• Title/Summary/Keyword: Gas Clean Up

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Removal of S $O_{2}$ and NO by Dry Sorbent(II) - Efficiency of Cu-Ce and Cu-7Al - (건식법에 의한 이산화황과 산화질소의 제거(II) - Cu-Ce 및 Cu-7Al의 효율 -)

  • 신창섭
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.4
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    • pp.288-294
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    • 1993
  • Flue gas control systems for small-scale combustors must be designed to provide highly effective removal of three criteria pollutants (S $O_{2}$, N $O_{x}$ and particulate matter), and must be safe, reliable and small. These requirements make dry, regenerative clean-up process particularly attractive and this paper describes a new concept for integrated pollutant control : a filter comprised of layered, gas permeable membranes that act as an S $O_{2}$ sorbant, a N $O_{x}$ reduction catalyst and a particulate filter. A mixed metal oxide sorbent, Cu-Ce was used as a sorbent/catalyst and the activity was compared with Cu-7Al. The S $O_{2}$ removal eficiency of Cu-Ce was increased with temperature increase up to 500$^{\circ}$C and the catalytic activity for NO was higher than that of Cu-7Al. By the sulfation of Cu-Ce, the reduction activity was increased at the temperature higher than 350$^{\circ}$C. The regeneration of Cu-Ce was very fast and some amount of elemental sulfar was found.

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The baking analysis for vacuum vessel and plasma facing components of the KSTAR tokamak (KSTAR 토카막 진공용기 및 플라즈마 대향 부품의 탈기체 처리를 위한 가열 해석)

  • Lee, K.H.;Im, K.H.;Cho, S.;Kim, J.B.;Woo, H.K.
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.247-254
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    • 2000
  • The base pressure of vacuum vessel of the KSTAR (Korea Superconducting Tokamak Advanced Research) Tokamak is to be a ultra high vacuum, $10^{-6}{\sim}10^{-7}Pa$, to produce clean plasma with low impurity containments. For this purpose, the KSTAR vacuum vessel and plasma facing components need to be baked up to at least $250^{\circ}C,\;350^{\circ}C$ respectively, within 24 hours by hot nitrogen gas from a separate baking/cooling line system to remove impurities from the plasma-material interaction surfaces before plasma operation. Here by applying the implicit numerical method to the heat balance equations of the system, overall temperature distributions of the KSTAR vacuum vessel and plasma facing components are obtained during the whole baking process. The model for 2-dimensional baking analysis are segmented into 9 imaginary sectors corresponding to each plasma facing component and has up-down symmetry. Under the resulting combined loads including dead weight, baking gas pressure, vacuum pressure and thermal loads, thermal stresses in the vacuum vessel during bakeout are calculated by using the ANSYS code. It is found that the vacuum vessel and its supports are structurally rigid based on the thermal stress analyses.

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A Numerical Study on the Fire Behavior Phenomena in a Special Fire Protection Compartment (특수 방호공간에서 가상화재의 발생으로 인한 화재거동에 관한 수치적 연구)

  • Kim, Tae-Kuk;Son, Bong-Sei
    • Journal of the Korean Society of Hazard Mitigation
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    • v.1 no.1 s.1
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    • pp.157-163
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    • 2001
  • The objective of the present study is to predict the characteristics of the fire and smoke propagations in a clean room. Numerical calculations have been performed by using the finite volume method to obtain temperature and velocity distributions in the clean room. In odor to account for the turbulent flow characteristics, the standard $k-{\varepsilon}$ model is used. From this study, it was found that the fire propagation could be fully developed only after 150 seconds when the ventilation system in the clean room was off. And the smoke mass fraction showed a similar distribution as the gas temperature. Since the simulated fire was proceeded up to $20{\sim}30%$ of the room within 60 seconds. it could be recommended that the occupants should be evacuated from the room within 30 seconds.

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A Study on the Performance Characteristic of Common Rail High Pressure Pump (커먼레일 시스템용 고압펌프의 성능 특성에 관한 연구)

  • Lee, Choon-Tae
    • Journal of Power System Engineering
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    • v.17 no.6
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    • pp.5-10
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    • 2013
  • Diesel engines have the advantages of good fuel efficiency and low emissions. Therefore, car makers have been developed various kinds of diesel engine management system to clean up emissions while improving fuel efficiency. One of them is the common rail system. In the common rail system, diesel fuel is injected into the combustion chamber at ultra high pressures up to 1,800 bar to ensure more complete combustion for cleaner exhaust gas, and highly precise multiple injection reduces NOx emission, combustion noise and vibration. Generally speaking, common rail system consists of booster pump, high pressure pump, common rail, injectors, control valves, and sensors. The high pressure pump receives low pressure fuel from the booster pump and supply high pressure fuel to injectors through the high pressure common injection rail. Therefore, high pressure pump has an important role in common rail system. In this paper, we have investigated the performance of high pressure pump of common rail system.

Production of DME from CBM by KOGAS DME Process (KOGAS DME 공정을 이용한 CBM으로부터 DME 생산)

  • Cho, Won-Jun;Mo, Yong-Gi;Song, Taek-Yong;Lee, Hyen-Chan;Baek, Young-Soon;Denholm, Douglas;Ko, Glen;Choi, Chang-Woo
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.925-933
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    • 2011
  • The traditional feedstock for dimethyl ether (DME) has been natural gas obtained by pipeline from a nearby natural gas or oil field. This report focuses on other feedstock: Coal bed methane (CBM). The resource availability and suitability of CBM for DME manufacturing have been investigated. CBM in a short time has become an important industry, providing an abundant clean-burning fuel and also suggesting as a feedstock for gas industry. The use of CBM will have very little impact on the KOGAS' DME process design and economics up to 50 vol% of $CO_2$ in the CBM source. Many of the CBM sources in Asia are high in $CO_2$, but pose no difficulties for the KOGAS' DME plant. Since tri-reformer requires substantial $CO_2$ in its feed, no $CO_2$ removal from the CBM feed is needed. The $CO_2$ in the CBM means that less $CO_2$ needs to be recycled from the downstream in the process.

Computational Fluid Dynamic Analysis for Improving the Efficiency of Desulfurization System for the Wet Flue Gas (습식 배연탈황 시스템의 효율 향상을 위한 전산해석)

  • Hwang, Woo-Hyeon;Lee, Kyung-Ok
    • Journal of the Korea Society of Computer and Information
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    • v.19 no.2
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    • pp.161-171
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    • 2014
  • In this paper the flow dynamics of the flue gas equipment in the desulfurization system was numerically analyzed by simulating the problems for the turbulent and combustion flow from Induced Draft Fan(I.D.Fan) outlet to Booster Up Fan(B.U.Fan) inlet using the commercial CFD software of CFD-ACE+ in CFDRC company for Computational Fluid Dynamic Analysis. The guide vane of this section was examined for the minimum pressure loss and the uniform flow dynamic to B.U.Fan with the proper velocity from I.D,Fan exit to B,U,Fan inlet section at the boiler both the maximum continuous rating and the design base. The guide vanes at I,D.Fan outlet and B.U.Fan inlet were removed and modified by numerical simulation of the CFD analysis. The flue gas at the system had the less pressure loss and the uniform flow dynamics of the flow velocity and flow line by comparing with the old design equipment.

Separation of $CH_4/CO_2/N_2$ Mixture by Pressure Swing Adsorption (PSA법을 이용하여 $CH_4/CO_2/N_2$ 혼합가스 중에서 메탄의 분리)

  • Cho, Woo-Ram;Jeong, Gu-Hyun;Shin, Young-Hwan;Yoo, Hee-Chan;Na, Byung-Ki
    • Clean Technology
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    • v.17 no.4
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    • pp.389-394
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    • 2011
  • A compact adsorption-based process for removal of carbon dioxide and nitrogen from natural gas has been discussed. Among the adsorption-based processes, especially, the pressure swing adsorption (PSA) process has been a suitable unit operation for the purification and separation of gas because of low operation energy and cost. A step cycle is made up of pressurization, feed, equalization, blowdown and rinse. In this work, the PSA process is composed of zeolite 13X and carbon molecular sieve (CMS) for removal of carbon dioxide and nitrogen from mixed gas containing $CH_4/CO_2/N_2$ (75:21:4 vol%). A CMS selectively removes carbon dioxide and a zeolite 13X separates nitrogen from methane. CMS is investigated experimentally due to the high throughput of the faster diffusing component ($CO_2$). The gas composition of top, bottom and feed tank was measured with the gas chromatography (GC) using TCD detector, helium as carrier gas and packed column for analysis of methane, carbon dioxide, and nitrogen.

Detection and Quantitation of Residual Antibiotics and Antibacterial Agents in Foods

  • Ryu, Jae-Chun;Seo, Ja-Won;Song, Yun-Seon;Park, Jong-Sei
    • Journal of Food Hygiene and Safety
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    • v.5 no.3
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    • pp.159-164
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    • 1990
  • To detect and quantitation residual antibiotics and antibacterial agents in meats, we performed a biological assay employing the three microorganisms Bacillus subtilis ATCC 6633, Micrococcus luteus ATCC 9341, and Bacillus cereus var. mycoides ATCC 11778 for the screening purpose and developed a Gas Chromatography-mass Spectrometry(GC/MS) analysis for the confirmation and quantiation. In the biological assay (paper disk method), three test solution are used depending on the character of the residual antibiotics and antibacterial agents, follow by a simple clean up procedure which includes homogenization with Mcilvaine buffer, defatting with includes homogenization with Mcilvaine buffer, defatting with hexane, extraction with chloroform, clean-up by Sep-Pak $C_{18}$ and Bakerbond SPE carboxylic acid column. The chloroform layer is used for the analysis of sulfa agents. macrolides antibiotics and antibacterial agents, Adsorbed materials in the Sep-Pak $C_{18}$ were also employed for th analysis of penicillins and tetracyclines. Effluents from the Sep-Pak $C_{18}$ were cleaned-up one more by Bakerbond 10 SPE COOH column and employed for the analysis of aminoglycosides. In the instrumental analysis by using the GC/MSD, residual antibiotics and antibacterial agent were quantitated by selected ion monitoring (SIM) mode after derivatization. A simultaneous analysis of six residual antibiotic and antibacterial agent such as oxytetracycline, penicillin, ampicillin, choliraphenicol and thiamphenicol was developed with simple cleanup procedures revealing good recovery and reproducibility. Also, simultaneous detection of macrolides antibiotics such as erythromycin, spiramycin, and oleandomycin was developed after acid hydrolysis due to their large molecular structures. Because of the high reproducibility and selectivity of these two methods, it is very desirable that the combination of the two methods be used in the bioassay for the screening of residual antibiotics and antibacterial agent and that GC/MSD analysis be used for the confirmation and quantitation.

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The Occurrence and Treatment Status of Off-site Contaminated Soils in Korea (국내 오염토양 반출정화사업 현황)

  • Han, SuHo;Jung, MungChae;Kim, JeongWook;Jeon, SoonWon;Nguyen, Quoc Tuan;Yoon, KyungWook;Min, SeonKi
    • Journal of Soil and Groundwater Environment
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    • v.25 no.4
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    • pp.1-6
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    • 2020
  • Recently, ex-situ remediation technologies has been emerging to clean up contaminated soils mainly because the in-situ techniques have limited applicability and technical difficulties in relatively small contaminated sites. Accordingly, implementation of off-site treatment and disposal have been continuously increased in soil remediation and restoration projects in Korea. However, in many cases, reclaimed soil is still not properly recycled or reused. Therefore, there is an urgent need to document the current status of soil management practices in soil remediation projects in the nation. This study presents a survey of soil contamination status and remedial approaches in Korea based on soil cleanup projects completed in 2015 - 2019, and proposes the possible options of the recycling or reusing the reclaimed soils under compliance with related regulations. The results of the soil survey showed soil contamination was most severe in gas stations, industrial facilities, and military areas. The major types of pollution were related to the petroleum-contaminated site (TPH and BTEX) with 77.0% occurrence in all the contaminated sites. The reclaimed soils were mostly reused as a ground filling-up soils in industrial facilities (60.0%) and warehouses (37.0%).

Research for the Analytical Method of Various Pesticides in Raw Milk by Gas Chromatography-Mass Spectrometry (GC/MSD를 사용한 원유 내 잔류농약의 분석법 연구)

  • Oh, N.S.;Shin, Y.K.;Baick, S.C.
    • Food Science of Animal Resources
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    • v.29 no.4
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    • pp.482-486
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    • 2009
  • The aim of this study was to optimize a simple, fast, and economical analysis procedure for the determination of 16 different pesticides in raw milk via GC/MSD. Analyses were performed via gas chromatography with electron impact mass spectrometric detection in the selected ion monitoring mode (GC/MSD-SIM) using Pentachloronitrobenzene as the internal standard. The modified sample preparation methodology was based on the Pesticide Analytical Manual (PAM) of the FDA concerning fat extraction, ACN-ether partitioning, and clean-up of the Sep-Pak florisil cartridge. The modified methodology for the determination of the 16 pesticides was validated. The range of LOQs of the 16 pesticides was likely three times lower than their Maximum Residence Levels (MRLs). The recoveries of most of the pesticides were acceptable at the fortification levels of 0.5 and 1.0 ${\mu}g/mL$ and their RSD (%) level was less than 20%. None of the 16 pesticides were detected in the selected raw milk samples.