• 한국정보전자통신기술학회논문지
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• 제2권4호
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• pp.29-36
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• 2009

본 논문은 버스에 사용되는 연소식 프리히터(Fuel Fired Heater) 퍼지 제어기(Fuzzy controller)를 설계하였다. 프리 히터는 얼마나 빠른 시간 안에 설정한 온도에 다다르는지와 공간내의 온도 편차가 얼마나 작게 발생하는지의 두 가지가 가장 중요한 요소이다. 기존의 연소식 프리히터의 온도 제어 방식으로 사용된 PI 제어기의 온도편차를 줄임과 동시에 응답특성을 개선한 퍼지 제어기를 설계하여 그 성능을 평가하였다. 설계된 퍼지 제어기에서 온도를 설정하면 기존의 PI 제어방식에서는 $25^{\circ}C$의 도달시간이 12분 소요되었으나 퍼지 제어방식에서는 9분 20초 소요되어 기존의 제어기보다 퍼지제어기가 2분 40초의 빠른 응답 성능으로 향상됨을 확인하였다. 난방의 온도 편차에서도 기존의 PI 제어 방식에서는 $2.4^{\circ}C$의 편차를 보인 반면 설계된 퍼지 제어기에서는 $1.6^{\circ}C$로 온도 편차 또한 개선되었음을 확인하였다.

• 한국추진공학회지
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• 제6권1호
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• pp.47-54
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• 2002

본 연구에서는 대기압하에서의 탄화수소계 연료인 제트유 연료액적에 대한 연소시 나타나는 액적의 연소특성 및 1차원 액적배열구조를 갖는 액적연소시 액적간격이 연소율 상수에 미치는 영향을 실험적으로 고찰하였다. 실험결과, 탄화수소계 연료인 제트유(jet A-1)는 실험조건하에서 단일 연료액적의 연소에 대해 액적크기에 상관없이 일정한 연소율 상수 $\kappa_c= 0.915{mm}^2$ 를 유지하였으며 대기압하에서 액적직경의 제곱$(d^2)$은 시간에 대하여 선형함수를 얻을 수 있었다. 또한, 1차원 배열구조를 갖는 액적연소(액적간격 $l/d_o$가 1.208~2.922)사이에 있어서 액적간격이 감소 할수록 액적의 연소율 상수 ${\kappa}_c$는 감소하였으며, 일정 액적간격을 가지는 액적군 연소시 3번째 액적 보다 2번째 액적의 연소율상수 ${\kappa}_c$에 미치는 영향이 더 크게 나타났다.

• 청정기술
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• 제13권4호
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• pp.293-299
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• 2007

막-전극 접합체(membrane electrode assembly, MEA)의 설계인자 즉, 구성요소들이 직접 메탄올 연료전지의 성능에 미치는 영향을 알아보았다. MEA에서의 촉매층과 고분자 분리막의 계면저항을 줄이기 위하여 직접 코팅법을 사용하여 제조한 MEA 구조와 조성의 최적화를 실시하였으며, 기체 확산층, 촉매량, 고분자 전해질 분리막의 두께가 직접메탄을 연료전지의 성능에 미치는 영향을 알아보고, 전기화학적 분석법을 사용하여 성능향상 요인을 분석하였다. 본 연구를 통해 직접코팅법으로 제조한 MEA의 구조와 조성에 따른 성능변화 특성을 파악할 수 있었으며, 연료극과 공기극에 총 $4\;m/cm^2$ (Pt 기준)의 촉매를 사용하였을 때, $80^{\circ}C$ 1기압의 운전 조건하에서는 최고성능 $147\;mW/cm^2$, $60^{\circ}C$, 1기압의 운전 조건하에서는 최고성능 $100\;mW/cm^2$을 확보하였다.

• 공업화학
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• 제22권5호
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• pp.447-452
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• 2011

석유자원의 고갈이 에너지 및 화학원료물질로 재생 가능한 바이오매스의 이용성을 증가시키고 있다. 본 총설에서는 바이오에너지 및 바이오화학원료인 C4-C6 생산에 관해 논하고자 한다. 주요한 C4 물질인 n-butanol과 n-butyric acid를 다량 생산하는 미생물은 Clostridium tyrobutyricum, Clostridium beijerinckii, Clostridium acetobutylicum이다. 대표적인 C6 물질인 n-hexanoic acid는 Clostridium kluyveri와 Megasphaera elsdenii가 다량 생산한다. 미생물 발효에 의해 보고된 n-butanol, n-butyric acid, n-hexanoic acid의 최대 생산량은 각각 21, 55, 19 g/L이었다. 배양과정에서 이들 생산물의 제거는 최종산물억제의 감소로 미생물에 의한 n-butanol, n-butyric acid, n-hexanoic acid의 생산량을 증가시켰다. 특히 C6 물질인 n-hexanoic acid는 n-hexanol로 될 수 있는 고 부가가치 물질로 생물학적 생산 연구가 꾸준히 진행 중인데, 신규한 미생물인 Clostridium sp. BS1은 galactitol을 이용하여 5 g/L의 n-hexanoic acid를 생산하였다.

• 한국연소학회지
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• 제3권1호
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• pp.59-69
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• 1998

The results of study on the active control of naturally occurring combustion oscillations with a single dominant frequency in an atmospheric dump combustor are presented. Control was achieved by an oscillatory infection of secondary fuel at the dump plane. A high speed solenoid valve with a maximum frequency of 250Hz was used as the actuator and a sound level meter, located at the combustor exit, measured the pressure fluctuations which served as the feedback signal for the control loop. Instability characteristics were mapped over a range of mean mixing section velocities from 6.7 m/s-9.3 m/s and with three mixing conditions. Different fuel/air mixing conditions were investigated by introducing varying percentages of primary fuel at two locations, one at the entrance to the mixing section and one 6 mixing tube diameters upstream of the dump plane. Control studies were conducted at a mean velocity of 9.3 m/s, with an air temperature of $415^{\circ}C$, and from flame blowout to the stoichiometric condition.

• 한국세라믹학회지
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• 제44권12호
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• pp.727-732
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• 2007

In order to fabricate a highly performing cathode for low-temperature type solid oxide fuel cells working at below $700^{\circ}C$, electrode microstructure control and electrode polarization measurement were performed with an electronic conductor, $La_{0.8}Sr_{0.2}MnO_3$ (LSM) and a mixed conductor, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$(LSCF). For both cathode materials, when $Sm_{0.2}Ce_{0.8}O_2$ (SDC) buffer layer was formed between the cathode and yttria-stabilized zirconia (YSZ) electrolyte, interfacial reaction products were effectively prevented at the high temperature of cathode sintering and the electrode polarization was also reduced. Moreover, cathode polarization was greatly reduced by applying the SDC sol-gel coating on the cathode pore surface, which can increase triple phase boundary from the electrolyte interface to the electrode surface. For the LSCF cathode with the SDC buffer layer and modified by the SDC sol-gel coating on the cathode pore surface, the cathode resistance was as low as 0.11 ${\Omega}{\cdot}cm^2$ measured at $700^{\circ}C$ in air atmosphere.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 추계학술대회 논문집
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• pp.615-616
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• 2006

A micro-fuel processor system integrating steam reformer and partial oxidation reactor was manufactured using low temperature cofired ceramic (LTCC). A CuO/ZnO/$Al_2O_3$ catalyst and Pt-based catalyst prepared by wet impregnation were used for steam reforming and partial oxidation, respectively. The performance of the LTCC micro-fuel processor was measured at various operating conditions such as the effect of the feed flow rate, the ratio of $H_2O/CH_3OH$, and the operating temperature on the LTCC reformer and CO clean-up system. The catalyst layer was loaded with "Fill and Dry" coating for small volume. The product gas was composed of $70\sim75%$ hydrogen, $20\sim25%$ carbon dioxide, and $1\sim2%$ carbon monoxide at $250\sim300^{\circ}C$, respectively.

• 대한기계학회논문집B
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• 제32권11호
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• pp.841-848
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• 2008

DME(Di-methyl Ether) has been expected to be one of the promising alternative fuels for compression ignition engines due to its low emission characteristics for particulate matter. However, its physical properties such as density, bulk modulus and viscosity are not comparable to those of conventional diesel fuel. Especially, problems caused by low lubricity and high compressibility need to be understood more thoroughly, when a DME fuel is used for compression ignition engine, especially with mechanical fuel supply system. In this study, measurement and calculation of DME's bulk modulus were carried out over the range of temperatures from $-3^{\circ}C$ to $53^{\circ}C$, and pressures from 50 bar to 250 bar using an experimental apparatus built in this work. The results show that DME is prone to be compressed more easily compared to diesel fuel. A comparison of bulk modulus with butane and propane were also made in this work.

• Nuclear Engineering and Technology
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• 제41권1호
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• pp.107-112
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• 2009

Corrosion of nickel-base alloys (Hastelloy C-276, Inconel 625, and Inconel X-750) in $500^{\circ}C$, 25MPa supercritical water (with 10 wppb oxygen) was investigated to evaluate the suitability of these alloys for use in supercritical water reactors. Oxide scales formed on the samples were characterized by gravimetry, scanning electron microscopy/energy dispersive spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The results indicate that, during the 1000h exposure, a dense spinel oxide layer, mainly consisting of a fine Cr-rich inner layer ($NiCr_{2}O_{4}$) underneath a coarse Fe-rich outer layer ($NiFe_{2}O_{4}$), developed on each alloy. Besides general corrosion, nodular corrosion occurred on alloy 625 possibly resulting from local attack of ${\gamma}$" clusters in the matrix. The mass gains for all alloys were small, while alloy X -750 exhibited the highest oxidation rate, probably due to the absence of Mo.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.157-159
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• 2001

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)C03 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(40vol%) was better excellent than the others.