• 제목/요약/키워드: Gas-Phase

검색결과 3,261건 처리시간 0.031초

Sol-Gel 방법으로 제작된 SnO2 seed layer를 적용한 고반응성 ZnO 가스 센서 (High-sensitivity ZnO gas Sensor with a Sol-gel-processed SnO2 Seed Layer)

  • 김상우;박소영;한태희;이세형;한예지;이문석
    • 센서학회지
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    • 제29권6호
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    • pp.420-426
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    • 2020
  • A metal oxide semiconductor gas sensor is operated by measuring the changes in resistance that occur on the surface of nanostructures for gas detection. ZnO, which is an n-type metal oxide semiconductor, is widely used as a gas sensor material owing to its high sensitivity. Various ZnO nanostructures in gas sensors have been studied with the aim of improving surface reactions. In the present study, the sol-gel and vapor phase growth techniques were used to fabricate nanostructures to improve the sensitivity, response, and recovery rate for gas sensing. The sol-gel method was used to synthesize SnO2 nanoparticles, which were used as the seed layer. The nanoparticles size was controlled by regulating the process parameters of the solution, such as the pH of the solution, the type and amount of solvent. As a result, the SnO2 seed layer suppressed the aggregation of the nanostructures, thereby interrupting gas diffusion. The ZnO nanostructures with a sol-gel processed SnO2 seed layer had larger specific surface area and high sensitivity. The gas response and recovery rate were 1-7 min faster than the gas sensor without the sol-gel process. The gas response increased 4-24 times compared to that of the gas sensor without the sol-gel method.

Gas Bubble Driven Circulation Systems에서의 이상유동 특성의 시뮬레이션 (A Simulation on the Two-Phase Flow Characteristics in Gas Bubble Driven Circulation Systems)

  • 최청렬
    • 한국시뮬레이션학회논문지
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    • 제7권2호
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    • pp.17-32
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    • 1998
  • The flow fields in Gas Bubble Driven Circulation Systems were numerically analyzed. In various gas flow rate and bubble size, the flow characteristics were predicted. Eulerian-Eulerian approach was used for the formulation of both the continuous and dispersed phases. The modification of the general purpose computer program PHOENICS code was employed to predict the mean flow fields, turbulent characteristics, gas dispersion, volume fraction. The predicted shows very satisfactory agreement with experimental results for all regions of ladle. The results are of interest in the design and operation of wide variety of material processing.

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Aqeous Neutralizer as Reactive Solvents for Odorous Ammonia Removal

  • Park, Young-G.
    • Environmental Engineering Research
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    • 제13권3호
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    • pp.119-124
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    • 2008
  • Ammonia is an inorganic compound that may cause severe odor problem. In this study the effectiveness of applying natural neutralizer to destroy and remove the odor-causing compound from gas streams was studied. Experimental result evaluated with a bench-scale apparatus via the neutralization of gas phase. This indicates that the natural neutralization depends on the gas concentration, gas residence time, temperature and pH. Removal efficiency of ammonia from gas stream was achieved by 95% using theconvection in the packed bed. This study proved the chemical neutralization technology was effective for controlling inorganic odor-causing compound.

Palladium-based Electrical and Optical Hydrogen Gas Sensors

  • Jinwoo, Lee;Minah, Seo
    • 센서학회지
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    • 제31권6호
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    • pp.397-402
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    • 2022
  • In this short review, we explore the recent progress in metal-based gas-sensing techniques. The strong interaction between the metal films and hydrogen gas can be considered to play a considerably important role in the gas-sensing technique. The physical and chemical reactions in Pd-Pd hydride systems were studied in terms of the phase transition and lattice expansion of the metals. Two types of represented detection, electrical and optical, were introduced and discussed along with their advantages.

고내구성 고감도 강산감지기능 초소수성 색소의 특성 및 응용 (Characteristics and Application of the Highly-Durable and Highly-Sensitive Super Hydrophobic Acid-gas Sensing Dye)

  • 김태경;이선애
    • 한국염색가공학회지
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    • 제27권2호
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    • pp.105-112
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    • 2015
  • In order to detect gas phase strong acid on fabrics, a hexyl-substituted monoazo yellow dye, which was the modified form of a conventional pH-indicating dye, Methyl Yellow, was studied in view of acid-gas sensing properties and its fastness. The dye was printed on polypropylene non-wovens for protective coveralls and examined under various conditions of strong acid such as hydrochloric acid. The dye showed color change from yellow to red on exposure to gas phase hydrochloric acid as low concentration as 1~3 ppm very instantly. Considering reuse of the dye-printed non-wovens, the repeatability of color change was tested on the same sample for 50 repeats and 100 days. The acid-gas sensing function was maintained almost the same level of initial performance. The color fastness of the dye on polypropylene non-wovens was very good showing higher than ratings 4 except for 3~4 to rubbing under wet condition.

Study on self-pulsation characteristics of gas centered shear coaxial injector for supercavitating underwater propulsion system

  • Yoon, Jung-Soo;Chung, Jae-Mook;Yoon, Young-Bin
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제3권4호
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    • pp.286-292
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    • 2011
  • In order to design a shear coaxial injector of solid particles for underwater propulsion system, basic experiments on gas-liquid shear coaxial injector are necessary. In the gas-liquid coaxial injector self-pulsation usually occurs with an intense scream. When self-pulsation occurs, mass flow rate oscillation and intense scream are detected by the interactions between the liquid and gas phase. Self-pulsation must be suppressed since this oscillation may cause combustion instabilities. Considerable research has been conducted on self-pulsation characteristics, but these researches are conducted in swirl coaxial injector. The main objective of this research is to understand the characteristics of self-pulsation in shear coaxial injector and reveal the mechanism of the phenomenon. Toward this object, self-pulsation frequency and spray patterns are measured by laser diagnostics and indirect photography. The self-pulsation characteristics of shear coaxial injector are studied with various injection conditions, such as the pressure drop of liquid and gas phase, and recess ratio. It was found that the frequency of the self-pulsation is proportional to the liquid and gas Reynolds number, and proportional to the L/d.

진공 열 플라즈마 용사공정을 통한 NiTiZrSiSn 벌크 비정질 코팅 형성 (Vacuum Plasma Sprayed NiTiZrSiSn Coating)

  • 윤상훈;김준섭;김수기;이창희
    • Journal of Welding and Joining
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    • 제25권4호
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    • pp.42-48
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    • 2007
  • An inert gas atomized NiTiZrSiSn bulk metallic glass feedstock was sprayed onto the copper plate using vacuum plasma spraying process. In order to change the in-flight particle energy, that is, thermal energy, the hydrogen gas flow rate in plasma gas mixture was increased at the constant flow rate of argon gas. Coating and single pass spraying bead were produced with the least feeding rate. Regardless of the plasma gas composition, fully melted through unmelted particle could be observed on the overlay coating. However, the frequency of the unmelted particle number density was increased with the decrease of the hydrogen gas flow rate. The amorphous phase fraction within coating was also affected by the number density of the unmelted particle.

가스 유입량이 기상이동법으로 금 나노박막위에 성장된 산화아연 입자에 미치는 영향 (Influence of gas flow on structural and optical properties of ZnO submicron particles grown on Au nano thin films by vapor phase transport)

  • 김소아람;남기웅;김민수;박형길;윤현식;임재영
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.211-212
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    • 2012
  • ZnO submicron particles were grown on Au-catalyzed Si substrate by a vapor phase transport (VPT) growth process under different mixture gas ratio at growth temperature of $900^{\circ}C$. The structural and optical properties of the ZnO submicron particles were investigated by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and photoluminescence (PL). The ZnO submicron particles could be clustered with the $O_2/Ar$ mixture gas ratio(%) higher than 10%, and it was mainly determined by the gas ambient. Particularly, when the $O_2/Ar$ mixture gas ratio was 30%, it was observed the ZnO submicron particles with diameters in the range of 125 to 500 nm and the narrowest full width at half maximum (FWHM) of XRD and PL spectra with $0.121^{\circ}$ and 92 meV, respectively. It was found that the structural and optical properties of the ZnO submicron particles were improved with increasing the $O_2/Ar$ mixture gas ratio through the XRD and PL spectra.

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스테인리스강의 가스질화에 미치는 열처리 조건의 영향에 관한 연구 (Effect of Heat Treatment Characteristic on the Gas Nitriding of Stainless Steels)

  • 김한군;황길수;선철곤
    • 열처리공학회지
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    • 제16권2호
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    • pp.78-82
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    • 2003
  • Nitrided compound layer and diffusion layer structure were observed by SEM. The compound layer and the constituent of nitrided surface of STS 304, STS 316, STS 410 and SACM 645 steel were analysed using EMPA and XRD respectively. The depth of nitriding layer that is obtained from similar nitriding condition decrease in the order of SACM 645 > STS 410 > STS 316 > STS 304. Result of phase transformation of the nitrided at $550^{\circ}C$ by XRD analysis were as follows; The austenitic stainless steel was mainly consist of $Cr_2N$ accompanying with $Fe_4N$ and $Fe_{2-3}N$ phase and martensitic stainless steel was mainly consist of present $Fe_{2-3}N+Cr_2N$ phase, but SACM 645 steel was $Fe_{2-3}N$ phase present only.