• 제목/요약/키워드: Gas exchange

검색결과 652건 처리시간 0.033초

고분자 전해질 연료전지 가스확산층의 압축상태 평면 기체투과율 측정 (Measurement of In-plane Gas Permeability of Gas Diffusion Layers in Proton Exchange Membrane Fuel Cells under Compressive Strain)

  • 오창준;이용택
    • 설비공학논문집
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    • 제28권9호
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    • pp.367-372
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    • 2016
  • Gas diffusion layer (GDL) of PEMFCs plays a role that it diffuses the reactant gases to the catalyst layer on the membrane and discharge water from the catalyst layer to the channel. Physical parameters related to the mass transport of GDL are mostly from the uncompressed GDLs while actual GDLs in the assembled stacks are compressed. In this study, the relation of compression and strain of GDLs with various Polytetrafluoroethylene (PTFE) loading is measured experimentally and In-plane gas permeability is measured at the condition that the GDLs are in compressive strain. The gas permeability decreased with the loading of PTFE and the presentation of gas permeability under compressive stain is expected to improve the accuracy of modeling work of mass transport in the GDL.

작업장에서 사용 가능한 방독마스크 정화통 교체주기 프로그램의 개발(II) - 냄새 서한도(odor threshold)를 이용하는 방법 (Development of feasible program of exchange period for chemical cartridge in the workplace (II) - Method of using odor threshold)

  • 한돈희;강민선;이광용
    • 한국산업보건학회지
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    • 제19권2호
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    • pp.102-112
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    • 2009
  • The greatest concern of vapor/gas respirators is when to exchange chemical cartridges, but it is very difficult to estimate the breakthrough time of them in the workplace spot due to so many factors influencing on breakthrough. There needs to study on estimating cartridge exchange period available practically in the spot, even if it is not precise. In the previous study, authors suggested the method on estimating service-life of chemical cartridges using cartridges discarded after use. This followed study was to estimate exchange period for chemical cartridges using comparison of concentrations between Korean Occupational Exposure Limits (KOELs) and odor thresholds of chemicals. Chemicals were divided into four groups, I, II, III and IV groups. Group I chemicals are relatively safe if cartridges are just or slightly delayed exchanged when smelling since odor thresholds were less than 0.5 times KOELs. Odor threshold of Group II chemicals are 0.5~2.0 times KOELs and potentially hazardous if cartridges are exchanged when smelling. Those chemicals should be conducted program on estimating service-life of cartridges, which was just previously published (J Kor Soc Occup Environ Hyg 2008;18(3) 204-215). Group III chemicals (odor thresholds are more than 2.0 times KOELs) and Group IV chemicals (odorless or no data for smelling) must be performed the above mentioned program before cartridges. Even if this method on cartridge exchange using odor threshold is practically widely used in the workplace spot in the present, program on estimating service-life of cartridges is recommended for all chemicals to reduce potentially hazards.

고분자 전해질 연료전지의 전해질 막내의 함수율과 성능 예측 (Prediction of Fuel Cell Performance and Water Content in the Membrane of a Proton Exchange Membrane Fuel Cell)

  • 양장식;최경민;김덕줄
    • 한국자동차공학회논문집
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    • 제14권6호
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    • pp.151-159
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    • 2006
  • A one-dimensional numerical analysis is carried out to investigate the effects of inlet gas humidities, inlet gas pressures, and thicknesses of membrane on the performance of a proton exchange membrane fuel cell. It is found that the relative humidity of inlet gases at anode and cathode sides has a significant effect on the fuel cell performance. Especially, the desirable fuel cell performance occurs at low relative humidity of the cathode side and at high humidity of the anode side. In addition, an increase in the pressure ranging from 1 atm to 4 atm at the cathode side results in a significant improvement in the fuel cell performance due to the convection effect by a pressure gradient toward the anode side, and with decreasing the thickness of membrane, the fuel cell performance is enhanced reasonably.

저속 2행정 디젤 기관의 소기 특성에 관한 연구 (A study on the scavenging characteristics in slow-speed two-stroke diesel engines)

  • 고대권;최재성
    • Journal of Advanced Marine Engineering and Technology
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    • 제19권3호
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    • pp.24-32
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    • 1995
  • The scavenging characteristics have a great influence on the performance of a diesel engine, especially slow-speed two-stroke diesel engines which are usually used as a marine propulsion power plant, and they are greatly affected by the conditions in the cylinder, intake and exhaust manifolds, and the opening and closing timing of scavenging ports or exhaust valves during the gas exchange process. Besides, there are many other factors to affect the scavenging characteristics and these factors interact each other very complicatedly. Therefore the simulation program of the gas exchange process is very useful to improve and predict the scavenging characteristics, due to the high costs associated with redesign and testing. In this paper it was attenpted to investigate the effect of the variation of the pressure ratio of intake to exhaust manifolds, and the variation of the opening and closing timing of a exhaust valve by using a computational program for a three-zone scavenging model which was developed by authors. The computed results showed that the scavenging efficiency and delivery ratio increased considerably, but the trapping efficiency decreased with increasing of the pressure ratio of intake to exhaust manifolds. The scavenging efficiency, trapping efficiency, and th conditions of the cylinder gases were affected by the opening timing of the exhaust valve, but the delivery ratio by the closing timing.

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양자교환막을 이용하여 생산된 수소의 불순물 분석 (Hydrogen Impurities Analysis From Proton Exchange Membrane Hydrogen Production)

  • 이택홍;김태완;박태성;최운선;김홍열;이홍기
    • 한국수소및신에너지학회논문집
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    • 제24권4호
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    • pp.288-294
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    • 2013
  • This gas analysis data come from the hydrogen which is produced by proton exchange membrane. Main impurities of hydrogen are methane, oxygen, nitrogen, carbon monoxide, and carbon dioxide. The concentration of impurities is ranged between 0.0191 to $315{\mu}mol/mol$ for each impurity. Methane contamination is believed from the electrode reaction between carbon doped electrode and produced hydrogen. Nitrogen contamination should take place the sampling process error, not from PEM hydrogen Production system.

고온형 고분자전해질 연료전지의 준3차원 모델링을 통한 국부적 동특성 해석에 관한 연구 (A Study on the Local Dynamic Characteristics of High Temperature Proton Exchange Membrane Fuel Cell by Quasi-three-dimensional Model)

  • 박재만;민경덕;강상규
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.81.1-81.1
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    • 2011
  • High temperature proton exchange membrane fuel cell (HT-PEMFC) has been regarded as a promising clean energy sources. In this study, a quasi-three-dimensional dynamic model of HT-PEMFC has been developed and the local dynamic characteristics are investigated. The model has the geometrical simplification of 2+1D reduction (quasi-3D). The one-dimensional model consists of nine control volumes in cross-sectional direction to solve the energy conservation and the species conservation equations. Then, the one-dimensional model is discretized into 25 local sections along the gas flow direction to account for gas and thermal transport in channels. With this discretization, the local characteristics of HT-PEMFC such as species conservation, temperature, and current density can be captured. In order to study the basic characteristics of HT-PEMFC, it is important to investigate the local dynamic characteristics. Thus, the model is simulated at various operating conditions and the local dynamic characteristics related to them are observed. The model is useful to investigate the distribution of HT-PEMFC characteristics and the physical phenomena in HT-PEMFC.

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An Approach for Reducing Carbon-14 Stack Emissions via Optimal Use of Ion Exchang Resins at CANDU Plant

  • Sohn, Wook;Chi, Jun-Ha;Kang, Duk-Won
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2003년도 춘계 학술발표회 논문집
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    • pp.445-455
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    • 2003
  • Relatively high carbon-14 emissions, which occurred at PHWR Plant during 1998 and 1999, made the site staff to implement several operational improvements: 1) the frequency and volume of the moderator cover gas purging were reduced through increased $O_2$ additions to the cover gas, 2) the 'old' resin columns were not used during re-start of the reactor from outage, 3) efforts were made to minimize air ingress, 4) the maximum service time of moderator ion-exchange columns were restricted to about 80 days. Through the improvements, the carbon-14 emission from each PHWR reactor returned to the normal levels during the remainder of 1999 and during 2000. We carried out a special surveillance at W-1 and W-3 from September 2001 to August 2002 to properly evaluate ways to optimize the use of moderator ion exchange resins from a C-14 perspective. The surveillance showed that only data that provided an operational marker for deciding when to remove the IX-resin column is an observed increase in the C-14 stack emissions themselves. Also, it is shown that any increase over the rate of 0.4 Ci $month^{-1}$ for two consecutive weeks may be the indication for an ion-exchange resin column change, especially if the IX-resin column has been in service for more than 80 days.

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가스분무장치에서 열유동 특성에 관한 전산해석 (Numerical Simulation on Flow and Heat Transfer in a Gas Atomizer)

  • 이성연
    • 한국분말재료학회지
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    • 제4권1호
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    • pp.55-62
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    • 1997
  • Flow and heat transfer characteristics of gas, and trajectories and cooling characteristics of droplets/particles in a gas atomizer were investigated by a numerical simulation using FLUENT code. Among several kinds of solution method, the k-$\varepsilon$ turbulent model, power-law scheme, SIMPLE algorithm is adopted in this study. Momentum and heat exchange between a continuous phase(gas) and a dispersed phase(particle) were taken into account. Particle trajectories are simulated using the Lagrangian method, and Rosin-Rammler formula is used for the particle size distribution. Streamlines, velocities and pressures of gas, and trajectories, velocities and cooling rates of particles have been investigated for the various gas inlet conditions. Small but very intensive recirculation is found just below the melt orifice, and this recirculation seems to cause the liquid metal to spread radially. Particle trajectory depends on the particle size, the location of particle formation and the turbulent motion of gas. Small particle cools down rapidly, while large diameter particles solidify slowly, and this is mainly due to the differences in thermal inertia.

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가스 제트 모델을 이용한 DME 분무 해석의 격자 의존성 저감 (Reduction of Grid Size Dependency in DME Spray Modeling with Gas-jet Model)

  • 오윤중;김사엽;이창식;박성욱
    • 한국분무공학회지
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    • 제15권4호
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    • pp.170-176
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    • 2010
  • This paper describes the grid-size dependency of the conventional Eulerian-Lagrangian method to spray characteristics such as spray penetration and SMD in modeling DME sprays. In addition, the reduction of the grid-size dependency of the present Gas-jet model was investigated. The calculations were performed using the KIVA code and the calculated results were compared to those of experimental result. The results showed that the conventional Eulerian-Laglangian model predicts shorter spray penetration for large cell because of inaccurate calculation of momentum exchange between liquid and gas phase. However, it was shown that the gas-jet model reduced grid-size dependency to spray penetration by calculating relative velocity between liquid and ambient gas based on gas jet velocity.

압력조절환기법과 용적조절환기법의 호흡역학 몇 가스교환의 비교 (Comparison of Respiratory Mechanics and Gas Exchange Between Pressure-controlled and Volume-controlled Ventilation)

  • 정성환;최원준;이정아;김진아;이문우;신형식;김미경;최강현
    • Tuberculosis and Respiratory Diseases
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    • 제46권5호
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    • pp.662-673
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    • 1999
  • 연구배경 : Pressure-controlled ventilation(PCV)은 최근 호흡부전 환자에게서 자주 사용되는 환기방식이다. 이론적으로 PCV은 초기에 높은 기류를 제공하므로 volume-controlled ventilation(VCV)에 비해 최고흡기압이 낮고 가스교환에 이점이 있을 것으로 사료된다. 그러나 PCV에서 최고흡기압이 낮은 것에 대해서는 대부분의 보고가 일치하고 있으나 가스교환에 대해서는 상반된 결과를 보고하고 있다. 따라서 본 연구는 호흡부전 환자에서 PCV과 VCV간의 호흡역학과 가스교환의 비교 및 I : E ratio의 변동에 따른 차이가 있는지를 알아보고자 본 연구를 시행하였다. 방 법 : 호흡부전으로 기계호흡을 받고 있는 9명의 환자를 대상으로 하였다. 각 대상환자에서 흡기산소농도, 일회호흡용적, 호흡수 및 호기말양압은 변화시키지 않고, PCV와 VCV을 번갈아 적용하고 I : E ratio를 1 : 2, 1 : 1.3 및 1.7 : 1로 변화시키면서 기도압과 동맥혈 가스분석, 호기 이산화탄소 농도를 측정하여 PCV과 VCV 간의 호흡역학과 가스교환을 비교하였다. 결 과 : PCV과 VCV 모두에서 I : E ratio를 증가시킴에 따라 평균기도압이 증가하였고, $PaCO_2$와 생리적 사강이 감소하였다. 그러나 P(A-a)$O_2$는 변하지 않았다. 각각의 I : E ratio 모두에서 최고흡기압은 PCV시 더 낮았으며, 평균기도압은 PCV에서 더 높았다. 그러나 $PaCO_2$, 생리적 사강 및 P(A-a)$O_2$는 PCV과 VCV간의 차이를 보이지 않았다. 결 론 : 동일한 일회호흡용적, 호흡수 및 I : E ratio 상태에서는 두 환기 양식의 차이에 따른 가스교환의 차이가 없었다.

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