• Title/Summary/Keyword: Gaseous

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STUDY ON ATMOSPHERIC BEHAVIOR OF POLYCYCLIC AROMATIC HYDROCARBONS IN URBAN AREA, JEONJU

  • Kim, Hyoung-Seop;Kim, Jong-Guk;Kim, Kyoung-Soo
    • Environmental Engineering Research
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    • v.12 no.3
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    • pp.118-127
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    • 2007
  • Between June and November 2002, the atmospheric concentrations and dry deposition fluxes of polycyclic aromatic hydrocarbons (PAHs) in Chonju were measured four times each over five days. The total concentration of PAHs in ambient air was $84\;ng/m^3$, with about 90% existing in the vapor phase. Plots of log ($K_p$) vs. log (${P_L}^0$) indicated that PAHs partitioning was not in equilibrium and the particulate characteristics did not change with seasonal variations. The PAHs fluxes to a water surface sampler (WSS) and a dry deposition plate (DDP) were about 14.15 and $1.92\;{\mu}g/m^2/d$, respectively. The flux of the gaseous phase, acquired by subtracting the DDP from the WSS results, was about $12.23\;{\mu}g/m^2/d$. A considerable correlation was shown between the atmospheric concentrations and deposition fluxes in the gaseous phase, but not in the particulate phase, as the fluxes of the particulate phase were dependent on the physical velocity differences of the particulates based on the particle diameter.

Photodegradation of Gaseous Toluene Using Short-Wavelength UV/TiO2 and Treatment of Decomposition Products by Wet Scrubber (단파장자외선/TiO2 공정에 의한 가스상 톨루엔의 분해 및 습식세정장치에 의한 분해생성물의 제거)

  • Jeong, Ju-Young;Jurng, Jong-Soo
    • Journal of Environmental Science International
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    • v.16 no.4
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    • pp.433-440
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    • 2007
  • The photodegradation and by-products of the gaseous toluene with $TiO_2$ (P25) and short-wavelength UV ($UV_{254+185nm}$) radiation were studied. The toluene was decomposed and mineralized efficiently owed to the synergistic effect of photochemical oxidation in the gas phase and photocatalytic oxidation on the $TiO_2$ surface. The toluene by the $UV_{254+185nm}$ photoirradiated $TiO_2$ were mainly mineralized $CO_2$ and CO, but some water-soluble organic intermediates were also formed under severe reaction conditions. The ozone and secondary organic aerosol were produced as undesirable by-products. It was found that wet scrubber was useful as post-treatment to remove water-soluble organic intermediates. Excess ozone could be easily removed by means of a $MnO_2$ ozone-decomposition catalyst. It was also observed that the $MnO_2$ catalyst could decompose organic compounds by using oxygen reactive species formed in process of ozone decomposition.

Chromium Poisoning of Neodymium Nickelate (Nd2NiO4) Cathodes for Solid Oxide Fuel Cells

  • Lee, Kyoung Jin;Chung, Jae Hun;Lee, Min Jin;Hwang, Hae Jin
    • Journal of the Korean Ceramic Society
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    • v.56 no.2
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    • pp.160-166
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    • 2019
  • In this study, we investigated the long-term stability of Nd2NiO4 solid oxide fuel cell (SOFC) cathodes to evaluate their chromium poisoning tolerance. Symmetrical cells consisting of Nd2NiO4 electrodes and a yttria-stabilized zirconia electrolyte were fabricated and the cell potential and polarization resistance were measured at 850 ℃ in the presence of gaseous chromium species for 800 h. Up to 500 h of operation, the cell potential remained constant at 500 mA/㎠. However, it increased slightly over the operation duration of 550-800 h. No appreciable increase was observed in the polarization resistance of the Nd2NiO4 cathode during the entire operation of 800 h. Physicochemical examinations revealed that the gaseous chromium species did not form chromium-related contamination not only in the Nd2NiO4 cathode but also at the cathode/electrolyte interface. The results demonstrated that Nd2NiO4 is resistant to chromium poisoning, and hence is a potential alternative to standard perovskite cathodes.

How does the gas in a disk galaxy affect the evolution of a stellar bar?

  • Seo, Woo-Young;Kim, Woong-Tae
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.44.1-44.1
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    • 2017
  • In barred galaxies, gaseous structures such a nuclear ring and dust lanes are formed by a non-axisymmetric stellar bar potential, and the evolution of the stellar bar is influenced by mass inflows to the center and central star formation. To study how the presence of the gas affects the evolution of the stellar bar, we use the mesh-free hydrodynamics code GIZMO and run fully self-consistent three-dimensional simulations. To explore the evolution with differing initial conditions, we vary the fraction of the gas and stability of initial disks. In cases when the initial disk is stable with Q=1.2, the bar strength in the model with 5% gas is weaker than that in the gas-free model, while the bar with 10% gas does not form a bar. This suggests that the gaseous component is unfavorable to the bar formation dynamically. On the other hand, in models with relatively unstable disk with Q=1.0, the presence of gas helps form a bar: the bar forms more rapidly and strongly as the gas fraction increases. This is because the unable disks form stars vigorously, which in turn cools down the stellar disk by adding newly-created stars with low velocity dispersion. However, the central mass concentration also quickly increases as the bar grows in these unstable models, resulting in fast bar dissolution in gas rich models. We will discuss our results in comparison with previous work.

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Optimization of Middle Pressure and Bypass Mass Flow Rate in Cryogenic Refrigeration Cascade Cycle (초저온 케스케이드 냉동사이클의 중간압력 및 바이패스 유량 최적화)

  • Oh, S.T.;Choi, W.J.;Lee, H.S.;Yoon, J.I.;Yoo, S.I.;Choi, K.H.;Lee, S.G.
    • Journal of Power System Engineering
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    • v.14 no.2
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    • pp.28-33
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    • 2010
  • In this research, cascade liquefaction process was simulated using two-staged direct expansion with inter-cooler. Evaporated gaseous refrigerant which has low pressure and temperature from the inter-cooler is mixed with gaseous refrigerant from outlet of 1st compressor, and flows into 2nd compressor. Therefore this prevents superheating compression. Compressor work of process which includes inter-cooler to all cycles shows the lowest value of 338.68 MW and it is lower 16.34% than that of basic process. Refrigeration capacity shows decreasing tendency as applied inter-cooler and that of process which includes inter-cooler to all cycles shows the lowest value of 449 MW. COP was increased when the inter-cooler was applied, and process which includes inter-cooler to all cycles shows highest value of 1.33. It shows that COP was increased because decrement of compressor work by applying inter-cooler was higher than decrement of refrigeration capacity.

Highly Sensitive Colorimetric Formaldehyde Gas Sensors using Nylon Sheet and Dye (나일론 시트와 염료를 이용한 고감도 색변환 포름알데히드 가스 센서)

  • Jung, Suenghwa;Cho, Yeong Beom;Kim, Yong Shin
    • Journal of Sensor Science and Technology
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    • v.26 no.6
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    • pp.420-426
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    • 2017
  • A colorimetric sensor was investigated to achieve a low-cost warning device for harmful gaseous formaldehyde (HCHO). The sensor is based on selective reactions between hydroxylamine sulfate and HCHO, leading to the production of sulfuric acid. The produced acid results in color-changing response through the acid-base reaction with dye molecules impregnated on a solid membrane substrate. For attaining this purpose, sensors were fabricated by drop-casting a dye solution prepared using different pH indicators on various commercially available polymer sheets, and their colorimetric responses were evaluated in terms of sensitivity and reliability. The colorimetric sensor using bromophenol blue (BPB) and nylon sheet was found to exhibit the best performance in HCHO detection. An initial bluish green of a sensor was changed to yellow when exposed to gaseous formaldehyde. The color change was recorded using an office scanner and further analyzed in term of RGB distance for quantifying sensor's response at different HCHO(g) concentrations. It exhibited a recognizable colorimetric response even at 50 ppb, being lower than WHO's standard of 80 ppb. In addition, the sensor was found to have quite good selectivity in HCHO detection under the presence of common volatile organic compounds such as ethanol, toluene, and hexane.

Diffusion and Disperision of Injected $CO_2$Gas Into the $N_2$Gas Flow ($N_2$기체의 흐름에 주입된 $CO_2$기체의 확산 및 분산)

  • 김유식;안대영
    • Fire Science and Engineering
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    • v.16 no.3
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    • pp.1-7
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    • 2002
  • Diffusion and dispersion of injected $CO_2$gas into the $N_2$ gas flow are complex. In the packed column with porous particles the axial dispersion and the extra-particle mass transport as well as the intra-particle mass transport are involved. The pulse spreads by stationary diffusion during the period of arrested flow. Hence, the effect of axial dispersion, and of entrance and exit, as well as that of intraparticle convection should be eliminated during the period. The effective diffusivity was determined experimentally by using the gas chromatography, which is to arrest the gas flow during the period after injecting the pulse. This experiment method hasn't been used often in the field. Effective diffusivities are raised with temperature increasing, and it is quite satisfied com-pared to literature values. In this study, the calculated data of gaseous chemical for extinguish fires could be helpful to appreciate several physical phenomenons. Also, it could be expected that, the calculated data of this study might be very useful for development of excellent gaseous chemical for extinguish fires and improvement of its efficiency.

Gas Fire Accident Cause Survey Study (가스화재사고 원인조사 연구(LP가스를 중심으로))

  • Kim, Young-Cheol;Cha, Jong-Ho
    • Journal of Korean Institute of Fire Investigation
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    • v.11 no.1
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    • pp.1-8
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    • 2008
  • The purpose of this paper is to report gas fire accident based on classification of the major gas fire causes (including handling mistakes, inferior goods, etc.), fire classifications (fire, explosion, leakages, etc.), damage levels(1st, 2nd, 3rd, 4th grade levels), casualties (death, serious wound, slight injury) since gas fire has been generated according to growth of gaseous fuel consumption on home and enterprises with various accident causes. Among gaseous fuels, LPG facility can be c1assified as gas container, pressure regulator, gas hose, interim valve, combustion port. Any fire or any explosion can be caused from handling mistakes, inferior goods on each parts as stated above. Exact gas fire causes shall be identified based on previous case studies on similar fires with consideration of lesson learns.

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The Effect of the Excess Air Factor on the Emission Characteristics of the SI Engine Fueled with Gasoline-Ethanol and Hydrogen Enriched Gas (공기과잉률의 변화가 에탄올 및 수소농후가스 혼합연료 기관의 배기 특성에 미치는 영향)

  • Park, Cheol-Woong;Choi, Young;Oh, Seung-Mook;Kim, Chang-Gi;Lim, Gi-Hun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.5
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    • pp.334-342
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    • 2009
  • Trends in the automotive market require the application of new engine technologies, which allows for the use of different types of fuel. Since ethanol is a renewable source of energy and has lower $CO_2$ emissions than gasoline, ethanol produced from biomass is expected to be used more frequently as an alternative fuel. It is recognized that for spark ignition (SI) engines, ethanol has the advantages of high octane number and high combustion speed. Due to the disadvantages of ethanol, it may cause extra wear and corrosion of electric fuel pumps. On-board hydrogen production out of ethanol is an alternative plan. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency and emissions. The combustion characteristics with hydrogen-enriched gaseous fuel from ethanol are also examined. As a result, thermal efficiency increase compared to gasoline. Also, reductions in $CO_2$, NOx, and THC combustion products for ethanol vs. gasoline are described.

Effect of Level of Leucaena leucocephala in the Diets of Jamunapari Goats on carbon Nitrogen and Energy Balances

  • Haque, N.;Khan, M.Y.;Murarilal, Murarilal
    • Asian-Australasian Journal of Animal Sciences
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    • v.10 no.5
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    • pp.455-459
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    • 1997
  • Fifteen intact male Jamunapari goats, average body weight $22.0{\pm}1.18kg$ were divided into three groups of 5 animals in each to investigate the effects of feeding leucaena on energy retention and distribution of retained energy. Leucaena leaves and twigs provided 0%, 25% and 50% of CP in the rations of animals in $L_1$ (control), $L_2$ and $L_3$ groups, respectively. Energy balances were determined in an open circuit respiration chamber from gaseous exchange and nitrogen carbon balances. Energy retentions calculated from gaseous exchange data were 181.6, 190.0 and 172.8 kJ/kg $W^{0.75}/d$ and from carbon-nitrogen balances were 178.2, 199.5 and 171.1 kJ/kg $W^{0.75}/d$ in $L_1$, $L_2$ and $L_3$ groups, respectively. No significant difference was observed among the groups in both the methods. The retention of nitrogen and energy in the form of protein was similar in different treatment groups. Similarly, no significant effect was observed on energy retention in the form of fat and total energy retention due to incorporation of leucaena in the diets.