• 한국환경과학회지
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• 제27권3호
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• pp.219-225
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• 2018

This study was conducted to investigate the possibility of utilizing various types of nozzles and gas-liquid mixers to increase the dissolution rate of plasma gas containing ozone generated in a dielectric barrier plasma reactor. After selecting the air atomizing nozzle with the highest gas dissolution rate among the 13 types of test equipment, we investigated the influence of the operating factors on the air atomizing nozzle to determine the optimal plasma gas dissolution method. The gas dissolution rate was measured by a simple and indirect method, specifically, the measurement of KLa instead of direct measurement of ozone concentration, which requires a longer analysis time. The results showed that the KLa value of the simple mix of air and water was $0.372min^{-1}$, Which is 1.44 times higher than that ($0.258min^{-1}$) of gas emitted from a normal diffuser. Among the nozzles of the same type, the KLa value was highest for the nozzle having the smallest orifice diameter. Among the 13 types of devices tested, the nozzle with highest KLa value was the M22M nozzle, which is a gas-liquid spray nozzle. The relationship between water circulation flow rate and KLa value in the experimental range was linear. The air supply flow rate and KLa value showed a parabolic-type correlation, while the optimum air supply flow rate for the water circulation flow rate of 1.8 L / min is 1.38 times.

• 한국기계가공학회지
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• 제13권4호
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• pp.21-27
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• 2014

The injection molding process has several advantages enabling it to produce large quantities of molded plastic products using a repetitive process. In recent years, it has been necessary to develop an injection molding process with micro/nano-sized patterns for application to the semiconductor industry and to the bio/nano manufacturing industry. In this study, we apply gas pressure to the inside of a mold and consider the gas dissolution phenomenon for a resin filling into a micro pattern with a line structure. Using numerical analysis, we calculate the filling ratio with respect to time for various internal gas pressures and various aspect ratios of the micro-patterns.

• 한국환경과학회지
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• 제26권6호
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• pp.711-717
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• 2017

Dielectric Barrier Discharge (DBD) plasma is a new technique for use in environmental pollutant degradation, which is characterized by the production of hydroxyl radicals as the primary degradation species. Due to the short lifetime of the chemically active species generated during the plasma reaction, the dissolution of the plasma gas has a significant effect on the reaction performance. The plasma reaction performance can be enhanced by combining the basic plasma reactor with a homogenizer system in which the bubbles are destroyed and turned into micro-bubbles. For this purpose, the improvement of the dissolution of plasma gas was evaluated by measuring the RNO (N-dimethyl-4-nitrosoaniline, an indicator of the generation of OH radicals). Experiments were conducted to evaluate the effects of the diameter, rotation speed, and height of the homogenizer, pore size, and number of the diffuser and the applied voltage on the plasma reaction. The results showed that the RNO removal efficiency of the plasma reactor combined with a homogenizer is two times higher than that of the conventional one. The optimum rotor size and rotation speed of the homogenizer were 15.1 mm, and 19,700 rpm, respectively. Except for the lowest pore size distribution of $10-16{\mu}m$, the pore size of the diffuser showed little effect on RNO removal.

• 설비공학논문집
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• 제16권9호
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• pp.863-871
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• 2004

The use of fossil fuels like coal, oil and natural gases around the world causes an increase of the carbon dioxide content in the atmosphere. In order to reduce the concentration of the greenhouse gas, the idea of carbon dioxide sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect. Therefore, in the present study, calculations of the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth by fixed pipeline are performed. The results show that carbon dioxide droplets change to carbon dioxide bubbles in gas phase around 500m in depth, and the droplets are completely dissolved below 500 m in depth if the liquide carbon dioxide is released both at 1,000 m in depth with the initial diameter of 0.007m or less and at 1,500m in depth with the diameter of 0.011m or less.

• Elastomers and Composites
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• 제57권4호
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• pp.215-221
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• 2022

In this study, high-penetration asphalt with low greenhouse gas emissions was used in the asphalt mixing process to reduce the carbon emissions during the reaction due to its capacity to be produced even at low temperatures. In effect, cationic, anionic, and non-ionic dispersants were added and mixed in different feeding ratios, seeking an effective dispersion of the modifiers (SIS, PS, TPEE, and SEBS) into the high-penetration asphalt matrix and forming an asphalt binder with a melting point of 120 ℃. The compatibility of the modifiers and the high-penetration asphalt was examined using SEM and DSC techniques, and the role of NDP-1 as a dispersant was carefully investigated with respect to dissolution time. The analyses showed that: (1) the dispersibility of the asphalt binder is good when the non-ionic dispersant is used; (2) as the concentration of the non-ionic dispersant increases, the dissolution time decreases and the domain size contracts; (3) the ND70-PS has the shortest dissolution time, the lowest agglomeration rate, and a single Tg value.

• 자원리싸이클링
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• 제19권5호
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• pp.3-12
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• 2010

고순도 백금족 금속은 첨단 산업의 기초 소재로 향후 국내 산업의 지속적인 발전에 꼭 필요하다. 국내에는 백금족 금속을 함유한 광물이 전무하므로 백금족 금속을 함유한 여러 폐자원으로부터 백금족 금속을 고순도로 분리 정제할 수 있는 기술의 개발이 시급하다. 백금족 금속의 화학적 성질과 침출거동에 대한 자료를 문헌에서 조사하였다. 또한 향후 백금족 금속과 같은 난용금속의 침출에 이용이 증가할 것으로 예상되는 염소가스를 취입한 염산용액의 열역학적 해석 방법을 소개하였다, 백금족 금속간의 화학적 성질과 침출거동의 미세한 차이정올 이용하면 백금족 금속을 고순도로 회수할 수 있는 기술 개발이 가능하다.

• 한국환경과학회지
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• 제30권5호
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• pp.399-406
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• 2021

The dissolution of ionized gas in dielectric barrier plasma, similar to the principle of ozone generation, is a major performance-affecting factor. In this study, the plasma gas dissolving performance of a gas mixing-circulation plasma process was evaluated using an experimental design methodology. The plasma reaction is a function of four parameters [electric current (X₁), gas flow rate (X₂), liquid flow rate (X₃) and reaction time (X₄)] modeled by the Box-Behnken design. RNO (N, N-Dimethyl-4-nitrosoaniline), an indictor of OH radical formation, was evaluated using a quadratic response surface model. The model prediction equation derived for RNO degradation was shown as a second-order polynomial. By pooling the terms with poor explanatory power as error terms and performing ANOVA, results showed high significance, with an adjusted R² value of 0.9386; this indicate that the model adequately satisfies the polynomial fit. For the RNO degradation, the measured value and the predicted values by the model equation agreed relatively well. The optimum current, gas flow rate, liquid flow rate and reaction time were obtained for the highest desirability for RNO degradation at 0.21 A, 2.65 L/min, 0.75 L/min and 6.5 min, respectively.

• 공업화학
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• 제33권2호
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• pp.229-233
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• 2022

In this study, a gas-liquid hybrid atmospheric pressure plasma reactor of the dielectric barrier discharge method was fabricated and characterized. The solubility of copper oxide in the organic acid solution was increased when argon having a larger atomic weight than helium was used during plasma discharge. There was no significant effect of mixing organic acid solutions under plasma discharge treatment on the variation of copper oxide's solubility. As the applied voltage for plasma discharge and the concentration of the organic acid solution increased, the dissolution and removal power of the copper oxide layer increased. Solubility of copper oxide was more affected by the concentration in organic acid solution rather than the variation of plasma applied voltage. The usefulness of hybrid plasma reactor for the surface cleaning process was confirmed.

• 자원리싸이클링
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• 제26권6호
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• pp.10-19
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• 2017

국내 석탄화력발전소의 습식배연탈황공정에서 탈황용 흡수제로 사용하는 국내산 고품위석회석의 결정구조가 분쇄특성 및 용해특성에 미치는 영향을 연구하였다. 광물학적 결정구조가 다른 제천-단양 지역 석회석 4종을 대상으로 결정구조, 분쇄일지수 및 용해도를 비교한 결과 석회석의 결정크기와 구조에 따라 분쇄일지수 차이가 발생하였으며 분쇄일지수가 상대적으로 낮은 석회석의 용해도가 높은 것으로 나타났다. 이에 따라 석회석의 CaO 함량과 함께 결정구조에 따른 분쇄특성도 중요한 반응인자로 확인되었다.

• Membrane and Water Treatment
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• 제6권2호
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• pp.113-126
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• 2015

Salinity gradient power (SGP) systems have strong potential to generate sustainable clean electricity for 24 hours. Here, we introduce a solid-salt pressure-retarded osmosis (PRO) system using crystal salt powders rather than seawater. Solid salts have advantages such as a small storage volume, controllable solubility, high Gibbs dissolution energy, and a single type of water intake, low pretreatment costs. The power densities with 3 M draw solutions were $11W/m^2$ with exothermic energy and $8.9W/m^2$ without at 35 bar using a HTI FO membrane (water permeability $A=0.375L\;m^{-2}h^{-1}bar^{-1}$). These empirical power densities are ~13% of the theoretical value.