• 제목/요약/키워드: Gases Concentrations

검색결과 284건 처리시간 1.078초

Study on a cavity ring-down spectrometer with continuous wave laser sources (연속발진 레이저를 이용한 공동 광자감쇠 분광기 연구)

  • 유용심;한재원;김재완;이재용;이해웅
    • Korean Journal of Optics and Photonics
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    • 제9권4호
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    • pp.240-244
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    • 1998
  • Cavity ring-down spectroscopy (CRDS) is a high-sensitive laser spectroscopic technique capable of measuring concentrations of trace gases. We have demonstrated a new design of the CRDS spectrometer with a continuous wave (CW) laser. The ring-dwon signal is produced through blocking the incident CW laser by scanning the cavity length fast toward off-resonance iwth PZT (piezoelectric transducer). We have also measured an absorption spectrum of acetylene overtone transitions near 570 nm at the pressure of 2700 Pa, and the minimum detectable absorption coefficient has been found to be about $3{\times}10^{-9}\cm^{-1}$.

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Changes of Smoke Components and Smoke Odor by Far Infra-red Radiation in a Closed Room

  • Hwang, Keon-Joong;Rhee, Moon-Soo;Ra, Do-Young
    • Journal of the Korean Society of Tobacco Science
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    • 제20권2호
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    • pp.198-204
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    • 1998
  • This study was conducted to evaluate the effect of far IR radiation for the elimination of sidestream smoke components in a closed room. The measurements covered particle sizes of 13.8-542.5 nm, particle concentration, TSP, UVPM, FPM, solanesol, and the following gases and vapor components of smoke: carbon dioxide, carbon monoxide, nicotine, and 3-ethenyl-pyridine. Also, the changes of smoke odor strength by far IR radiation were tested by using the electronic nose system. There was no difference between control and far IR radiation in changes of the concentration of $CO_2$ and CO. The concentrations of TSP, UVPM, FPM, solanesol, nicotine, and 3-ethenylpyridine were reduced by far IR radiation. The growth and diminishing rate of RSP diameter was accelerated by far IR radiation compared with control. There was a little difference of smoke odor change with far IR radiation by electronic nose system analysis. Our results indicated that the use of far IR radiation had a little effect on changes of solid, vapor, and odor of smoke, but it had no effect on gaseous components.

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A Study on the Analysis of Solar Radiation Characteristics on a High Elevated Area (고지대 일사량 특성분석에 관한 연구)

  • Jo, Dok-Ki;Kang, Young-Heack;Auh, Chung-Moo
    • Journal of the Korean Solar Energy Society
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    • 제23권3호
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    • pp.23-28
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    • 2003
  • The purpose of this study is to procure basic data to be used for solar power plant and concentrating collector designs. Site elevation is one of the major factors which influences the incoming insolation to the earth surface. Because the nonpermanent gases such as ozone, water vapor are unmixed components of the atmosphere and their concentrations are the function of height, the site elevation effects the relative proportion of the atmospheric constituents. We have measured solar radiation on Jiri Mt. (1,400m) and in Gurye area(115m) at the near same latitude. These values were then compared to obtain their characteristics and to investigate the potential for the solar utilization for both high and low elevated areas. From the experimental results, we concluded that 1) Daily mean horizontal global radiation and normal beam radiation on Mt. Jiri are 9.5%, and 35.3% higher than Gurye area respectively for a clear day. 2) A significant difference in atmospheric clearness index is observed between Mt. Jiri and Gurye areas.

Design Parameters Estimations for Bubble Column Reactors to Remove Toxic Gases (독성가스 제거용 기포탑 반응기의 설계기법)

  • Oh, Junghwan;Hong, Min Sun
    • Korean Journal of Hazardous Materials
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    • 제6권2호
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    • pp.95-104
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    • 2018
  • Gas-liquid bubble column reactors are extensively used in industrial processes. A detailed knowledge of bubble size distribution is needed for determining the mass transfer in gas-liquid film. Experimental data on bubble size distribution and liquid-side mass transfer coefficient($k_L$) were used to calculate the estimated time to saturation in bubble column reactor. Also, the gas flux was evaluated to the liquid-side mass transfer coefficient($k_L$) and solubility data for hydrogen sulfide($H_2S$) and chlorine($Cl_2$) absorption into water. Simulation results show that $H_2S$ absorption time to 50 % of saturation concentrations are 611 sec and 1,329 sec when bubble diameters are 0.5 mm and 4.5 mm, while absorbing 1 % $H_2S$ gas. In case of $Cl_2$, absorption time range 657 to 1,400 sec when bubble size range 0.5 mm to 4.5 mm, while absorbing 1 % $Cl_2$ gas. Calculated simulation results can be used in the design of emergency relief bubble reactors.

Special monitoring results for determination of radionuclide composition of Russian NPP atmospheric releases

  • Vasyanovich, Maxim;Vasilyev, Aleksey;Ekidin, Aleksey;Kapustin, Ivan;Kryshev, Alexander
    • Nuclear Engineering and Technology
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    • 제51권4호
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    • pp.1176-1179
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    • 2019
  • Measurements of activity concentrations of radionuclides in atmospheric releases were performed in 2017-2018 at vent stacks of seven Russian nuclear power plants. The selected instruments and research methods, with detection limits significantly lower than the existing detection limit of Russian NPPs routine control, allowed to reliably determine up to 26 radionuclides. Analysis of experimental data allows to determine the list of radionuclides for calculation the effective dose rates to public and the permissible annual discharge levels for each Russian NPP. Radiocarbon is determined as major contributor for the dose from the atmospheric releases of LWGR reactors - up to 98% for EGP-6 and RBMK-1000 (Smolensk NPP) reactors. For PWR reactors (VVER) radionuclides contribution to the annual dose from atmospheric releases is more complicated, but, in general, dose is formed by tritium, $^{14}C$ and noble gases. The special monitoring results with ranking of measured radionuclides according to their contribution to the effective dose makes it possible to optimize the list of controlled radionuclides in airborne releases of Russian NPPs from 94 to 8-16 for different NPPs.

Development of GHG Reduction Technology by Collecting Greenhouse Gas (CO2) in Livestock Facilities and Supply of Facility House (축산시설 내 온실가스(CO2) 포집 및 시설하우스 공급을 통한 온실가스 저감기술 개발)

  • Nah, Gyu Dong;Cho, Man Su
    • Journal of Environmental Health Sciences
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    • 제44권6호
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    • pp.599-607
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    • 2018
  • Objectives: Carbon dioxide ($CO_2$) may be one of the biggest causes of climate change. The purposes of this study were to reduce greenhouse gases and to increase strawberry production by developing the supply devices in livestock facilities using the membrane technology Methods: Carbon dioxide was collected from beside to livestock facilities. The injection of $CO_2$ was stopped when it reached 1,000 ppm in the facility house. Case group with injection of $CO_2$ was compared to control group with normal environment. The experiments were conducted for 8 days from December 11, 2017. Results: Total strawberry production was found to be 1,317 kg in the case group and 1,176 kg in the control group. The correlation between $CO_2$ and crop yields has led to some statistical evidence that carbon dioxide helps to grow (${\beta}=0.832$, p<0.05). Conclusions: This study identified the potential for efforts to reduce the $CO_2$ in farming households. Increased concentrations of $CO_2$ have shown that strawberries have a better growth condition. In addition, it can be explained that the plants need wide leaves to quickly absorb much $CO_2$.

Analysis of Working Environment and Ventilation Efficiency in Pig House using Computational Fluid Dynamics (전산유체역학을 사용한 양돈장 내 작업환경 환기효율성 분석)

  • Oh, Byung-Wook;Lee, Seong-Won;Kim, Hyo-Cher;Seo, Il-Hwan
    • Journal of The Korean Society of Agricultural Engineers
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    • 제61권2호
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    • pp.85-95
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    • 2019
  • The internal environment in pig house is closely related to the animal productivity. In addition, it is important to consider a working environment inside the pig house due to high gas and dust concentrations. The poor working environment inside the pig house can cause health problems including respiratory diseases. To analyze the working environment, it is important to evaluate the ventilation efficiency to effectively remove harmful gases and dust. The purpose of this study is to develop a 3D CFD model to analyze the working environment in the pig house. CFD model was validated by comparing air temperature distributions between CFD computed and field measured data. The average air flow rate at the pig height was 40.1 % lower than the working height when incoming air was concentrated on upper layer by the installed ventilation system on the experimental pig house. Using the validated CFD model, the regional ventilation efficiency was computed by the TGD(tracer gas decay) method at the pig and working heights. There was a difference of ventilation efficiency on 14 % between the air stagnated section and the rest sections. Stagnated gas concentration can be effected by animal and human health.

Numerical analysis on in-core ignition and subsequent flame propagation to containment in OPR1000 under loss of coolant accident

  • Song, Chang Hyun;Bae, Joon Young;Kim, Sung Joong
    • Nuclear Engineering and Technology
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    • 제54권8호
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    • pp.2960-2973
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    • 2022
  • Since Fukushima nuclear power plant (NPP) accident in 2011, the importance of research on various severe accident phenomena has been emphasized. Particularly, detailed analysis of combustion risk is necessary following the containment damage caused by combustion in the Fukushima accident. Many studies have been conducted to evaluate the risk of local hydrogen concentration increases and flame propagation using computational code. In particular, the potential for combustion by local hydrogen concentration in specific areas within the containment has been emphasized. In this study, the process of flame propagation generated inside a reactor core to containment during a loss of coolant accident (LOCA) was analyzed using MELCOR 2.1 code. Later in the LOCA scenario, it was expected that hydrogen combustion occurred inside the reactor core owing to oxygen inflow through the cold leg break area. The main driving force of the oxygen intrusion is the elevated containment pressure due to the molten corium-concrete interaction. The thermal and mechanical loads caused by the flame threaten the integrity of the containment. Additionally, the containment spray system effectiveness in this situation was evaluated because changes in pressure gradient and concentrations of flammable gases greatly affect the overall behavior of ignition and subsequent containment integrity.

Removal of NOx using electron beam process with NaOH spraying

  • Shin, Jae Kyeong;Jo, Sang-Hee;Kim, Tae-Hun;Oh, Yong-Hwan;Yu, Seungho;Son, Youn-Suk;Kim, Tak-Hyun
    • Nuclear Engineering and Technology
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    • 제54권2호
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    • pp.486-492
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    • 2022
  • Nitrogen oxides (NOx; NO and NO2) are major air pollutants and can cause harmful effects on the human body. Electron Beam Flue Gas Treatment (EBFGT) is a technology that generates electrons with an energy of 0.5-1 MeV using electron accelerators and effectively processes exhaust gases. In this study, NOx was removed using an electron beam accelerator with spraying additives (NaOH and NH4OH). NO and NO2 were 100% and more than 94% removed, respectively, at an electron beam absorbed dose of 20 kGy and an additive concentration of 0.02 M (mol/L). In most cases, NOx was removed better with lower initial NOx concentrations and higher electron beam absorbed doses. As the irradiation strength (mA) of the electron beam increases, the probability of electron impact on the material accordingly rises, which may lead to increase removal efficiency. The results of the present study show that the continuous electron beam process using additives achieved more effective removal efficiency than either individual process (wet-scrubbing or EB irradiation only).

Quantitative Analysis of SO2 and NO2 Adsorption and Desorption on Quartz Crystal Microbalance Coated with Cobalt Gallate Metal-Organic Framework

  • Junhyuck Ahn;Taewook Kim;Sunghwan Park;Young-Sei Lee;Changyong Yim
    • Journal of Sensor Science and Technology
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    • 제32권3호
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    • pp.147-153
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    • 2023
  • Metal-organic frameworks (MOFs) of cobalt gallate were synthesized and deposited on gold electrodes using self-assembly monolayers (SAMs) and hydrothermal processing. These MOF films exhibit strong adsorption capabilities for gaseous particulates, and the use of SAMs allows the synthesis and deposition processes to be completed in a single step. When cobalt gallate is mixed with SAMs, a coordination bond is formed between the cobalt ion and the carboxylate or hydroxyl groups of the SAMs, particularly under hydrothermal conditions. Additionally, the quartz crystal microbalance (QCM) gas sensor accurately measures the number of particulates adsorbed on the MOF films in real-time. Thus, the QCM gas sensor is a valuable tool for quantitatively measuring gases, such as SO2, NO2, and CO2. Furthermore, the QCM MOF film gas sensor was more effective for gas adsorption than the MOF particles alone and allowed the accurate modeling of gas adsorption. Moreover, the QCM MOF films accurately detect the adsorption-desorption mechanisms of SO2 and NO2, which exist as gaseous particulate matter, at specific gas concentrations.