• 제목/요약/키워드: Gas mixture

검색결과 2,015건 처리시간 0.031초

Transport properties of polycrystalline TaNx thin films prepared by DC reactive magnetron sputtering method

  • Hwang, Tae Jong;Jung, Soon-Gil
    • 한국초전도ㆍ저온공학회논문지
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    • 제23권2호
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    • pp.1-5
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    • 2021
  • We have investigated the electrical transport properties of polycrystalline tantalum nitride (TaNx) films. Various compositions of tantalum (nitride) thin films have been deposited on SiO2 substrates by reactive DC magnetron sputtering while changing the ratio of nitrogen partial pressure. The substrate temperature was maintained at 283 K during deposition. X-ray diffraction analyses indicated the presence of α-Ta and β-Ta phases in the Ta film deposited in pure argon atmosphere, while fcc-TaNx phases appeared in the sputtering gas mixture of argon and nitrogen. The N/Ta atomic ratio in the film increased ranging from 0.36 to 1.07 for nitrogen partial pressure from 7 to 20.7%. The superconducting transition temperatures of the TaNx thin films were measured to be greater than 3.86 K with a maximum of 5.34 K. The electrical resistivity of TaNx thin film was in the range of 177-577 𝜇Ωcm and increased with an increase in nitrogen content. The upper critical filed at zero temperature for a TaN0.87 thin film was estimated to exceed 11.3 T, while it showed the lowest Tc = 3.86 K among the measured superconducting TaNx thin films. We try to explain the behavior of the increase of the residual resistivity and the upper critical field for TaNx thin films with the nitrogen content by using the combined role of the intergrain Coulomb effect and disorder effect by grain boundaries.

수송부문 연료전환 효과 분석: 사업용 승용차 부문을 중심으로 (An Analysis of the Effects of Fuel-transition in Transportation Sector: Focusing on Business Cars)

  • 김재엽;김비아;박명덕
    • 자원ㆍ환경경제연구
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    • 제29권4호
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    • pp.443-468
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    • 2020
  • 전기차 관련 기술 발달과 보급 확대로 화물, 이륜차 등 일반승용 부문을 넘어 육상수송 전반에 걸친 연료전환 효과가 발생하고 있다. 본 연구는 대도시에서 긴 주행거리를 운행하는 사업용 승용차(택시)의 연료전환에 따라 발생하는 대기환경편익을 택시의 운행특성과 충전전력의 발전원별 비중을 동시에 반영하여 추정하였다. 분석 결과 LPG를 연료로 하는 택시의 연료 전환 효과는 제8차 전력수급기본계획을 기초로 한 발전원별 비중을 고려했을 때 약 21.5원/km로 분석되었으며, 택시 한 대가 출고되어 폐차될 때까지의 전체 운행거리를 기준으로 할 때 약 860만 원 수준으로 추정되었다. 이러한 연구 결과는 최근 국내외에서 활발히 추진되고 있는 재생에너지발전 및 전기자동차 보급 확대 정책의 필요성 및 당위성을 보여준다.

주택 내 수소연료전지 전용실의 폭발 위험성에 대한 실험적 연구 (An Experimental Study on the Explosion Hazards in the Fuel Cell Room of Residential House)

  • 박병직;김양균;황인주
    • 한국안전학회지
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    • 제36권4호
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    • pp.71-79
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    • 2021
  • In this study, a real-scale fuel-cell room of volume 1.36 m3 is constructed to confirm the explosion characteristics of hydrogen-air mixture gas in a hydrogen-powered house. A volume concentration of 40% is applied in the fuel-cell room as the worst-case scenario to examine the most severe accident possible, and two types of doors (made of plastic sheet and wood) are fabricated to observe their effects on the overpressure and impulse. The peak overpressure and impulse based on distance from the ignition source are experimentally observed and assessed. The maximum and minimum overpressures with a plastic-sheet door are about 20 and 6.7 kPa and those with a wooden door are about 46 and 13 kPa at distances of 1 and 5 m from the ignition source, respectively. The ranges of impulses for distances of 1-5 m from the ignition source are about 82-28 Pa·s with a plastic-sheet door and 101-28 Pa·s with a wooden door. The amount of damage to people, buildings, and property due to the peak overpressure and impulse is presented to determine the safe distance; accordingly, the safe distance to prevent harm to humans is about 5 m based on the 'injuries' class, but the structural damage was not serious.

경제성분석 프로그램을 이용한 도심형 마이크로그리드 최적 설계 (Optimal Design of Urban MICROGRID using Economical Analysis Program)

  • 유승덕;임성우;임유석;황성욱;이학주
    • KEPCO Journal on Electric Power and Energy
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    • 제8권2호
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    • pp.69-72
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    • 2022
  • This paper actually investigates the load on major large-scale buildings in the downtown area, examines the economic feasibility of installing PV and ESS in a microgrid target building, and evaluates whether an electric vehicle capable of V2G through two buildings is effective as an economical analysis program (HOMER) was analyzed using. It is economical to install a mixture of ESS rather than using the whole PV, and it is shown that if there is an electric vehicle using the V2G function of EV, there is an economic effect to replace the PV. So that Incentives and policies are needed to replace a large area of PV and utilize the existing parking lot to lead EV as a resource of the microgrid. Currently, P2X technology that stores power as ESS or converts it to other energy to control when surplus renewable energy occurs in large-capacity solar power plants and wind farms, etc. This is being applied, and efforts are being made to maintain the stability of the system through the management of surplus power, such as replacing thermal energy through a heat pump. Due to the increase in electric vehicles, which were recognized only as a means of transportation, technologies for using electric vehicles are developing. Accordingly, existing gas stations do not only supply traditional chemical fuels, but electricity, and super stations that also produce electricity have appeared. Super Station is a new concept power plant that can produce and store electricity using solar power, ESS, V2G, and P2G. To take advantage of this, research on an urban microgrid that forms an independent system by tying a large building and several buildings together and supplies power through a super station around the microgrid is in full swing.

2기통 소형 터보가솔린엔진에서 배기 밸브 타이밍 제어에 따른 LIVC, EIVC 상태에서의 엔진 효율 영향 (Effect of Controlling Exhaust Valve Timing on Engine Efficiency in LIVC and EIVC States in a 2-Cylinder Small Turbo Gasoline Engine)

  • 장진영;우영민;신영진;고아현;정용진;조종표;김강출;표영덕;한명훈
    • 한국분무공학회지
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    • 제27권3호
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    • pp.117-125
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    • 2022
  • This study examines whether engine fuel efficiency is improved by optimization of the exhaust valve timing in a state where the intake valve timing has been optimized in a small turbo gasoline engine that has intake cams and exhaust cams with fixed valve opening periods. When the exhaust valve is opened late, the expansion stroke is longer, and the efficiency can be improved. A 2-cylinder turbo gasoline engine with 0.8 liters of displacement and an MPI (Multi Point Injection) fuel system was used. The engine was operated at 1,500 and 3,000 rpm, and the load conditions included a partial load of 50 N·m and a high load of 70 N·m. Data was recorded as the exhaust valve timing was controlled, and this was used to calculate the efficiency of combustion using a heat release, the fuel conversion efficiency, and the pumping loss. Results and the hydrocarbon concentrations in the exhaust gas were compared for each condition. Experiment results confirmed that additional fuel efficiency improvements are possible through exhaust valve timing control at 1,500 rpm and 50 N·m. However, in other operating conditions, fuel efficiency improvements could not be obtained through exhaust valve timing control because cases where the pumping loss and fuel/air mixture slip increased when the exhaust valve timing changed and the fuel efficiency declined.

CO2 냉각모듈을 적용한 고곡률 성형품의 사출금형 급속냉각 (Rapid cooling of injection mold for high-curvature parts using CO2 cooling module)

  • 이세호;이호상
    • Design & Manufacturing
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    • 제16권4호
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    • pp.67-74
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    • 2022
  • Injection molding is a cyclic process comprising of cooling phase as the largest part of this cycle. Providing efficient cooling in lesser cycle times is of significant importance in the molding industry. Recently, lots of researches have been done for rapid cooling of a hot-spot area using CO2 in injection molding. The CO2 flows under high pressure through small, flexible capillary tubes to the point of use, where it expands to create a snow and gas mixture at a temperature of -79℃. The gaseous CO2 removes heat from the mold and releases it into the atmosphere. In this paper, a CO2 cooling module was applied to an injection mold in order to cool a large area cavity uniformly and quickly, and the cooling performance of the injection mold was investigated. The product was a high-curvature molded part with a molding area of 300x100mm. Heat cartridges were installed in a stationary mold, and CO2 cooling module was inserted inside a movable mold. Through structural analysis, it was confirmed that the maximum deformation of mold with CO2 cooling module was 0.09mm. A CO2 feed system with a heat exchanger was used for cooling experiments. The CO2 was injected into the holes on both sides of the supply pipe of the cooling module and discharged through hexagon blocks to cool the mold. It took 5.8 seconds to cool the mold from an average temperature of 140℃ to 70℃. Through the experiment using CO2 cooling module, it was found that a cooling rate of up to 12.98℃/s and an average of 10.18℃/s could be achieved.

Quantitative analysis of retained austenite in Nb added Fe-based alloy

  • Kwang Kyu Ko;Jin Ho Jang;Saurabh Tiwari;Hyo Ju Bae;Hyo Kyung Sung;Jung Gi Kim;Jae Bok Seol
    • Applied Microscopy
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    • 제52권
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    • pp.5.1-5.10
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    • 2022
  • The use of Pipelines for long-distance transportation of crude oil, natural gas and similar applications is increasing and has pivotal importance in recent times. High specific strength plays a crucial role in improving transport efficiency through increased pressure and improved laying efficiency through reduced diameter and weight of line pipes. TRIP-based high-strength and high-ductility alloys comprise a mixture of ferrite, bainite, and retained austenite that provide excellent mechanical properties such as dimensional stability, fatigue strength, and impact toughness. This study performs microstructure analysis using both Nital etching and LePera etching methods. At the time of Nital etching, it is difficult to distinctly observe second phase. However, using LePera etching conditions it is possible to distinctly measure the M/A phase and ferrite matrix. The fraction measurement was done using OM and SEM images which give similar results for the average volume fraction of the phases. Although it is possible to distinguish the M/A phase from the SEM image of the sample subjected to LePera etching. However, using Nital etching is nearly impossible. Nital etching is good at specific phase analysis than LePera etching when using SEM images.

Effects of Powder Property and Sintering Atmosphere on the Properties of Burnable Absorber Fuel : I. $UO_2-Gd_2O_3$ Fuel

  • K. W. Song;Kim, K. S.;H. S. Yoo;Kim, J. H.
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1997년도 춘계학술발표회논문집(2)
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    • pp.171-176
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    • 1997
  • UO$_2$-Gd$_2$O$_3$fuel has been sintered to study the effect of powder property and sintering atmospheres on densification and microstructure. Three types of powders have been used; AUC-UO$_2$ powder and ADU-UO$_2$ powder were mixed with Gd$_2$O$_3$ Powder, and co-milled AUC-UO$_2$ and Gd$_2$O$_3$ powder. UO$_2$-(2, 5, 10)wt% Gd$_2$O$_3$pellets have been sintered at 168$0^{\circ}C$ for 4 hours in the mixture of H$_2$ and $CO_2$ gases, of which oxygen potential has been controlled by the ratio of $CO_2$ to H$_2$ gas. Densities of UO$_2$-Gd$_2$O$_3$ fuel pellets are quite dependent on powder types, and UO$_2$-Gd$_2$O$_3$ fuel using co-milled UO$_2$ powder yields the highest density. A long range homogeneity of Gd is determined by powder mixing. As the oxygen potential of sintered atmosphere increases, the sintered densities of UO$_2$-Gd$_2$O$_3$ pellets decrease but grain size increases. In addition, (U, Gd)O$_2$ solid solution becomes more homogeneous. The UO$_2$-Gd$_2$O$_3$fuel having adequate density and homogeneous microstructure can be fabricated by co-milling powder and by high oxygen potential.

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Hard TiN Coating by Magnetron-ICP P $I^3$D

  • Nikiforov, S.A.;Kim, G.H.;Rim, G.H.;Urm, K.W.;Lee, S.H.
    • 한국표면공학회지
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    • 제34권5호
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    • pp.414-420
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    • 2001
  • A 30-kV plasma immersion ion implantation setup (P $I^3$) has been equipped with a self-developed 6'-magnetron to perform hard coatings with enhanced adhesion by P $I^3$D(P $I^3$ assisted deposition) process. Using ICP source with immersed Ti antenna and reactive magnetron sputtering of Ti target in $N_2$/Ar ambient gas mixture, the TiN films were prepared on Si substrates at different pulse bias and ion-to-atom arrival ratio ( $J_{i}$ $J_{Me}$ ). Prior to TiN film formation the nitrogen implantation was performed followed by deposition of Ti buffer layer under A $r^{+}$ irradiation. Films grown at $J_{i}$ $J_{Me}$ =0.003 and $V_{pulse}$=-20kV showed columnar grain morphology and (200) preferred orientation while those prepared at $J_{i}$ $J_{Me}$ =0.08 and $V_{pulse}$=-5 kV had dense and eqiaxed structure with (111) and (220) main peaks. X-ray diffraction patterns revealed some amount of $Ti_{x}$ $N_{y}$ in the films. The maximum microhardness of $H_{v}$ =35 GN/ $M^2$ was at the pulse bias of -5 kV. The P $I^3$D technique was applied to enhance wear properties of commercial tools of HSS (SKH51) and WC-Co alloy (P30). The specimens were 25-kV PII nitrogen implanted to the dose 4.10$^{17}$ c $m^{-2}$ and then coated with 4-$\mu\textrm{m}$ TiN film on $Ti_{x}$ $N_{y}$ buffer layer. Wear resistance was compared by measuring weight loss under sliding test (6-mm $Al_2$ $O_3$ counter ball, 500-gf applied load). After 30000 cycles at 500 rpm the untreated P30 specimen lost 3.10$^{-4}$ g, and HSS specimens lost 9.10$^{-4}$ g after 40000 cycles while quite zero losses were demonstrated by TiN coated specimens.s.

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설비공학 분야의 최근 연구 동향 : 2010년 학회지 논문에 대한 종합적 고찰 (Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2010)

  • 한화택;이대영;김서영;최종민;김수민;권영철;백용규
    • 설비공학논문집
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    • 제23권6호
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    • pp.449-469
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    • 2011
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering during 2010. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) Research trends of thermal and fluid engineering have been surveyed as groups of general thermal and fluid flow, fluid machinery, and new and renewable energy. Various topics were presented in the field of general thermal and fluid flow. Research issues mainly focused on the thermal reliability of axial fan and compressor in the field of fluid machinery. Studies on the design of ground source heat pump systems and solar chemical reactors were executed in the field of new and renewable energy. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer in thermoelectric cooling/power generation systems, combined heat and power systems, carbon nano fluid with PVP, channel filled with metal foam and smoke ventilation in a rescue station of a railroad tunnel. Also the studies on flow boiling of R123/oil mixture in a plain tube bundle and R410A charge amount in an air cooled mini-channel condenser were reported. In the area of industrial heat exchangers, researches on plate heat exchanger, shell and tube heat exchanger, enthalpy exchanger, micro channel PCHE were performed. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer in thermoelectric cooling/power generation systems, combined heat and power systems, carbon nano fluid with PVP, channel filled with metal foam and smoke ventilation in a rescue station of a railroad tunnel. Also the studies on flow boiling of R123/oil mixture in a plain tube bundle and R410A charge amount in an air cooled mini-channel condenser were reported. In the area of industrial heat exchangers, researches on plate heat exchanger, shell and tube heat exchanger, enthalpy exchanger, micro channel PCHE were performed. (3) Refrigeration systems with alternative refrigerants such as hydrocarbons, mixed refrigerants, and CO2 were studied. Performance improvement of refrigeration systems are tried applying various ideas of refrigerant subcooling, dual evaporator with hot gas bypass control and feedforward control. The hybrid solar systems combining the solar collection devices with absorption chillers or compression heat pumps are simulated and studied experimentally as well to improve the understanding and the feasibility for actual applications. (4) Research trend in the field of mechanical building facilities has been found to be mainly focused on field applications rather than performance improvements. Various studies on heating and cooling systems, HVAC facilities, indoor air environments and energy resources were carried to improve the maintenance and management of building service equipments. In the field of heating and cooling systems, papers on a transformer cooling system, a combined heat and power, a slab thermal storage and a heat pump were reported. In the field of HVAC facilities, papers on a cooling load, an ondol and a drying were presented. Also, studies on HVAC systems using unutilized indoor air environments and energy resources such as air curtains, bioviolence, cleanrooms, ventilation, district heating, landfill gas were studied. (5) In the field of architectural environment and energy, studies of various purposes were conducted such as indoor environment, building energy, renewable energy and green building. In particular, renewable energy and building energy-related researches have mainly been studied reflecting the global interest. In addition, many researches which related the domestic green building certification of school building were performed to improve the indoor environment of school.