• Title/Summary/Keyword: Gases Concentrations

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Etch Characteristics of CoTb and CoZrNb Thin Films by High Density Plasma Etching (고밀도 플라즈마 식각에 의한 CoTb과 CoZrNb 박막의 식각 특성)

  • Shin, Byul;Park, Ik Hyun;Chung, Chee Won
    • Korean Chemical Engineering Research
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    • v.43 no.4
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    • pp.531-536
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    • 2005
  • Inductively coupled plasma reactive ion etching of CoTb and CoZrNb magnetic materials with the photoresist mask was performed using $Cl_2/Ar$ and $C_2F_6/Ar$ gas mixtures and characterized in terms of etch rate and etch profile. As the concentrations of $Cl_2$ and $C_2F_6$ gases increased, the etch rates of magnetic films decreased and the etch slopes became slanted. The $Cl_2/Ar$ gas was more effective in obtaining fast etch rate and steep sidewall slope than the $C_2F_6/Ar$ gas. As the coil rf power and dc bias increased, fast etch rate and steep etch slope were obtained but the redeposition on the sidewall was observed. This is due to the increase of ion and radical densities in plasma with increasing the coil rf power and the increase of incident ion energy to the substrate with increasing the dc bias voltage. By applying high density reactive ion etching to magnetic tunnel junction stack containing various magnetic films and metal oxide, steep etch slope and clean etch profile without redeposition were obtained.

Variations of N2O by no tillage and conventional-tillage practices under the different kinds of fertilizer applications on the cultivation of soybean in Korea

  • Yoo, Jin;Oh, Eun-Ji;Kim, Suk-Jin;Woo, Sun-Hee;Chung, Keun-Yook
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.314-314
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    • 2017
  • Anthropogenic activities have increased the concentrations of greenhouse gases, such as $CO_2$, $CH_4$, $N_2O$, HFCs, $SF_6$, and PFCs, in the atmosphere. Among others, $N_2O$ is well known as an important greenhouse gas accounting for 7.9% of the total greenhouse effect and the effect of its emission is 310 times greater than that of $CO_2$. Agricultural $N_2O$ emissions are now thought to contribute to about 60% of the global anthropogenic $N_2O$ emission, which have been increased primarily due to fertilizer N consumption and manure management. Therefore, the reduction of $N_2O$ emissions in agriculture is being required. This study was conducted to determine the variation of $N_2O$ emissions by no-tillage (NT) and conventional tillage (CT) practices in the cultivation of soybean from the sandy loam soils under the different kinds of fertilizer treatments June through September 2016 in Cheong-ju, Republic of Korea. An experimental plot, located in the temperate climate zone, was composed of two main plots that were NT and CT, and were divided into four plots, respectively, in accordance with types of fertilizers (chemical fertilizer, liquid pig manure, hairy vetch and non-fertilizer). Among all the treatments, $N_2O$ emission was the highest in August and the lowest in June. When $N_2O$ emissions were evaluated during the growing season (June to September) in all fertilizer treatments, NT with hairy vetch treatment emitted the highest $N_2O$ emission in August, whereas, $N_2O$ emissions was the lowest in NT with non-fertilizer treatment in June, respectively (p = 0.05). Based on the cumulative amount of $N_2O$ emissions during the growing season of soybean, NT had lower $N_2O$ emission than CT by 0.01 - 0.02 kg $N_2O$, although NT had higher $N_2O$ emission than CT by 0.03 kg $N_2O$ in only the chemical fertilizer treatments. As a result, it seems that the applications of liquid pig manure and hairy vetch rather than chemical fertilizer could decrease the $N_2O$ emission in NT, compared to CT.

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Spatial Distribution of Air Pollution Level inside Roadway Tunnels in Urban Area (도시 자동차도로 터널 내부의 대기오염도 공간분포 특징)

  • Park, Bo-Eun;Lee, Seung-Bok;Lee, Dong-Hun;Lee, Seung Jae;Woo, Dae-Kwang;Choi, Jae-Hyun;Jin, Hyoun-Cher;Bae, Gwi-Nam;Yun, Seong-Taek
    • Particle and aerosol research
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    • v.8 no.1
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    • pp.17-28
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    • 2012
  • Air pollution levels of gases and aerosol particles inside the Jeongneung and Hongjimun tunnels of the Naebu express way in Seoul were investigated through on-road measurement using a mobile emission laboratory (MEL) on February 8, 2011. The concentrations of $NO_x$, $CO_2$, number concentration of particles ranging 21-560 nm, and surface area of particles deposited on a human lung almost linearly increased with increasing distance from the tunnel entrance, and decreased rapidly before the tunnel exit. This trend was observed regardless of tunnel length and driving directions, which thought to be caused by semi-transverse ventilation facilities of the tunnels. The concentration increments per 1-m distance for $NO_x$, $CO_2$, deposited particle surface area, and number of particles ranging 21-560 nm were 0.61~0.80 ppb, 0.16~0.21 ppm, $0.20{\sim}0.29{\mu}m^2/cm^3$, and 117~192 particles/$cm^3$, respectively. Average pollution levels inside the two tunnels for $CO_2$, deposited particle surface area, and number of particles >5.6 nm ranged 681~748 ppm, $246{\sim}381{\mu}m^2/cm^3$, and $2.4{\sim}6.7{\times}10^5$ particles/$cm^3$, respectively. In case of $NO_x$, the maximum concentration exceeded 1 ppm. These pollution levels inside the tunnels are much higher than those at urban background sites. This result can be utilized as basic data to evaluate the effectiveness of present ventilation system for reducing the pollution level caused by vehicles inside the tunnels.

Physical Characterization of GaAs/$\textrm{Al}_{x}\textrm{Ga}_{1-x}\textrm{As}$/GaAs Heterostructures by Deep Level transient Spectroscopy (DLTS 방법에 의한 GaAs/$\textrm{Al}_{x}\textrm{Ga}_{1-x}\textrm{As}$/GaAs 이종구조의 물성분석에 관한 연구)

  • Lee, Won-Seop;Choe, Gwang-Su
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.460-466
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    • 1999
  • The deep level electron traps in AP-MOCVD GaAs/undoped Al\ulcornerGa\ulcornerAs/n-type GaAs heterostructures have been investigated by means of Deep Level Transient Spectroscopy DLTS). In terms of the experimental procedure, GaAs/undoped Al\ulcornerGa\ulcornerAs/n-type GaAs heterostructures were deposited on 2" undoped semi-insulating GaAs wafers by the AP-MOCVD method at $650^{\circ}C$ with TMGa, AsH3, TMAl, and SiH4 gases. The n-type GaAs conduction layers were doped with Si to the target concentration of about 2$\times$10\ulcornercm\ulcorner. The Al content was targeted to x=0.5 and the thicknesses of Al\ulcornerGa\ulcornerAs layers were targeted from 0 to 40 nm. In order to investigate the electrical characteristics, an array of Schottky diodes was built on the heterostructures by the lift-off process and Al thermal evaporation. Among the key results of this experiment, the deep level electron traps at 0.742~0.777 eV and 0.359~0.680 eV were observed in the heterostructures; however, only a 0.787 eV level was detected in n-type GaAs samples without the Al\ulcornerGa\ulcornerAs overlayer. It may be concluded that the 0.787 eV level is an EL2 level and that the 0.742~0.777 eV levels are related to EL2 and residual oxygen impurities which are usually found in MOCVD GaAs and Al\ulcornerGa\ulcornerAs materials grown at $630~660^{\circ}C$. The 0.359~0.680 eV levels may be due to the defects related with the al-O complex and residual Si impurities which are also usually known to exist in the MOCVD materials. Particularly, as the Si doping concentration in the n-type GaAs layer increased, the electron trap concentrations in the heterostructure materials and the magnitude of the C-V hysteresis in the Schottky diodes also increased, indicating that all are intimately related.ated.

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Quality Changes of Fresh-Cut Potatoes during Storage Depending on the Packaging Treatments (신선한 감자절편의 포장방법에 따른 저장 중 품질변화)

  • Lim, Jeong-Ho;Choi, Jeong-Hee;Hong, Seok-In;Jeong, Moon-Cheol;Kim, Dong-Man
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.933-938
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    • 2005
  • To investigate pertinent packaging treatment of fresh-cut potatoes (Solanum tuberosum L.), potato cubes were subjected to passive, gas exchange, and vacuum packaging conditions. Low density polyethylene film (LDPE), polypropylene film (PP), anti-fogging film (AP), and perforated film (PF) were used as passive packaging treatments. Mixed gases of 5% $CO_2/5%\;O_2$ (MA1) and 10% $CO_2/5%\;O_2$ (MA2) were applied as gas exchange packaging. Packs filled with cubes were kept at $5^{\circ}C$, and changes in weight loss, surface color, vitamin C content and sensory quality of cubes were analyzed during storage. Respiration rate of cubes was 2.11 times higher than that of intact raw potatoes at $5^{\circ}C$. Gas concentrations in passive packaging was maintained at 1-2% $O_2$ and 4-14% $CO_2$ after 7 days. Gas levels changed depending on films used. Cubes packed in PP and MA2 showed lowest weight loss and browning during storage. Firmness of cubes was not affected by packaging treatment. Vitamin C content was highest in cubes packed with AF. Cubes packed in MA2 showed highest quality upto 10days storage, followed by those packed in PP and AF.

Monitoring of Hydrogen Sulfide in Anaerobic Co-digestion of Swine Manure and Food Waste (돈분 및 음식물쓰레기 혼용 혐기소화 시 황화수소 가스 모니터링)

  • Shin, JoungDu;Sung, Shihwu;Kim, Hyunook;Kim, SamcCeun;Lee, MyoungSun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.4
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    • pp.43-49
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    • 2008
  • Objective of this study was to monitor the hydrogen sulfide production rate and concentration in anaerobic co-digestion of swine manure and food waste for biogas production in order to alternate the petroleum based energy. Anaerobic co-digestion for biogas production was performed in serum bottles at 2% volatile solids (VS) concentration and various mixing ratios of two substrates(swine manure: food waste = 100:0 ~ 0:100). Although hydrogen sulfide production rates were varied with digestion periods at different treatments, it was observed that hydrogen sulfide produced in the swine manure alone was lower at 2.4 fold than that of food waste. For effects of hydrogen sulfide concentration in the different mixing ratios of swine manure to food waste, the higher food waste ratio the higher hydrogen sulfide concentration. Also its average concentrations were varied from 0.1452% in the swine waste only to 0.3420% in the food waste alone. For the composition ratio of bio-gas in their anaerobic co-digestion, it appeared that there was 53.2% of $CH_4$, 23.9% of $CO_2$, 0.3% of $H_2S$ and 22.7% of miscellaneous gases including moisture.

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Effect of Foaming Agent Content on the Apparent Density and Compressive Strength of Lightweight Geopolymers (발포제 함량에 따른 경량 다공성 지오폴리머의 밀도와 강도 특성)

  • Lee, Sujeong;An, Eung-Mo;Cho, Young-Hoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.363-370
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    • 2016
  • Lightweight geopolymers are more readily produced and give higher fire resistant performance than foam cement concrete. Lowering the density of solid geopolymers can be achieved by inducing chemical reactions that entrain gases to foam the geopolymer structure. This paper reports on the effects of adding different concentrations of aluminum powder on the properties of cellular structured geopolymers. The apparent density of lightweight geopolymers has a range from 0.7 to $1.2g/m^3$ with 0.025, 0.05 and 0.10 wt% of a foaming agent concentration, which corresponds to about 37~60 % of the apparent density, $1.96g/cm^3$, of solid geopolymers. The compressive strength of cellular structured geopolymers decreased to 6~18 % of the compressive strength, 45 MPa of solid geopolymers. The microstructure of geopolymers gel was equivalent for both solid and cellular structured geopolymers. The workability of geopolymers with polyprophylene fibers needs to be improved as in fiber-reinforced cement concrete. The lightweight geopolymers could be used as indoor wall tile or board due to fire resistance and incombustibility of geopolymers.

Effects of Packaging Treatment on Quality of Fresh-cut Mushrooms (Agaricus bisporus Sing.) during Storage (신선편이가공 양송이의 포장방법에 따른 품질변화)

  • Lim Jeong-Ho;Choi Jeong-Hee;Hong Seok-In;Jeong Moon-Cheol;Kim Dong-Man
    • Food Science and Preservation
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    • v.13 no.1
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    • pp.1-7
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    • 2006
  • The effects of packaging material and method on quality of fresh-cut mushrooms (Agaricus bisporus Sing.) were investigated in terms of weight loss, surface color, phenolics, vitamin C and sensory characteristics during storage at $5^{\circ}C$. The fresh-cut mushrooms were subjected to passive, gas exchange and vacuum packaging conditions at st. Polyethylene film (PE), polypropylene film (PP), anti-fogging film (AP) and pen orated film (PF) were used for the passive packaging. The mixed gas of $5\% CO_2/\;2\%O_2$ (MA1) and $10\%CO_2/\;2\%O_2$(MA2) were applied for the gas exchange packaging. The respiration rate of sliced mushroom was 1.27 times higher than intact mushroom at $5^{\circ}C$. Gas concentrations in the passive packaging were $1-2\%\;O^2\;and\;5-16\%m$ during storage of sliced mushrooms for 14 days at $5^{\circ}C$, and levels of the gases were different by the films used The mushroom in perforated film (PF) showed the highest weight loss of $4.56\%$. Anti-fogging film (AF) was somewhat effective for prevention of the weight loss compared with other films after 14 days storage. The mushrooms in MA1 and MA2 packages showed lower delta L value than in other films. PE packaging mitigated decrease of free and bound phenolics during storage. The mushrooms in MA2 kept better quality in sensory aspect, and then in MA1, PE and PP in order during storage at $5^{\circ}C$.

Spectroscopical Analysis of SiO2 Optical Film Fabricated by FHD(Flame Hydrolysis Deposition) (FHD(Flame Hydrolysis Deposition)공정으로 제작된 SiO2 광도파막의 분광학적 분석)

  • Kim, Yun-Je;Shin, Dong-Wook
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.896-901
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    • 2002
  • Since many process parameters of FHD(Flame Hydrolysis Deposition) are involved in forming multi-component amorphous silica film ($SiO_2-B_2O_3-P_2O_5-GeO_2$), it has not been easy to predict the optical, mechanical and thermal properties of deposited film from the simple process parameters, such as source flow rate. Furthermore, the prediction of final composition of film becomes even more difficult after sintering at high temperature due to the evaporation of volatile dopants. The motivation of the study was to clarify the quantitative relationship between simple process parameters such as the flow rate of source gases and resulting chemical composition of sintered film. Hence, the compositional analysis of silica soot by FTIR(Fourier Transformation Infrared Spectroscopy) and ICP-AES(Inductively Coupled Plasma-Atomic Emission Spectrometry) under the control of the amount of dopant was carried out to obtain the quantitative composition. By measuring spectrum of absorbance from FTIR, the compositional change of B-O, Si-O, OH($H_2O$) in silica film was measured. The concentrations of these dopants were also measured by ICP-AES, which were compared with the FTIR result. The final quantitative relationship between simple process parameters and composition was deduced from the comparison between two results.

Study on the Growth Environment of 'Gangwha-mugwort' Through the Climatological Characteristic Analysis of Gangwha Region (강화지역의 기후특성 분석을 통한 '강화약쑥'의 생육 환경 연구)

  • Ahn, Joong-Bae;Hur, Ji-Na;Jung, Hae-Gon;Park, Jong-Ho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.2
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    • pp.71-78
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    • 2012
  • Eupatilin, one of representative medical components of mugwort, can be efficiently extracted from the 'Gangwha Sajabalssuk'. The Eupatilin content may depend on environmental factors such as soil and regional climate in addition to a genetic factor and Gangwha region has a profitable environmental condition for the mugwort growth. In this study, the climatological characteristics of Gangwha was analyzed in order to find the environmental condition of mugwort containing high Eupatilin in term of atmospheric, oceanographic and land variables. The climate of Gangwha is characterized by the relatively low daily temperature and large diurnal variation with plenty of solar radiation, long sunshine duration and less cloudiness. According to our correlation analysis, the long sunshine duration and the large diurnal temperature variation are highly correlated with the Eupatilin contents. The result implies that Gangwha has the favorable conditions for the cultivation and the habitat of the high-Eupatilin concentrated mugwort. Because of the sea surrounding Gangwha Island with low salinity and moderate wind, the salt contained in sea breeze is relatively low compared to other regions. Furthermore, Gangwha has clean atmospheric environment compared to other regions because the concentrations of toxic gases harmful to crop growth such as nitrogen dioxide ($NO_2$), sulfite gas ($SO_2$) and fine dust (PM-10) are lower in the air. The ozone ($O_3$) concentration is moderate and within the level of natural production. It is also found that moderately coarse texture or fine loamy soils known as good for water drainage and for the growth and cultivation of the 'Gangwha-mugwort' are distributed throughout the areas around mountainous districts in Gangwha, coinciding with those of mugwort habitat.