• Title/Summary/Keyword: Gaseous

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THE MEMBRANE BIOFILM REACTOR IS A VERSA TILE PLATFORM FOR WATER AND WASTEWATER TREATMENT

  • Rittmann, Bruce E.
    • Environmental Engineering Research
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    • v.12 no.4
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    • pp.157-175
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    • 2007
  • The membrane biofilm reactor (MBfR) creates a natural partnership of a membrane and biofilm, because a gas-transfer membrane delivers a gaseous substrate to the biofilm that grows on the membrane's outer wall. $O_2$-based MBfRs (called membrane aerated biofilm reactors, or MABRs) have existed for much longer than $H_2$-based MBfRs, but the $O_2$-based MBfR is a versatile platform for reducing oxidized contaminants in many water-treatment settings: drinking water, ground water, wastewater, and agricultural drainage. Extensive bench-scale experimentation has proven that the $H_2$-based MBfR can reduce many oxidized contaminant to harmless or easily removed forms: e.g., ${NO_3}^-$ to $N_2$, ${ClO_4}^-$ to $H_2O$ and $Cl^-$, ${SeO_4}^{2-}$ to $Se^0$, and trichloroethene (TCE) to ethene and $Cl^-$. The MBfR has been tested at the pilot scale for ${NO_3}^-$ and ${ClO_4}^-$ and is now entering field-testing for many of the oxidized contaminants alone or in mixtures. For the MBfR to attain its full promise, several issues must be addressed by bench and field research: understanding interactions with mixtures of oxidized contaminants, treating waters with a high TDS concentration, developing modules that can be used in situ to augment pre-denitrification of wastewater, and keeping the capital costs low.

Effects of Operation Conditions on Hydrocarbon Components Emitted from SI Engine with Gaseous Fuels (기체 연료를 사용한 전기점화기관에서 운전조건이 HC 배출물 성분에 미치는 영향)

  • 박종범;최희명;이형승;김응서
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.1
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    • pp.108-121
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    • 1998
  • Using gas chromatography, the light hydrocarbon emissions were analyzed from SI engine fueled with methane and liquified petroleum gas(LPG), and the effects of fuel and engine operating condition were discussed. For this purpose, 14 species of light hydrocarbon including 1, 3-butadiene were separated, calibrated with standard gas, and measured from undiluted emissions. The brake specific hydrocarbon emission(BSHC) and ozone forming potential(BSO)3 were calculated and discussed with the changes of fuel, engine speed, load, fuel/air equivalence ratio, coolant temperature, and spark timing. As a result, exhaust emission was composed of mainly fuel composed of mainly fuel comp- onent and other olefin components of similar carbon number. The olefin components such as ethylene and propylene determine most of the ozone forming potential. The fraction of fuel component in total hydrocarbon emission was bigger with methane fuel than with LPG fuel. Also fuel fraction increased at high speed or high speed or high temperature of exhaust gas, and to lesser extent with high coolant temperature and retarded spark. However, the effect of equivalence ratio had different tendency according to fuels.

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A Study on the Combustion Characteristics and the Control on the Fuel Flow Rate of LPG Intake Port Injection Engine (흡기포트 분사식 LPG 엔진의 연료량 제어 및 연소 특성에 관한 연구)

  • 김우석;이종화;정창현
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.6
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    • pp.31-39
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    • 2000
  • In this paper, characteristics of a port injection type LPG fuel system were investigated to adopt the system to a spark ignition engine through rig test. Engine combustion characteristics for limited conditions and the precise control method of LPG fuel supply were also studied. As a basic experiment, the effects and the relationships of parameters such as orifice area, fuel delivery pressure, fuel temperature and flow coefficient were established. From this, one dimensional compressible flow equation can be applied to control gaseous fuel flow rate by setting pressure difference between vaporizer and manifold to a certain range, for example about 1.2 bar in a naturally aspirated engine. The combustion analysis results of LPG engine were also compared with those of gasoline engine according to spark timing and load change. At part load and stoichiometric condition, the MBT spark timing of LPG fueled engine is retarded by 2$^{\circ}$ - 4$^{\circ}$CA compared to that of gasoline engine. On the contrary, the spark timing of LPG fueled engine can be advanced by 5$^{\circ}$- 10$^{\circ}$ CA at WOT, which results from higher Octane Number and burned fraction of LPG fuel compared to gasoline.

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Combustion Characteristics and Exhaust Emissions in Spark-ignition Engine Using Gasoline-ammonia (가솔린 엔진에서 가솔린-암모니아 혼합 연료의 연소 및 배기 특성)

  • Ryu, Kyunghyun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.6
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    • pp.155-165
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    • 2013
  • The effect of gaseous ammonia direct injection on the engine performance and exhaust emissions in gasoline-ammonia dual fueled spark-ignition engine was investigated in this study. Results show that based on the gasoline contribution engine power increases as the ammonia injection timing and duration is advanced and increased, respectively. However, as the initial amount of gasoline is increased the maximum power output contribution from ammonia is reduced. For gasoline-ammonia, the appropriate injection timing is found to range from 320 BTDC at low loads to 370 BTDC at high loads and the peak pressures are slightly lower than that for gasoline due to the slow flame speed of ammonia, resulting in the reduction of combustion efficiency. The brake specific energy consumption (BSEC) for gasoline-ammonia has little difference compared to the BSEC for gasoline only. Ammonia direct injection causes slight reduction of $CO_2$ and CO for all presented loads but significantly increases HC due to the low combustion efficiency of ammonia. Also, ammonia direct injection results in both increased ammonia and NOx in the exhaust due to formation of fuel NOx and ammonia slip.

A Study on the Malfunction Prevention for Transponder of Record Type Fire Alarm System (R형 자탐설비의 중계기 오동작 방지 대책에 대한 연구)

  • Yoo, Jae Ick;Jung, Jae Hee
    • Journal of the Korean Society of Safety
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    • v.29 no.5
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    • pp.54-59
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    • 2014
  • The record type receivers that are operated in large industrial sites have strength in preventing fire. However, because of its long circuit lines and multiple detectors, the receivers are vulnerable to lightning, noise, and breakdown of equipments, resulting in malfunction. In case of malfunctioning of detection circuits of main protection areas, such as electrical room and server room, potential release of gaseous extinguisher agents may lead to property and life damage. In this paper, we present the results on the characteristics of the transponder that initiates the solenoid valves, with respect to various electromagnetic and lightning inflow conditions. Based on the measured data, we analyzed the systematic problems of the transponder. In order to prevent receiver malfunctions, a sequential circuit was configured with two additional transponders and a timer. The circuit was tested with a simulator with preference and delay circuit algorithms.

The Morphology and Adhesion of TiCN Film formed by PECVD (PECVD 에 의해 형성된 TiCN 박막의 형상 및 밀착성)

  • Huh, J.;Nam, T.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.3
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    • pp.118-126
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    • 2002
  • TiCN thin films were deposited on tool steels at $510^{\circ}C$ by PECVD from a $TiCl_4+N_2+CH_4+H_2+Ar$ gaseous mixture. The microstructures and preferred orientation were investigated. The micro-scratch tests were performed using a system equipped with an acoustic emission sensor. Critical loads were determined to evaluate the adhesion of TiCN to substrate. The influences of the microstructures of substrates, double layered coatings, and coatings after nitriding(duplex coating) were investigated. The experimental results showed that the microstructures of substrates and double layered coating did not affect the critical loads considerably. By the duplex coating, critical loads were not always increased. In some cases, duplex coatings decreased critical loads significantly despite of absence of black layer. In this study, we tried to relate the results of scratch test to the residual stress analysis. Nitriding before the coating reduces the tensile residual stress in the film, which gives rise to low critical load in scratch test.

Changes in Atmospheric Mercury Concentrations in Seoul, Korea and its Significance: A Case Study Between 1997 and 2002

  • Kim Ki-Hyun;Kim Min-Young;Hong SM
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E1
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    • pp.1-11
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    • 2005
  • The concentration levels of gaseous elemental mercury (GEM) in ambient air have been investigated from a monitoring station located in Yang Jae district of Seoul, Korea for a long-term period covering 1997 through 2002. The mean concentration of Hg, if computed based on its hourly measurement data for this six-year period, was $5.32\pm3.53 ng m^{-3} (N = 27,170)$. The inspection of the diurnal distribution patterns indicated the presence of notably high concentration levels during nighttime relative to daytime (e.g., the mean hourly value as high as $9 ng m^{-3}$ in winter nighttime). When divided seasonally, the highest mean of $6.12 ng m^{-3}$ was also observed during winter followed by spring, fall, and summer. The results of our analysis confirmed the relative dominance of winter (seasonally) or nighttime (diurnally), while exhibiting a complicated trend on a long-term basis. Examination of our data over a different temporal scale consistently indicated that dynamic changes in Hg concentrations occurred through time in line with changes in the strength and diversity of the source processes. It is thus acknowledged that the presence of unusually high Hg levels is the consequence of intense man-made activities, while such signatures can vary in a competitive manner.

Characteristics of Exhaust Emission Reduction of Heavy Duty Diesel Engine by Oxidation Catalyst - Engine Bench Test - (산화촉매에 의한 대형디젤엔진의 배출가스 정화특성 -실차실험을 중심으로-)

  • 조강래;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.5
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    • pp.443-454
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    • 1998
  • Pt-V catalytic converter was installed on a heavy duty diesel engine and the characteristics of the emission reduction were tested using a engine dynamometer at various operating conditions. The emission reduction performance of Pt-V catalyst was also compared with that of a commercialized Pt catalyst currently being used in some of the heavy duty diesel engines in advanced countries. The effects of Pt-V and Pt catalysts on regulated and unregulated emissions were investigated using a 0.05 weight percent sulfur content fuel with an engine dynamometer Experiments for gaseous emissions (CO, HC and aldehyde) as well as particulate emissions (TPM, SOF and sulfate) have been conducted at several operating conditions such as T-7 mode, D-13 mode and S-13 mode before and after installing the Pt-V and Pt catalysts in the exhaust system. The emission reduction performance of Pt catalyst with respect to CO, HC, SOF, PAHs and aldehyde was found to be a little higher than that of Pt-V catalyst, but the Pt catalyst showed innate disadvantage of causing an increase of PM due to the sulfate formation via high SO2 conversion at high exhaust temperature, especially above 45$0^{\circ}C$.

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Seasonal Variations in Mercury Deposition over the Yellow Sea, July 2007 through April 2008

  • Ghim, Young Sung;Oh, Hyun Sun;Kim, Jin Young;Woo, Jung-Hun;Chang, Young-Soo
    • Asian Journal of Atmospheric Environment
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    • v.10 no.3
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    • pp.146-155
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    • 2016
  • Spatial and temporal variations of mercury, including dry and wet deposition fluxes, were assessed over Northeast Asia, targeting the Yellow Sea, using meteorology and chemistry models. Four modeling periods, each representative of one of the four seasons, were selected. Modeling results captured general patterns and behaviors, and fell within similar ranges with respect to observations. However, temporal variations of mercury were not closely matched, possibly owing to the effects of localized emissions. Modeling results indicated that dry deposition is correlated with wind speed, while wet deposition is correlated with precipitation amount. Overall, the wet deposition flux of $66ng/m^2-day$ was about twice as large as the dry deposition flux of $32ng/m^2-day$, when averaged over the four modeling periods. Dry deposition occurred predominantly in the form of reactive gaseous mercury (RGM). In contrast, RGM accounted for only about two-thirds of wet deposition, while particulate mercury accounted for the remainder.

Preparation of Ultrafine TiCN Powders by Mg-reduction of Metallic Chlorides (마그네슘의 금속염화물 환원에 의한 초미립 TiCN 분말합성)

  • Lee, Dong-Won;Kim, Jin-Chun;Kim, Yong-Jin;Kim, Byoung-Kee
    • Journal of Powder Materials
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    • v.16 no.2
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    • pp.98-103
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    • 2009
  • The ultrafine titanium carbonitride particles ($TiC_{0.7}N_{0.3}$) below 100nm in mean size were successfully synthesized by Mg-thermal reduction process. The nanostructured sub-stoichiometric titanium carbide ($TiC_{0.7}$) particles were produced by the magnesium reduction at 1123K of gaseous $TiC_{l4}+xC_2Cl_4$ and the heat treatments in vacuum were performed for five hours to remove residual magnesium and magnesium chloride mixed with $TiC_{0.7}$. And final $TiC_{0.7}N_{0.3}$ phase was obtained by nitrification under normal $N_2$ gas at 1373K for 2 hrs. The purity of produced $TiC_{0.7}N_{0.3}$ particles was above 99.3% and the oxygen contents below 0.2 wt%. We investigated in particular the effects of the temperatures in vacuum treatment on the particle refinement of final product.