Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Characteristics and Application of the Highly-Durable and Highly-Sensitive Super Hydrophobic Acid-gas Sensing Dye

고내구성 고감도 강산감지기능 초소수성 색소의 특성 및 응용

  • Kim, Taekyeong (Department of Textile System Engineering, Kyungpook National University) ;
  • Lee, Seonae (Department of Textile System Engineering, Kyungpook National University)
  • 김태경 (경북대학교 섬유시스템공학과) ;
  • 이선애 (경북대학교 섬유시스템공학과)
  • Received : 2015.03.17
  • Accepted : 2015.04.20
  • Published : 2015.06.27
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Abstract

In order to detect gas phase strong acid on fabrics, a hexyl-substituted monoazo yellow dye, which was the modified form of a conventional pH-indicating dye, Methyl Yellow, was studied in view of acid-gas sensing properties and its fastness. The dye was printed on polypropylene non-wovens for protective coveralls and examined under various conditions of strong acid such as hydrochloric acid. The dye showed color change from yellow to red on exposure to gas phase hydrochloric acid as low concentration as 1~3 ppm very instantly. Considering reuse of the dye-printed non-wovens, the repeatability of color change was tested on the same sample for 50 repeats and 100 days. The acid-gas sensing function was maintained almost the same level of initial performance. The color fastness of the dye on polypropylene non-wovens was very good showing higher than ratings 4 except for 3~4 to rubbing under wet condition.

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References

  1. Y. A. Son and S. H. Kim, Anthraquinone and Indole based Chemosensor for Fluoride Anions Detection, Textile Coloration and Finishing, 26(1), 1(2014). https://doi.org/10.5764/TCF.2014.26.1.1
  2. Y. A. Son, Design and Synthesis of Novel Rhodamine-based Chemosensor Probe Toward $Cu^{2+}$ Cation, Textile Coloration and Finishing, 26(1), 7(2014). https://doi.org/10.5764/TCF.2014.26.1.7
  3. A. Gupta, M. Kim, and J. S. Park, Efficient Fluorescence Quenching of tert-butyl substituted Phthalocyanines with Picric Acid, Textile Coloration and Finishing, 26(4), 277(2014). https://doi.org/10.5764/TCF.2014.26.4.277
  4. T. K. Kim, J. S. Jung, K. J. Jang, S. H. Yoon, and M. K. Kim, Synthesis and Application of Alkyl-substituted High Chroma Yellow Dyes for Unmodified Polypropylene Fiber, Fibers and Polymers, 10(2), 148(2009). https://doi.org/10.1007/s12221-009-0148-z
  5. T. K. Kim, K. J. Jang, and S. H. Jeon, Calculation and Analysis of Hydrophobicity of the Dyes Synthesized for Unmodified Polypropylene Fibers Using Molecular Descriptors, Textile Coloration and Finishing, 21(5), 21(2009). https://doi.org/10.5764/TCF.2009.21.5.021
  6. T. K. Kim and S. H. Jeon, Coloration of Ultra High Molecular Weight Polyethylene Fibers Using Alkyl-substituted Monoazo Yellow and Red Dyes, Fibers and Polymers, 14(1), 105(2013). https://doi.org/10.1007/s12221-013-0105-8
  7. K. M. Tawarah and H. M. Abu-Shamleh, A Spectrophotometric Study of the Tautomeric and Acid-Base Eqiulibria of Methyl Orange and Methyl Yellow in Aqueous Acidic Solutions, Dyes and Pigments, 16, 241(1991). https://doi.org/10.1016/0143-7208(91)85014-Y
  8. S. W. Nam, B. Y. Seo, and D. S. Lee, "Dye Chemistry", Bosung Publish Co., Seoul, pp.422-425, 2004.
  9. H. Zollinger, "Color Chemistry", WILEY-VCH, Weinheim, pp.556-559, 2003.
  10. R. W. G. Hunt, "Measuring Colour", Eliis Horwood, New York, pp.61-81, 1991.
  11. M. D. Fairchild, "Color Appearance Models", WILEY, England, pp.77-82, 2005.

Cited by

  1. Synthesis and application of acid-gas sensing dyes having alkyl groups symmetrically substituted on monoazo chromophore vol.16, pp.10, 2015, https://doi.org/10.1007/s12221-015-5428-1