• Title/Summary/Keyword: Gas Mixtures

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A Study on the Co-pyrolysis Characteristics of PVC and PS Mixtures with ZnO (ZnO를 첨가한 PVC와 PS 혼합물의 열분해 특성에 관한 연구)

  • Oh, Sea Cheon;Jung, Myung Uk;Kim, Hee Taik;Lee, Hae Pyeong
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.513-518
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    • 2005
  • The co-pyrolysis characteristics of poly(vinyl chloride) (PVC) and polystyrene (PS) mixtures with ZnO have been studied by thermogravimetry (TG) and gas chromatograph-mass spectrometry (GC-MS) under various mixing ratios and reaction temperatures. From this work, it was found that the yield of liquid products increased as PS in mixtures increased, whereas that of gaseous products decreased. And as ZnO in mixtures increased, the yields of gaseous products and HCI decreased. The optimal reaction temperature for the maximum yield of liquids products and the control of HCI gas was $500^{\circ}C$.

Analysis on the Mean energy of electrons in $SF_6-Ar$ Mixtures Gas used by MCS-BEq Algorithm ($SF_6-Ar$ 혼합기체(混合氣體)의 MCS-BEq알고리즘에 의한 전자(電子) 평균(平均)에너지 해석(解析))

  • Kim, Sang-Nam;Ha, Sung-Chul
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.05a
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    • pp.281-284
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    • 2004
  • Mean energy of electrons in $SF_6-Ar$ Mixtures Gas used by MCS-BEq algorithm has been analysed over the E/N range $30{\sim}300[Td]$ by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6-Ar$, 0.1[%] and 5.0[%], $SF_6-Ar$ mixtures were measured by time-of-flight(TOF) method. The transport Coefficients for electrons in (100[%])$SF_6$. (100[%])Ar, (0.2[%])$SF_6-Ar$ and (0.5[%]) $SF_6-Ar$, (5.0[%]) $SF_6-Ar$, (0.1[%])$SF_6-Ar$ mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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Effect of irradiation on the oxidation kinetics of TODGA-based extraction mixtures at atmospheric pressure

  • Skvortsov, I.V.;Belova, E.V.;Yudintsev, S.V.
    • Nuclear Engineering and Technology
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    • v.52 no.9
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    • pp.2034-2040
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    • 2020
  • The gas evolution from mixtures consisting of 0.2 M solution of N,N,N',N'-tetra-n-octyldiglycolamide (TODGA) in n-alcohol (n-decanol or n-nonanol) with Isopar-M diluent was investigated during thermal oxidation. The effect of ionizing radiation on their thermal stability has been studied. It has been determined that the volume of gaseous thermolysis products increases by 260% in the case of n-nonanol and 80% in the case of n-decanol compared to non-irradiated solutions. It has been shown that the gas evolution rate and gas volume increase when the irradiated mixture saturated with nitric acid is heated. However, there are no prerequisites for the development of autocatalytic oxidation.

Bonding structure of the DLC films deposited by RE-PECVD (RE-PECVD법에 의해 증착된 DLC박막의 결합 특성)

  • 최봉근;신재혁;안종일;심광보
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.1
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    • pp.27-32
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    • 2004
  • The diamond-like carbon (DLC) films were deposited on the Si (100) wafer by a rf-PECVD method as a function of the mixture rate of methane-hydrogen gas and bias voltage. The bonding structure and mechanical properties of these deposited DLC films were investigated using FT-IR, Raman, and nano-indenter. The deposition rates of DLC films increased with increased flow rate of methane in the gas mixtures and increased bias voltage. The $sp^3/sp^2$ bonding ratio of carbon in thin film and the hardness increased with increasing flow rate of hydrogen in the gas mixtures and increasing bias voltage.

Impulse breakdown Characteristics in SF6/N2, Gas Mixtures with a Temperature Variation (온도변화에 따른 SF6/N2 혼합가스의 임펄스 절연파괴특성)

  • Li, Feng;Lee, Bok-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.12
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    • pp.79-86
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    • 2008
  • This paper presents the experimental results of impulse breakdown characteristics in $SF_6/N_2$ gas mixtures under a highly non-uniform electric field with a change in temperature. The test temperature ranges from -25[$^{\circ}C$] to 25[$^{\circ}C$]. The processes of impulse preliminary breakdown developments were analyzed by the measurements of current pulse and luminous signals. As a result, the temperature dependance of breakdown voltage for the negative polarity was much stronger than that for the positive polarity. When increasing the temperature, The leader stepping time for the negative polarity was shown to be longer than that for the positive polarity. The results presented in this paper can be used as a useful information in designing the gas insulation lines with prominent ability for lightning surge.

High Temperature Corrosion in Carbon-Rich Gases

  • Young, D.J.
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.69-76
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    • 2008
  • Common methods for large scale hydrogen production, such as steam reforming and coal gasification, also involve production of carbonaceous gases. It is therefore necessary to handle process gas streams involving various mixtures of hydrocarbons, $H_2$, $H_2O$, CO and $CO_2$ at moderate to high temperatures. These gases pose a variety of corrosion threats to the alloys used in plant construction. Carbon is a particularly aggressive corrodent, leading to carburisation and, at high carbon activities, to metal dusting. The behaviour of commercial heat resisting alloys 602CA and 800, together with that of 304 stainless steel, was studied during thermal cycling in $CO/CO_2$ at $650-750^{\circ}C$, and also in $CO/H_2/H_2O$ at $680^{\circ}C$. Thermal cycling caused repeated scale separation, which accelerated chromium depletion from the alloy subsurface regions. The $CO/H_2/H_2O$ gas, with $a_C=2.9$ and $p(O_2)=5\times10^{-23}$ atm, caused relatively rapid metal dusting, accompanied by some internal carburisation. In contrast, the $CO/CO_2$ gas, with $a_C=7$ and $p(O_2)=10^{-23}-10^{-24}$ atm caused internal precipitation in all three alloys, but no dusting. Inward diffusion of oxygen led to in situ oxidation of internal carbides. The very different reaction morphologies produced by the two gas mixtures are discussed in terms of competing gas-alloy reaction steps.

Binary and ternary gas mixtures of He-Ne-Xe for improvement of vacuum ultraviolet luminous efficiency in ac-PDPs.

  • Jung, Kyu-Bong;Lee, Jun-Ho;Park, Won-Bae;Jeon, Wook;Oh, Phil-Young;Cho, Guang-Sup;Uhm, Han-Sup;Choi, Eun-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.522-524
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    • 2004
  • The improvement of luminance and luminous efficiency is the one of the most important part in AC-PDPs. To achieve high luminance and luminous efficiency, high VUV emission efficiency is needed. We measured the emission spectra of vacuum ultraviolet(VUV) rays in surface discharge AC-PDP with binary and ternary gas mixtures of Ne-Xe and He-Ne-Xe. The influence of He-Ne-Xe gas-mixture ratio on excited $Xe^{\ast}$ resonant atoms and $Xe_2$$^{\ast}$ dimers has been investigated. It is found that luminous efficiency of ternary gas mixture, He-Ne-Xe, is shown to be much higher than that of binary gas mixture of Ne-Xe.

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Study on Combustion Characteristics of the Opposed Flames for Different Oxidant Compositions by Considering the Non-gray Radiation by the Gas Mixtures (비회색 혼합가스 복사를 고려한 산화제의 성분 변화에 따른 대향류화염의 연소 특성 연구)

  • Park, Won-Hee;Jo, Bum-Jin;Park, Jong-Hyuk;Kim, Tae-Kuk
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1341-1346
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    • 2004
  • Detailed flame structures of the opposed flames formed for different oxidant compositions are studied numerically. The detailed chemical reactions are modeled by using the CHEMKIN code. Only the $CO_{2}$ and $H_{2}O$ are assumed to participate by absorbing the radiative energy while all other gases are assumed to be transparent. The discrete ordinates method and a narrow band based WSGGM with a gray gas regrouping technique are applied for modeling the radiative transfer through non-homogeneous and non-isothermal combustion gas mixtures generated by the opposed flow flames. The results show that the different radiation model can cause different results for flame structures and the WSGGM with gray gas regrouping is successful in modeling the opposed flames with non-gray gas mixture. The results also show that a reasonable information on the flame structure can be obtained from the modeling by considering different chemical compositions of the oxidant.

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A Study on Characteristics of Insulation Breakdown and Surface Discharge by the Oxygen Concentration in the Dry Air in Quasi-Uniform Field (준평등전계중 Dry Air내 산소의 농도에 따른 절연파괴 및 연면방전 특성 연구)

  • Beak, Jong-Hyun;Seok, Jeong-Hoo;Choi, Byoung-Ju;Bae, Sungwoo;Kim, Ki-Chai;Park, Won-Zoo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.11
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    • pp.41-46
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    • 2015
  • This study was conducted to discover a substitute of $SF_6$ gas. $SF_6$ gas is widely used across the industries. Thanks to superior electrical properties, in particular, it has been commonly used in electrical industry. However, there have been a lot of studies on its serious effect on global warming. As a substitute of this synthetic gas, a mixture of dry air and $N_2/O_2$ was chosen in this study. In case of $N_2/O_2$, dielectric strength differs depending on the mixing ratio. This study examined dielectric breakdown and flashover after adjusting oxygen percentage in the dry air. This test was conducted in a quasi-uniform electric field depending on pressure, oxygen concentration and gas mixtures. The test results found that dielectric voltage and flashover voltage were the highest at a certain oxygen concentration. It is the results of this photoionization and electron attachment of oxygen.

In Vitro Evaluation of Probiotic Properties of Two Novel Probiotic Mixtures, Consti-Biome and Sensi-Biome

  • You Jin Jang;Bonggyu Min;Jong Hyun Lim;Byung-Yong Kim
    • Journal of Microbiology and Biotechnology
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    • v.33 no.9
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    • pp.1149-1161
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    • 2023
  • Changes in the gut microbiome cause recolonization by pathogens and inflammatory responses, leading to the development of intestinal disorders. Probiotics administration has been proposed for many years to reverse the intestinal dysbiosis and to enhance intestinal health. This study aimed to evaluate the inhibitory effects of two newly designed probiotic mixtures, Consti-Biome and Sensi-Biome, on two enteric pathogens Staphylococcus aureus and Escherichia coli that may cause intestinal disorders. Additionally, the study was designed to evaluate whether Consti-Biome and Sensi-Biome could modulate the immune response, produce short-chain fatty acids (SCFAs), and reduce gas production. Consti-Biome and Sensi-Biome showed superior adhesion ratios to HT-29 cells and competitively suppressed pathogen adhesion. Moreover, the probiotic mixtures decreased the levels of pro-inflammatory cytokines, such as tumor necrosis factor-α, interleukin (IL)-6 and IL-1β. Cell-free supernatants (CFSs) were used to investigate the inhibitory effects of metabolites on growth and biofilms of pathogens. Consti-Biome and Sensi-Biome CFSs exhibited antimicrobial and anti-biofilm activity, where microscopic analysis confirmed an increase in the number of dead cells and the structural disruption of pathogens. Gas chromatographic analysis of the CFSs revealed their ability to produce SCFAs, including acetic, propionic, and butyric acid. SCFA secretion by probiotics may demonstrate their potential activities against pathogens and gut inflammation. In terms of intestinal symptoms regarding abdominal bloating and discomfort, Consti-Biome and Sensi-Biome also inhibited gas production. Thus, these two probiotic mixtures have great potential to be developed as dietary supplements to alleviate the intestinal disorders.