• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.561-566
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• 2008

The reciprocating compressor is widely used in the industry field, because it has simple principle and high efficiency. In this work, in order to improve design of discharge passage line in hydrogen compression system Numerical analysis was conducted. General information about an internal gas flow is presented by numerical analysis approach. Relating with hydrogen compressing system, which have an important role in hydrogen energy utilization, this should be a useful tool to observe the flow quickly and clearly. Flow characteristic analysis, including velocity, pressure and turbulence kinetic energy distribution of hydrogen gas going out from the cylinder to discharge-path line are presented in this paper. Discharge-passage model is designed based on real model of hydrogen compressor. Pressure boundary conditions are applied considering the real condition of operating system. The result shows velocity, pressure and turbulent kinetic energy are not distributed uniformly along the passage of the Hydrogen system. Path line or particles tracks help to demonstrate flow characteristics inside the passage. The existence of vortices and flow direction can be precisely predicted. Based on this result, the design improvement might be done.

• Transactions of the Korean Society of Mechanical Engineers
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• v.11 no.3
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• pp.501-508
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• 1987

Experimental studies of particle (TiO$\_$2/) deposition from the laminar hot gas particle flow (about 1565K) onto the cold wall surface (about 1215K-1530K) were carried out by the 'real time' laser light reflectivity method (LLRM) and the photographs of scanning electron microscope(SEM). The LLRM was used for the measurement of thermophoretic deposition rates of small particles (d$\_$p/<3.mu.m), and the photographs of SEM were used for determining what factors control the collection of particles having diameters ranging from 0.2 to 30 microns. Two phenomena are primarily responsible for transport of the particles across the laminar boundary layers and deposition: (1) particle thermophoresis (i.e. particles migration down a temperature gradient), and (2) particle inertial impaction, the former effect being especially larger factor of the particle deposition in its size over the range of 0.2 to 1 microns. And also, this study indicates that thermophoresis can be important for particles as large as 15 microns. Beyond d$\_$p/=16.mu.m, this effect diminishes and the inertial impaction is taken into account as a dominant mechanism of particle deposition. The results of present experiments found to be in close agreement with existing theories.

• International Journal of Automotive Technology
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• v.7 no.1
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• pp.1-7
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• 2006

The ignition delay of a dual fuel system has been numerically investigated by adopting a constant volume chamber as a model problem simulating diesel engine relevant conditions. A detailed chemical kinetic mechanism, consisting of 28 species and 135 elementary reactions, of dimethyl ether (DME) with methane ($CH_{4}$) sub-mechanism has been used in conjunction with the multi-dimensional reactive flow KIVA-3V code to simulate the autoignition process. The start of ignition was defined as the moment when the maximum temperature in the combustion vessel reached to 1900 K with which a best agreement with existing experiment was achieved. Ignition delays of liquid DME injected into air at various high pressures and temperatures compared well with the existing experimental results in a combustion bomb. When a small quantity of liquid DME was injected into premixtures of $CH_{4}$/air, the ignition delay times of the dual fuel system are longer than that observed with DME only, especially at higher initial temperatures. The variation in the ignition delay between DME only and dual fuel case tend to be constant for lower initial temperatures. It was also found that the predicted values of the ignition delay in dual fuel operation are dependent on the concentration of the gaseous $CH_{4}$ in the chamber charge and less dependent on the injected mass of DME. Temperature and equivalence ratio contours of the combustion process showed that the ignition commonly starts in the boundary at which near stoichiometric mixtures could exists. Parametric studies are also conducted to show the effect of additive such as hydrogen peroxide in the ignition delay. Apart from accurate predictions of ignition delay, the coupling between multi-dimensional flow and multi-step chemistry is essential to reveal detailed features of the ignition process.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07a
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• pp.332-335
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• 2004

Boron Phosphide films were deposited on(III) Si substrate at $650^{\circ}C$, by the reaction of $B_2H_6$ with $PH_3$ using CVD. $N_2$ was employed as carrier gas. The optimal gas rates were 20 ml/min for $B_2H_6$, 60 ml/min for $PH_3$ ml/min and $1{\ell}/min$ for $N_2$. The films were annealed for 1hour in $N_2$ ambient at $550^{\circ}C$ and measured. The measurement of AFM shows that the average surface roughness is each $10.108{\AA}$ and $29.626{\AA}$. So, we could know every commonplace thing. The measurement of XRD shows that the films have the preferred orientation of(1 0 1). From SEM images, we could see that Boron Phosphide is showed of a structure, which is grain size, which is grain boundary size. Also, the measurement of AES is shown the films have $B_{13}P_2$ Stoichiometry. From WDX See that ingredient is detected each Boron and Phosporus. So, we could see that deposited BP thin film. In this study, we obtained the BP thin film by deposited in atmosphere pressure, and known to applicate as microwave absorbtion material of BP thin film.

• Membrane Journal
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• v.16 no.4
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• pp.252-258
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• 2006

A numerical analysis was performed for a separation process of carbon dioxide from a flue gas stream using polyethersulfone hollow fiber membranes. Countercurrent flow governing equations were regarded to be two point boundary-value problem and the nonlinear ordinary differential equation were simultaneously solved using the finite- difference method. A computer program was developed using the Compaq Visual Fortran 6.6 software. The carbon dioxide permeate driving force and the fred gas residence time at the inside of membrane were found to be very important factors affecting the permeation characteristics of carbon dioxide. The carbon dioxide concentration in the permeate and the flow rate of the permeate were found to be slightly larger by a few percent with a countercurrent flow analysis than those with a cocurrent flow analysis.

• Journal of the Korean Geosynthetics Society
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• v.17 no.4
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• pp.81-92
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• 2018

Recently, the use of natural gas has steadily increased due to its economical advantage and increased demand of clean energy uses. Accordingly, construction of LNG storage tanks is also increased. Secure of the stability of LNG tanks storage requires high technology as natural gas is stored in a liquid state for efficiency of storage. When a cryogenic LNG fluid leaks on ground due to a defect in LNG tank, damage is expected to be significant. Many researchers evaluated the critical and negative effects of LNG leakage, but there is limited research on the effect of cryogenic fluid leakage on the ground supporting LNG tanks. Therefore, in this study, the freezing expansion of the ground during cryogenic LNG fluid leakage was evaluated considering various outflow situations and ground conditions. The LNG leakage scenarios were simulated based on numerical analyses results varying the surcharge load, temperature boundary conditions, and soil types including freeze-sensitive soil. Consequently, short and long term ground temperature variations after LNG leakage were evaluated and the resulting ground behavior including vertical displacement behavior and porosity were analyzed.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.57 no.2
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• pp.149-161
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• 2021

The concern on the greenhouse gas emission is strongly increasing globally. In fishery industry section, the greenhouse gas emissions are an important issue according to The Paris Climate Change Accord in 2015. The Korean government has a plan to reduce the GHG emissions as 4.8% compared to the BAU in fisheries until 2020. Furthermore, the Korean government has also declared to achieve the carbon neutrality in 2050 at the Climate Adaptation Summit 2021. However, the investigation on the GHG emissions from Korean fisheries did not carry out extensively. Most studies on GHG emissions from Korean fishery have dealt with the GHG emissions by fishery classification so far. However, follow-up studies related to GHG emissions from fisheries need to evaluate the GHG emission level by species to prepare the adoption of environmental labels and declarations (ISO 14020). The purpose of this research is to investigate which degree of GHG emitted to produce the species (hairtail and small yellow croaker) from various fisheries. Here, we calculated the GHG emission to produce the species from the fisheries using the Life Cycle Assessment method. The system boundary and input parameters for each process level are defined for the LCA analysis. The fuel use coefficients of the fisheries for the species are also calculated according to the fuel type. The GHG emissions from sea activities by the fisheries will be dealt with. Furthermore, the GHG emissions for producing the unit weight species and annual production are calculated by fishery classification. The results will be helpful to understand the circumstances of GHG emissions from Korean fisheries.

• Korean Journal of Metals and Materials
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• v.50 no.9
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• pp.659-667
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• 2012

Alloy 617 is a Ni-base superalloy and a candidate material for the intermediate heat exchanger (IHX) of a very high temperature gas reactor (VHTR) which is one of the next generation nuclear reactors under development. The high operating temperature of VHTR enables various applications such as mass production of hydrogen with high energy efficiency. Alloy 617 has good creep resistance and phase stability at high temperatures in an air environment. However, it was reported that the mechanical properties decreased at a high temperature in an impure helium environment. In this study, high-temperature corrosion tests were carried out at $850^{\circ}C-950^{\circ}C$ in a helium environment containing the impurity gases $H_2$, CO, and $CH_4$, in order to examine the corrosion behavior of Alloy 617. Until 250 h, Alloy 617 specimens showed a parabolic oxidation behavior at all temperatures. The activation energy for oxidation in helium environment was 154 kJ/mol. The SEM and EDS results elucidated a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbides. The thickness and depths of degraded layers also showed a parabolic relationship with time. A normal grain growth was observed in the Cr-rich surface oxide layer. When corrosion tests were conducted in a pure helium environment, the oxidation was suppressed drastically. It was elucidated that minor impurity gases in the helium would have detrimental effects on the high-temperature corrosion behavior of Alloy 617 for the VHTR application.

• Journal of Electrochemical Science and Technology
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• v.13 no.1
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• pp.112-119
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• 2022

Molten carbonate fuel cells (MCFCs) are environmentally friendly, large-capacity power generation devices operated at approximately 650℃. If MCFCs are to be commercialized by improving their competitiveness, their cell life should be increased by operating them at lower temperatures. However, a decrease in the operating temperature causes a reduction in the cell performance because of the reduction in the electrochemical reaction rate. The cell performance can be improved by introducing a coating on the cathode of the cell. A coating with a high surface area expands the triple phase boundaries (TPBs) where the gas and electrolyte meet on the electrode surface. And the expansion of TPBs enhances the oxygen reduction reaction of the cathode. Therefore, the cell performance can be improved by increasing the reaction area, which can be achieved by coating nanosized LiCoO₂ particles on the cathode. However, although a coating improves the cell performance, a thick coating makes gas difficult to diffuse into the pore of the coating and thus reduces the cell performance. In addition, LiCoO₂-coated cathode cell exhibits stable cell performance because the coating layer maintains a uniform thickness under MCFC operating conditions. Therefore, the performance and stability of MCFCs can be improved by applying a LiCoO₂ coating with an appropriate thickness on the cathode.

• Economic and Environmental Geology
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• v.55 no.6
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• pp.617-632
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• 2022

In recent years, environmental pollution and determining the main factors causing this pollution have become an important issue. This study investigates the relationship between the agricultural sector and environmental pollution in Azerbaijan for 1992-2018. The dependent variable in the study is the agricultural greenhouse gas emissions (CO₂ equivalent). Eight variables were selected as explanatory variables: four agricultural inputs and four agricultural macro indicators. Unit root tests, ARDL boundary test, FMOLS, DOLS and CCR long-term estimators, Granger causality analysis, and variance decomposition analyses were used to investigate the effect of these variables on agricultural emissions. The results show that chemical fertilizer consumption, livestock number, and pesticide use positively and statistically significantly affect agricultural emissions from agricultural input variables. In contrast, agricultural energy consumption has a negative and significant effect. From agricultural macro indicator variables, it was found that the crop and animal production index had a positive and significant effect on agricultural emissions. According to the Granger causality test results, it was concluded that there are a causality relationship from chemical fertilizer consumption, livestock number, crop and livestock production index variables towards agricultural emissions. Considering all the results obtained, it is seen that the variables that have the most effect on the increase in agricultural emissions in Azerbaijan are the number of livestock, the consumption of chemical fertilizers, and the use of pesticides, respectively. The results from the research will contribute to the information on agricultural greenhouse gas emissions and will play an enlightening role for policymakers and the general public.