• Title/Summary/Keyword: Gases Concentrations

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Construction of Basin Scale Climate Change Scenarios by the Transfer Function and Stochastic Weather Generation Models (전이함수모형과 일기 발생모형을 이용한 유역규모 기후변화시나리오의 작성)

  • Kim, Byung-Sik;Seoh, Byung-Ha;Kim, Nam-Won
    • Journal of Korea Water Resources Association
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    • v.36 no.3 s.134
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    • pp.345-363
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    • 2003
  • From the General Circulation Models(GCMs), it is known that the increases of concentrations of greenhouse gases will have significant implications for climate change in global and regional scales. The GCM has an uncertainty in analyzing the meteorologic processes at individual sites and so the 'downscaling' techniques are used to bridge the spatial and temporal resolution gaps between what, at present, climate modellers can provide and what impact assessors require. This paper describes a method for assessing local climate change impacts using a robust statistical downscaling technique. The method facilitates the rapid development of multiple, low-cost, single-site scenarios of daily surface weather variables under current and future regional climate forcing. The construction of climate change scenarios based on spatial regression(transfer function) downscaling and on the use of a local stochastic weather generator is described. Regression downscaling translates the GCM grid-box predictions with coarse resolution of climate change to site-specific values and the values were then used to perturb the parameters of the stochastic weather generator in order to simulate site-specific daily weather values. In this study, the global climate change scenarios are constructed using the YONU GCM control run and transient experiments.

Methane Gas Emission from an Artificial Reservoir under Asian Monsoon Climate Conditions, with a Focus on the Ebullition Pathway (아시아 몬순 기후지역에 위치한 대형 인공호에서 기포형태로의 메탄 (CH4) 가스 배출량)

  • Kim, Kiyong;Jung, Sungmin;Choi, Youngsoon;Peiffer, Stefan;Knorr, Klaus-Holger;Kim, Bomchul
    • Korean Journal of Ecology and Environment
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    • v.51 no.2
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    • pp.160-167
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    • 2018
  • The role played by reservoirs in the biogeochemical cycles of elements is a subject of ongoing debate. Recent research has revealed that reservoirs emit significant levels of greenhouse gases. To assess the importance of reservoirs in monsoon climate areas as a source of methane gas into the atmosphere, we investigated variations in organic carbon (OC) input into the reservoir, oxic state changes, and finally the amount of methane emitted (focusing on the ebullition pathway) in Lake Soyang, which is the largest reservoir in South Korea. Total organic carbon (TOC) concentrations were higher during summer after two years of heavy rainfall. The sedimentation rates of particulate organic carbon (POC) and particulate organic nitrogen (PON) were higher in the epilimnion and hypolimnion than the metalimnioin, indicating that autochthonous and allochthonous carbon made separate contributions to the TOC. During stratification, oxygen depletion occurred in the hypolimnion due to the decomposition of organic matter. Under these conditions, $H_2S$ and $CH_4$ can be released from sediment. The methane emissions from the reservoir were much higher than from other natural lakes. However, the temporal and spatial variations of methane ebullition were huge, and were clearly dependent on many factors. Therefore, more research via a well-organized field campaign is needed to investigate methane emissions.

Enhancement of Ozone and Carbon Monoxide Associated with Upper Cut-off Low during Springtime in East Asia

  • Moon, Yun-Seob;Drummond, James R.
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.5
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    • pp.475-489
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    • 2010
  • In order to verify the enhancement of ozone and carbon monoxide (CO) during springtime in East Asia, we investigated weather conditions and data from remote sensors, air quality models, and air quality monitors. These include the geopotential height archived from the final (FNL) meteorological field, the potential vorticity and the wind velocity simulated by the Meteorological Mesoscale Model 5 (MM5), the back trajectory estimated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model, the total column amount of ozone and the aerosol index retrieved from the Total Ozone Mapping Spectrometer (TOMS), the total column density of CO retrieved from the Measurement of Pollution in the Troposphere (MOPITT), and the concentration of ozone and CO simulated by the Model for Ozone and Related Chemical Tracers (MOZART). In particular, the total column density of CO, which mightoriginate from the combustion of fossil fuels and the burning of biomass in China, increased in East Asia during spring 2000. In addition, the enhancement of total column amounts of ozone and CO appeared to be associated with both the upper cut-off low near 500 hPa and the frontogenesis of a surface cyclone during a weak Asian dust event. At the same time, high concentrations of ozone and CO on the Earth's surface were shown at the Seoul air quality monitoring site, located at the surface frontogenesis in Korea. It was clear that the ozone was invaded by the downward stretched vortex anomalies, which included the ozone-rich airflow, during movement and development of the cut-off low, and then there was the catalytic photochemical reaction of ozone precursors on the Earth's surface during the day. In addition, air pollutants such as CO and aerosol were tracked along both the cyclone vortex and the strong westerly as shown at the back trajectory in Seoul and Busan, respectively. Consequently, the maxima of ozone and CO between the two areas showed up differently because of the time lag between those gases, including their catalytic photochemical reactions together with the invasion from the upper troposphere, as well as the path of their transport from China during the weak Asian dust event.

Drilling Gas Hydrate at Hydrate Ridge, ODP Leg 204

  • Lee Young-Joo;Ryu Byong-Jae;Kim Ji-Hoon;Lee Sang-Il
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.663-666
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    • 2005
  • Gas hydrates are ice-like compounds that form at the low temperature and high pressure conditions common in shallow marine sediments at water depths greater than 300-500 m when concentrations of methane and other hydrocarbon gases exceed saturation. Estimates of the total mass of methane carbon that resides in this reservoir vary widely. While there is general agreement that gas hydrate is a significant component of the global near-surface carbon budget, there is considerable controversy about whether it has the potential to be a major source of fossil fuel in the future and whether periods of global climate change in the past can be attributed to destabilization of this reservoir. Also essentially unknown is the interaction between gas hydrate and the subsurface biosphere. ODP Leg 204 was designed to address these questions by determining the distribution, amount and rate of formation of gas hydrate within an accretionary ridge and adjacent basin and the sources of gas for forming hydrate. Additional objectives included identification of geologic proxies for past gas hydrate occurrence and calibration of remote sensing techniques to quantify the in situ amount of gas hydrate that can be used to improve estimates where no boreholes exist. Leg 204 also provided an opportunity to test several new techniques for sampling, preserving and measuring gas hydrates. During ODP Leg 204, nine sites were drilled and cored on southern Hydrate Ridge, a topographic high in the accretionary complex of the Cascadia subduction zone, located approximately 80km west of Newport, Oregon. Previous studies of southern Hydrate Ridge had documented the presence of seafloor gas vents, outcrops of massive gas hydrate, and a pinnacle' of authigenic carbonate near the summit. Deep-towed sidescan data show an approximately $300\times500m$ area of relatively high acoustic backscatter that indicates the extent of seafloor venting. Elsewhere on southern Hydrate Ridge, the seafloor is covered with low reflectivity sediment, but the presence of a regional bottom-simulating seismic reflection (BSR) suggests that gas hydrate is widespread. The sites that were drilled and cored during ODP Leg 204 can be grouped into three end-member environments basedon the seismic data. Sites 1244 through 1247 characterize the flanks of southern Hydrate Ridge. Sites 1248-1250 characterize the summit in the region of active seafloor venting. Sites 1251 and 1252 characterize the slope basin east of Hydrate Ridge, which is a region of rapid sedimentation, in contrast to the erosional environment of Hydrate Ridge. Site 1252 was located on the flank of a secondary anticline and is the only site where no BSR is observed.

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Application of biofilter for removing malodomus gas generated from compost factory (퇴비화 '공장에서 발생되는악취'를 제거하기 위한 Biofilter의 적용)

  • Kim, Chang-Il;Lee, Jae-Ho;Kim, Dae-Seung;Nam, Sang-Il;Nam, Yi
    • Journal of Korea Soil Environment Society
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    • v.4 no.3
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    • pp.45-56
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    • 1999
  • A biofilter was established to remove the ammonia, which is representative nitrogen-contained malodorous gas. in a compost factory. Removal efficiency of ammonia and hydrogen sulfide also was investigated. A quantity of malodor gas produced in a compost factory was affected greatly by the weather. compost states and working condition of a fertilizing mixer, and the produced gas concentrations doubled by above various parameters. By operating a water scrubbing system for removing water-soluble malodorous gases effectively. we could improve the removal efficiency over three times. We investigated long-term stability of biofilter under continuous gas flow(SV=500h-1) for 100 days. The results showed 30 days of microbial retention time. After the days, deodorization efficiency of biofilter was kept steady state. and the removal efficiency was kept over 95% for ammonia and 97% for hydrogen so]fide. respectively. The electric consumption of the biofilter, which could treat malodorous gas of 100$\textrm{m}^3$/min, applied in the compost factory was evaluated about 80u0day and water consumption was 80~100$\ell$/day. These results concluded that the biofilter is a excellent deodorization technology as well as cost-effective for removing malodorous gas produced in a compost factory.

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Atmospheric Background Values at Dokdo Island, Korea (독도에서의 대기 background 농도)

  • LEE Dong-In
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.1
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    • pp.80-86
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    • 1995
  • To investigate the background concentration of air pollutants (SO_2,\;CO,\;NO_2,\;O_3,\;TSP)$ and the composition of atmospheric aerosols, air samplings using teflon bags and a high volume air sampler were accomplished from 7 to 8 lune 1991 (first time) and from 25 to 26 June 1992 (second time) at the top of Dokdo island, Korea. During observation periods, mean concentrations of $SO_2,\;CO'\;NO_2\;and\;O_3$ gases were 2.3 ppb, 5.57 ppm, 6 ppb and 7 ppb, respectively, and mean concentration of TSP using a high volume air sampler was $153{\mu}g/m^3$. The composition of atmospheric aerosols by SEM-EMAX analyses were mostly Na, Cl and Si, and their sizes were more than $1{\mu}m$ diameter. From the results, it is found that atmospheric background values at Dokdo island is influenced by oceanic water quality evaporated from sea surface water, and this island has to be used as a stationary observation site for meteorological and air quality data.

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Study on Plans for the Establishment of Strategy on Climate Change Adaptation in Korea (국가 기후변화 적응 전략 수립 방안에 관한 연구)

  • Kwon, Won-Tae;Baek, Hee-Jeong;Choi, Kyung-Cheol;Chung, Hyo-Sang
    • Atmosphere
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    • v.15 no.4
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    • pp.213-227
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    • 2005
  • The global mean surface temperature has already increased by $0.6{\pm}0.2^{\circ}C$ over the last century, and warming in Korea is approximately twice as large as the global average. The Intergovernmental Panel on Climate Change (IPCC) has concluded that the majority of warming over the past 50 years could be attributed to human activities (IPCC, 2001a). In addition, the global surface temperature is expected to increase by 1.4 to $5.8^{\circ}C$ depending on the greenhouse gas emission scenarios during the $21^{st}$ century.Climate change resulting from increased greenhouse gas concentrations has the potential to harm societies and ecosystems. Reductions in emissions of greenhouse gases and their concentration in the atmosphere will reduce the degree and likelihood of significant adverse conditions due to the anticipated climate change. Mitigation policy has generally been the primary focus of public attention and policy efforts on climate change. However, some degree of climate change is inevitable due to the combination of continued increases in emissions and the inertia of the global climate system. Adaptation actions and strategies are needed for a complementary approach to mitigation. The United Nations Framework Convention on Climate Change (UNFCCC) currently addresses vulnerability and adaptation in the context of climate change negotiations and in future adaptation may be an important element of work under the Kyoto Protocol. There are several on-going programs to develop effective adaptation strategies and their implementation. But in general, many other countries are still on an initiating stage. The climate change science programs of the United States, Japan, England, and Germany are initiated to understand the current status of climate change science and adaptation researches in the developed countries. In this study, we propose the improvement on systems in policy and research aspects to effectively perform the necessary functions for development of nation-wide adaptation measures and their implementation. In policy aspect, the Korean Panel on Climate Change (KPCC) is introduced as a coordinating mechanism between government organizations related with climate change science, impact assessment and adaptation. Also in research aspect, there is a strong consensus on the need for construction of a national network on climate change research as trans-disciplinary research network.

Development of 10 μmol/mol Hydrogen Sulfide Primary Standard Gas for Odor Measurements (악취측정용 10 μmol/mol 황화수소 표준가스 개발)

  • Kim, Yong-Doo;Bae, Hyun-Kil;Kim, Dalho;Oh, Sang-Hyub;Lee, Jin Hong;Lee, Sangil
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.46-51
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    • 2018
  • Hydrogen sulfide from landfill and sewage treatment plant is a major odor component and causes many civil petitions. Rapidly developing industries release hydrogen sulfide, an odorous gas, to the atmosphere. This study aims to develop a $10{\mu}mol/mol$ concentration level hydrogen sulfide primary standard gas for odor measurement. The hydrogen sulfide gas was prepared at a nominal concentration of $10{\mu}mol/mol$ in nitrogen using the gravimetric method described in ISO 6142. Replicate standard gases were produced in 4 aluminium cylinders, and their concentrations were verified by GC-AED. The uncertainty of production was less than 0.50 %, and the variation of the 4 replicates was 0.22 %. The wall adsorption of hydrogen sulfide in cylinders was 0.10 % at 1500 psi, and the concentration was estimated to be long-term stable for one year. The relative expanded uncertainty of the preparation consistency, adsorption and long-term stability of this hydrogen sulfide standard gas was less than 1.05 % (95 % of confidence level, k=2).

Greenhouse Gas (CH4, CO2, N2O) Emissions from Estuarine Tidal and Wetland and Their Characteristics (온실기체 (CH4, CO2, N2O)의 하구언갯벌 배출량과 배출특성연구)

  • Kim, Deug-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.225-241
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    • 2007
  • A closed flux chamber system was used for measuring major greenhouse gas (GHG) emission from tideland and/or wetland soils in estuarine area at Saemankum, Kunsan in southwestern Korea during from months of February to June 2006. Hourly averaged GHG soil emissions were measured two to three times a day during the ebb tide hours only. Site soils were analyzed for soil parameters (temperature, pH, total organic contents, N and C contents in soil) in the laboratory. Soil GHG fluxes were calculated based on the GHG concentration rate of change measured inside a closed chamber The analysis of GHG was conducted by using a Gas Chromatography (equipped with ECD/FID) at laboratory. Changes of daily, monthly GHGs' fluxes were examined. The relationships between the GHG emissions and soil chemical contents were also scrutinized with respect to gas production and consumption mechanism in the soil. Soil pH was pH $7.47{\pm}0.49$ in average over the experimental period. Organic matter contents in sample soil was $6.64{\pm}4.98\;g/kg$, and it shows relatively lower contents than those in agricultural soils in Kunsan area. Resulting from the soil chemistry data, soil nitrogen contents seem to affect GHG emission from the tidal land surface. The tidal soil was found to be either source or sink for the major GHG during the experimental periods. The annual average of $CH_{4}\;and\;CO_{2}$ fluxes were $0.13{\pm}0.86\;mg\;m^{-2}h^{-1}\;and\;5.83{\pm}138.73\;mg\;m^{-2}h^{-1}$, respectively, which will be as a source of these gases. However, $N_{2}O$ emission showed in negative flux, and the value was $-0.02{\pm}0.66\;mg\;m^{-2}h^{-1}$, and it implies tidal land surface act as a sink of $N_{2}O$. Over the experimental period, the absolute values of gas fluxes increased with soil temperature in general. Averages of the ambient gas concentration were $86.8{\pm}6.\;ppm$ in $CO_{2},\;1.63{\pm}0.34\;ppm\;in\;CH_{4},\;and\;0.59{\pm}0.15\;ppm\;in\;N_{2}O$, respectively. Generally, under the presence of gas emission from agricultural soils, decrease of gas emission will be observed as increase in ambient gas concentration. We, however, could not found significant correlation between the ambient concentrations and their emissions over the experimental period. There was no GHG compensation points existed in tide flat soil.

Determination of Major Reduced Sulfur Gases Emitted from Wastes Stored in Environmental Facility Using GC/FPD (GC/FPD를 이용한 환경기초시설 폐기물의 대기중 황계열 악취물질 배출특성에 관한 연구)

  • Lee, Taeyoon;Lee, Jeakeun;Lee, Junki
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.2
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    • pp.37-43
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    • 2009
  • With the economic development of Korea, sewage treatment facilities and waste food treatment facilities have been steadily increased. These facilities have positive effects such as the conservation of the water resources quality and waste food recycling while they also affect the neighborhood life with severe odor problems. Therefore, it was first collected sludge samples from 5 sewage treatment facilities and 5 waste food treatment facilities where the amounts of waste produced from above sites are relatively immense in Busan and estimate the $H_2S$ emission rates. Then it was selected 1 sample which has the highest emission rate of $H_2S$. Using flux chamber and GC/FPD analyses, it was tried to quantify the emitted amount of sulfonic gas concentration under anoxic condition. The sludge sample obtained from Noksan sewage treatment facility has the highest emission rate of $H_2S$. This sample contained 156.18 mg/kg $H_2S$. The odor compounds were analyzed using GC/FPD and the concentrations were converted to odor quotient. Among odor compounds the ratio of $CH_3SH$ (methylmercaptan) for the total odor quotient was 47.3% and considered to be the main odor compound in the sample.

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