• 제목/요약/키워드: Gaseous

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Effect of Moisture in Arc Welding Electrode on Mechanical Properties of Weld Metal (아아크 용접봉 피복제 의 함수량 이 용접금속 의 기계적 성질에 미치는 영향)

  • 윤희만;김연식;박종은
    • Journal of Welding and Joining
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    • v.2 no.1
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    • pp.30-40
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    • 1984
  • Moisture content in the coating of an electrode is known to cause defects such as porosities, fish eyes and cracks in the weld metal, however, quantitative relationship between them is not clearly understood. In this study widely consumed and the most common type of arc welding rods such as ilmenite and low hydrogen type were chosen for the investigation, and attempts were made to correlate the relationship between the mechanical properties and gas contents when welding was carried out with electrodes of various moisture contents. As the relative humidity changed from 70% to 92%, it was determined that moisture content to reach saturation was in the range of 0.6~6.8%. As the moisture content in the electrode coating was increased, the amount of gaseous components (H, O, N) in the weld metal was accordingly increased, especially diffusible hydrogen showed prominent effect, i.e. it increased proportionally to the increase of the moisture content. The mechanical properties of the weld metal was observed to become more inferior as the diffusible hydrogen was greater. It was determined for ilmenite type of electrode that the increase of hydrogen content was approximately 1.8ml per unit weight percent increase of moisture and also tensile strength resulted lowering from $45.3kg/\textrm{mm}^2$ to $42.7kg/\textrm{mm}^2$ as moisture content increased from 0.7% to 6.8%. For low hydrogen type the increase of the hyrogen was about 2.4ml per unit percent of moisture and tensile strength decreased from $63.0kg/\textrm{mm}^2$ to $53.8kg/\textrm{mm}^2$ particularly in the region of moisture content 0.1~4.2%.

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Modelling of effluent and GHGs for wastewater treatment plants using by MS Excel simulator(PKES) (MS Excel 시뮬레이터(PKES)를 이용한 하수처리장 유출수 및 온실가스 모델링)

  • Bin, Jung-In;Lee, Byung-Hun
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.6
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    • pp.735-745
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    • 2014
  • This paper presents PKES(PuKyung -Excel based Simulator) for WWTPs(wastewater treatment plants) by using MS Excel and VBA(Visual Basic for Application). PKES is a user-friendly simulator for the design and optimization of the whole plant including biological and physico-chemical processes for the wastewater and sludge treatment. PKES calculates the performance under steady or dynamic state and allows changing the mathematical model by the user. Mathematical model implemented in PKES is a improved integration model based on ASM2d and ADM1 for simulation of AS(activated sludge) and AD(anaerobic digestion). Gaseous components of $N_2$, $N_2O$, $CO_2$ and $CH_4$ are added for estimation of GHGs(greenhouse gases) emission. The simulation results for comparison between PKES and Aquasim(EAWAG) showed about the same effluent concentrations. As a result of verification using by measured data of BOD, TSS, TN and TP for 2 years of operation, calculated effluent concentrations were similar to measured effluent concentrations. The values of average RMSE(root mean square error) were 1.9, 0.8, 1.6 and 0.2 mg/L for BOD, TSS, TN and TP, respectively. Total GHGs emission of WWTP calculated by PKES was 138.5 ton-$CO_2$/day and GHGs emissions of $N_2O$, $CO_2$ and $CH_4$ were calculated at 21.7, 28.9 and 87.9 ton-$CO_2$/day, respectively. GHGs emission of activated sludge was 32.5 % and that of anaerobic digestion was 67.5 %.

Preparation of Ultrafine C/N Controled TiCxNy Powders by Magnesium Reduction (마그네슘환원에 의한 C/N 조성제어 초미립 TiCxNy 분말 합성)

  • Lee, Dong-Won;Kim, Byoung-Kee;Yun, Jung-Yeul;Yu, Ji-Hoon;Kim, Yong-Jin
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.142-147
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    • 2010
  • The ultrafine titanium carbonitride ($TiC_xN_y$) particles below 100 nm in mean size, including various carbon and nitrogen contents (x=0.55~0.9, y=0.1~0.5), were successfully synthesized by new Mg-thermal reduction process. Nanostructured sub-stoichiometric titanium carbide ($TiC_x$) particles were initially produced by the magnesium reduction of gaseous $TiCl_4+x/2C_2Cl_4$ at $890^{\circ}C$ and post heat treatments in vacuum were performed for 2 hrs to remove residual magnesium and magnesium chloride mixed with $TiC_x$. Finally, well C/N-controled $TiC_xN_y$ phases were successfully produced by nitrification heat treatment under normal $N_2$ gas atmosphere at $1150^{\circ}C$ for 2 hrs. The values of purity, mean particle size and oxygen content of produced particles were about 99.3%, 100 nm and 0.2 wt.%, respectively.

중수로 환형기체 계통의 방사능 inventory 평가

  • Kim, Jin-Tae;Kang, Deok-Won;Son, Uk
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.90-95
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    • 2003
  • Chemical management of annulus gas system is carried out for the purpose of ensuring the safety and reliability of the system via securing the integrity of the system, detecting the D$_2$O in-leakage of coolant and/or moderator, and reducing the radiation dose. Since the quality of CO_2$ gas, which is used as a filling gas for annulus gas system at CANDU plants, has a propound effect on the integrity of the system material and the radiation dose, CO_2$ gas of high quality is needed. If the quality of CO_2$ gas does not meet the specification, it may give rise to undesirable effect not only on the annulus gas system, but also on the environment due to the production of radioactive nuclei. Therefore, it is very important to check the impurities of CO_2$ gas. Based on this background, the inventories of C-14 and Ar-41 in CO_2$ gas that is supplied as annulus gas were estimated using the data on concentrations of the impurities of $CO_2$ such as C, N_2$ and Ar. The results of this study is expect to give useful information on optimization of CO_2$ impurities maintenance and management of gaseous radioactive wastes produced at CANDU plants.

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Effect of Gallium Addition to HZSM-5 on Catalytic Pyrolysis of an LDPE-LLDPE-EVA Copolymer Mixture (HZSM-5를 이용한 LDPE-LLDPE-EVA공중합체 혼합물의 접촉 열분해 반응에 미치는 Gallium 첨가 효과)

  • Jeon, Jong-Ki;Kim, Hyunjin;Kim, Min Ji;Kang, Tae-Won;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.18 no.1
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    • pp.58-63
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    • 2007
  • The aim of the present work is to study the effect of gallium addition to HZSM-5 on recovery rates of gaseous and liquid products and carbon number distribution in the catalytic cracking of a polymer mixture, LDPE, LLDPE, and EVA copolymer, with a composition similar to that found in real agricultural film wastes. Ga/HZSM-5 system produced a larger amount of aromatic hydrocarbons than HZSM-5. The yield of aromatic compound in vapor phase contact was higher than that in liquid phase contact. The yield of aromatic compound increased with the amount of catalyst and with the reaction temperature of catalyst bed. The effect of gallium addition on the carbon number distribution was not great.

The Effect of Oxygen in Low Temperature SCR over Mn/$TiO_2$ Catalyst (Mn/$TiO_2$ 촉매를 이용한 저온 SCR 반응에서 산소의 영향)

  • Lee, Sang Moon;Choi, Hyun Jin;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.119-123
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    • 2012
  • This study presents the effect of oxygen on the $NH_3$ selective catalytic reduction (SCR) by Mn/$TiO_2$ catalyst. The lattice oxygen of catalysts is participate in the low temperature SCR, and the gaseous oxygen directly takes part in the rexoidtion of reduced catalyst. These redox properties of oxygen an play important role in SCR activity and the available capability of lattice oxygen depends on the manganese oxidation state of the catalyst surface. $MnO_2$ species has a higher redox property than that of $Mn_2O_3$ species on deposited $TiO_2$ surface and these manganese oxide states strongly depend on the $TiO_2$ surface area.

Syntheses and Mechanical Properties of Quaternary Cr-Si-O-N Coatings by Hybrid Coating System (하이브리드 코팅시스템에 의한 Cr-Si-O-N 코팅막 합성 및 기계적 성질)

  • Lee, Jeong-Doo;Wang, Qi Min;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.5
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    • pp.238-242
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    • 2010
  • In the present work, the influence of oxide on the Cr-Si-N coatings was investigated for the Cr-Si-O-N coatings on AISI 304 and Si wafer deposited by hybrid system, which combines the DC magnetron sputtering technique and arc ion plating (AIP) using Cr and Si target in an $Ar/N_2/O_2$ gaseous mixture. As the O content in the Cr-Si-N coatings increased, the diffraction patterns of the Cr-Si-O-N coatings showed CrN and $Cr_2O_3$ phases. However, as the O content increased to 28.8 at.%, diffraction peak of $Cr_2O_3$ was disappeared in the Cr-Si-O-N coating. The $d_{200}$ value was decreased with increasing of O content. The average grain size increased from about 40 nm to 65 nm as the O content increased. The maximum micro-hardness of the Cr-Si-O-N coating was obtained 4507 Hk at the O content of 24.8 at.%. The average friction coefficient of the Cr-Si-O-N coatings was gradually decreased by increasing the O content and the average friction coefficient decreased from 0.37 to 0.25 by increasing the O content. These results indicated that amorphous phase was increased in the Cr-Si-O-N coatings by increasing of O content.

Some Insights into the Basic QA/QC for the Greenhouse Gas Analysis: Methane and Carbon Dioxide (온실가스 기기분석의 정도관리를 위한 고려사항 연구 - CH4과 CO2를 중심으로 -)

  • Jeong, Jae-Hak;Lim, Ho-Soo;Kim, Ki-Hyun;Bae, Wi-Sup;Jeon, Eui-Chan
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.712-718
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    • 2006
  • In order to investigate the analytical uncertainties associated with sampling and analysis of major greenhouse gaseous pollutants(carbon dioxide and methane), we attempted to quantify their adsorptive loss due to the contact with the container wall(such as Tedlar bag and vial). Using the GC/FID method, some basic experimental parameters(such as reproducibility and method detection limit) have been evaluated as part of the essential QA/QC The reproducibilities of carbon dioxide and methane were estimated as 2.02 and 0.2%, respectively. In addition, method detection limits were measured as 0.61 and 0.06 ng, respectively. A test of sample loss rate has also been made for Tedlar bag and vial by assessing the absolute amount of sample loss on the wall. By transferring the samples contained in Tedlar bag to various sizes of Tedlar bags, we measured differences in the absolute loss quantity due to such transfer. In addition, we also examined such loss mechanism as a function of elapsed time and light penetration rate for vial. As results, carbon dioxide and methane have shown about 2% of sample loss due to such contact. It is also noticed that the amount of loss with vial surface is lower than that of Tedlar bag. Therefore, field collection of greenhouse gases using various container types should be made more cautiously to minimize the possibility of sample loss and bias related to such loss.

Research Trends for Performance, Safety, and Comfort Evaluation of Agricultural Tractors: A Review

  • Kabir, Md. Shaha Nur;Ryu, Myong-Jin;Chung, Sun-Ok;Kim, Yong-Joo;Choi, Chang-Hyun;Hong, Soon-Jung;Sung, Je-Hoon
    • Journal of Biosystems Engineering
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    • v.39 no.1
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    • pp.21-33
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    • 2014
  • Background: Significant technological development and changes happened in the tractor industries. Contrariwise, the test procedures of the major standard development organizations (SDO's) remained unchanged or with a little modification over the years, demanding new tractor test standards or improvement of existing ones for tractor performance, safety, and comfort. Purpose: This study focuses on reviewing the research trends regarding performance, safety and comfort evaluation of agricultural tractors. Based on this review, few recommendations were proposed to revise or improve the current test standards. Review: Tractor power take-off power test using the DC electric dynamometer reduced human error in the testing process and increased the accuracy of the test results. GPS signals were used to determine acceleration and converted into torque. High capacity double extended octagonal ring dynamometer has been designed to measure drawbar forces. Numerical optimization methodology has been used to design three-point hitch. Numerous technologies, driving strategies, and transmission characteristics are being considered for reducing emissions of gaseous and particulate pollutants. Engine emission control technology standards need to be revised to meet the exhaust regulations for agricultural tractors. Finite Element Analysis (FEA) program has been used to design Roll-Over Protective Structures (ROPS). Program and methodology has been presented for testing tractor brake systems. Whole-body vibration emission levels have been found to be very dependent upon the nature of field operation performed, and the test track techniques required development/adaptation to improve their suitability during standardized assessment. Emphasizes should be given to improve visibility and thermal environment inside the cab for tractor operator. Tractors need to be evaluated under electromagnetic compatibility test conditions due to large growing of electronic devices. Research trends reviewed in this paper can be considered for possible revision or improvement of tractor performance, safety, and comfort test standards.

Design and Performance Tests of a Cryogenic Blower for a Thermal Vacuum Chamber (열진공 챔버용 극저온 블로워 설계 및 성능평가)

  • Seo, Heejun;Cho, Hyokjin;Park, Sungwook;Moon, Gueewon;Huh, Hwanil
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.11
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    • pp.1008-1015
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    • 2015
  • Thermal vacuum test should be performed prior to launch to verify satellites' functionality in extremely cold/hot temperatures and vacuum conditions. A thermal vacuum chamber used to perform the thermal vacuum tests of a satellite system and its components. A cryogenic blower is a core component of the gaseous nitrogen (GN2) closed loop thermal control system for thermal vacuum chambers. A final goal of this research is development of cryogenic blower. Design requirements of a blower are 150 CFM flow rate, 0.5 bara pressure difference, hot and cold temperatures. This paper describes the performance analysis of impeller by 1D, CFD commercial software, the design of the thermal protection interface between the driving part and the fluid part. The performance of the cryogenic blower is confirmed by test at the standard air condition and is verified by on the thermal vacuum chamber at the real operating condition.