• Clean Technology
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• v.17 no.1
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• pp.56-61
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• 2011

In this study, hydrocarcking of vacuum residue was carried out in an autoclave reactor at $450^{\circ}C$ and $500^{\circ}C$ with a commercial catalyst (HDM) and the quantitative product distributions were analyzed by GC-SIMDIS method or simple distillation. During catalytic hydrocracking, thermal cracking also occurred together with catalytic cracking and the higher conversion and selectivity of gasoline and naphtha were obtained at high reaction temperature. GC-SIMDIS and simple distillation revealed different results for the analysis of products produced at different hydrocracking temperatures; almost same results were obtained for the product produced at $500^{\circ}C$ but different ones for the product produced at $450^{\circ}C$. In the analysis of product produced at $450^{\circ}C$, the GC-SIMDIS showed that a main product was VGO while a main product in the simple distillation was diesel, which implies that the simple distillation for the $450^{\circ}C$ reaction was not accurate due to thermal cracking of the product by the simple distillation.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.553-556
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• 2005

Pyrolysis of polyethylene was carried out in the stainless steel reactor of internal volume of $40cm^3$. Pyrolysis reactions were performed at temperature $390-450^{\circ}C$ and the pyrolysis product were collected separately as reaction products and gas products. The molecular weight distributions(MWDs) of each liquid product were determined by GC-SIMDIS. Molecular weight of each product were decreased wi th increase of react ion temperature and time.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.4
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• pp.1059-1066
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• 2008

Characteristics of pyrolysis and liquid product distribution of ABS plastics have been studied in the thermogravimetric(TG) reactor and bomb microreactor. Pyrolysis reactions were performed at temperature $400\sim450^{\circ}C$ and yield of each pyrolytic product was obtained by the weight measurement method. The molecular weight distributions of liquid products were determined by the GC-SIMDIS method. It was observed that solid residue which could not be detected in the thermogravimetric experiments was significantly formed in the batch-type microreactor. It was found that the yield and average molecular weight of liquid products were decreased with the increase of reaction temperature and time. but the formation of styrene monomer was significantly increased. The chain-end scission rate parameters were determined to be 54.1kcal/mole far ABS by the Arrhenius plot.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.540-544
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• 2008

Pyrolytic characteristics of mixed plastics containing 22 wt.% HDPE, 17 wt.% LDPE, 27 wt.% PP, 12 wt.% PS, 16 wt.% ABS, 6 wt.% PVC have been studied in the batch-type microreactor of stainless steel. Thermal degradation experiments were performed at temperature of $410{\sim}450^{\circ}C$. The yield of each pyrolytic products were obtained by the weight measurement and molecular weight distribution of pyrolytic liquid products determined by the GC-SIMDIS method. It was shown that the yield and molecular weight of pyrolytic liquid product were decreased with the increase of reaction temperature and time. It was know that 20wt% of PVC composing of the mixed plastics was converted to the gas products of chloride during the pyrolysis process. The chain-end scission rate parameter was determined to be 50.2 kcal/mole of mixed plastics by the Arrhenius plot.

• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.556-561
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• 2019

In this study, the physical and chemical analyses of petroleum residues (pyrolized fuel oil, PFO) were conducted and major components were selected to investigate their fire and explosion characteristics. Major component distribution areas of the PFO were identified via the GC-SIMDIS and MALDI-TOF analyses. In addition, the qualitative analysis of major component distribution areas was performed by GC-MS analysis. Major components of pyrolysis residue were selected based on the results of various analyses such as EA, SARA and TGA. As a result, benzene, toluene and xylene were selected as major components. Finally, the process hazard analysis software tool (PHAST) analysis was performed to investigate the range of maximum damage effect in case of fire and explosion. Toluene presented the highest risk due to the radiation effect of $227kW/m^2$ and 118 m in the case of jet fire. Xylene and benzene showed the maximum radiant heat values of 114 and $151kW/m^2$, respectively. It was also confirmed from the analysis of pasquill stability and wind speed that the radiant heat increased up to 55% according to wind speed in benzene, which was considered to be a main factor increasing the influence range.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.652-656
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• 2018

In this study, effects of the reaction pressure were studied for petroleum-based pitch synthesis. A two-stage reaction process was performed based on different reaction pressure conditions. Each stage experiments for the two-stage reaction were consecutively carried out. The first stage was consisted of three different pressure conditions; high (10 bar), normal and low (0.1 bar). And the second stage was carried out at the normal and low (0.1 bar) pressure. The pitch synthesis was realized at $400^{\circ}C$ for 2 h. Thermal properties and molecular weight distributions of each samples were investigated by analyzing the softening point and MALDI-TOF data. Volatilized components during the pith synthesis were measured by GC-SIMDIS. In case of the first-step reaction with the high pressure condition, the low molecular weight component participated to the pitch formation more effectively and the pitch with the low softening point was obtained. However, for the case of the first-step with the low pressure, the low molecular weight component was vent outside and the partial coke formation occurred. Eventually, pitch properties such as the softening point and yield were controlled effectively by changing the pressure in the pitch synthesis reaction.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.468-470
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• 2008

열중량반응기와 미분반응기를 이용하여 ABS의 열분해 및 생성물분포 특성을 연구하였으며 미분반응기를 이용한 실험의 열분해온도는 $410{\sim}450^{\circ}C$이었다. 각 상의 열분해생성물의 수율은 무게측정을 통해 얻었으며 액상생성물의 탄소수분포는 GC-SIMDIS 방법을 통해 측정하였다. 열중량 분석실험에서는 측정할 수 없었던 다량의 고상잔류물의 생성을 회분식 미분반응기실험을 통해 확인할 수 있었다. 반응온도와 시간이 증가할수록 액상생성물의 수율과 평균분자량은 감소하였으나 액상생성물 중의 스티렌모노머의 생성은 두드러지게 증가하였다. ABS 열분해 반응에서 말단절단의 속도계수인 활성화에너지 값은 54.1kcal/mole이었다.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.3
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• pp.126-133
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• 2013

Recently, it was reported that complaints about problems being experienced with the performance of vehicles operating on autogas in Korea. The problem was being assumed due to contaminants in LPG and an oily material which was being deposited in vaporizer, injector in LPG fuel system. This study is focused on the analysis of contaminant of automobile parts on LPG fuel system. The sampling points of contaminants are injectors, fuel filters, vaporizer in automobile equipment and it was also investigated by GC-MS, ICP-AES, SIMDIS and EDS. According to results, it was presumed that this contaminants had been analyzed plasticizers with hydrocarbons with high boiling point, Fe from steel corrosion, greases from gas station.