• 제목/요약/키워드: Fresh Material

검색결과 519건 처리시간 0.025초

Adsorbate Interactions of Cu(II) Ion-Exchanged into Mesoporous Aluminosilicate MCM-41 Analyzed by Electron Spin Resonance and Electron Spin Echo Modulation

  • Kim, Jeong-Yeon;Yu, Jong-Sung
    • 한국자기공명학회논문지
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    • 제3권2호
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    • pp.109-126
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    • 1999
  • The location of Cu(II) exchanged into measoporous aluminosilicate MCM-41(AlMCM-41) material and its interaction with various adsorbate molecules were investigated by electron spin resonance and electron spin echo modulation spectroscopies. Cu(II) is fully coordinated to adsorbates in a wide open mesopore of AlMCM-41 for the formation of favorable complexes. It was found that in the fresh hydrated material, Cu(II) is octahedrally coordinated to six water molecules as evidenced by an isotropic room temperature ESR signal. This species is located in a cylindrical MCM-41 channel and rotates rapidly at room temperature. Evacuation at room temperature removes some of these water molecules, leaving the Cu(II) coordinated to less water molecules and anchored to oxygens in an MCM-41 channel wall. Dehydration at 450$^{\circ}C$ produces one Cu(II) species located on the internal wall of a channel, which is easily accessible to adsorbates. Adsorption of adsorbate molecules such as water, methanol, ammonia, pyridine, aniline, acetonitrile, benzene, and ethylene on a dehydrated Cu-AlMCM-41 material causes changes in the ESR spectrum of Cu(II), indicating the complex formation with these adsorbates. Cu(II) forms a complex with six molecules of methanol as evidenced by an isotropic room temperature ESR signal and ESEM analysis like upon water adsorption. Cu(II) also forms a square planar complex containing four molecules of N-containing adsorbates such as ammonia, pyridine and aniline based on resolved nitrogen superhyperfine interaction and their ESR parameters. However, Cu(II) forms a complex with six-molecules of acetonitrile based on ESR parameters. Only one molecule of benzene or ethylene is coordinated to Cu(II).

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한국서남해안지역(韓國西南海岸地域)에 분포(分布)하는 함유질물층(含油質物層)에 대(對)한 지질학적(地質學的) 및 지구화학적연구(地球化學的硏究) (Geologic and Geochemical study on the rock sequences containing oily materials in Southwestern Coast Area of Korea)

  • 이대성;이하영
    • 자원환경지질
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    • 제9권1호
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    • pp.45-73
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    • 1976
  • This study has been made for the enlargement of a previous work of 1964 which was carried out by an author of this work emphasizing the stratigraphy, micropaleontology, depositional environment, and structural tectonics of the studied area. The stratigraphic sequences of the area are groupped into four units: (1) basement of Pre-Cretaceous, (2) lower sediments of Late Cretaceous, (3) upper sediments of Late Cretaceous and (4) igneous rocks of Late Cretaceous and Tertiary (?). The oldest rocks consisting of schists and gneisses of Pre-Cambrian and schistose granite' of Jurassic age are exposed at the base of this area on which the thick Cretaceous sediments were deposited. These old rocks are unconformably overlain by the lower sedimens of Late Cretaceous composed of three members, an alternation of black shale and tuffaceous sediments, fine tuff and rhyollite flow in ascending order. The oily material was found from the black shales of the alternation m"ember as semi-solid greaselike material, oily order and microscopic granular spherical material and oily stain. The lower sediments are also overlain, in low-angleunconfromity, by the 'upper sediments having three members, an alternation of volcanic conglomerate and andesitic tuff, rhyollitic tuff and andesite flow in the same order. The igneous suit of diabase, diorites, biotite granite, porphyritic granite and porphyries of the latest Cretaceous and small exposure of pitchstone of Tertiary (?) intruded into the pre-existed rocks above mentioned. Considerable amount of ostra- coda microfossils have been chemically extracted from the black shales of the lower sediments and the identification of the fossils suggests that the depositional environment of the sediments were under fresh or brackish water condition. The distribution of the geology and its tectonic data also suggest a combination of dome and basin structures in the area of San-i peninsula and Jin-do as shown in fig. 8. Between these two units an anticlinal structure was constructed. As a result of this study, a seismic survey in a district between U-su-yong and north coast of Jin-do is recommended to determine the underground features.

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불소-실리카 복합형 균열저감제가 첨가된 콘크리트의 재료 특성과 수축균열 저항성 (Material Properties and Shrinkage Crack Resistance of Concrete Produced with Fluorine-Silicate Hybrid Type Crack Reducing Agent)

  • 이만익;박종화;남재현;김도수;김재온
    • 콘크리트학회논문집
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    • 제18권4호
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    • pp.553-558
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    • 2006
  • 본 연구에서는 배합강도 30MPa로 설계된 25-30-18 규격의 콘크리트 배합에 불소화합물 및 실리카로 구성된 불소-실리카 복합형 균열저감제(FS)를 시멘트 중량을 기준으로 0.5% 간격으로 2.0%까지 첨가한 후 슬럼프 경시 변화, 공기량 경시 변화 및 블리딩 등의 굳지 않은 콘크리트의 재료특성을 평가하였다. 또한, 콘크리트 수화온도 변화에 미치는 영향과 소성수축 및 건조수축의 저항성에 미치는 효과를 파악하였다. FS가 첨가된 콘크리트의 재료특성에서 슬럼프 및 공기량 경시 변화는 무첨가 콘크리트에 비해 큰 차이가 없었으나 블리딩과 수화온도는 저감되는 것으로 나타났다. 특히, 경화 전 후 소성수축 및 건조수축에 기인된 콘크리트의 수축균열 저항성이 FS를 $1.0{\sim}1.5%$의 첨가함으로써 크게 저감됨을 알 수 있었다.

고강도 Self-Leveling재의 최적 결합재비 (The Optimum Binder Ratio for High-Strength Self-Leveling Material)

  • 김진만
    • 한국건축시공학회지
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    • 제2권4호
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    • pp.89-98
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    • 2002
  • Self-leveling material(SLM) is one of the floor finishing materials which make flat surface like as water level by itself in a short time. So it is possible to increase construction speed and enhance economical efficiency In this study, author intended to develop SLM for the industrial warehouse and factory loading heavy weight machinery and vehicles. The demanded properties for this type of SLM are above 200mm of flow value and above 300kgf/$cm^2$ of 28-days compressive strength. To possess demended strength and fluidity, SLM have to be composed of many types of binders and chemical additives. So it is difficult to decide suitable mixing proportion of composition materials. In this study, author investigated the weight percentage effect of main composition materials for high-strength self-leveling material, by experimental design such as tables of orthogonal arrays and simplex design, and by statistical analysis such as analysis of variance and analysis of response surface. Variables of experiments were ordinary Portland cement(OPC), alumina cement(AC), anhydrous gypsum(AG), lime stone(LS) and sand, and properties of tests were fluidity of fresh state and strength of hardened state. Results of this study are showed that suitable mix proportions of binders for the high strength self-leveling materials are two groups. One is 78~85.5% OPC, 7.5~9.5% AC, 9~12.5% AG and the other is 72.5~78% OPC, 9~12.5% AC, 13~15% AG.

Efficacy of supplementary cementitious material and hybrid fiber to develop the ultra high performance hybrid fiber reinforced concrete

  • Sharma, Raju;Bansal, Prem Pal
    • Advances in concrete construction
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    • 제8권1호
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    • pp.21-31
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    • 2019
  • The rich recipe of ultra high performance concrete (UHPC) offers the higher mechanical, durability and dense microstructure property. The variable like cement/sand ratio, amount of supplementary cementitious material, water/binder ratio, amount of fiber etc. alters the UHPC hardened properties to any extent. Therefore, to understand the effects of these variables on the performance of UHPC, inevitably a stage-wise development is required. In the present experimental study, the effect of sand/cement ratio, the addition of finer material (fly ash and quartz powder) and, hybrid fiber on the fresh, compressive and microstructural property of UHPC is evaluated. The experiment is conducted in three phases; the first phase evaluates the flow value and strength attainment of ingredients, the second phase evaluates the efficiency of finer materials (fly ash and quartz powder) to develop the UHPC and the third phase evaluate the effect of hybrid fiber on the flow value and strength of ultra high performance hybrid fiber reinforced concrete (UHP-HFRC). It has been seen that the addition of fly ash improves the flow value and compressive strength of UHPC as compared to quartz powder. Further, the usage of hybrid fiber in fly ash contained matrix decreases the flow value and improves the strength of the UHP-HFRC matrix. The dense interface between matrix and fiber and, a higher amount of calcium silicate hydrate (CSH) in fly ash contained UHP-HFRC is revealed by SEM and XRD respectively. The dense interface (bond between the fiber and the UHPC matrix) and the higher CSH formation are the reason for the improvement in the compressive strength of fly ash based UHP-HFRC. The differential thermal analysis (DTA/TGA) shows the similar type of mass loss pattern, however, the amount of mass loss differs in fly ash and quartz powder contained UHP-HFRC.

고로슬래그미분말 및 강섬유를 적용한 고유동 흙막이 벽체 재료의 성능 평가 (Performance of High-Flowable Retaining Wall Material Using Ground Granulated Blast-Furnace Slag and Steel Fiber)

  • 김동규;유강민;이승태
    • 한국지반환경공학회 논문집
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    • 제23권11호
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    • pp.5-11
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    • 2022
  • 본 연구는 고로슬래그미분말(SG) 및 강섬유(SF)를 적용한 고유동 흙막이 벽체 재료(RWM)의 역학적 성능을 평가하기 위한 것으로써, 흙막이 벽체 재료의 재료분리저항성, 유동성, 연행공기량을 확보하기 위하여 고성능감수제, 공기연행제 및 증점안정화제를 굳지 않은 흙막이 벽체 재료에 적정량을 사용하였다. 흙막이 벽체 재료 경화체의 강도특성을 고찰하기 위하여 압축, 할열 인장 및 휨강도를 소정의 재령에서 측정하였으며, 표면전기저항, 흡수율 실험을 통하여 흙막이 벽체 재료의 역학적 성능을 평가하였다. 실험결과에 따르면 SGC 배합은 OPC 배합에 비하여 대체적으로 우수한 성능을 나타내었으며, SF는 흙박이 벽체 재료의 역학적 성능향상에 효과적인 것으로 조사되었다. 특히, SG의 사용은 흙막이 벽체 재료의 장기강도 발현 뿐만 아니라 차수성능 향상에 기여할 것으로 판단된다.

고유동 흙막이 벽체 재료의 역학적 성능 및 내구성에 대한 강섬유 혼입률의 영향 (Effect of Steel Fiber Addition on the Mechanical Properties and Durability of High-Flowable Retaining Wall Material)

  • 김동규;이승태
    • 한국지반환경공학회 논문집
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    • 제24권6호
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    • pp.13-20
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    • 2023
  • 본 연구는 강섬유(SF) 혼입률에 따른 고유동 흙막이 벽체 재료(RWM)의 역학적 성능 및 내구성을 평가하기 위한 것으로써, 흙막이 벽체 재료의 재료분리저항성, 유동성, 연행공기량을 확보하기 위하여 적정량의 고성능감수제(SP), 공기연행제(AEA) 및 증점 안정화제(VMA)를 사용하였다. 흙막이 벽체 재료 경화체의 압축 및 쪼갬 인장강도를 소정의 재령에서 측정하였으며, 흙막이 벽체 재료의 역학적 성능은 표면전기저항성 및 흡수율 실험을 통하여 고찰하였다. 또, 염소이온 침투저항성 및 동결융해 저항성 실험을 통하여 흙막이 벽체 재료의 내구성능을 고찰하였다. 실험결과에 의하면, 강섬유를 적용한 배합이 강섬유 무혼입 배합에 비하여 우수한 성능을 나타내었으며, 2% 적용 배합이 경제성 및 성능 관점에서 상대적으로 효과적인 것으로 관찰되었다. 따라서, 적절한 SF의 적용은 흙막이 벽체 재료의 성능 향상에 기여할 것으로 판단된다.

DETERMINATION OF MOISTURE AND NITROGEN ON UNDRIED FORAGES BY NEAR INFRARED REFLECTANCE SPECTROSCOPY(NIRS)

  • Cozzolino, D.;Labandera, M.;Inia La Estanzuela
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1620-1620
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    • 2001
  • Forages, both grazed and conserved, provide the basis of ruminant production systems throughout the world. More than 90 per cent of the feed energy consumed by herbivorous animals world - wide were provided by forages. With such world - wide dependence on forages, the economic and nutritional necessity of been able to characterize them in a meaningful way is vital. The characterization of forages for productive animals is becoming important for several reasons. Relative to conventional laboratory procedures, Near Infrared Reflectance Spectroscopy (NIRS) offers advantages of simplicity, speed, reduced chemical waste, and more cost-effective prediction of product functionality. NIR spectroscopy represents a radical departure from conventional analytical methods, in that entire sample of forage is characterized in terms of its absorption properties in the near infrared region, rather than separate subsamples being treated with various chemicals to isolate specific components. This forces the analyst to abandon his/her traditional narrow focus on the sample (one analyte at a time) and to take a broader view of the relationship between components within the sample and between the sample and the population from which it comes. forage is usually analysed by NIRS in dry and ground presentation. Initial success of NIRS analysis of coarse forages suggest a need to better understand the potential for analysis of minimally processed samples. Preparation costs and possible compositional alterations could be reduced by samples presented to the instrument in undried and unground conditions. NIRS has gained widespread acceptance for the analysis of forage quality constituents on dry material, however little attention has been given to the use of NIRS for chemical determinations on undried and unground forages. Relatively few works reported the use of NIRS to determine quality parameters on undried materials, most of them on both grass and corn silage. Only two works have been found on the determination of quality parameters on fresh forages. The objectives of this paper were (1) to evaluate the use of NIRS for determination of nitrogen and moisture on undried and unground forage samples and (2) to explore two mathematical treatments and two NIR regions to predict chemical parameters on fresh forage. Four hundred forage samples (n: 400) were analysed in a NIRS 6500 instrument (NIR Systems, PA, USA) in reflectance mode. Two mathematical treatments were applied: 1,4,4,1 and 2,5,5,2. Predictive equations were developed using modified partial least squares (MPLS) with internal cross - validation. Coefficient of determination in calibration (${R^2}_{CAL}$) and standard error in cross-validation (SECV) for moisture were 0.92 (12.4) and 0.92 (12.4) for 1,4,4,1 and 2,5,5,2 respectively, on g $kg^{-1}$ dry weight. For crude protein NIRS calibration statistics yield a (${R^2}_{CAL}$) and (SECV) of 0.85 (19.8) and 0.85 (19.6) for 1,4,4,1 and 2,5,5,2 respectively, on a dry weight. It was concluded that NIRS is a suitable method to predict moisture and nitrogen on fresh forage without samples preparation.

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실리카퓸과 메타카올린을 사용한 다성분계 고강도콘크리트의 특성 (Properties of Ternary or Quaternary High Strength Concrete Using Silica Fume & Meta Kaolin)

  • 박조범;김호수;전준영;김은겸;류득현
    • 콘크리트학회논문집
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    • 제20권3호
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    • pp.307-315
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    • 2008
  • 본 연구에서는 고가의 실리카퓸의 대체 재료로서 메타카올린을 사용할 목적으로 광물질 혼화재와 혼합사용한 고강도콘크리트의 특성을 검토하였다. OPC 100%와 고로슬래그시멘트, 그리고 OPC와 플라이애쉬 20% 사용한 배합을 기준배합으로 하였으며, 각각의 배합에 실리카퓸과 메타카올린을 20% 범위 내에서 혼합하여 대체하였다. 실험 결과, 목표 유동성을 만족한 기준 배합에 대하여 실리카퓸만 대체하였을 경우에는 점성이 저하되었으며, 슬럼프플로우는 감소하였고, 공기량은 증가하였다. 이에 비하여 메타카올린의 사용량이 증가할수록 콘크리트의 점성이 증가되면서 슬럼프 플로우는 증가하였고, 공기량은 감소, 그리고 고성능감수제 사용량도 감소하였다. 경화 콘크리트의 특성은 압축강도와 초음파 속도, 그리고 단위용적질량이 메타카올린 사용량에 따라 증가하였는데, 이러한 원인은 굳지 않은 콘크리트의 공기량에 영향을 받는 것으로 판단되어 고강도콘크리트는 공기량을 조절하는 것이 중요한 항목으로 나타났다. 따라서 고강도콘크리트용 혼화재로서 실리카퓸의 대체 재료로서 메타카올린의 활용이 가능할 것으로 전망되며, 혼합 사용하는 경우에는 유동성과 강도 특성을 고려하여 실리카퓸과 메타카올린은 각각 10% 정도가 적정 사용량인 것으로 판단된다.

동종 아킬레스건을 이용한 관절경적 후방 십자 인대 재건술 (Arthroscopic PCL Reconstruction using fresh-frozen Achilles Allograft)

  • 전철홍;김동철;신호식
    • 대한관절경학회지
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    • 제4권2호
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    • pp.105-110
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    • 2000
  • 목적 : 동종 아킬레스건을 이용하여 후방 십자 인대 재건술을 시행하고 자각증상과 운동능력 회복정도 등 임상적 결과를 분석하여 동종 이식건의 효용성을 살펴보았다. 대상 및 방법 : 동종 아킬레스건을 이용하여 관절경하에 후방 십자 인대 재건술을 시행한 환자 중 1년 이상 추시 가능한 34명 35예를 주관적, 객관적 지표, Telos stress arthrometer와 Modified Feagin Scoring system을 이용하여 분석하였다. 평균 연령은 36.2세($16\~57$세) , 평균 추시 기간은 18 개월($12\~27$개월)이었다. 결과 : 추시 분석 상 Lysholm Knee Scoring System은 술 전 47.5점에서 87.4점, Telos arthrometer를 이용한 후방 스트레스 단순 방사선 사진상 술 전 7.1mm에서 술 후 2.3mm로 회복되었으며, Modified Feagin Scoring system상 양호 이상이 32예$(91.5\%)$ 이었다. 결론 : 동종 아킬레스건을 이용한 후방 십자 인대 재건술은 임상적으로 좋은 결과를 보이고, 충분한 강도와 길이를 제공하여 자가건의 단점을 보완할 수 있어, 자가건의 대치물로써 권장할만한 치료 방법이나 향후 장기적인 추시가 되어져야 할 것이다.

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