out that the difference between the domestic label fuel economy of the vehicle and the real road fuel economy felt by the driver compared to the new vehicle condition as the mileage increases. Using domestic label fuel economy measurement method, Four gasoline vehicles and four diesel vehicles were tested for the fuel economy of a new vehicle with a mileage of 150 km or less and domestic fuel economy test $6,500{\pm}1,000km$ durability condition and 15,000 km durability. It is confirmed that the certain portion (6,500 km endurance vehicle) The increase in mileage did not affect the fuel economy or the emission gas significantly, indicating that vehicle durability was limited.

Measurement of VOCs Concentrations at Jeonju Industrial Area and Emission Characteristics (전주공단지역의 주요VOCs 배출농도 측정 및 배출원별 특성 분석)

  • Kim, Deug-Soo;Yang, Go-Soo;Park, Bi-O
    • Journal of Environmental Science International
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    • v.16 no.3
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    • pp.299-310
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    • 2007
  • It will be necessary to make proper management plans to preserve the air quality in good level for the public. In order to make these plans, source information and detail emission inventories of the city and near industrial areas should be given. However, lack of the source measurements data makes us more difficult to complete the source inventory. VOC source Inventory could be utilized for the feasibility study to estimate the contribution of VOC sources presenting to the receptor such as residential area. It may give policy maker an idea how to control the air quality, and improve their social environment in the area. This study shows data that measured VOCs concentrations from the local industrial areas in Jeonju during from May 2005 to January 2006. The samples were collected from the near sources in 7 major factories in the industrial park as well as 5 general sources in near city Jeonju area to elucidate the abundances of speciated VOCs and their spacial and temporal distributions depending on source bases. Industrial sources are as follows; chemical, food, paper, wood, metal, non-metal (glass), and painting (coating) industries. The 5 general sources are sampled from tunnel, gasoline gas station, dry cleaning shop, printing (copy) shop, and road pavement working place in urban area. To understand the near source effect at receptor, samples from the 2 receptor sites (one is at center of the industrial complex and the other site is at distance residential area downwind from the center) were collected and analyzed for the comparison to source concentration. The mass contributions of the speciated VOC to total mass of VOCs measured from the different sources and ambient (2 receptors) were presented and discussed.

Biomass Energy in the USA: A Literature Review (III) - Bioethanol production from Biomass and Feedstock Supply - (미국 에너지 시장에 공급되는 바이오에너지에 관한 연구 (III) - 바이오매스를 이용한 에탄올 생산과 원료공급에 대하여 -)

  • Kim, Yeong-Suk;Gorman, Thomas
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.1
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    • pp.1-10
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    • 2007
  • This study was reviewed on the bioethanol production from biomass resources and feedstock supply in America. U.S. Department of Energy (USDE) and the u.s. Department of Agriculture USDA) are both strongly committed to expand the role of biomass as an energy source. They support biomass fuels and products as a way to reduce the need for oil and gas imports, to strengthen the nation's energy security and environmental quality. And it was envisioned a 20 percent replacement of the current U.S.transportation fuel consumption in 2030. Also it was reviewed policies to encourage the expanding of Bio-based fuel use to replace gasoline, such as Clean Air Act, Federal Clean Fuel Program and American Jobs Creation Act. In feedstock supply it was assumed forest biomass will be supplied in 368 million dry tons yearly and the agriculture derived biomass adopted by new technologies and land use change will be supplied in 998 million dry tons, including highly 818 million dry tons of lignocellulosic biomass such as perenial crops (hybrid trees, grasses) corn stover, other crop residues. This amount is 5 times to the amount from based current agricultural technology and crop land.

Measurements of Flame Temperature and Radiation Heat Flux from Pool Fire with Petroleum Diesel Fuel (디젤연료의 액면화재로부터 화염온도와 복사열 측정)

  • Lim, Woo-Sub;Choi, Jae-Wook
    • Fire Science and Engineering
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    • v.21 no.3
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    • pp.78-83
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    • 2007
  • Diesel, a kind of petroleum, which is used in vehicles, vessels, boilers etc causes great damage when a fire happens, because it has higher caloric value than gasoline or kerosene has at burning. Therefore, pool fire experiment was carried using diesel which is sold on the gas station and radiation heat flux that occurs from flame and inner temperature of flame at burning was estimated. The maximum instantaneous flame temperature of diesel was more than $900^{\circ}C$, and the average of maximum flame temperature was $800^{\circ}C$ which occurred at 0.5 H/D distance from the surface of inflammable liquid, the distance has more long that has the lower the temperature of flame. In case of radiation heat flux, it grew to vary according to the size and amount of sample. When the size of a container for experiment was 0.5 m and sample layer was 13 mm and 20 mm, the radiant heat was 92.29 kW and 117.43 kW each. When the container was 1.0 m, it was 364.35 kW and 405.88 kW each.

Study on Emission Characteristics Depending on Mixing Fuels of Bio-Alcohol (바이오알코올 혼합연료에 따른 배출 특성 연구)

  • KIM, SHIN;KIM, JAE-KON;LEE, MIN-HO;HWANG, IN-HA;LEE, JUNG-MIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.654-660
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    • 2018
  • The dependence on global fossil fuels has been gradually reducing all over the world. Some countries which recognized the important of environmental values were joining to carry out international GHG goals. Our country has also participated with high targets (37% reduction compared to BAU 2030 years). So we need to supply materials of lower GHG value such as a bio-diesel. Bio-alcohol is one of the similar bio-fuels that can be reducing GHG. A lot of countries had tried to commercialize through various R&D for bio-alcohol. In this study, we analyzed the fuel characteristics of bio-alcohol fuel produced by domestic technology. And we evaluated a possibility to use as vehicle fuel through mixing of bio-alcohol and gasoline. The mixed fuels were satisfied with 2.3 wt% of oxygen content that is standard of the petroleum and petroleum alternative fuel business Act. We tried to evaluate a emission characteristic of vehicle by mixed fuel. In accordance with the results we tried to find a correlation between fuel and emission.