• Title/Summary/Keyword: Gas Sampling

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Rapid Measurement of VOC Using an Analysis of Soil-Gas (Soil-Gas의 분석을 이용한 휘발성 유기화합물 오염도 신속측정)

  • 김희경;조성용;황경엽
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.3-9
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    • 1998
  • This paper presents soil-gas surveying technique to delineate an area contaminated with volatile organic compounds, which are common solvents and constituents of gasoline. The sampling method of soil-gas surveying is 1) grab sampling, which actively takes sample using a pump, or 2) passive sampling, which takes sample through diffusion in a trap filled with absorbent. The grab sampling shows the level of contamination at a certain location at a certain time, while the passive sampling shows the change in the contamination at a certain location. The analysis of soil gas can be performed with 1) a small portable detectors such as PID (photoionization detector) or FID (flame-ionization detector) to measure the total hydrocarbon in the soil gas, 2) a gas detector tube, which is filled with indicator reagents and changes its color with concentrations of the gas of interest, or 3) a portable GC (gas chromatograph), which can analyze different compounds simultaneously. The soil-gas surveying technique is a much less expensive method to investigate area contaminated volatile organic compounds and thus can be used as a screening tool to identify an area, which needs to be further investigated.

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On the Sampling and Transport of Radioactive Aerosols from Waste Thermal Process

  • Yang, Hee-Chul;Kim, Joon-Hyung;Yong Kang
    • Nuclear Engineering and Technology
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    • v.29 no.4
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    • pp.269-279
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    • 1997
  • The errors associated with incorrect sampling and transport of radioactive aerosol from radwaste thermal process off-gas are analyzed and the conditions of representative sampling and correct transport of radioactive aerosol for off-gas system evaluation are discussed. An estimation method of sampling errors for individual radionuclides is proposed and applied to simulated vitrification melter aerosols. Prediction methods for particle deposition in sample transport tube under laminar as well as turbulent flow conditions are also described by example calculations with simulated incinerator off-gas From the results of example calculations and plots, instrumental and operational conditions of radioactive aerosol sampling system with minimized errors and correction methods for nonideal sampling and transport are recommended.

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NUMERICAL ANALYSIS OF A SAMPLING MODULE FOR A FAST RESPONSE EXHAUST GAS ANALYZER

  • Kim, W.S.;Lee, J.H.;Yoo, J.S.;Rhee, B.O.;Park, J.I.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.149-154
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    • 2007
  • The engine behavior in a transient condition is important to not only emission regulations but also fuel economy. A fast response gas analyzer can be a useful tool to investigate exhaust gas in a transient operation. It should be designed to analyze gas concentration with a short time constant by a fast sampling module and an appropriate measuring method for each emission element. In this study, a new fast sampling module is introduced and flow analysis is performed by numerical simulation. The analysis has shown the proper operating condition and the sensitivity of the module for practical application. Calculated flow to the sampling module has $0.5{\sim}4%$ error, while backflow toward the expansion tube is expected when pressure in CP (Constant Pressure) chamber is over 0.6 bar. For a stable supply of flow to the optical cell, sample gas pressure should be in the range, $0.35{\sim}1.90$ bar, when the pressure in the CP camber and the optical cell are 0.2 bar and 0.158 bar, respectively.

Aerosol Filtration/Sampling Device Based on Irrigated Rotating Wires

  • M. J. Shaw;M. R. Kuhlman;;J. A. Gieseke
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.265-267
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    • 2000
  • The objective of this study is to analyze, design and evaluate a new gas cleanup or sampling system that will remove erosive, corrosive, and fouling contaminants present in an effluent stream as either solid or liquid particles providing a clean gas stream. The gas clean-up or sampling system considered in this study is an irrigated, rotating element device. The device consists of a central disk-like hub from which emanate radially wires or cylindrical elements. (omitted)

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The Use of Gas Chromatograph for the Measurement of Engine Exhaust Gas Composition (엔진 배기가스 성분 측정 을 위한 Gas Chromatograph 의 이용)

  • 김승수;정영교
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.6
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    • pp.743-749
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    • 1985
  • In this study the usefulness of Gas Chromatograph for the measurement of engine exhaust gas composition was confirmed. It was found that the composition of standard gas which was used for the calibration of Gas Chromatograph should not be greatly different from that of exhaust gas. Although self-evident, it cannot be overemphasized that utmost attention should be paid to prevent even a minute amount of air being mixed into the gas throughout the sampling process.

Gas-Particle Partitioning of PCBs in Ambient Air, Yokohama Japan (일본 요코하마 대기 중 PCBs의 가스-입자 분배)

  • Kim Kyoung-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.3
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    • pp.285-293
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    • 2005
  • This study was aimed at estimation of gas-particle partitioning of polychlorinated biphenyls (PCBs) in ambient air. The samples were collected at urban site in Japan from March 2002 to January 2003. The concentration of total PCBs (from 4 CB to 10 CB) and TEQ (Toxic equivalent) ranged from 62 to $247\;pg/m^3$ and from 2 to $14\;fgTEQ/m^3 $, respectively. The average contribution $(\%)$ of gas phase to total PCBs concentration was above $80\%$, which suggests that in the atmosphere PCBs predominantly existed in the gas phase. The weak correlations between total PCBs concentration and temperature was found. However this result was due to a typhoon during summer and raining during sampling period. The gas-particle partition coefficient (Kp) was obtained as a function of temperature. The partition ratio of gaseous and particulate phase PCBs can be estimated for an arbitrary temperature. The plot of gas/particle partition coefficient (log Kp) vs. sub-cooled liquid vapor pressure $(log\;P_L)$ had reasonable correlations for individual samples but the slope varied among the samples (coefficients of determination for log Kp versus log $P_L$ plot were> 0.76 $(p<0.0001)$, except for 3 samples). As a result, the variations in the slope among the sampling period may be due to change of temperature, raining during sampling period and wind in this study.

Filter-based Correction for Positive Sampling Artifacts in the Determination of Ambient Organic Carbon (여과지를 이용한 유기탄소의 측정 오차 보정)

  • Kang, Byung-Wook;Yeon, Ik-Jun;Cho, Byung-Yeol;Park, Sang-Chan;Lee, Hak-Sung;Jeon, Jun-Min;Na, Kwang-Sam
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.1
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    • pp.63-72
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    • 2011
  • This study describes the impact of positive sampling artifact caused by a filter-based sampling in the determination of ambient organic carbon (OC). Three different sampling media combinations were employed for this investigation: (1) Quartz filter-alone (Q-alone), (2) quartz filter behind quartz-fiber filter (QBQ), and (3) quartz filter and quartz filter behind Teflon filter (Q-QBT). The measurement of ambient OC was carried out at a semi-urban site near oceanside at the end of November of 2008. It was found that Q-alone sampling configuration resulted in a higher OC than QBQ and Q-QBT by 14% and 28%, respectively due to no correction for positive artifact caused by adsorption of gas-phase OC onto the filter. A lower quantity of OC was collected from the backup quartz filter on QBQ than that from Q-QBT. A possible explanation is that the front quartz filter of QBQ was not fully saturated with gas-phase OC during the sampling period, allowing smaller amount of gas-phase OC to reach the backup quartz filter. The contribution of positive artifact to $PM_{2.5}$ mass was approximately 2.15 ${\mu}g/m^3$ which is equivalent to 6% in terms of Q-QBT sampling configuration. The positive artifact was found to be more dominated during summer than during winter, showing temperature dependence. It was concluded that Q-QBT sampling configuration offers less impact of positive artifact on ambient OC sampling than QBQ in quantification of OC.

An Experimental Study of Silica Particle Growth in a Coflow Diffusion Flame Utilizing Light Scattering and Local Sampling Technique (II) - Effects of Diffusion - (광산란과 입자포집을 이용한 동축류 확산화염 내의 실리카 입자의 성장 측정(II) - 확산의 영향 -)

  • Cho, Jaegeol;Lee, Jeonghoon;Kim, Hyun Woo;Choi, Mansoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1151-1162
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    • 1999
  • The effects of radial heat and $H_2O$ diffusion on the evolution of silica particles in coflow diffusion flames have been studied experimentally. The evolution of silica aggregate particles in coflow diffusion flames has been measured experimentally using light scattering and thermophoretic sampling techniques. The measurements of scattering cross section from $90^{\circ}$ light scattering have been utilized to calculate the aggregate number density and volume fraction using with combination of measuring the particle size and morphology through the localized sampling and a TEM image analysis. Aggregate or particle number densities and volume fractions were calculated using Rayleigh-Debye-Gans and Mie theory for fractal aggregates and spherical particles, respectively. Flame temperatures and volumetric differential scattering cross sections have been measured for different flame conditions such as inert gas species, $H_2$ flow rates, and burner injection configurations to examine the relation between the formation of particles and radial $H_2O$ diffusion. The comparisons of oxidation and flame hydrolysis have also been made for various $H_2$ flow rates using $N_2$ or $O_2$ as a carrier gas. Results indicate that the role of oxidation becomes dominant as both carrier gas($O_2$) and $H_2$ flow rates increases since the radial heat diffusion precedes $H_2O$ diffusion in coflow flames used in this study. The effect of carrier gas flow rates on the evolution of silica particles have also been studied. When using $N_2$ as a carrier gas, the particle volume fraction has a maximum at a certain carrier gas flow rate and as the flow rate is further increased, the hydrolysis reaction Is delayed and the spherical particles finally evolves into fractal aggregates due to decreased flame temperature and residence time.

Forecasting Daily Demand of Domestic City Gas with Selective Sampling (선별적 샘플링을 이용한 국내 도시가스 일별 수요예측 절차 개발)

  • Lee, Geun-Cheol;Han, Jung-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6860-6868
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    • 2015
  • In this study, we consider a problem of forecasting daily city gas demand of Korea. Forecasting daily gas demand is a daily routine for gas provider, and gas demand needs to be forecasted accurately in order to guarantee secure gas supply. In this study, we analyze the time series of city gas demand in several ways. Data analysis shows that primary factors affecting the city gas demand include the demand of previous day, temperature, day of week, and so on. Incorporating these factors, we developed a multiple linear regression model. Also, we devised a sampling procedure that selectively collects the past data considering the characteristics of the city gas demand. Test results on real data exhibit that the MAPE (Mean Absolute Percentage Error) obtained by the proposed method is about 2.22%, which amounts to 7% of the relative improvement ratio when compared with the existing method in the literature.

Development of an Evaluation Method for the Flow Rate Performance of Gas Sampling Pumps Using Adsorbent Tubes (흡착튜브를 이용한 가스상물질 채취용 펌프의 유량성능 평가방법)

  • Kim, Nam Hee;Song, Ho June;Kim, Ki Youn;Ma, Hye Lan;Yi, Gwang Yong;Jeong, Jee Yeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.2
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    • pp.201-207
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    • 2014
  • Objectives: Flow rate stability is very important for obtaining reliable measurements. However there is no easily used method for checking whether the flow rate set at the initial stage is sustained during sampling. The purpose of this study was to develop a method to evaluate the flow rate performance of gas sampling pumps with adsorbents commonly used to sample gases. Materials and methods: We tested the back pressure of gas sampling pumps commonly used in Korea with adsorbents such as charcoal and silica tubes and attempted to discover the combination conditions of adsorbents in accordance with back pressure required by ISO standard 13137. Results: We found the combination of sampling adsorbents to be applicable to the pressure drop required by the ISO standard for evaluating flow rate stability under increasing pressure drop and long term (eight-hour) performance. Conclusions: This evaluation method of using a sampling media matrix for checking flow rate stability as proposed by this study could be a highly useful tool for determining the reliability of the performance pumps before sampling.