• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.48-56
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• 2018

A potassium copper hexacyanoferrate (KCuHCF) embedded magnetic hydrogel bead (HCF-Mbead) was synthesized via a facile double crosslinking methods of $Fe^{3+}$ ionic binding and freeze-thaw for effective $Cs^+$ removal. The HCF-Mbead had a hierarchical porous structure facilitating fast access of $Cs^+$ ions to embedded active sites. The adsorbent showed enhanced $Cs^+$ removal properties in terms of capacity (69.2 mg/g), selectivity ($K_d=4{\times}10^4mL/g$, 1 ppm $Cs^+$ in seawater) and stability (>99.5% removal in pH 3~11) with rapid magnetic separation. This study further opens the possibility to develop an efficient material that links the integration of adsorption and recovery.

• Structural Monitoring and Maintenance
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• 제5권2호
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• pp.313-323
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• 2018

The presence of water inside concrete structures is an essential condition for the deterioration of the structures. The free water in the concrete pores and micro-cracks is the culprit for the durability related problems, such as alkali-aggregate reaction, carbonation, freeze-thaw damage, and corrosion of steel reinforcement. To ensure the integrity and safe operation of the concrete structures, it is very important to monitor water seepage inside the concrete. This paper presents the experimental investigation of water seepage monitoring in a concrete slab using piezoelectric-based smart aggregates. In the experimental setup, an $800mm{\times}800mm{\times}100mm$ concrete slab was fabricated with 15 SAs distributed inside the slab. The water seepage process was monitored through interrogating the SA pairs. In each SA pair, one SA was used as actuator to emit harmonic sine wave, and the other was used as sensor to receive the transmitted stress wave. The amplitudes of the received signals were able to indicate the water seepage process inside the concrete slab.

• 대한원격탐사학회지
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• 제33권1호
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• pp.47-60
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• 2017

The permafrost active layer plays an important role in permafrost dynamics. Ecological patterns, processes, and water and ice contents in the active layer are spatially and temporally complex depending on landscape heterogeneity and local-scale variations in hydrological processes. Although there has been emerging interest in the application of optical remote sensing techniques to permafrost environments, optical sensors are significantly limited in accessing information on near surface geo-cryological conditions. The primary objective of this study was to investigate capability of L-band SAR data for monitoring spatio-temporal variability of permafrost ecosystems and underlying soil conditions. This study exploits information from different polarimetric SAR observables in relation to permafrost environmental conditions. Experimental results show that each polarimetric radar observable conveys different information on permafrost environments. In the case of the dual-pol mode, the radar observables consist of two backscattering powers and one correlation coefficient between polarimetric channels. Among them, the dual-pol scattering powers are highly sensitive to freeze/thaw transition and can discriminate grasslands or ponds in thermokarst area from other permafrost ecosystems. However, it is difficult to identify the ground conditions with dual-pol observables. Additional backscattering powers and correlation coefficients obtained from quad-pol mode help understanding seasonal variations ofradar scattering and assessing geo-cryological information on soil layers. In particular, co-pol coherences atHV-basis and circular-basis were found to be very usefultools for mapping and monitoring near surface soil properties.

• Journal of Nutrition and Health
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• 제19권1호
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• pp.3-15
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• 1986

This study was intended to investigate the rheological properties of the development formula of infant foods and the results are summarized as follow ; 1) Consistency of starch solutions measured by Brabender Anylograph and Brookfield viscometer showed that waxy rice and riece with malt had lower consistency and more rheological stability.The flow type of tested raw materials and formula was found to ？ pseudoplastic, as judged by n-value of 0.332 -0.692, and no yield value. 2) The influenced of temperature on consistency could be accounted for by the equation, In (n) = K(1/T) + const. this relationship indicated that consistency of tested sample increased as temperature decreased. The consistency of waxy rice, rice with malt and formula A were less affected by the temperature change. 3) Infant foods with malt(formula A ) ad with waxy rice maintained better freeze-thaw stability in terms of consistency and starch aggregation indicating that this infant food could be stored for a long term in the freezer section of the home refrigeratory without adverse effect on the product quality. 4) From the above experiments, it would necessarily follow that infant food can be easily made at home the food-stuffs generally available around us, and that the easiest and safest way to store them lies in making them into semisolid state, and in keeping them in frozen state.

• Food Science and Biotechnology
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• 제15권3호
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• pp.453-457
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• 2006

Activity and stability of kiwifruit actinidine was determined in various conditions of pH, salt, and temperature using N-${\alpha}$-CBZ-lysine P-nitrophenyl ester as the substrate. Actinidine activity was low below pH 6, and undetectable below pH 3. The enzyme was stable in a pH range of 6.0-8.5. At $4^{\circ}C$ the enzyme was inactive in the presence of greater than 36% vinegar and in 2 M NaCl. Actinidine at $25^{\circ}C$ was unstable in 24% vinegar but stable in up to 3 M NaCl. With regard to freeze-thaw stability, actinidine retained 85% residual activity after being frozen at $-20^{\circ}C$ for 3 days. Based on Arrenius and Lineweaver-Burk plots, actinidine became unstable at greater than $45^{\circ}C$ with only 30% residual activity remaining after 6 min. The Km, kcat, and kcat/Km values of actinidine were $56\;{\mu}M$, 67/sec, and $1.2\;{\mu}M/sec$, respectively.

• Computers and Concrete
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• 제29권 5호
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• pp.335-346
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• 2022

Geopolymers are an important alternative material supporting recycling, sustainability, and waste management. Durability properties are among the most critical parameters to be investigated; in this study, the durability of manufactured geopolymer samples under the attack of 10% magnesium sulfate and 10% sodium sulfate solution was investigated. 180 cycles of freezing and thawing were also tested. The experimentally obtained results investigate the durability of geopolymer mortar prepared with fly ash (class F) and alkali activator. Three different quarry dust wastes replaced the river sand aggregate: limestone, marble, and basalt powder as fine filler aggregate in three different replacement ratios of 25%, 50%, and 75% to produce ten series of geopolymer composites. The geopolymer samples' visual appearance, weight changes, UPV, and strength properties were studied for up to 12 months at different time intervals of exposure to sulfate solutions to investigate sulfate resistance. In addition, Scanning Electron Microscopy (SEM), EDS, and XRD were used to study the microstructure of the samples. It was beneficial to include quarry waste as a filler aggregate in durability and mechanical properties. The compact matrix was demonstrated by microstructural analysis of the manufactured specimens. The geopolymer mortars immersed in sodium sulfate showed less strength reduction and deterioration than magnesium sulfate, indicating that magnesium sulfate is more aggressive than sodium sulfate. Therefore, it is concluded that using waste dust interrogation with partial replacement of river sand with fly ash-based geopolymers has satisfactory results in terms of durability properties of freeze-thaw and sulfate resistance.

• Geomechanics and Engineering
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• 제38권6호
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• pp.541-551
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• 2024

Bottom ash classifies as a hazardous industrial-waste material that adversely affects human health. This study proposes its mixing with controlled low strength materials (CLSM) as a probable recycling approach. To this end, experiments have been performed to investigate the applicability of bottom-ash-based CLSM that comprises eco-friendly soil binders, water, fly ash, and a combination of bottom ash and weathered granite soil. The physical and chemical properties of the weathered granite soil, bottom ash, fly ash, and soil binders are analyzed via laboratory tests, including X-ray diffraction and scanning electron microscopy. To determine an appropriate CLSM mixing proportion, the flowability test is first performed on three mixture types having three replacement ratios of fly ash each. Subsequently, compressive-strength tests are performed. Based on the results of these tests, four mixtures are selected for the freeze-and-thaw test to determine the appropriate mixing proportion. Finally, the ground model and soil-contamination tests are performed to examine the field applicability of the mixture. This study confirms that bottom-ash-based CLSM causes negligible soil contamination, and it satisfies the prescribed performance requirements and contamination standards in Korea.

• 산업기술연구
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• 제25권A호
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• pp.49-56
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• 2005

Recently, very-early strength latex-modified concrete(below ; VES-LMC) has been developed for repairing and overlaying the old concrete bridge deck. VES-LMC provides the advantage of very-early-strength, as well as high flexural strength, bond strength, durability, resistance to corrosion, reduced water permeability and resistance to damage from freeze-thaw cycles. The compressive and flexural strength of VES-LMC are 21 MPa and 4.5 MPa at 3 hours after concrete placing, respectively. However, VES-LMC would have a relatively large shrinkage at early-age because of reduced water-cement ratio, big water self-dissipation, and rapid hydration reaction. Therefore, the purpose of this study was to evaluate the early-age and restrained shrinkage of VES-LMC, having an experimental variables such as latex contents and cement types. The latex contents included 0%, 5%, 10%, 15% and 20%, and the cement types included ordinary portland cement and very-early strength cement.

• 한국수소및신에너지학회논문집
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• 제13권4호
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• pp.321-329
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• 2002

Clostridium butyricum, Lactobacillus amylophillus, Lactobacillus amylovorus, Lactobacillus acidophillus, AI-9 produced hydrogen and /or organic acids using glucose, lactose and starch at the anaerobic culture conditions. Cl. butyricum NCIB 9576 evolved 1,700 ml H2/L-culture broth and accumulated butyric acid, acetic acid, propionic acid and ethanol in its culture broth when lactose was used as a carbon source during 24 hrs of fermentation. L. amylovorus ATCC 33620 accumulated lactic and acetic acids and some reducing sugars when starch was used as a carbon source without hydrogen production. Instead of starch as a carbon source, L. amylovorus ATCC 33620 produced lactic acid from algal biomass during fermentation and the acid-heat or freeze-thaw pretreatment of algal biomass accelerate the lactic acid fermentation.

• Journal of Microbiology and Biotechnology
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• 제18권5호
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• pp.946-951
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• 2008

The opd gene, encoding organophosphorus hydrolase (OPH) from Flavobacterium sp. capable of degrading a wide range of organophosphate pesticides, was surface- and intracellular-expressed in Synechococcus PCC7942, a prime example of photoautotrophic cyanobacteria. OPH was displayed on the cyanobacterial cell surface using the truncated ice nucleation protein as an anchoring motif. A minor fraction of OPH was displayed onto the outermost surface of cyanobacterial cells, as verified by immunostaining visualized under confocal laser scanning microscopy and OPH activity analysis; however, a substantial fraction of OPH was buried in the cell wall, as demonstrated by proteinase K and lysozyme treatments. The cyanobacterial outer membrane acts as a substrate (paraoxon) diffusion barrier affecting whole-cell biodegradation efficiency. After freeze-thaw treatment, permeabilized whole cells with intracellular-expressed OPH exhibited 14-fold higher bioconversion efficiency ($V_{max}/K_m$) than that of cells with surface-expressed OPH. As cyanobacteria have simple growth requirements and are inexpensive to maintain, expression of OPH in cyanobacteria may lead to the development of a low-cost and low-maintenance biocatalyst that is useful for detoxification of organophosphate pesticides.