• 한국전기전자재료학회논문지
• /
• 제27권2호
• /
• pp.85-90
• /
• 2014

Ag paste has been used in the front electrode of the Si-solar cell. It is composed by Ag powder, glass frit, binder, solvent and dispersant. The role of the binder and the solvent is to make a flow and a printing property. However, it was not enough to report the printing properties with the variation of binder in the controled viscosity. In this study, we selected 3 kinds of typical binder which were used as binder for the paste in the industry, such as Ethyl cellulose, Hydroxypropyl cellulose and Acrylic. Ag pastes using these were prepared, controled viscosity and printed on the SiNx coated Si wafer. In the 'A paste' used Acrylic binder, printed hight was highest and 'H paste' used Hydroxypropyl cellulose binder was lowest. Because 'H paste' was high viscosity due to the molecular weight, the solvent was added in the paste to control the viscosity. Therefore, the content of solid was lower in 'H paste'. The relative pattern width which is related to the spreading of paste was the best in the case of 'H paste' and 'EH paste' at $30^{\circ}C$. It is thought that the optimization of the relative pattern width is possible for a paste by the controling shear thinning phenomenon. In the case of 'A paste', though printing hight was best, the pattern width was dependant on the temperature.

• 한국태양에너지학회 논문집
• /
• 제40권5호
• /
• pp.35-45
• /
• 2020

Photovoltaic (PV) power system prices have been steadily dropping in recent years due to their mass production and advances in relevant technology. Crystalline silicon (c-Si wafers) account for the largest share of the price of solar cells; reducing the thickness of these wafers is an essential part of increasing the price competitiveness of PV power systems. However, reducing the thickness of c-Si wafers is challenging; typically, phenomena such as bowing and cracking are encountered. While several approaches to address the bowing phenomenon of the c-Si solar cells exist, the only method to study the crack phenomenon (related to the strength of the c-Si solar cells) is the bending test method. Moreover, studies on determining the strength properties of the solar cells have focused largely on c-Si wafers, while those on the strength properties of front and rear-side electrodes and SiNx, the other components of c-Si solar cells, are scarce. In this study, we analyzed the strength characteristics of each layer of c-Si solar cells. The strength characteristics of the sawing mark direction produced during the production of c-Si wafers were also tested. Experiments were conducted using a 4bending tester for a specially manufactured c-Si solar cell. The results indicate that the back side electrode is the main component that experienced bowing, while the front electrode was the primary component regulating the strength of the c-Si solar cell.

• 융복합기술연구소 논문집
• /
• 제8권1호
• /
• pp.33-39
• /
• 2018

The screen printing method for forming the electrode by applying the existing pressure is difficult to apply to thin wafers, and since expensive Ag paste is used, it is difficult to solve the problem of cost reduction. This can solve both of the problems by forming the front electrode using a plating method applicable to a thin wafer. In this paper, the process conditions of electrode formation are optimized by using LIEP (Light-Induced Electrode Plating). Experiments were conducted by varying the Ni plating bath temperature $40{\sim}70^{\circ}C$, the applied current 5 ~ 15 mA, and the plating process time 5 ~ 20 min. As a result of the experiment, it was confirmed that the optimal condition of the structural characteristics was obtained at the plating bath temperature of $60^{\circ}C$, 15 mA, and the process time of 20 min. The Cu LIEP process conditions, experiments were conducted with Cu plating bath temperature $40{\sim}70^{\circ}C$, applied voltage 5 ~ 15 V, plating process time 2 ~ 15 min. As a result of the experiment, it was confirmed that the optimum conditions were obtained as a result of electrical and structural characteristics at the plating bath temperature of $60^{\circ}C$ and applied current of 15 V and process time of 15 min. In order to form Ni silicide, the firing process time was fixed to 2 min and the temperature was changed to $310^{\circ}C$, $330^{\circ}C$, $350^{\circ}C$, and post contact annealing was performed. As a result, the lowest contact resistance value of $2.76{\Omega}$ was obtained at the firing temperature of $310^{\circ}C$. The contact resistivity of $1.07m{\Omega}cm^2$ can be calculated from the conditionally optimized sample. With the plating method using Ni / Cu, the efficiency of the solar cell can be expected to increase due to the increase of the electric conductivity and the decrease of the resistance component in the production of the solar cell, and the application to the thin wafer can be expected.

• 전기전자학회논문지
• /
• 제17권3호
• /
• pp.234-240
• /
• 2013

본 논문에서는 단일-극 커패시터 방식의 터치센서를 위한 incremental 델타-시그마 아날로그-디지털 변환기를 설계하였다. 델타-시그마 모듈레이터의 구조는 단일비트 2차 cascade of integrators with distributed feedback(CIFB)를 사용하였으며 $0.18-{\mu}m$ CMOS 공정을 이용하여 제작하였다. Incremental 델타-시그마 아날로그-디지털 변환기의 입력으로 이어지는 센서가 넓은 입력 범위를 얻고 높은 정확성을 가지도록 변환기 앞에 shielding 신호와 디지털적으로 조절 가능한 오프-셋 커패시터를 위치시켰다. 본회로의 공급전압은 2.6 V에서 3.7 V이며 ${\pm}10-pF$의 입력범위를 가지고 fF 이하의 해상도를 필요로 하는 단일-극 커패시터 방식의 터치센서에 적합하다.

• 한국전자파학회논문지
• /
• 제29권7호
• /
• pp.477-483
• /
• 2018

본 논문에서는 FM 방송대역(88~108 MHz)에서 동작하는 자동차 전면 글래스 상에 설계되는 투명 안테나를 제안한다. 투명 안테나는 전형적으로 차량 지붕에 설치된 샤크핀 안테나의 공간적 제한을 피하기 위해 차량 전면 글래스에 구현하였다. 전면 글래스에 설계되는 안테나는 낮은 수심감도와 다른 서비스대역의 안테나로부터의 방사간섭 문제를 합리적으로 해결할 수 있다. 전면 글래스는 고유한 closed-line 구조를 가지고 있으며, 이 구조로 인해 전면 글래스 외곽의 차체 표면으로 전류가 흐르게 되어 FM 방송대역 이전 부분에서 첫 공진점이 발생한다. Closed-line 구조를 이용한 표면 전류 길이 제어를 통해 첫 공진점이 FM 대역에서 동작하는 안테나를 설계하였다. 또한, RF 수동소자로 설계하기 적합한 투명전극 소자 마이크로 메탈메쉬 필름의 투명성을 통해 시각적 인식의 최소화 하였다. 측정된 안테나는 FM 대역에서 반사계수는 -6 dB 이하이며, average peak gain은 -0.9 dB이다. 본 연구를 통해 제안된 전면 글래스 투명안테나는 미래의 자동차 안테나 개발에 필요한 공간과 설계 자유에 대한 가능성을 보여주었다.

• 한국자동차공학회논문집
• /
• 제3권1호
• /
• pp.54-64
• /
• 1995

The effects of swirl on early flame development and late combustion characteristic were investigated using a high speed single-shot visualized 51 engine. LDV measurements were performed to get better understanding of the flow field in this combustion chamber. Spark plugs were located at half radius (R/2) and central location of bore. High speed schlieren photographs at 20,000 frames/sec were taken to visualize the detailed formation and development of the flame kernel with cylinder pressure measurements. This study showed that high swirl gave favorable effects on combustion-related performances in terms of the maximum cylinder pressure and flame growth rate regardless of spark position. However, at R/2 ignition the low swirl shown desirable effects at low engine speed gave worse performances as engine speed increased than without swirl. There were distinct signs of slow-down in flame growth during the period when the flame front expanded from 2.5mm in radius until it reached 5.0mm apparently due to the presence of ground electrode. There seemed to be heat transfer effect on the flame expansion speed which was evidenced in high swirl case by the slowdown of the late flame front presumably caused by relatively large heat loss from burned gas to wall compared with low- or no-swirl cases.

• E2M - 전기 전자와 첨단 소재
• /
• 제9권6호
• /
• pp.593-599
• /
• 1996

Laser scribing of silicon plays an important role in metallization including the grid pattern and the front surface geometry which means aspect ratio of metal contacts. To make a front metal electrode of buried contact solar cell, we used ND:YAG lasers that deliver average 3-4W at TEM$\_$00/ mode power to sample stage. The Q-switched Nd:YAG laser of 1.064 gm wavelength was used for silicon scribing with 20-40.mu.m width and 20-200.mu.m depth capabilities. After silicon slag etching, the groove width and depth for buried contact solar cell are -20.mu.m and 30-50.mu.m respectively. Using MEL 40 Nd:YAG laser system, we can scribe the silicon surface with 18-23.mu.m width and 20-200.mu.m depth controlled by krypton arc lamp power, scan speed, pulse frequency and beam focusing. We fabricated a buried contact Silicon Solar Cell which had an energy conversion efficiency of 18.8 %. In this case, the groove width and depth are 20.mu.m and 50.mu.m respectively.

• Journal of the Optical Society of Korea
• /
• 제19권3호
• /
• pp.217-221
• /
• 2015

Developing a metallization that has low cost and high efficiency is essential in solar-cell industries, to replace expensive silver-based metallization. Ni/Cu two-step metallization is one way to reduce the cost of solar cells, because the price of copper is about 100 times less than that of silver. Alkaline electroless plating was used for depositing nickel seed layers on the front electrode area. Prior to the nickel deposition process, 2% HF solution was used to remove native oxide, which disturbs uniform nickel plating. In the subsequent step, a nickel sintering process was carried out in $N_2$ gas atmosphere; however, copper was plated by light-induced plating (LIP). Plated nickel has different properties under different bath conditions because nickel electroless plating is a completely chemical process. In this paper, plating bath conditions such as pH and temperature were varied, and the metal layer's structure was analyzed to investigate the adhesion of Ni/Cu metallization. Average adhesion values in the range of 0.2-0.49 N/mm were achieved for samples with no nickel sintering process.

• 한국표면공학회지
• /
• 제37권2호
• /
• pp.86-91
• /
• 2004

Effect of potassium formate, glycine and oxalic acid in a sulfate solution on the deposit composition and current efficiency of trivalent chromium plating was studied. The trivalent chromium layers prepared by solutions with potassium formate, glycine and oxalic acid contain a few carbon inside. The solutions containing potassium formate, glycine and oxalic acid are relatively stable with pH change. The solution with the potassium formate shows 6-30％ current efficiency with current density, whereas, the solutions with oxalic acid and glycine show about 5％ current efficiency, respectively. The improved current efficiency is related to enough supply of chromium ions to the electrode due to the increase of pH at the front of electrode.

• 반도체디스플레이기술학회지
• /
• 제13권2호
• /
• pp.29-35
• /
• 2014

In this study general solar cell production process was complemented, with research on improvement of solar cell efficiency through surface structure and thermal annealing process. Firstly, to form the pyramid structure, the saw damage removal (SDR) processed surface was undergone texturing process with reactive ion etching (RIE). Then, for the formation of smooth pyramid structure to facilitate uniform doping and electrode formation, the surface was etched with HND(HF : HNO3 : D.I. water=5 : 100 : 100) solution. Notably, due to uniform doping the leakage current decreased greatly. Also, for the enhancement and maintenance of minority carrier lifetime, antireflection coating thermal annealing was done. To maintain this increased lifetime, front electrode was formed through Au plating process without high temperature firing process. Through these changes in two processes, the leakage current effect could be decreased and furthermore, the conversion efficiency could be increased. Therefore, compared to the general solar cell with a conversion efficiency of 15.89%, production of high efficiency solar cell with a conversion efficiency of 17.24% was made possible.