• Title/Summary/Keyword: Functional Material

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SOL-GEL PROCESSING AND MATERIAL SCIENCE

  • Korobova, N.E.;Soh, Deawha;Chu, Sun-Nam
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.477-480
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    • 1998
  • Sol-gel processing, which started some decades back as a laboratory curiosity, has proved to be a powerful and versatile technique for the synthesis of materials. The utility of the sol-gel method for producing glass and ceramic materials in the form of powders, fibers, thin films and bulk shapes with high purity, functional microstructures and potentially high chemical homogeneity at relatively low temperature (compared to conventional processing) has been discussed.

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Environmentally Friendly Preparation of Functional Nanomaterials and Their Application

  • Lee, Sun-Hyung;Teshima, Katsuya;Endo, Morinobu;Oishi, Shuji
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.5.1-5.1
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    • 2010
  • One of the most important environmental problems is global warming. Global warming is caused by increase in the amounts of water vapor, methane, carbon dioxide and other gases being released into the atmosphere as a result of the burning of fossil fuels. It has thus become important to reduce fossil fuel use. Environmentally friendly preparation of functional materials has, therefore, attracted much interest for environmental problems. Furthermore, nature mimetic processes are recently been of great interest as environmentally friendly one. There have been many studies on fabrication of various functional nanocrystals. Among various nanocrystal fabrication techniques, flux growth is an environmentally friendly, very convenient process and can produce functional nanocrystals at temperatures below the melting points of the solutes. Furthermore, this technique is suitable for the synthesis of crystals having an enhedral habit. In flux growth, the constituents of the materials to be crystallized are dissolved in a suitable flux (solvent) and crystal growth occurs as the solution becomes critically supersaturated. The supersaturation is attained by cooling the solution, by evaporation of the solvent or by a transport process in which the solute is made to flow from a hotter to a cooler region. Many kinds of oxide nanocrystals have been grown in our laboratory. For example, zero- (e.g., particle), one- (e.g., whisker and tube) and two-dimensional (e.g., sheet) nanocrystals were successfully grown by flux method. Our flux-growth technique has some industrial and ecological merits because the nanocrystal fabrication temperatures are far below their melting points and because the used reagents are less harmless to human being and the environment.

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Performance Evaluation of Fine-Dust Blocking Effect of Functional Clothing (미세먼지 차단 기능성 의류 제품의 성능 평가에 관한 연구)

  • Seok-Ju, Hwang;Chang-Hoon, Lee;Jin-Kyung, Kwon;Young-Sil, Kim;Eun-Jin, Choi;Da-Jin, Kim;Min, Kim;Se-Jin, Yook
    • Particle and aerosol research
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    • v.18 no.4
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    • pp.137-145
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    • 2022
  • As many studies on the harmfulness of fine dust have been reported, awareness of its seriousness is spreading. Recently, interest in indoor air quality as well as air pollution is increasing, and research on measures to block fine dust flowing into the room from the outside is being conducted. The clothing company is launching functional clothing to prevent fine dust attached to clothing from entering the room through outdoor activities. However, it is difficult to confirm whether there is actually fine-dust blocking performance, and there is no evaluation standard. In this study, the contamination rate caused by fine dust was quantitatively compared through image processing after contamination of the outer fabric for 4 types of commercially available functional clothing with fine-dust blocking effect. The difference in particle contamination according to the material of the outer fabric was analyzed by comparing the surface resistance, and it was found that the higher the surface resistance of the outer fabric material, the more fine dust was attached. The analysis method of this study is expected to be able to quantitatively compare and evaluate the fine-dust blocking performance of functional clothing.

Incorporation of Graphitic Porous Carbon for Synthesis of Composite Carbon Aerogel with Enhanced Electrochemical Performance

  • Singh, Ashish;Kohli, D.K.;Singh, Rashmi;Bhartiya, Sushmita;Singh, M.K.;Karnal, A.K.
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.204-211
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    • 2021
  • We report, synthesis of high surface area composite carbon aerogel using additive based polymerization technique by incorporating graphitic porous carbon as additive. This additive was separately prepared using sol-gel polymerization of resorcinol-furfuraldehyde in iso-propyl alcohol medium at much above the routine gelation temperature to yield porous carbon (CA-IPA) having graphitic layered morphology. CA-IPA exhibited a unique combination of meso-pore dominated surface area (~ 700 m2/g) and good conductivity of ~ 300 S/m. The composite carbon aerogel (CCA) was synthesized by traditional aqueous medium based resorcinol-formaldehyde gelation with CA-IPA as additive. The presence of CA-IPA favored enhanced meso-porosity as well as contributed to improvement in bulk conductivity. Based on the surface area characteristics, CCA-8 composition having 8% additive was found to be optimum. It showed specific surface area of ~ 2056 m2/g, mesopore area of 827 m2/g and electrical conductivity of 180 S/m. The electrode formed with CCA-8 showed improved electrochemical behavior, with specific capacitance of 148 F/g & ESR < 1 Ω, making it a better choice as super capacitor for energy storage applications.

Electronic State of ZnO Doped with Elements of IIIB family, Calculated by Density functional Theory (범밀도함수법을 이용하여 계산한 IIIB족 원소가 도핑된 ZnO의 전자상태)

  • Lee, Dong-Yoon;Lee, Won-Jae;Min, Bok-Ki;Kim, In-Sung;Song, Jae-Sung;Kim, Yang-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.7
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    • pp.589-593
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    • 2005
  • The electronic states of ZnO doped with Al, Ga and In, which belong to III family elements in periodic table, were calculated using the density functional theory. In this study, the calculation was performed by two Programs; the discrete variational Xa (DV-Xa) method, which is a sort of molecular orbital full potential method; Vienna Ab-initio Simulation Package (VASP), which is a sort of pseudo potential method. The fundamental mixed orbital structure in each energy level near the Fermi level was investigated with simple model using DV-Xa. The optimized crystal structures calculated by VASP were compared to the measured structures. The density of state and the energy levels of dopant elements were shown and discussed in association with properties.

An evaluation on crystallization of amorphous (InTe)x(GeTe)y thin films by nano-pulse illumination (나노-펄스 노출에 따른 비정질(InTe)x(GeTe)y박막의 결정화 속도 평가)

  • Song, Ki-Ho;Seo, Jae-Hee;Lee, Hyun-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.419-420
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    • 2008
  • In this work, we report several experimental data capable of evaluating the phase transition characteristics of (InTe)x(GeTe)y (x = 0.1, 0.3, y =1) pseudo-binary thin films. (InTe)x(GeTe)y phase change thin films have been prepared by thermal evaporator. The crystallization characteristics of amorphous (InTe)x(GeTe)y thin films were investigated by using nano-pulse scanner with 658 nm laser diode (power : 1~17 mW, pulse duration : 10~460 ns) and XRD measurement. It was found that the crystalline speed of In-Ge-Te thin films are faster than $Ge_2Sb_2Te_5$[1] and also the crystalline temperature is higher. Changes in the optical transmittance of as-deposited and annealed films were measured using a UV-VIS-IR spectrophotometer and four-point probe was used to measure the sheeresistance of InGeTe films annealed at different temperature.

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The Development of Functional $TiO_2$-Biodegradable Plastic Composite Material by Thermal Spraying (용사를 이용한 고기능 $TiO_2$-생분해성 플라스틱 복합재료의 개발)

  • ;;Akira Ohmori;Takahiro Nakatsuji
    • Proceedings of the KWS Conference
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    • 2004.05a
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    • pp.316-318
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    • 2004
  • In recent years, plastic waste has been recognized as a worldwide environmental issue. To solve the disposal problem of the plastic waste, alternative treatment such as the use of biodegradable plastic(polybutylene succinate: PBS) is indeed highly in demand due to its merit of PBS buried in soil decomposed into carbon dioxide and water. In the present study, for the production of further functional PBS with TiO$_2$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare photocatalytic TiO$_2$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions using three kinds of agglomerated powders (P200: 200nm, P30: 30nm, P7: 7nm). The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. Therefore, such functional TiO$_2$-Plastic composite material is expected to considerably contribute to the reduction of aggravated environmental problem.

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Effect of the grain boundary on the magnetic properties of the multi-seeded melt growth processed YBCO superconductors (다중종자결정성장법으로 제조한 YBCO 초전도체의 결정입계에 따른 자기적 성질의 영향)

  • Kim, Chan-Joong;Joo, Jin-Ho;Han, Young-Hee;Han, Sang-Chul;Sung, Tae-Hyun;Hong, Gye-Won;Kim, Ho-Jin
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.293-297
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    • 2000
  • Multiseeding with (100)/(100) grain junctions of top-seeded melt growth (TSMG) processed YBCO superconductors was studied. The effect of the number of seeds and the distance between two seeds on the levitation forces and the trapped magnetic fields of the TSMG-processed YBCO samples was investigated. Multiple seeding shortened the processing time for the fabrication of TSMC-processed YBCO superconductors. The large magnetic field was trapped at the grain junction when two seeds was placed without spacing, while the amount of the magnetic field decreased when the seed distance increased. This is attributed to the increased amount of the residual melt phases around the grain junctions.

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[ ${\beta}-cyclodextrin$ ] inclusion properties with guest molecules using hetero-bi-functional reactive dye

  • Kim, Byung-Soon;Kim, Young-Sung;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.32-35
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    • 2007
  • Cyclodextrin is a cyclic oligosaccharid material which shows an ability to incorporate organic guest molecules inside their cavity area. Thus, this ${\beta}-cyclodextrin$ treatment on fiber substrates may provide the changed surface characteristics of the substrates such as solubility, chemical reactivity and spectral property. In this context, the aim of this present work is to make a bridge connection using hetero-bi-functional reactive dye between fiber substrates and ${\beta}-cyclodextrin$. In addition, the corresponding Berberine inclusion behaviors into the inner cavity of ${\beta}-cyclodextrin$ was examined. The %exhaustion of Berberine inclusion as a guest molecule within the ${\beta}-cyclodextrin$ was measured using UV-Vis spectrophotometer. The findings showed that the %exhaustion of Berberine inclusion increased with increasing the prepared dye bridge compound and ${\beta}-cyclodextrin$ host material.

Application for Functional Construction Materials of Artificial Soil Manufactured Using Coal Bottom Ash (석탄 저회로 제조한 인공토양의 기능성 건설재 적용 가능성)

  • Kim, Kangduk;Lee, Yeongsaeng
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.300-306
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    • 2014
  • To recycle coal bottom ash(denoted here as CBA) generated from thermal power plants as a functional construction material, artificial soil(denoted as AS) containing CBA with dredged soil(denoted as DS) at a ratio(wt%) of 70 : 30 was manufactured by means of material engineering with sintering in a rotary kiln at $1125^{\circ}C$ using a green body formed via extrusion processing. The properties of the soil mechanics of the AS and the as-received CBA were analyzed and compared. Compaction testing results determined an optimum moisture content of the AS and CBA at 18%. During these tests, the maximum dry unit weights of the materials were similar, at 1.57 and 1.58 $t/m^3$, respectively. The compressive strength levels of the AS and CBA concrete specimens were 5.1 and 5.4 $t/m^3$, respectively, both of which increased after materials engineering processing. In a consolidation test, the compression index of the AS and CBA was found to be $0.114{\pm}0.001$ in both cases. The values were similar regardless of the materials engineering processes, but during the consolidation of AS, its coefficient was higher than that of the CBA materials.