• Title/Summary/Keyword: Fuel Cell Temperature

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Prediction of MCFC Unit Cell Performance Using 3-D Heat & Fluid Analysis with Electrochemical Reaction (전기화학반응을 포함한 3차원 열$\cdot$유동해석을 통한 용융탄산염 연료전지의 단위 전지 성능해석)

  • Kim Y. R.;Choi D. H.
    • 한국전산유체공학회:학술대회논문집
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    • 2004.10a
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    • pp.141-144
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    • 2004
  • An analysis procedure for the MCFC channel flow has been developed to predict the fuel cell performance. The channel formed by the uniformly distributed trapezoidal supports is approximated by the porous medium that yields the equivalent pressure drop. The Wavier-Stokes, energy, and species equations are solved to obtain the velocity, temperature and concentration fields for a local current density which is computed from electrochemical correlations. The fuel cell characteristics, such as the temperature, pressure, mole concentration, voltage and current density distributions, are presented and discussed.

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Fabrication and Property Evaluation of Tubular Segmented-in-Series Solid Oxide Fuel Cell (SOFC) (세그먼트 관형 SOFC의 제작 및 특성 평가)

  • Yun, Ui-Jin;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul;Han, Kyoo-Seung
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.562-566
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    • 2012
  • A novel design of tubular segmented-in-series(SIS) solid oxide fuel cell (SOFC) sub module was presented in this paper. The tubular ceramic support was fabricated by the extrusion technique. The NiO-YSZ anode and the yttria-stabilized zirconia (YSZ) electrolyte were deposited onto the ceramic support by dip coating method. After sintering at $1350^{\circ}C$ for 5 h, a dense and crack-free YSZ film was successfully fabricated. Also, the multi-layered cathode composed of LSM-YSZ composite, LSM and LSCF were coated onto the sintered ceramic support by dip coating method and sintered at $1150^{\circ}C$. The performance of the tubular SIS SOFC cell and sub module electrically connected by the Ag-glass interconnect was measured and analysed with different fuel flow and operating temperature.

Preparation of multi-component ceramic proton conductors for intermediate temperature fuel cell (중온형 연료전지를 위한 다성분계 세라믹 수소이온 전도체 제조)

  • Lim, Byeong-mu;Seo, Dong-ho;Park, Sang-sun;Lee, Hong-yeon;Shul, Yong-Gun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.410-411
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    • 2009
  • The multi-component ceramic proton conductor, $BaZr(Y)O_3-SiO_2-TiO_2-ZrO_2$ (BZY-STZ) and $LaPO_4-SiO_2-TiO_2-ZrO_2$ (LP-STZ), were synthesized by micro-emersion and sol-gel technique. The characterization of proton conductors were carried out using X-ray diffraction(XRD), thermogravimetric analysis(TGA), differential thermal analysis(DTA), impedance analysis. The proton conductors indicate the possibility of application for the intermediate temperature up to $700^{\circ}C$.

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Operation Characteristics and Analysis of Temperature Gradients in a 5-kW Molten Carbonate Fuel Cell Stack (5 kW 용융탄산염 연료전지 스택내 운전특성 및 온도 변화 해석)

  • Lim, Hee-Chun;Koh, Joon-Ho;Ryu, Jeong In
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.2
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    • pp.107-118
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    • 1999
  • A 5-kW MCFC stack with $3,000cm^2$ electrode area was tested to investigate cell performance and operation characteristics. The stack performance was evaluated based on electrical output and I-V change. The stack showed high cell performance (7.6 kW) than the design performance and operated for more than 5,760 hours, but a significant temperature gradient inside the stack was observed. A 3-dimensional mathematical model for molten carbonate fuel cell (MCFC) was developed for the purpose of simulation of stack performance during the operation. The model was solved using PHOENICS, a computational fluid dynamics (CFD) code. The simulation result demonstrated a close prediction of the temperature gradient and stack performance.

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Effect of Coolant on PEMFC Performance in Low Humidification Condition (저가습 조건에서 냉각 유체의 고분자전해질 연료전지에 대한 영향)

  • Lee, Hung-Joo;Song, Hyun-Do;Kwon, Jun-Taek;Kim, Jun-Bom
    • Journal of the Korean Electrochemical Society
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    • v.10 no.1
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    • pp.25-30
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    • 2007
  • Proton exchange membrane fuel cell(PEMFC) performance could be affected by various factors such as cell temperature, total pressure, partial pressure of reactants and relative humidity. Hydrogen ion is combined with water to form hydronium ion [$H_3O^+$] and pass through membrane resulting electricity generation. Cooling system is needed to remove heat and other uses on large scale fuel cell. In case that collant conductivity is increased, fuel cell performance could be decreased because produced electricity could be leaked through coolant. In this study, triple distilled water(TDW) and antifreeze solution containing ethylene glycol was used to observe resistance change. Resistance of TDW was taken 28 days to reach preset value, and effect on fuel cell operation was not observed. Resistance of antifreeze solution was not reached to preset value up to 48 days, but performance failure occurred presumably caused by bipolar plate junction resulting stoppage resistance experiment. Generally PEMFC humidification is performed near-saturated operating conditions at various temperatures and pressures, but non-humidifying condition could be applied in small scale fuel cell to improve efficiency and reduce system cost. However, it was difficult to operate large scale fuel cell without humidifying, especially higher than $50{\sim}60^{\circ}C$. In case of small flux such as 0.78 L/min, temperature difference between inlet and outlet was occurred larger than other cases resulting performance decrease. Non-humidifying performance experiments were done at various cell temperature. When both of anode and cathode humidification were removed, cell performance was strongly depended on cell operating temperature.

DEVELOPMENT OF ELECTROREFINER WASTE SALT DISPOSAL PROCESS FOR THE EBR- II SPENT FUEL TREATMENT PROJECT

  • Simpson, Michael F.;Sachdev, Prateek
    • Nuclear Engineering and Technology
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    • v.40 no.3
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    • pp.175-182
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    • 2008
  • The results of process development for the blending of waste salt from the electrorefining of spent fuel with zeolite-A are presented. This blending is a key step in the ceramic waste process being used for treatment of EBR-II spent fuel and is accomplished using a high-temperature v-blender. A labscale system was used with non-radioactive surrogate salts to determine optimal particle size distributions and time at temperature. An engineering-scale system was then installed in the Hot Fuel Examination Facility hot cell and used to demonstrate blending of actual electrorefiner salt with zeolite. In those tests, it was shown that the results are still favorable with actinide-loaded salt and that batch size of this v-blender could be increased to a level consistent with efficient production operations for EBR-II spent fuel treatment. One technical challenge that remains for this technology is to mitigate the problem of material retention in the v-blender due to formation of caked patches of salt/zeolite on the inner v-blender walls.

Analytic study on thermal management operating conditions of balance of 100kW fuel cell power plant for a fuel cell electric vehicle (100kW급 연료전지 열관리 시스템 실도로 운전조건 해석적 연구)

  • Lee, Ho-Seong;Lee, Moo-Yeon;Cho, Choong-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.2
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    • pp.1-6
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    • 2019
  • The objective of this study was to investigate performance characteristics of thermal management system(TMS) in a fuel cell electric vehicle with 100kW Fuel Cell(FC) system. In order to build up analytic modelling for TMS, each component was installed and tested under various operating conditions, such as water pump, radiator, 3-Way valve, COD heater, and FC stack etc. and as the results of them, correlations reflecting component's characteristics with flow rate, air velocity were developed. Developed analytic modelling was carried out under various operating conditions on the road. To verify modelling's accuracy, after prediction for optimum coolant flow rate was fulfilled under certain operating conditions, such as FC system, water pump speed, opening of 3-way valve, and pipe resistance, analytic and experimental values were compared and good agreement was shown. In order to predict cold-start operating performance for analytic modelling, coolant temperature variation was analyzed with $-20^{\circ}C$ ambient temperature and duration was predicted to rise in optimum temperature for FC. Because there is appropriate temperature difference between inlet and outlet of FC stack to operate FC system properly, related analysis was performed with respect to power consumption for TMS and heat rejection rate and performance map was depicted along with FC operating conditions.