• Bulletin of the Korean Chemical Society
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• 제7권4호
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• pp.267-271
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• 1986

The ionomeric blend and the ionic aggregation studies by using a Fourier-transform infrared spectroscopy(FT-IR) are presented. Two ionomers were prepared, one is barium polyacrylate and the other is barium polystyrenesulfonate. The blend of the two ionomers of the barium salts shows intermolecular ionic interaction between the carboxylated ionomer and the sulfonated ionomer. This interaction leads to considerable differences between the spectrum of the blend and the sum of the spectra of the pure ionomers. From our results, it is shown that ionic interactions must play an important role in the compatibility of the two ionomers. In the ionic aggregation study, the bands due to asymmetric stretching mode of carboxylate anion(COO-) in the carboxylated ionomer and the ionomer blend increase in intensity with increasing the divalent barium cations. These results indicate the formation of ion pairs. The doublet due to the asymmetric stretching modes of the carboxylate anion(COO-) is concerned with a sort of local structure found in the ion aggregation. By considering a possible structure for multiplets in the blend, the spectral splitting and the frequency shift are well explained.

• 비파괴검사학회지
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• 제16권1호
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• pp.1-9
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• 1996

본 연구는 원자력발전소 1차측 배관계통의 약 60% 이상을 차지하고 있는 오스테나이트계 스테인레스강 배관 용접부 검사시 낮은 신호 대 잡음비로 결함 발견 및 신호 해석에 있어 많은 문제점을 야기한다. 이러한 문제점을 해결하기 위하여 레이다에서 확립된 신호 처리 기술인 스플릿-스펙트럼 기법을 도입하여 주파수를 다양하게 하고 이 다양한 주파수에 따른 RF신호의 진폭들을 최소화, 극성치 확률 분석 및 최소화-극성치 확률 분석법을 이용하여 개선된 신호 대 잡음비를 얻고자 하였다.

• Computers and Concrete
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• 제8권5호
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• pp.563-581
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• 2011

The signal-based acoustic emission (AE) characterization of concrete fracture process utilizing home-programmed AE monitoring system was performed for three kinds of static loading tests (Cubic-splitting, Direct-shear and Pull-out). Each test was carried out to induce a distinct fracture mode of concrete. Apart from monitoring and recording the corresponding fracture process of concrete, various methods were utilized to distinguish the characteristics of detected AE waveform to interpret the information of fracture behavior of AE sources (i.e. micro-cracks of concrete). Further, more signal-based characters of AE in different stages were analyzed and compared in this study. This research focused on the relationship between AE signal characteristics and fracture processes of concrete. Thereafter, the mode of concrete fracture could be represented in terms of AE signal characteristics. By using cement-based piezoelectric composite sensors, the AE signals could be detected and collected with better sensitivity and minimized waveform distortion, which made the characterization of AE during concrete fracture process feasible. The continuous wavelet analysis technique was employed to analyze the wave-front of AE and figure out the frequency region of the P-wave & S-wave. Defined RA (rising amplitude), AF (average frequency) and P-wave & S-wave importance index were also introduced to study the characters of AE from concrete fracture. It was found that the characters of AE signals detected during monitoring could be used as an indication of the cracking behavior of concrete.

• 정보처리학회논문지C
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• 제9C권3호
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• pp.439-444
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• 2002

본 논문은 무선인터넷서되스의 기반기술인 무선CATV 시스템 방식중에 디지털 MMDS(Multipoint Multichannel Distribution System)의 시스템 파라미터에 따른 링크버짓 분석과 송신 출력과 변조방식에 따른 셀반경을 제시한다. 또한, 본 논문에서는 셀 분할에 따른 C/I와 가입자수를 제시한다. 본 논문에서, 디지털 MMDS의 시스템 파라미터에 따른 링크버짓 분석한 결과를 토대로 0dBW에서 -9dBW가지 송신출력과 QPSK, 16QAM, 그리고 64QAM 변조방식에 따라 구한 결과의 셀 반경은 최대 134km에서 최소 4.3km가지 가능했다 또한, 본 논문에서, 4섹터, 6섹터 그리고 8섹터 셀에서, 편파, 주파수 대역, 주파수 재사용 빈도, C/I에 따라 구한 결과의 가입자수는 최대 5,200DSI(Digital Subcriber Interface)에서 최소 1,300DSI까지 가능했다.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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• pp.65-65
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• 2000

Microwave response of intrinsic Josephson junctions in mesa structure formed on HgI2-intercalated Bi2Sr2CaCu2O8+x single crystals was studied in a wide range of microwave frequency. With irradiation of 73${\sim}$76 GHz microwave, the supercurrent branch becomes resistive above a certain onset microwave power. At low current bias, the current-voltage characteristics show linear behavior, while at high current bias, the resistive branch splits into multiple sub-branches. The voltage spacing between neighboring sub-branches increase with the microwave power and the total number of sub-branches is almost identical to the number of intrinsic Josephson junctions in the mesa. All the experimental results suggest that each sub-branch represents a specific mode of collective motion of Josephson vortices generated by the microwave irradiation. With irradiation of microwave of microwave of frequency lower than 20 GHz, on the other hand, no branch splitting was observed and the current-voltage characteristics exhibited complex behavior at hlgh blas currents. This result can be explained in terms of incoherent motion of Josephson vortices generated by non-uniform microwave irradiation.

• 한국통신학회논문지
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• 제23권4호
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• pp.1072-1086
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• 1998

변환, 분할대역, 그리고 웨이브릿 분해 기법들은 상관성 제거 효과, 에너지 집중 효과, 다중비율/다중해상도 구조, 그리고 주파수 분해 능력 등과 같은 성질들에 의해서 영상 부호화의 강력하고 전형성을 지닌 변환 도구로 널리 활용되고 있다. 특히 변환계수 및 분할대역 계수들이 지니는 주파수 대역별로 변화되는 통계적인 특성과 인간 시각 특성과 주파수 대역간의 관계는 영상부호화에 효율성을 부가할 수 있도록 한다. 따라서 다양하게 변형된 형태로 상기한 기법들을 확장함에 의해서 보다 혁신적인 성능 개선을 시도하는 연구가 매우 널리 진행되고 있다. 그러므로 본 논문에서는 이러한 변환 도구들을 체계적으로 분석하여, 일반화된 관점에서 분석하고자 한다. 구체적으로는 기본이 되는 블록 단위의 직교 변환에서 부터 시작하여, 인접 블록으로 확장되는 겹침 변환, 분할대역 필터군, 웨이브릿 변환을 대상으로 체계화 작업을 진행하였다. 또한 이들 일반화된 변환들을 계층적 블록, 가변크기 블록, 그리고 임의 형태 블록으로 확장하는 기법들에 대한 조사도 진행하였다. 아울러 벡터단위로 변환, 분할대역 분해, 웨이브릿 변환을 확장하는 기법과 선형이지만 시간적으로는 변화하는 주파수 대역별 분해 기법으로의 확장에 대해서도 살펴본다.

• 한국통신학회논문지
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• 제29권4A호
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• pp.378-383
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• 2004

OFDM 기술은 전송 대역을 다수의 협대역으로 분할한 뒤 다수의 부반송파를 이용하여 고속의 데이터를 전송한다. 여기서 부반송파 대역은 협대역으로서 코히런스 대역보다 작아야 한다. 본 논문은 주파수 다이버시티 효과를 증대시켜 성능을 개선시키는 새로운 기술인 반송파 간섭신호를 OFDM 시스템에 적용한 반송파 간섭신호 OFDM을 제안한다. 본 반송파 간섭신호를 적용한 OFDM 시스템의 성능 검증을 위해 다중레벨 변조를 적용하였으며 높은 지연확산을 가지는 페이딩 채널 환경에서 성능을 조사하였다. 본 OFDM 시스템의 성능 조사는 친사용자 환경의 시뮬레이션 플렛포옴인 SPW를 사용하여 구현한 시abf레이터를 이용하였다. 시뮬레이션 결과에서 반송파 간섭신호를 적용한 OFDM 시스템은 주파수 선택적 페이딩 채널에 대해 강한 특성과 개선된 성능을 제공함을 알 수 있었는데 특히 보호구간 800㎱ 에 비해 높은 지연 확산 현상을 나타내는 151㎱ 채널 모델에서 적절한 전송 전력이 제공될 경우 $10^{-3}$ 혹은 더 양호한 비트오율을 얻을 수 있었다.

• 한국자기학회지
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• 제9권1호
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• pp.7-16
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• 1999

본 연구에서는 화학량론적 YIG(yttrium iron garnet : Y3Fe5O12)를 중심으로 하여 조성에 따른 비화학량론적인 YIG(Y3-xFe5+xO12)를 고상반응법으로 제작하고 5.11GHz(G-band)와 23.39 GHz(K-band)의 마이크로파 영역에서 강자성 공명 현상을 이용하여 자기적 특성을 조사하였다. 측정된 분광학적 분리상수 g는 2.02~2.35이다. 포화자화와 유효자화의 값은 x=-0.05의 조성비를 중심으로 이트륨(Y3+)초과와 철(Fe3+)이 초과함에 따라 감소하는 경향을 보였으며, 이와 반대로 선폭( p-p)은 급격히 증가하였다. 자기적 특성의 온도 의존성을 조사하기 위해 K-band에서 80K에서 상온까지 공명흡수선을 측정하여 조성에 따른 M(0), Bloch 상수 B, C 및 스핀파 경도상수 D(약 162~206eV$\AA$2)와 교환상호작용의 평균자승 영역(약 5.84~12.13$\AA$2)의 변화를 조사하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.176-177
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• 2013

Surface plasmon polaritons (SPPs) have attracted the attention of scientists and engineers involved in a wide area of research, microscopy, diagnostics and sensing. SPPs are waves that propagate along the surface of a conductor, usually metals. These are essentially light waves that are trapped on the surface because of their interaction with the free electrons of conductor. In this interaction, the free electrons respond collectively by oscillating in resonance with the light wave. The resonant interaction between the surface charge oscillation and the electromagnetic field of the light constitutes the SPPs and gives rise to its unique properties. In this papers, we studied theoretical and experimental extraordinary transmittance (T) and reflectance (R) of 2 dimensional metal hole array (2D-MHA) on GaAs in consideration of the diffraction orders. The 2d-MHAs was fabricated using ultra-violet photolithography, electron-beam evaporation and standard lift-off process with pitches ranging from 1.8 to $3.2{\mu}m$ and diameter of half of pitch, and was deposited 5-nm thick layer of titanium (Ti) as an adhesion layer and 50-nm thick layer of gold (Au) on the semiinsulating GaAs substrate. We employed both the commercial software (CST Microwave Studio: Computer Simulation Technology GmbH, Darmstadt, Germany) based on a finite integration technique (FIT) and a rigorous coupled wave analysis (RCWA) to calculate transmittance and reflectance. The transmittance was measured at a normal incident, and the reflectance was measured at variable incident angle of range between $30^{\circ}{\sim}80^{\circ}$ with a Nicolet Fourier transmission infrared (FTIR) spectrometer with a KBr beam splitter and a MCT detector. For MHAs of pitch (P), the peaks ${\lambda}$ max in the normal incidence transmittance spectra can be indentified approximately from SP dispersion relation, that is frequency-dependent SP wave vector (ksp). Shown in Fig. 1 is the transmission of P=2.2 um sample at normal incidence. We attribute the observation to be a result of FTIR system may be able to collect the transmitted light with higher diffraction order than 0th order. This is confirmed by calculations: for the MHAs, diffraction efficiency in (0, 0) diffracted orders is lower than in the (${\pm}x$, ${\pm}y$) diffracted orders. To further investigate the result, we calculated the angular dependent transmission of P=2.2 um sample (Fig. 2). The incident angle varies from 30o to 70o with a 10o increment. We also found the splitting character on reflectance measurement. The splitting effect is considered a results of SPPs assisted diffraction process by oblique incidence.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2010년도 춘계학술발표대회
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• pp.3.1-3.1
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• 2010

Water splitting reaction using photocatalysts is of great interest in the utilization of solar energy [1]. In the present work, visible light-responsive $TiO_2$ thin films (Vis-$TiO_2$) were prepared by a radio frequency magnetron sputtering (RF-MS) deposition method and applied for the separate evolution of $H_2$ and $O_2$ from water as well as the photofuel cell. Special attentions will be focused on the effect of HF treatment of Vis-$TiO_2$ thin films on their photocatalytic activities. Vis-$TiO_2$ thin films were prepared by an RF-MS method using a calcined $TiO_2$ plate and Ar as the sputtering gas. The Vis-$TiO_2$ thin films were then deposited on the Ti foil substrate with the substrate temperature at 873 K (Vis-$TiO_2$/Ti). Vis-$TiO_2$/Ti thin films were immersed in a 0.045 vol% HF solution at room temperature. The effect of HF treatments on the activity of Vis-$TiO_2$/Ti thin films for the photocatalytic water splitting reaction have been investigated. Vis-$TiO_2$/Ti thin films treated with HF solution (HF-Vis-$TiO_2$/Ti) exhibited remarkable enhancement in the photocatalytic activity for $H_2$ evolution from a methanol aqueous solution as well as in the photoelectrochemical performance under visible light irradiation as compared with the untreated Vis-$TiO_2$/Ti thin films. Moreover, Pt-loaded HF-Vis-$TiO_2$/Ti thin films act as efficient and stable photocatalysts for the separate evolution of $H_2$ and $O_2$ from water under visible light irradiation in the presence of chemical bias. Thus, HF treatment was found to be an effective way to improve the photocatalytic activity of Vis-$TiO_2$/Ti thin films. Furthermore, unique separate type photofuel cell was fabricated using a Vis-$TiO_2$ thin film as an electrode, which can generate electrical power under solar light irradiation by using various kinds of biomass derivatives as fuel. It was found that the introduction of an iodine ($I^-/{I_3}^-$) redox solution at the cathode side enables the development of a highly efficient photofuel cell which can utilize a cost-efficient carbon electrode as an alternative to the Pt cathode.