• Title/Summary/Keyword: GAs analysis

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A Study on Electrolysis of Heavy Water and Interaction of Hydrogen with Lattice Defects in Palladium Electrodes (팔라디움전극에서 중수소의 전기분해와 수소와 격자결함의 반응에 관한 연구)

  • Ko, Won-Il;Yoon, Young-Ku;Park, Yong-Ki
    • Nuclear Engineering and Technology
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    • v.24 no.2
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    • pp.141-153
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    • 1992
  • Excess tritium analysis was peformed to verify whether or not cold fusion occurs during electrolysis of heavy water in the current density range of 83~600 mA/$\textrm{cm}^2$ for a period of 24 ~ 48 hours with use of palladium electrodes of seven different processing treatments and geometries. The extent of recombination of D$_2$ and $O_2$gases in the electrolytic cell was measured for the calculation of accurate enthaplpy values. The behavior and interaction of hydrogen atoms with defects in Pd electrodes were examined using the Sieverts gas charging and the positron annihilation(PA) method. Slight enrichment of tritium observed was attributed to electrolytic enrichment but not to the formation of a by-product of cold fusion. The extent of recombination of D$_2$and $O_2$gases was 32%. Hence the excess heat measured during the electrolysis was considered to be due to the exothermic reaction of recombination but not to nuclear fusion. Lifetime results from the PA measurements on the Pd electrodes indicated that hydrogen atoms could be trapped at dislocations and vacancies in the electrodes and that dislocations were slightly more preferred sites than vacancies. It was also inferred from R parameters that the formation of hydrides was accompanied by generation of mostly dislocations. Doppler broadening results of the Pd electrodes indicated that lattiec defect sites where positrons were trapped first increased and then decreased, and this cycle was repeated as electrolysis continued. It can be inferred from PA measurements on the cold-rolled Pd and the isochronally annealed Pd hydride specimens that microvoid-type defects existed in the hydrogen-charged electrode specimen.

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Nitridation Behavior of Kaolin with Reduced Alumina Content Obtained by Acid Treatment (산처리에 의하여 알루미나 함량을 줄인 카올린의 질화거동)

  • 배원태;정원도;조철구
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.347-356
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    • 1992
  • Various kaolin samples with different alumina content were prepared from calcined admixture of kaolin and ammonium sulfate by varying the treatment time in sulfuric acid. Samples were nitridated under N2 or N2-H2 atmosphere with changing the amount of added carbon, the reaction time and temperature. As the alumina content lowered, the size of kaolin particles decreased and the specific surface area increased. XRD analysis indicated that ${\alpha}$-quartz remained by decomposition of halloysite and meta-halloysite. Experimental results of nitridation behavior are summerized as follows; 1) Nitridation under N2 atmosphere. With the increase of C/SiO2 ratio and with the decrease of Al2O3 content, disappearance of XRD pattern peaks of mullite, ${\alpha}$-quartz and ${\alpha}$-Al2O3 were accelerated at 1300$^{\circ}C$. SiC was the main phase in the reaction product of acid-treated kaolin samples nitridated at 1300$^{\circ}C$ for 10 hours regardless of C/SiO2 ratio. But the XRD peak intensities of ${\beta}$-Si3N4, ${\beta}$-sialon and SiC did not show much difference when untreated raw kaolin was fired at the same condition. When the ratio of C/SiO2 was 3.5, ${\beta}$-sialon and ${\beta}$-Si3N4 existed in the reaction product of about 22% alumina containing kaolin sample fired at 1350$^{\circ}C$ for 7 hours. Only ${\beta}$-sialon existed in the same sample fired at 1400$^{\circ}C$ for 10 hours. ${\beta}$-sialon was obtained from all of the acid-treated kaolin samples fired at 1400$^{\circ}C$ for 40 hours, but AlN and SiC remained in the untreated kaolin sample. Z value of the ${\beta}$-sialon obtained from the 22% alumina containing kaolin sample fired at 1400$^{\circ}C$ for 40 hours was about 1.3(XRD) and 1.5(EDS). 2) Nitridation under 80N2+2OH2 mixed gas atmosphere with the C/SiO2 ratio of 1 Mullite was not found, but ${\alpha}$-Si3N4, and ${\beta}$-sialon were present in the reaction product of about 22% alumina containing kaolin sample fired at 1300$^{\circ}C$ for 10 hours. When untreated kaolin sample was nitridated at the same condition, mullite remained. AlN and SiC were not found in the reaction product of about 22% alumina containing kaolin sample fired at 1350$^{\circ}C$ for 5 hours. On the other hand, AlN and SiC remained in the product of untreated kaolin fired at the same condition.

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Concentrations of PBDE Congeners in Breast Milk and Predictors of Exposure in Seoul Residents (서울 거주 산모 모유 중 PBDEs 이성질체 농도 및 노출 요인에 관한 연구)

  • We, Sung-Ug;Yoon, Cho-Hee;Min, Byung-Yoon
    • Journal of Environmental Health Sciences
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    • v.37 no.6
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    • pp.440-449
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    • 2011
  • Objectives: This study was designed to determine the levels of polybrominated diphenyl ethers (PBDEs) in breast milk and to evaluate the relations with factors affecting these levels. Methods: The congener levels of PBDE in 22 samples of breast milk were analyzed using a high resolution gas chromatograph with a high resolution mass detector. In accordance with our standard operating procedures, the recoveries of internal standards had to range between 68% and 118%. Since the distribution of PBDE concentrations is close to log-normal, the data were logarithmically transformed before analysis. Test subjects were healthy primipara and multipara mothers with a mean age of 32 (SD = 2.7) in 2006. Results: Seven PBDE congeners (BDE-28, 47, 99, 100, 153, 154, and 183) were detected and identified in all of the pooled breast milk samples, indicating widespread contamination from PBDEs in the environment in Korea. Residue levels of total PBDEs (sum PBDEs from tri- to hepta-BDE) ranged from 0.84-13.1 ng/g lipid with median and geometric mean levels of 2.6 ng/g lipid and 2.74 ng/g lipid, respectively. PBDE congeners 47, 99 and 153 markedly predominated and accounted for about 75% of the amount of the PBDE congeners analyzed. BDE-47 was the dominant congener in most samples, whereas BDE-153 was predominant in a few (n = 7/22). BDE-47 was highly correlated with total PBDEs (r = 0.987, p < 0.01). In analyses of the differences of the means of log transformed breast milk PBDE levels for groups of potential covariates, only breast milk BDE-47 and BDE-99 levels were significantly associated with fish (p < 0.05) and meat consumption (p < 0.01). However, we did not find significant correlations between PBDE levels and maternal age, body mass index (BMI), parity, job presence and smoking status. Conclusions: Our findings are mainly limited due to the small sampling size and low doses of PBDEs exposure. Background and human exposure data of PBDEs is lacking, and longitudinal investigations into the environment and biota are encouraged to determine the health impact on future populations in Korea.

Evaluation of Insulation Deterioration for the Development of SVM Algorithm to Diagnose OF Cable (OF 케이블 진단용 SVM 알고리즘 개발을 위한 절연열화 평가)

  • Kwak, Byeong Sub;Jun, Tae-Hyun;Kim, Ah-Reum;Park, Hyun-joo
    • KEPCO Journal on Electric Power and Energy
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    • v.5 no.4
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    • pp.263-273
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    • 2019
  • South Korea's OF cable is reaching its expected design life of 30 years, and as a result, the risk of failure is increasing. Therefore, it is necessary to diagnose the long-term operating OF cables through accurate diagnosis at the right time to prevent the failure. Currently, the KEPCO periodically conducts DGA. However, the gas found in DGA is caused by oil deterioration as well as insulation paper. Therefore, the analysis of the degree of polymerization and furan compounds which is an evaluation of insulation paper considered to be the life of OF cables is required. In addition, the results of the evaluation of deterioration of insulation paper need to be checked for correlation with the results of DGA. In this study, DGA carried out through GC, the degree of polymerization was analyzed using an automatic viscometer, and HPLC was used to detect the furan compounds. In addition, the obtained results were applied to the SVM technique, which was recently introduced to determine abnormalities in OF cable. And the results which were accurate and reliable were obtained.

Spectroscopic Observation of AG Peg and Efficiency Changes of Bowen Fluorescence Mechanism (AG Peg의 분광 관측과 Bowen 형광 기작의 효율 변화)

  • Hyung, Siek;Lee, Seong-Jae;Lee, Kang Hwan
    • Journal of the Korean earth science society
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    • v.38 no.6
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    • pp.405-420
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    • 2017
  • We investigated the H I, He II and O III emission lines of the symbiotic star AG Peg, using the spectroscopic data secured at different phases in three periods at the Lick Observatory. We measured FWHM and the intensity of six O III Bowen lines and studied the efficiency of fluorescence mechanism. The mean FWHM of O III normal and Bowen lines observed during three time periods did not make much difference, while Bowen line intensities are about 4.0 times higher than the normal lines. Comparing the predicted and the observed ratios, we found that the observed intensities are higher than predicted intensities, except for O III ${\lambda}$ 3759.87. The O III ${\lambda}$ 3791.26 and 3754.67 intensity ratios observed only in 2001 are in good agreement with the predictions by Saraph and Seaton (1980). We obtained the Bowen efficiency parameter (R)=0.47 for 2002, but we could not find R for the other two periods of time. Because of this, based on the 2002 efficiency result, we calculated the intensity ratio of O III normal and Bowen lines relative to He II ${\lambda}$ 4685.68 and derive the efficiency variation with time period. The result showed that the efficiency is the highest in 1998 and the lowest in 2001. We conclude that the efficiencies with phase are caused by the electron temperature changes in the ionized gas. The efficiencies of AG Peg are likely to increase along with electron temperature. Our analysis results may be useful in understanding the physical conditions of the ionized shell in symbiotic star and the intensity ratio and efficiency variation.

Study on Deodorizing Effects of Mume Fructus, Eriobotryae Folium, Acanthopanacis Cortex and Angelicae Dahuricae Radix for the Development of a Gargle Solution (구강함수제 개발을 위한 오매, 비파엽, 오가피, 백지의 구취억제효과 연구)

  • Jang, Sun-Young;Park, Jae-Woo;Yoon, Seong-Woo;Ryu, Bong-Ha;Kim, Jin-Sung
    • The Journal of Korean Medicine
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    • v.31 no.4
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    • pp.115-128
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    • 2010
  • Objectives: The aim of this study was to investigate deodorizing effectsof medicinal herbs (Mume Fructus, Eriobotryae Folium, Acanthopanacis Cortex, Angelicae Dahuricae Radix) for development of a gargle solution. Methods: 1. The antimicrobial effects of medicinal herbs were evaluated with the minimal bactericidal concentration (MBC) and the change of the number of viable cells in the herb extracts(1%) for 48 hrs against P. gingivalis 2561 and Pr. intermedia ATCC 25611. 2. Deodorizing activity of each herb and Garglin $Mint^{(R)}$gainst methyl mercaptan were analyzed by gas chromatography (GC). 3. We used the malodor modeling of the salivary sediment system with a Halimeter. 4. In the preliminary clinical study, the baseline concentration of VSC in the oral cavity of each subject was measured by Halimeter. Subjects would gargle for 30 seconds with cysteine. After 4 minutes subjects would gargle for 30 seconds with Garglin and herb extracts (2%). Subsequently, concentration of VSC were measured at 0, 4, 8, 12 and 20 minutes. Results: 1. MBC of Mume Fructusfor P. gingivalis 2561 was determined to be <1% and MBCs of Eriobotryae Folium for P. gingivalis 2561 and Pr. intermedia ATCC 25611 were determined to be <2% and <1%, respectively. Mume Fructus (1%) completely suppressed the P. gingivalis cell viability from 5 hrs and Eriobotryae Folium (1%) completely suppressed the Pr. intermedia cell viability from 48 hrs. 2. In GC analysis, deodorizing activities were 91.54% with Mume Fructus, 87.97% with Eriobotryae Folium, 100% with Acanthopanacis Cortex, 72.36% with Angelicae Dahuricae Radix and 40.54% with Garglin $Mint^{(R)}$. 3. In malodor modeling of the salivary sediment system, each of the medicinal herbs had significantly inhibitory effect on malodor formation (p<0.05). 4. In the preliminary clinical study, the concentration of VSC of the herb groups was significantly lower than of the control group, but not in Garglin $Mint^{(R)}$. Conclusions: Mume Fructus, Eriobotryae Folium, Acanthopanacis Cortex and Angelicae Dahuricae Radixhave deodorizing activities and potential as an effective mouthwash against oral malodor.

Analysis on Heat Transfer Coefficient of The Fluidized - Bed Combustion for Management of Sludge (슬러지 처리를 위한 유동층 연소로의 열전달률 해석)

  • Kim, Seong-Jung;Lee, Je-Hak
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.3
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    • pp.27-33
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    • 2012
  • According to the statistics of the Ministry of Environment, the emission of sewage sludge is increased by 7~9% yearly. In the future, it will be increased continuously because of extension of sewage disposal plants, high class treatment for removing nitrogen and phosphorus. Until now, we have depended on reclamation for lots of quantity and some part has been treated by ocean emission. But, direct reclamation of organic waste will be prohibited and even ocean emission will be prohibited now, so the treatment of sludge is put on emergency alert. Bio-gas can be produced by applying anaerobic digestion method for the recycling or refuse derived fuel can be conducted by applying carbonization method. However, the process is difficult, causes bad smell and makes it the second waste, so it cannot be practical method in fact. This study applied a fluidized bed combustor for sewage sludge treatment technologies that can actually take advantage of key technologies in order to verify its purpose is to demonstrate selected. If applying the fluidized bed combustor, it can be easily utilized as the replaced resource of energy(fuel) in the countries whose energy resources are insufficient, like our country. Especially, if applying only original strengths of the fluidized bed combustor sufficiently, the sewage sludge can be treated simply, eco-friendly, sanitarily and economically. Particularly, it is verified as the energy technology suitable for government's green growth policy.

Spatial Distribution and Variation of Long-range Transboundary Air Pollutants Flux during 1997~2004 (장거리이동 대기오염물질 이동량의 공간적 분포와 변화 추이(1997~2004))

  • Han J. S.;Kim Y. M.;Ahn J. Y.;Kong B. J.;Choi J. S.;Lee S. U.;Lee S. J.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.99-106
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    • 2006
  • Aircraft measurements have been executed for the purpose of monitoring the long range transported air pollution and estimation of air pollutant in/out-flux over the Yellow sea. Total 74 missions of measurements have been done since 1997, mainly in spring and fall. The main study domain was over $124^{\circ}$E $/sim$ $124^{\circ}$E, $35^{\circ}$N $/sim$ $37^{\circ}$N below 3,000m. In long-term trends, mixing ratios of $SO_{2}$N were around 2 ppbv expect in summer ( < 1 ppbv). NOx exhibited 24 ppbv and have no clear annual trends over the Yellow Sea. The concentrations of 03 were 51, 58, 41 ppbv in spring, summer and fall-winter, respectively. Backward trajectory was performed for three days to investigate the source regions of the air mass. Six regions were divided around Korea peninsular centering at $36^{\circ}$N, $126^{\circ}$E. I, II, III, IV and V regions represents in sequence northeast China and Siberia, Sandong peninsula and Balhae gulf, Sanghi and southern China, the south Pacific included Jeju island and the East sea included Japan. L region correspond to the airmass from Korea peninsula. Influx of $SO_{2}$N was approximately five times higher than outflux in yearly flux variation and showed a decreasing long-term trend since 1998. NOx outflux was average 0.095 ton/km/hr and three times higher than $SO_{2}$ outflux. In/out flux of 03 showed even distribution in yearly basis except 2002 (influx 5.45 ton/km/hr). The transported amounts from I, II, III regions were much higher than those from other region. In seasonal flux variation, influx levels of gas phases were the lowest in summer and the levels gradually increased from fall toward spring. As a result, transport of pollutants begins from fall and prevails in winter and spring.

Study on Fuel Specificity and Harmful Air Pollutants Factor of Agglomerated Wood Charcoal (시중에 유통되고 있는 성형목탄의 연료특성과 유해인자에 대한 연구)

  • JEOUNG, Taek Yong;YANG, Seung Min;KANG, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.253-266
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    • 2020
  • This study selected three types of agglomerated wood charcoal (Agglomerated wood charcoal with charcoal powder, Carbonized wood briquette, Ignition-type of perforated charcoal) that are in circulation in Korea among fuel-type wood products and analyzed the fuel characteristics, harmful substance content, and emissions of air pollutants generated by combustion. The first results showed that charcoal-grilled carbon, which is the raw material of charcoal, produced higher CO than saw-billed carbon. The second result is that the emission standards of air pollutants generated by the combustion of molded wood coal are not up to the emission standards of nitrogen oxides and sulfur oxides in the entire product, compared with the emission criteria of the atmospheric environment preservation method (based on 2019, carbon monoxide: 200 ppm, nitrogen oxides, 150 ppm sulfur oxides: 100 ppm), but the carbon dioxide moulding and carbon dioxide levels were not up. Based on the analysis of combustion gas generated during combustion derived from this study, future research is needed for comparing with the emission standards of pellets, which are wood products for fuel, among the existing biomass burning standards and for reducing carbon monoxide generated during incomplete combustion of agglomerated wood charcoal.

Physicochemical and Archaeometric Characteristics of Goryeo Period Potteries from the Sandongri in Seosan, Korea (서산 산동리 고려시대 도기의 물리화학적 및 고고과학적 특성)

  • Lee, Chan Hee;Jin, Hong Ju
    • Journal of Conservation Science
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    • v.32 no.2
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    • pp.123-139
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    • 2016
  • The excavated potteries of Goryeo Period from the Sandongri archaeological site in Seosan were studied on physicochemical analyses. Surface color of the samples are mainly grayish blue, and showed the natural glaze by melting the body soils during the burning. Partly, swelling surface are observed bloated marks because of blow out gas by burning. The potteries are some possibility of making the similar source clay on the basis of magnetic susceptibilities (about $1{\times}10^{-3}SI\;unit$) and general occurrences. Values of specific gravity, apparent porosity and absorption ratio are divided two groups as highly different cases of bloating surface samples. The source clay of the potteries used mainly microcrystalline clay, the mineral compositions are quartz and some colored minerals. Based on the analysis, the burning temperature of the potteries are assumed that they were around $1,100^{\circ}C$ because detection of quartz and mullite within hard and compact matrices. As geochemical variations of the samples, evolution trends of rare earth, compatible and incompatible elements showed very similar patterns excepting the some major elements, that means the potteries are interpreted to making by elutriation processes using the same raw clays from very similar basement rocks of genetically.