• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.2
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• pp.1-9
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• 2010

LES(Large eddy simulation) of breakup and droplet atomization of a liquid jet into cross turbulent flow was performed. Two phase flow of gas and liquid phases were modeled by the mixed numerical scheme of both Eulerian and Lagrangian methods for gas and liquid droplet respectively. The breakup process of a liquid column and droplets was observed by implementing the blob-KH wave breakup model. The penetration depth into cross flow was comparable with experimental data for several variants of the liquid-gas momentum flux ratio by varying liquid injection velocity. SMD(Sauter Mean Diameter) distribution downstream of jet was analyzed.

• Korean Chemical Engineering Research
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• v.56 no.2
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• pp.186-190
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• 2018

For the first time, the characteristics of solid circulation rate ($G_S$) were investigated in a three-phase (gas-liquid-solid) viscous circulating fluidized bed (TPCFB). The solid circulation rate was controlled separately by adjusting the experimental apparatus as well as operating variables. Effects of primary and secondary liquid velocities ($U_{L1}$ and $U_{L2}$), gas velocity ($U_G$), particle size ($d_p$), height of particles piled up in the solid recycle device (h), and viscosity of continuous liquid media (${\mu}_L$) on the value of $G_S$ were determined. The experimental results showed that the value of $G_S$ increased with increases in the values of $U_{L1}$, $U_{L2}$, h and ${\mu}_L$, while it decreased with increasing $U_G$ and $d_p$ in TPCFBs with viscous liquid media. The values of $G_S$ were well correlated in terms of dimensionless groups within this experimental conditions.

• Bulletin of the Korean Chemical Society
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• v.16 no.5
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• pp.410-416
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• 1995

The proton transfer energies of gas phase glycine and alanine and those of hydrated glycine and alanine were calculated both with Hartree-Fock and $M{\Phi}ller-Plesset$ ab initio molecular orbital (MO) calculations with 6-31G** basis set. The transition states of the proton transfer of gas phase glycine was also investigated. For zwitterions, both for glycine and alanine, the water bound to -NH3+ site stabilize the complex more compared with the water bound to -CO2-. The proton transfer energy, ΔEpt, of glycine, alanine, mono-hydrated glycine, mono-hydrated alanine, di-hydrated glycine and di-hydrated alanine were obtained as 30.78 (MP2: 22.57), 31.43, 23.99 (MP2: 17.00), 24.98, 22.87, and 25.63 kcal/mol, respectively. The activation energy for proton transfer from neutral (Nt) glycine to zwitterion (Zw) glycine, Ea, was obtained as 16.13 kcal/mol and that for reverse process, Ear, was obtained as 0.85 kcal/mol. Since the transition state of the proton transfer of gas phase glycine locate near the glycine zwitterion on the potential energy surface and the shape of the potential well of the zwitterion is shallow, the zwitterion easily changed to neutral glycine through the proton transfer.

• Food Science of Animal Resources
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• v.44 no.4
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• pp.934-950
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• 2024

This study addresses the prevalent issue of meat species authentication and adulteration through a chemometrics-based approach, crucial for upholding public health and ensuring a fair marketplace. Volatile compounds were extracted and analyzed using headspace-solid-phase-microextraction-gas chromatography-mass spectrometry. Adulterated meat samples were effectively identified through principal component analysis (PCA) and partial least square-discriminant analysis (PLS-DA). Through variable importance in projection scores and a Random Forest test, 11 key compounds, including nonanal, octanal, hexadecanal, benzaldehyde, 1-octanol, hexanoic acid, heptanoic acid, octanoic acid, and 2-acetylpyrrole for beef, and hexanal and 1-octen-3-ol for pork, were robustly identified as biomarkers. These compounds exhibited a discernible trend in adulterated samples based on adulteration ratios, evident in a heatmap. Notably, lipid degradation compounds strongly influenced meat discrimination. PCA and PLS-DA yielded significant sample separation, with the first two components capturing 80% and 72.1% of total variance, respectively. This technique could be a reliable method for detecting meat adulteration in cooked meat.

• Bulletin of the Korean Chemical Society
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• v.34 no.9
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• pp.2691-2696
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• 2013

The electronic cigarette (E-cigarette) is a battery-powered device that aerosolizes nicotine so that it is readily delivered into the respiratory tract. The analytical data regarding the substances present in E-cigarettes are very limited. The aim of this study was to measure the concentration of aldehydes-formaldehyde (FA), acetaldehyde (AA) and, acrolein (AL)-in 225 replacement liquid brands from 17 E-cigarette shops sold in the Republic of Korea by headspace solid-phase micro extraction and gas chromatography-mass spectrometry (HS-SPME GC-MS). The concentration range of FA and AA was 0.02-10.09 mg/L (mean = 2.16 mg/L, detected in 207 of 225 samples) and 0.10-15.63 mg/L (mean = 4.98 mg/L, detected in all samples), respectively. AL was not detected in any of 225 replacement liquids. FA and AA were originally present in almost all replacement liquids of electronic cigarettes.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.135-137
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• 2014

Excess enthalpy flame propagating an porous inert medium, which recirculate exhaust heat to the upstream cold mixture, is theoretically analyzed. Using the activation-energy asymptotics, the flame structure is divided into the thin reaction and the gas-phase preheat zone, as is traditionally done. Ahead and behind of the two, there exist an outer preheat zone, where heat is convectively transferred from solid to gas, and a downstream re-equilibrium zone, where thermal equilibrium between phases is established. Asymptotic solutions of species and energy equations in each zone are obtained and then matched to each other, and finally the mass burning rate is obtained as a function of the flame propagation velocity with respect to the solid phase and physical properties of gas and solid.

• Transactions of the Korean Society of Mechanical Engineers
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• v.6 no.4
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• pp.331-340
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• 1982

Numerical analysis is made on the turbulent heat transfer with suspension of solid particles in circular tube with constant heat flux. The mean motion of suspending particles in mixture is treated as the secondary gas flow with virtual density and viscosity. Our modeling of turbulent transport phenomena of suspension flow is based on this assumption and conventional mixing length theory. This paper gives the evidence that the mixing length models can be extended to close the governing equations for two phase turbulent flow with solid boundary at a first order level. Results on Nusselt numbers obtained by analytical treatments are compared with available experimental data and discussed. They suggest that the most important parameters of two phase turbulent heat transfer phenomena are relative particle diameter to pipe diameter, gas-solid loading ratio, and specific heat of suspending material.

• Journal of ILASS-Korea
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• v.16 no.1
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• pp.37-43
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• 2011

The present study conducted computational simulation for multiphase flow in the flame spray coating process with commercially available Ni-Cr powders. The flows in a flame spray gun is characterized by very complex phenomena including combustion, turbulent flows, and convective and radiative heat transfer. In this study, we used a commercial computational fluid dynamics (CFD) code of Fluent (ver. 6.3.26) to predict gas dynamics involving combustion, gas and particle temperature distributions, and multi-dimensional particle trajectories with the use of the discrete phase model (DPM). We also examined the effect of particle size on the flame spray process. It was found that particle velocity and gas temperature decreased rapidly in the radial direction, and they were substantially affected by the particle size.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.11
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• pp.1604-1611
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• 2003

The experimental investigation of a coal splitter used in the 500㎿(e) boilers of fossil power plant is carried out to validate the design criteria. To predict air flow and the amount of particles at the exit, velocity and the weight of particles are measured on test planes using the coal splitter model with two-dimensional phase doppler particle analyzer and the glass fiber filter. It is found that the position of guide plate influences significantly both flow rates of gas and particle at the exit. Gas flow rate was a linear function of the guide plate, whereas particle flow rate was a exponential function of it.

• Journal of Power System Engineering
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• v.10 no.2
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• pp.16-21
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• 2006

On this study, numerical analysis was performed for the 3 dimensional flow field of gas and particle phase for axial inlet cyclone, a part of dust collector. We applied FVM to visualize the gas phase. The flow was solved using ${\kappa}-{\varepsilon}$ turbulence model. The major parameters considered in this study were helical guide vane, inner diameter, length. Particle trajectory calculations were performed for the particle sizes of $5{\mu}m{\sim}75{\mu}m$. The distribution curve of particle sizes was made of Rosin-Rammler function. The simulation results show various gas flows, particle trajectories on numerical models.