• Title/Summary/Keyword: Galvanic Cell

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A Electrochemical Study on the Effect of Post-Weld Heat Treatment about Corrosion Resistance Property of SS400 Steel for Ship's Materials (선박재료용 SS400강의 내식성에 대한 용접후열처리효과에 관한 전기화학적 연구(I))

  • 김진경
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.6
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    • pp.806-813
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    • 1999
  • The effect of Post-Weld Heat Treatment(PWHT) of SS400 Steel was investigated with parameters such as micro vickers hardness corrosion potential polarization behaviors galvanic current Al anode generating current Al anode weight loss etc. Hardness of each parts(HAZ, BM, WM)by PWHT is lower than that of each parts by Non Post-Weld Heat Treatment(NPWHT) However hardness of WM of HAZ part was the highest among those three parts and HAZ area were also acted as cathode without any case of heat treatment. Potential difference between each three parts by PWHT was also smaller compared to NPWHT. Therefore it is suggested that Corrosion resistance property is increased by PWHT. However both Al anode generating current and anode weight loss was also decreased by PWHT compared to NPWHT when SS400 steel is cathodically protected by Al anode.

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Electrochemical Corrosion Characteristics of the Intermetallic Compound NiTi from Pure Metals (금속간 화합물 NiTi와 순금속 니켈 및 티타늄의 전기화학적 부식 특성)

  • Lee, Kyu Hwan;Shin, Myung Chul
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.97-101
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    • 1992
  • Potentiodynamic corrosion tests were conducted to know the corrosion characteristics of the NiTi intermetallic compound composed of pure Ni and Ti in artificial saline. Tafel extrapolation and linear polarization technique show similar results. Corrosion current Icorr and corrosion rate was increased in the order of NiTi

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Micro-electrochemical Characteristics of Sensitized 304 Stainless steel Using Micro-droplet cell Techniques (마이크로 드로플릿 셀 기법을 이용한 예민화 된 304 스테인리스강의 미세전기화학 특성)

  • Kim, Kyu-Seop;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.300-309
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    • 2010
  • The influences of sensitization on localized corrosion resistance of 304 stainless steel, were investigated, using micro-dropletcell techniques. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local current with the potentiodynamic polarization, linear polarization and a.c. impedance. Micro-electrochemical tests were carried out inside of the grain and on grain boundaries separately. It was found that sensitization decreased the pitting potential, increasing corrosion current density around grain boundaries. Galvanic current density was also measured between grain and grain boundaries.

An Electrochemical Evaluation of the Corrosion Property on the Welded Zone of Sea Water Pipe according to Welding Materials (용접 재료 별 해수 배관 용접부위의 부식 특성에 관한 전기화학적 평가)

  • Kim, Jin-Gyeong;Won, Chang-Uk;Jo, Hwang-Rae;Lee, Myung-Hoon;Kim, Yun-Hae;Moon, Kyung-Man
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.39-46
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    • 2007
  • The sea water pipe of a ship's engine room is a severely corrosive environment caused by fast flawing sea water containing chloride ions and high conductivity. Therefore, leaking of sea water may occur as a result of local corrosion of the welded zone. Leaking is usually controlled by various welding methods. In this study, when the sea water pipe is welded with certain welding methods and welding electrodes, the corrosion resistance of WM (Welding metal) and HAZ (Heat affected zone) was investigated using electrochemical methods. Although the corrosion potential of the HAZ is higher than that of WM, the corrosion resistance of WM is superior to HAZ. However, when WM and HAZ are both opened to the sea water, the WM part with the anode was more seriously corroded than was the HAZ of the cathode by performance of a galvanic cell due to difference of the corrosion potential between HAZ and WM. In particular TIG welding showed relatively good results in corrosion resistance of both HAZ and WM compared to other welding methods.

Activity Measurement in Liquid Zn-(In, Sn) Alloy Using E.M.F Method (기전력법에 의한 용융 ZR-(In, Sn) 합금의 활동도 측정)

  • Jung Woo-Gwang
    • Korean Journal of Materials Research
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    • v.15 no.1
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    • pp.47-53
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    • 2005
  • The E.M.F. of the galvanic cell with fused salt was measured to determine the activities of zinc at 720-860 K over the entire composition range of liquid Zn-In and Zn-Sn alloys. The cell used was as follows: $$(-)W{\mid}Zn(pure){\mid}Zn^{2+}(KCl-LiCl){\mid}Zn(in\;Zn-In\;or\;Zn-Sn\;alloy){\mid}W(+)$$ The activities of zinc in the alloys showed positive deviation from Raoult's law over the entire composition range. The activity of cadmium and some thermodynamic functions such as Gibbs free energy, enthalpy and entropy were derived from the results by the thermodynamic relationship. The comparison of the results and the literature data was made. The liquid Zn-In and Zn-Sn alloys are found to be close tn the regular solution. The concentration fluctuations in long wavelength limit, $S_{cc}(o)$, in the liquid alloy were calculated from the experimental results.

A Transformer-less Boost Converter with High Gain and Low Current Ripple for Fuel Cell Application (연료전지 응용을 위한 높은 승압비와 낮은 전류리플을 갖는 무변압기형 부스트 컨버터)

  • Yang, Jin-Young;Park, Chan-Ki;Choi, Se-Wan;Nam, Seok-Woo
    • The Transactions of the Korean Institute of Power Electronics
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    • v.13 no.2
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    • pp.79-87
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    • 2008
  • Boost Converters have been used to step up and regulate the low and widely varing voltage from the fuel cell. A transformer-less boost converter which does not have lossy, bulky, and costly high frequency transformers has an advantage in applications where galvanic isolation is not required. In this paper a new transformer-less boost converter is proposed. The proposed boost converter has practically usuable 6 to 8 times of step up ratio and is suitable for fuel cell applications due to very low input and output current ripples. The proposed converter is verified through the theorical analysis, simulation and experimental waveform.

Glucose Oxidation on Gold-modified Copper Electrode

  • Lim, Ji-Eun;Ahn, Sang Hyun;Pyo, Sung Gyu;Son, Hyungbin;Jang, Jong Hyun;Kim, Soo-Kil
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2685-2690
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    • 2013
  • The activities of Au-modified Cu electrodes toward glucose oxidation are evaluated according to their fabrication conditions and physico-chemical properties. The Au-modified Cu electrodes are fabricated by the galvanic displacement of Au on a Cu substrate and the characteristics of the Au particles are controlled by adjusting the displacement time. From the glucose oxidation tests, it is found that the Au modified Cu has superior activity to the pure Au or Cu film, which is evidenced by the negative shift in the oxidation potential and enhanced current density during the electrochemical oxidation. Though the activity of the Au nanoparticles is a contributing factor, the enhanced activity of the Au-modified Cu electrode is due to the increased oxidation number of Cu through the electron transfer from Cu to more electronegative Au. The depletion of electron in Cu facilitates the oxidation of glucose. The stability of the Au-modified Cu electrode was also studied by chronoamperometry.

Corrosion mitigation of photovoltaic ribbon using a sacrificial anode (희생양극을 이용한 태양광 리본의 부식 저감)

  • Oh, Wonwook;Chan, Sung-Il
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.3
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    • pp.681-686
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    • 2017
  • Degradation is commonly observed in field-aged PV modules due to corrosion of the photovoltaic ribbon. The reduced performance is caused by a loss of fill factor due to the high series resistance in the PV ribbon. This study aimed to mitigate the degradation by corrosion using five sacrificial anodes - Al, Zn and their alloys - to identify the most effective material to mitigate the corrosion of the PV ribbon. The corrosion behavior of the five sacrificial anode materials were examined by open circuit potential measurements, potentiodynamic polarization tests, and galvanic current density and potential measurements using a zero resistance ammeter. Immersion tests for 120 hours were also conducted using materials and damp heat test tests were performed for 1500 hours using 4 cell mini modules. The Al-3Mg and Al-3Zn-1Mg sacrificial anodes had a low corrosion rate and reduced drop in power, making then suitable for long-term use.

Connectivity and Electrical Conductivity of YSZ-NiO Composite

  • Park, Young-Min;Park, Gyeong-Man
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.141-145
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    • 1998
  • The electrical properties of the mixed conducting yttria(8 mol%) stabilized zirconia(YSZ)-nickel oxide(NiO) composites were examined by a.c. impedance, 4-probe d.c. conductivity between 400 and $1000^{\circ}C$. The oxygen partial pressure dependence of conductivity, and electromotive force measurement of galvanic cell enabled to determine the electronic contribution to the conduction. Up to 6 vol% NiO addition, the conductivity decreased since the electronic NiO acted as an insulator in ionic matrix. However the ionic transport was dominant until NiO content reaches 26 vol%. Mixed conduction was observed between 26 and 68 vol% of NiO. The effect of composition on the electrical property was explained by the microstructure and thus by the distribution of two phases.

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A study on the effect of the external electric type corrosion resistance for the bolt connection in weathering steel box girders. (무도장 내후성 강교량의 Box Girder 내부볼트 연결부에 대한 외부전원식 정기방식효과에 관한 연구)

  • Park Yong-Gul;Kim Hun-Tae;Baek Chan Ho;Choi Jung Youl
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.988-993
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    • 2004
  • This paper considers corrosion problems in the bolt connection of weathering steel box girder bridge using the external electric type corrosion resistance method which resisted to local corrosion in coated steel surface with contacted air. The weathering steel was created a rust itself in the passive state. but a coated box girder type was easily dew form could be made galvanic cell that accelerated corrosion. so that it was ruled by protection coat with some paint. Therefore, it needed that can be applied the external electric type corrosion resistance method in coated surface. As a result of the test of polarization amount had measured that the weathering steel was higher currents than the general steel by about $5\~10\%$. Therefore. an external electric type corrosion resistance method can be used to protect local corrosion in the coated bolt connection of weathering steel box girders effectively.

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