• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.430.1-430.1
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• 2014

According to advanced nanotechnology in the field of biomedical engineering, many studies of the interaction between topography of surfaces and cellular responses have been focused on nanostructure. In order to investigate this interaction, it is essential to make well-controlled nanostructures. Electron beam lithography (EBL) have been considered the most typical processes to fabricate and control nano-scale patterns. In this work, $TiO_2$ nanowire array was fabricated with hybrid process (top-down and bottom-up processes). Nanodot arrays were patterned on the substrate by EBL process (top-down). In order to control the spacing between nanodots, we optimized the EBL process using Poly(methyl methacrylate) (PMMA) as an electron beam resist. Metal lift-off was used to transfer the spacing-controlled nanodots as a seed pattern of $TiO_2$ nanowire array. Au or Sn nanodots which play an important role for catalyst using Vapor-Liquid-Solid (VLS) method were patterned on the substrate through the lift-off process. Then, the sample was placed in the tube furnace and heated at the synthesis temperature. After heat treatment, $TiO_2$ nanowire array was fabricated from the nanodots through VLS method (bottom-up). These results of spacing-controlled nanowire arrays will be used to study the interaction between nanostructures and cellular responses in our next steps.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.1
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• pp.39-48
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• 2020

The present study investigates the chemical reaction and performance of ternary blended binders by mixing ferronickel slag. Cement was replaced using ground granulated blast furnace slag and ferronickel slag, combined up to 50% of the replacement rate. The blended cements were tested by setting times, length change, compressive strength at 1, 3, 7, 28 days. X-ray diffraction and scanning electron microscope were conducted for detecting hydration products while the MIP and microhydation heat were used for examining morphological characteristics. The results showed that by adding ferronickel slag, Pozzolanic reaction occurred, forming a dense pore structure and the effect of reducing hydration heat and dry shrinkage was also found. The compressive strength at 28 days was lower than that of 100% OPC control specimen (OSP0), but ternary blended cements showed no significant difference compared to binary blended (OSP50). If the optimal mix is derived later and used for the purpose, the potential for use as a cement binder is expected.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.5
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• pp.193-198
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• 2011

Recently sapphire crystals are used in LED applications. The Czochralski (CZ) growth process is one of the most important techniques for growing high quality sapphire single crystal. A successful growth of perfect single crystals requires the control of heat and mass transport phenomena in the CZ growth furnace. In this study, the growth processes of the sapphire crystal in an inductively heated CZ furnace have been analyzed numerically using finite element method. The results shown that the high temperature positions moved from the crucible surface to inside the melt and the crystal-melt interface changed to the flat shape when the rpm was increased. Also the crystal-melt interface shape has been influenced by the shoulder shape of the grown crystal during the initial stage.

• Journal of the Korea Concrete Institute
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• v.12 no.2
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• pp.99-107
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• 2000

This research investigates experimentally an effect on the properties of the high flowing concrete to be poured in the under-ground slurry wall of Inchon LNG receiving terminal(#213,214-TK) according to variations of concrete materials. Variables for sensitivity test were selected items as followings. 1) Concrete temperature (3cases), 2) Unit water (5cases), 3) Fineness modulus of fine aggregate (5cases), 4) Particle size of lime stone powder (3cases), 5) Replacement ratio of blast-furnace slag (4cases) and 6) Addition ratio of high range water reducing agent (5cases). And fresh conditions of the super flowing concrete should be satisfied with required range including slump flow(65$\pm$5cm), 50cm reaching time of flow(4~10sec), V-lot flowing time(10~ 20sec), U-box height(min. 300mm) and air content(4$\pm$1%). As results for sensitivity test, considered flow-ability, self-compaction and segregation resistance of the high flowing concrete, material variations and conditions of fresh concrete should be satisfied with the range as follwings. 1) Concrete temperature are 10~2$0^{\circ}C$(below 3$0^{\circ}C$), 2) Surface moisture of fine aggregate is within $\pm$ 0.6%, 3) Fineness modulus of fine aggregate is 2.6$\pm$0.2, 4)Replacement ratio of blast-furnace slag is 45~50% and 5) Addition ratio of high range water reducing agent is within 1%. Based on the specification for quality control, we successfully finished concrete pouring on the under-ground slurry wall having 75,000㎥(#213,214-TK) and accumulated real date in site.

• Journal of the Korean Society of Safety
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• v.33 no.5
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• pp.60-69
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• 2018

This study aims to investigate in the assessment of salt damage conditions in concrete structures under marine environment conditions. It aims also to improve the durability of new concrete bridge through applying the life prediction method of salt damaged bridges. As measuring chloride contents of these bridges on the southwest coastal area, it is shown that the average amount of chloride on these surfaces close to shore is $10.5kg/m^3$. This figure is much higher than that of the Standard Specification for Concrete($1.5kg/m^3{\sim}2.5kg/m^3$). In contrast, it is shown the average amount of chloride on these surfaces in tide zone is $13.1kg/m^3$. Its figure is much lower than that of the Standard Specification for Concrete($20kg/m^3$). And the life of bridges is estimated about 17 years. To improve the durability for salt damage, these bridges are applied to surface treatment method which the replacement rate of furnace slag is 60%. Under this condition, it is expected to be 110 years. Consequently, it is clear that the use of slag replacement rate, surface treatment agent, and anti-corrosion agent to control chloride penetration effects of a submerge-based concrete bridge will be required.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.340-347
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• 2008

In the case of a melting process, the velocity of waste-gas has been measured to produce the melt of an equal condition and to analyze the combustion situation of the fuel which was inputted in a furnace. Recently, there are many kinds of measuring equipments of gas-velocity on the market. But, the waste-gas produced from a melting process is high temperature, the slow speed and includes much dust. Existent measuring equipments are not suited to these conditions. Therefore, we made the measuring equipment of new method which is enough detailed to react on the slow speed and sustains in high temperature. As shown in the result of field test, the manufactured measuring equipment is so sensitive as to react on a small change of velocity and senses temperature change rapidly, we expect that this equipment helps in temperature control of a melting furnace.

• Advances in materials Research
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• v.9 no.3
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• pp.219-231
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• 2020

The aim of this study is to investigate the durability of fly ash based geopolymer mortar with and without protective coatings in aggressive chemical environments. The source materials for geopolymer are Fly ash and Ground Granulated Blast furnace Slag (GGBS) and they are considered in the combination of 80% & 20% respectively. Two Molarities of NaOH solution were considered such as 8M and 10M. The ratio of binder to sand and Sodium silicate to Sodium hydroxide solution (Na₂SiO₃/NaOH) are taken as 1:2 and 2 respectively. The alkaline liquid to binder ratio is 0.4. Compressive strength tests were conducted at various ages of the mortar specimens. In order to evaluate the performance of coatings on geopolymer mortar under aggressive chemical environment, the mortar specimens were coated with two different types of coatings such as epoxy and Acrylic. They were then subjected to different chemical environments by immersing them in 10% standard solutions of each ammonium nitrate, sodium chloride and sulphuric acid. Drop in compressive strength as a result of chemical exposure was considered as a measure of chemical attack and the drop in compressive strength was measured after 30 and 60 days of chemical exposure. The compressive strength results following chemical exposure indicated that the specimens containing the acrylic coating proved to be more resistant to chemical attacks. The control specimen without coating showed a much greater degree of deterioration. Therefore, the application of acrylic coating was invariably much more effective in improving the compressive strength as well as the resistance of mortar against chemical attacks. The results also indicated that among all the aggressive attacks, the sulphate environment has the most adverse effect in terms of lowering the strength.

• Resources Recycling
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• v.23 no.4
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• pp.37-46
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• 2014

Carbon dioxide generated from construction materials and construction material industry among the fields of construction is approximately 67 million tons. It is about 30% of the carbon dioxide generated in the fields of construction. In order to reduce carbon dioxide in the fields of construction, it is necessary to control the use of fossil fuel consumed and decrease carbon emission by reducing the secondary and tertiary curing generating carbon dioxide in construction material industry. Therefore, this study manufactured mortar by having cement as the Plain and substituting three binding materials up to 50% and then adopted different curing methods to analyze congelation and strength characteristics. Test results for strength property by changing binding materials showed that specimens with blast furnace slag, CSA 15% and CAMC 5% resulted in positive effect for strength.

• Journal of Environmental Health Sciences
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• v.45 no.3
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• pp.258-266
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• 2019

Objectives: In this study, blood lead was analyzed using graphite furnace atomic absorption spectrometry (GF-AAs) and inductively coupled plasma mass spectrometry (ICP-MS). We tried to examine the difference and consistency of the analytical values and the applicability of the analytical method. Methods: We selected 57 people who agreed to participate in this study. After confirming the linearity of the calibration standard curves in GF-AAs and ICP-MS, the concentrations of lead in quality control material and samples were measured, and the degree of agreement was compared. Results: The detection limit of the ICP-MS was lower than that of GF-AAs. The coefficient of variation of reference materials was shown to be stable in the ICP-MS and GF-AAs. When the correspondence between the two equipments was verified by bias of the analysis values, a concordance was shown, and approximately 98% of the ideal reference lines were present within ${\pm}40%$ of the deflection. Conclusion: GF-AAs showed high sensitivity to single heavy metal analysis, but it took much time and showed higher detection limit than ICP-MS. Therefore, it would be considered necessary to switch to ICP-MS analysis method, considering that the level of lead exposure is gradually decreasing.

• Journal of the Korea Institute of Building Construction
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• v.19 no.5
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• pp.421-429
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• 2019

The changes in the resistance to chloride ingress of concrete using a ground granulated blast furnace slag (GGBFS) according to curing conditions were examined. The curing conditions were divided in air-dry curing and under-water curing. Three concrete mixures with the GGBFS replacement ratio of 0%(control), 30%, and 60% were prepared. For tests, evaluations of concrete compressive strength, and chloride ion diffusion coefficient were performed. As the GGBFS replacement ratio increased, the concrete compressive strength of the in air-dry cured specimens decreased compared to under-water cured specimens. When the chloride ion diffusion coefficient was measured, the chloride ion diffusion coefficient decreased as the GGBFS replacement ratio increased. However, the diffusion coefficient of the in air-dry cured specimen was increased up to 111% compared with the under-water cured specimen.