• KSBB Journal
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• 제9권3호
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• pp.239-245
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• 1994

Alcohol oxidase와 alcohol dehydrogenase를 DEAE-Cellulose와 ePG에 고정화시켜 에탄올을 산 화시키는 반응을 기상에서 수행하였다. 이 기상반응 의 반응활성은 반응온도와 효소의 hydration 정도에 큰 영향을 받았다. 온도에 의한 효소활성의 변화는 액상에셔의 경우와 비슷한 경향을 보였다. 즉 기상 반응에서도 $35^{\circ}C$에서 $40^{\circ}C$ 사이에서 최고의 활성을 나타내였다. 효소의 hydration 정도는 효소의 활성 에 매우 큰 영향을 끼치는 인자였는데 water activity가 0.8 정도까지는 water activIty가 증가함 에 따라 효소의 활성이 급격히 증가하다가 그 이상 에서는 다소 감소하는 경향을 보였다. 쇼소의 얀정 성도 water activity에 의해서 크게 영향을 받았는데 water actIvity가 0.5 정도까지는 water activity가 증가함에 따라 안정성이 비교적 급격히 감소하였고 그 이상의 water activity에서는 효소의 안정성이 water activity의 영향을 크게 받지 않고 어느 정도 엘정하게 유지되었다. 담체의 흡착성능이 기상반응에 마치는 영향을 알아보가 위하여 셔로 흡 착성능이 다른 DEAE-Cellulose와 CPG에 고정화 된 효소를 사용하여 반응을 비교해 본 결과 담체의 흡착성능은 반응에 별 영향을 주지 못했다. Alcoh이 O oxidase의 기상반응 속도상수(Km=0.24mM)는 액상에서의 값(Km=11.22mM)과 order of magni tude가 약 2 정도의 차이를 보여주었는데 이는 기질 인 에탄올의 기 액 평형상태에셔의 각상간의 농도의 order of magnitude 차와 비슷하였다. 같은 산화효 소류이나 조효소를 펠요로 하고 반응속도식이 많이 다른 alcohol dehydrogenase 효소에도, 기상반응 속도상수와 사용기질의 기 액평형 데이타와의 이와 같은 연관성이 성립하였다. 이같은 연관성이 산화환 원효소류가 아닌 다른 효소류에도 적용될지의 여부는 앞으로의 연구로 밝혀야 할 것이다.

• 융복합기술연구소 논문집
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• 제4권2호
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• pp.47-50
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• 2014

Voloxidation is a process for converting $UO_2$ into $U_3O_8$ while removing some volatile products in spent fuels (SF). Various oxidative gas conditions including air and mixture of Ar and $O_2$ could be adopted for the process. The gas flows into a reactor under high temperature ($>500^{\circ}C$) and components of SF are reacted with the gas. SF is composed of various components such as actinides, lanthanides, and alkali metals. Therefore, it is of significance to understand their behavior during the reactions for process development. However, due to the limit of available experiments, phase diagram analysis should be preceded. TPP diagram is constructed with respect to temperature-pressure-pressure. It shows a stable phase depending on partial pressures of gas components as well as temperature. In this work, we investigated TPP diagrams for actinides, lanthanides and other oxides to determine stable oxide forms under different gas conditions. The results would be used to set up a material balance under a pyroprocessing scheme of SF and compare the gas conditions for the optimization of fission products removal.

• 한국수산과학회지
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• 제50권6호
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• pp.837-840
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• 2017

We developed a method to rapidly evaluate the freshness of fish using a sensor gas chromatography (SGC) system. Mackerel Scomber japonicus was stored at $4^{\circ}C$ for 12 days to create an environment similar to the natural decomposition process. Trimethylamine (TMA) content in mackerel muscle was measured at 3-day intervals using a spectrophotometer. The gas-phase concentration of TMA in whole mackerel was also determined using an SGC system. The muscle TMA content increased over time during storage, as did the gas-phase concentration of TMA. Therefore, this study demonstrated that an SGC system can be used to rapidly measure the gas-phase concentration of TMA in fish during processing.

• 대한기계학회논문집
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• 제10권3호
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• pp.335-342
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• 1986

본 연구에서는 이러한 가능성을 알아 보기 위하여 오리피스판을 통하여 기액 2상흐름이 있을 때 각 상의 유량변화레 따른 순간압력강하치를 분석하고자 한다. 우선 평균압력강하치를 측정하여 식 (1)과 비교 분석하며, 교란치의 평균진폭과 교란 강도를 구하여 기공율의 변화에 따른 이러한 통계치들의 경향을 고찰한다. 그리고 순간압력강하 곡선에 대한 통계함수들, 확률밀도함수(probability density function) 와 자기상관함수(auto-correlation function)을 구하여 이 들의 통계적 성질을 구명 하고 2상 유동량의 결정에 대한 교란치의 할동도를 토의한다.

• 한국가스학회지
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• 제13권4호
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• pp.1-7
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• 2009

최근 연료경제성 및 강화되는 배출가스 규제를 만족하기 위하여 대체연료의 하나인 LPG에 대한 수요가 증가하고 있다. 현재 LPG 차량에 적용되고 있는 제3세대 LPG 연료공급방식인 LPLi(Liquid Phase LPG Injection) 시스템은 가솔린 차량과 비교하여 배출가스는 적게 배출하면서 동등한 출력을 낼 수 있게 하는 핵심 기술이다. LPG 연료를 고압의 액상 상태로 공급하기 위해서는 LPG 펌프가 필요하다. 연료펌프의 성능을 저하 시킬 수 있는 연료 내 불순물을 제거하기 위하여 연료펌프에는 연료필터가 장착되어 있으며 장착되는 연료필터의 종류에 따라서 연료펌프의 성능도 변하게 된다. 본 연구에서는 임펠라 방식을 채택한 LPG 연료펌프에서 극세사, 이중메쉬, 외장형 필터의 세 가지 필터에서 부하별 토출성능 및 효율을 파악하였으며 온도 변화에 따른 펌프유량 변화를 측정하였다.

• 열처리공학회지
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• 제18권5호
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• pp.281-287
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• 2005

Titanium aluminium nitride((TiAl)N) film is anticipated as an advanced coating film with wear resistance used for drills, bites etc. and with corrosion resistance at a high temperature. In this study, (TiAl)N thin films were deposited both at room temperature and at elevated substrate temperatures of 573 to 773 K by using a two-facing-targets type DC sputtering system in a mixture Ar and $N_2$ gases. Atomic compositions of the binary Ti-Al alloy target is Al-rich (25Ti-75Al (atm%)). Process parameters such as precursor volume %, substrate temperature and Ar/$N_2$ gas ratio were optimized. The crystallization processes and phase transformations of (TiAl)N thin films were investigated by X-ray diffraction, field-emission scanning electron microscopy. The microhardness of (TiAl)N thin films were measured by a dynamic hardness tester. The films obtained with Ar/$N_2$ gas ratio of 1:3 and at 673 K substrate temperature showed the highest microhardness of $H_v$ 810. The crystallized and phase transformations of (TiAl)N thin films were $Ti_2AlN+AlN{\rightarrow}TiN+AlN$ for Ar/$N_2$ gas ratio of 1:3, $Ti_2AlN+AlN{\rightarrow}TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 1:1 and $TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN{\rightarrow}Ti_2AlN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 3:1. The above results are discussed in terms of crystallized phases and microhardness.

• 한국수소및신에너지학회논문집
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• 제34권1호
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• pp.8-16
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• 2023

In this work, we report basic performance test results of a lab-scale three phase alternative current (AC) arc plasma torch system for plasma gas reforming applications. The suggested system primarily consists of three graphite electrodes inclined at 12.5° to the central axis, a 𝞥 150 mm cylindrical gas path and a three phase-60 Hz AC power supply. At air flow rate of 50 Lpm and arc currents of 100-175 A, test results revealed that plasma resistances were decreasing from 1.08 Ω to 0.53 Ω with the increase of plasma power from 9.3 kW to 13.8 kW, causing the decrease of power factor and increase of the line voltages. However, the injected air can be heated quickly up to the temperatures of >1,200℃ when injecting AC arc plasma powers of >10 kW.

• 열처리공학회지
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• 제22권2호
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• pp.88-94
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• 2009

The effect of high temperature gas nitrding (HTGN) on the surface microstructure in pure Ti was investigated. Two phases of TiN and $Ti_2N$ appeared at the outmost surface, and the wide ${\alpha}$-Ti layer was formed at the next layer. On the other hand, the interior region, where the nitrogen was not permeated, exhibited ${\alpha}$'phase. The outmost surface of TiN and $Ti_2N$ showed the maximum hardness of 1000Hv, while the interior ${\alpha}$'phase was ${\sim}350$ Hv. The permeation depth of nitrogen increased with increasing the gas nitriding temperature and time. The nitrogen concentration of the surface layer seems to be over 12.7% at $1100^{\circ}C$.

• 대한기계학회논문집B
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• 제20권8호
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• pp.2681-2692
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• 1996

The finite-volume method for radiation in a three-dimensional non-orthogonal gas turbine combustion chamber with absorbing, emitting and anisotropically scattering medium is presented. The governing radiative transfer equation and its discretization equation using the step scheme are examined, while geometric relations which transform the Cartesian coordinate to a general body-fitted coordinate are provided to close the finite-volume formulation. The scattering phase function is modeled by a Legendre polynomial series. After a benchmark solution for three-dimensional rectangular combustor is obtained to validate the present formulation, a problem in three-dimensional non-orthogonal gas turbine combustor is investigated by changing such parameters as scattering albedo, scattering phase function and optical thickness. Heat flux in case of isotropic scattering is the same as that of non-scattering with specified heat generation in the medium. Forward scattering is found to produce higher radiative heat flux at hot and cold wall than backward scattering and optical thickness is also shown to play an important role in the problem. Results show that finite-volume method for radiation works well in orthogonal and non-orthogonal systems.

• 한국전산유체공학회지
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• 제11권1호
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• pp.29-35
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• 2006

A code is developed to analyze a spherically symmetric underwater explosion. The arbitrary Lagrangian-Eulerian(ALE) Godunov scheme for two-phase flow is used to calculate numerical fluxes through moving control surfaces. For detonation gas of TNT and liquid water, the Jones-Wilkins-Lee(JWL) equation of states and the isentropic Tait relation are used respectively. It is suggested to use the Godunov variable to estimate the velocity of a material interface. The code is validated through comparisons with other results on the gas-water shock tube problem. It is shown that the code can handle generation of discontinuity and recovering of continuity in the normal velocity near the material interface during shock waves interact with the material interface. The developed code is applied to analyze a spherically symmetric underwater explosion. Repeated transmissions of shock waves are clearly captured. The calculated period and maximum radius of detonation gas bubble show good agreements with experimental and other numerical results.