• Title/Summary/Keyword: Free carbon

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Highly sensitive and selective enzymatic detection for hydrogen peroxide using a non-destructively assembled single-walled carbon nanotube film (탄소나노튜브 대면적 어셈블리를 통한 고감도-고선택성 과산화수소 센서 개발)

  • Lee, Dongwook;Ahn, Heeho;Seo, Byeong-Gwuan;Lee, Seung-Woo
    • Journal of Sensor Science and Technology
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    • v.30 no.4
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    • pp.229-235
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    • 2021
  • This study presents a simple approach for the assembly of a free-standing conductive electronic nanofilm of single-walled carbon nanotubes (SWNTs) suitable for enzymatic electrochemical biosensors. A large-scale SWNT electronic film was successfully produced by the dialysis of p-Terphenyl-4,4''-dithiol (TPDT)-treated SWNTs. Furthermore, Horseradish peroxidase (HRP) was immobilized on the TPDT-SWNT electronic film, and the enzymatic detection of hydrogen peroxide (H2O2) was demonstrated without mediators. The detection of H2O2 in the negative potential range (-0.4 V vs. Ag/AgCl) was achieved by direct electron transfer of heme-based enzymes that were immobilized on the TPDT-SWNT electronic film. The SWNT-based biosensor exhibited a wide detection range of H2O2 from 10 µM to 10 mM. The HRP-doped SWNT electronic film achieved a high sensitivity of 342 ㎛A/mM·cm2 and excellent selectivity against a variety of redox-active interfering substances, such as ascorbic acid, uric acid, and acetaminophen.

Impact of Transportation on Air Quality and Carbon Emissions in Developing Countries: A Case of Myanmar (개발도상국의 교통수단이 대기 질 및 탄소배출에 미치는 영향: 미얀마를 중심으로)

  • Wut Yee Lwin;Byoung-Jo Yoon
    • Journal of the Society of Disaster Information
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    • v.19 no.1
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    • pp.231-240
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    • 2023
  • Purpose: The purpose of this study is to analyze air quality and carbon emissions in developing countries, particularly Myanmar, and explore the impact of transportation on CO2 emissions during peak hours relative to free-flow conditions. Method: This study conducted a traffic survey in two major cities in Myanmar to quantify carbon dioxide emissions from the transportation sector, using IPCC's tier 1 and tier 2 approaches, with statistical analysis performed using Python 3 and Microsoft Excel for comparative analysis of critical factors in CO2 emissions. Result: The result of this study is an estimate of the vehicle kilometers traveled (VKT) and fuel consumption in Yangon city for the year 2019, based on data from various sources including the Myanmar Statistical data base, YUTRA project survey, and Ministry of Electric and Energy. The study also analyzes the average travel time index (TTI) for the four roads in Yangon, which indicates the impact of congestion on vehicle travel time and CO2 emissions. Overall, the study provides important insights into the transport sector in Yangon city and can be used to inform policies aimed at reducing greenhouse gas emissions and improving traffic conditions. Conclusion: The study concludes that congestion plays a significant role in increasing fuel use and emission levels in the road transport sector in Myanmar. The analysis provides valuable insights into the impact of the sector on the environment and emphasizes the importance of addressing congestion to reduce fuel use and emissions. However, the study's scope is limited to Yangon city and Mandalay city, and some mean values may not accurately represent the entire country and other developing countries.

Porosity-dependent vibration investigation of functionally graded carbon nanotube-reinforced composite beam

  • Abdulmajeed M. Alsubaie;Ibrahim Alfaqih;Mohammed A. Al-Osta;Abdelouahed Tounsi;Abdelbaki Chikh;Ismail M. Mudhaffar;Saeed Tahir
    • Computers and Concrete
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    • v.32 no.1
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    • pp.75-85
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    • 2023
  • This work utilizes simplified higher-order shear deformation beam theory (HSDBT) to investigate the vibration response for functionally graded carbon nanotube-reinforced composite (CNTRC) beam. Novel to this work, single-walled carbon nanotubes (SWCNTs) are distributed and aligned in a matrix of polymer throughout the beam, resting on a viscoelastic foundation. Four un-similar patterns of reinforcement distribution functions are investigated for the CNTRC beam. Porosity is another consideration taken into account due to its significant effect on functionally graded materials (FGMs) properties. Three types of uneven porosity distributions are studied in this study. The damping coefficient and Winkler's and Pasternak's parameters are considered in investigating the viscosity effect on the foundation. Moreover, the impact of different parameters on the vibration of the CNTRC beam supported by a viscoelastic foundation is discussed. A comparison to other works is made to validate numerical results in addition to analytical discussions. The findings indicate that incorporating a damping coefficient can improve the vibration performance, especially when the spring constant factors are raised. Additionally, it has been noted that the fundamental frequency of a beam increases as the porosity coefficient increases, indicating that porosity may have a significant impact on the vibrational characteristics of beams.

Finite element bending and buckling analysis of functionally graded carbon nanotubes-reinforced composite beam under arbitrary boundary conditions

  • Belarbi, Mohamed-Ouejdi;Salami, Sattar Jedari;Garg, Aman;Hirane, Hicham;Amine, Daikh Ahmed;Houari, Mohammed Sid Ahmed
    • Steel and Composite Structures
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    • v.44 no.4
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    • pp.451-471
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    • 2022
  • In the present paper, the static bending and buckling responses of functionally graded carbon nanotubes-reinforced composite (FG-CNTRC) beam under various boundary conditions are investigated within the framework of higher shear deformation theory. The significant feature of the proposed theory is that it provides an accurate parabolic distribution of transverse shear stress through the thickness satisfying the traction-free boundary conditions needless of any shear correction factor. Uniform (UD) and four graded distributions of CNTs which are FG-O, FG-X, FG- and FG-V are selected here for the analysis. The effective material properties of FG-CNTRC beams are estimated according to the rule of mixture. To model the FG-CNTRC beam realistically, an efficient Hermite-Lagrangian finite element formulation is successfully developed. The accuracy and efficiency of the present model are demonstrated by comparison with published benchmark results. Moreover, comprehensive numerical results are presented and discussed in detail to investigate the effects of CNTs volume fraction, distribution patterns of CNTs, boundary conditions, and length-to-thickness ratio on the bending and buckling responses of FG-CNTRC beam. Several new referential results are also reported for the first time which will serve as a benchmark for future studies in a similar direction. It is concluded that the FG-X-CNTRC beam is the strongest beam that carries the lowest central deflection and is followed by the UD, V, Λ, and FG-O-CNTRC beam. Besides, the critical buckling load belonging to the FG-X-CNTRC beam is the highest, followed by UD and FG-O.

Effects of Nitrogen Sources on PRE-point and Free amino acids in Soybean Leaves different In Phosphorus Sensitivity (인산감수성(燐酸感受性)이 다른 대두엽(大豆葉)의 광합성(光合成) 호흡(呼吸) 평형(平衡)과 유리(遊離) 아미노산에 대(對)한 질소원(窒素源)의 영향(影響))

  • Stutte, Charls A.;Park, Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.4
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    • pp.239-244
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    • 1973
  • Effects of nitrogen sources on free amino acids, and on photosynthsis-respiration equilibrium point of various positional leaf in soybean were investigated in relation to phosphorus sensitivity. The content of free amino acids was highest in ammonium and lowest in urea treated leaves. Glycine, serine, alanine and especially histidine were high in the ammonium treated leaves. Aspartic acid was high in the nitrate treated leaves. Photosynthesis respiration equilibrium point was higher in the sensitive cultivars, and higher with ammonium than with nitrate. The excess ammonium in plant appears to draw out an intermediate metabolite from carbon fixation pathway resulting in photosynthetic inhibition and activate pentoses phosphate pathway and photorespiration. Such phenomena were likely accentuated in phosphorus sensitive variety.

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Evaluation of Cigarette Quality by Measurement of Oxygen Free Radicals in Smoke (담배 연기 중 산소 자유 라디칼 측정에 의한 품질 평가)

  • Ji-Chang Park;Kyung-Ran Yoon;Young-Ha Rhee;Cheong Ho Lee
    • Journal of the Korean Society of Tobacco Science
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    • v.12 no.1
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    • pp.19-27
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    • 1990
  • To evaluate tobacco quality, several mathods including sensory test, or measurement of some toxic compounds such as tar, nicotine and carbon monoxide in cigarette smoke have been used. However, many detrimental effects of smoking on the physiological functions including respiratory system reported were turned out to be the action of reactive oxygen species. Therefore, the amounts of oxygen free radicals such as superoxide, hydroxyl radical, even hydrogen peroxide in the cigarette smoke are thought the very important factors. In the present study, we have determined the generation of superoxide and the content of hydrogen peroxide using superoxide dismutase and catalase in the gas and particulate phases obtained from cigarette smoke, respectively. In the aqueous extracts of total particulate materials, suproxide and hydrogen peroxide were detected, and there was an excellent correlation between oxygen tint of oxygen free radicals in cigarette smoke may be a useful index for evaluation of cigarette quality in the aspect of smoking and health.

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Buckling and free vibration analysis of tapered FG- CNTRC micro Reddy beam under longitudinal magnetic field using FEM

  • Mohammadimehr, M.;Alimirzaei, S.
    • Smart Structures and Systems
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    • v.19 no.3
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    • pp.309-322
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    • 2017
  • In this paper, the buckling, and free vibration analysis of tapered functionally graded carbon nanotube reinforced composite (FG-CNTRC) micro Reddy beam under longitudinal magnetic field using finite element method (FEM) is investigated. It is noted that the material properties of matrix is considered as Poly methyl methacrylate (PMMA). Using Hamilton's principle, the governing equations of motion are derived by applying a modified strain gradient theory and the rule of mixture approach for micro-composite beam. Micro-composite beam are subjected to longitudinal magnetic field. Then, using the FEM, the critical buckling load, and natural frequency of micro-composite Reddy beam is solved. Also, the influences of various parameters including ${\alpha}$ and ${\beta}$ (the constant coefficients to control the thickness), three material length scale parameters, aspect ratio, different boundary conditions, and various distributions of CNT such as uniform distribution (UD), unsymmetrical functionally graded distribution of CNT (USFG) and symmetrically linear distribution of CNT (SFG) on the critical buckling load and non-dimensional natural frequency are obtained. It can be seen that the non-dimensional natural frequency and critical buckling load decreases with increasing of ${\beta}$ for UD, USFG and SFG micro-composite beam and vice versa for ${\alpha}$. Also, it is shown that at the specified value of ${\alpha}$ and ${\beta}$, the dimensionless natural frequency and critical buckling load for SGT beam is more than for the other state. Moreover, it can be observed from the results that employing magnetic field in longitudinal direction of the micro-composite beam increases the natural frequency and critical buckling load. On the other hands, by increasing the imposed magnetic field significantly increases the stability of the system that can behave as an actuator.

Study on the characteristic of liner and cover material by accelerating agent type (급결제 종류에 따른 광산 차수재의 특성 연구)

  • Cho, Yong-Kwang;Nam, Seong-Young;Lee, Yong-Mu;Kim, Chun-Sik;Seo, Shin-Seok;Jo, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.75-81
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    • 2018
  • At present research on mining backfill materials is being carried out to prevent ground subsidence and breaking by underground cavern of exhausted mines. However, backfill materials can cause secondary environmental issues such as ground pollution. To solve these issues, liner and cover materials are constructed before backfill materials constructed, to inhibit toxic substances form moving to the surroundings. Liner and cover materials, however, should have an accelerating performance after construction and when the accelerating performance is degraded, the work efficiency can be lowered, and the construction cost can be increased, by many rebound content. Therefore, this study develops mining liner and cover materials, and evaluates their accelerating performance and physical properties of liner and cover materials by types and content of accelerating agent. In case of aluminate accelerating agent, it is mixed with more than 5% of liner and cover materials(binder/ratio); thus an accelerating performance satisfying Korean Industrial Standards(KS) occurs, and in case of alkali-free accelerating agent, when it is mixed with more than 7%(binder/ratio), accelerating performance satisfying KS occurs. The more the accelerating agent capacity increases, the more compressive strength decreases. In addition, it is confirmed that compressive strength of aluminate accelerating agent is more degraded than compressive strength of the alkali-free accelerating agent. It is also confirmed that drying shrinkage stability of the alkali-free accelerating agent is better than the drying shrinkage stability of the aluminate accelerating agent.

Analyzing Thinning Effects on Growth and Carbon Absorption for Cryptomeria japonica Stands Using Distance-Independent Growth Simulations (거리독립 생장예측 시뮬레이션기법 적용에 의한 삼나무임분의 임분생장 및 탄소고정에 미치는 간벌시업 효과 분석)

  • Kwon, Kibeom;Han, Hee;Seol, Ara;Chung, Hyejean;Chung, Joosang
    • Journal of Korean Society of Forest Science
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    • v.105 no.1
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    • pp.132-138
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    • 2016
  • The objectives of this study were to infer the parameters of forest stand growth functions of STEMS for Cryptomeria japonica stands of Jeju Hannam Experimental Forest, Korea Forest Research Institute, and to investigate the effects of thinning regimes on the patterns of stand growth and carbon absorption. The forest stand growth functions for the potential diameter growth, modifier, crown ratio and mortality are the major ones composing the independent-tree/distance-free forest stand growth simulator, STEMS. The parameters were inferred using the sets of growth data obtained from stem analyses of 39 trees, chosen from 13 sample plots of the forest stands. The effects of thinning regimes on the patterns of stand growth and carbon absorption were investigated by simulating the stand growth patterns of the case study stand with 3 different thinning regimes: no-thinning, early thinning with low intensity and late thinning with high intensity using the simulator. According to the results of the analyses, the different thinning regimes cause significant effects on the growth patterns of average DBH, average height, diameter distribution and stand volume as well as the amount of carbon absorptions.

Effects of La Addition and Preparation Methods on Catalytic Activities for Methane Partial Oxidation Catalysts (메탄 부분산화반응 촉매에 La 첨가 및 제조방법에 따른 촉매활성에 미치는 영향)

  • Cheon, Han-Jin;Shin, Ki-Seok;Ahn, Sung-Hwan;Yoon, Cheol-Hun;Hahm, Hyun-Sik
    • Journal of the Korean Institute of Gas
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    • v.14 no.2
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    • pp.7-14
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    • 2010
  • Synthesis gas was produced by the partial oxidation of methane. For the preparation of catalysts, Ni, known to be active in this reaction and cheap, was used as the active component and $CeO_2$, having high oxygen storage capability and high redox ability, was used as the support. The catalysts were prepared by the impregnation and urea methods. The catalyst prepared by the urea method showed about 11 times higher surface area and finer particle size than that prepared by the impregnation method. The catalysts prepared by the urea method showed higher methane conversion and synthesis gas selectivity than that prepared by the impregnation method. In this reaction, carbon deposition is a problem to be solved, so La was added to the catalyst system to reduce the carbon deposition. TGA analysis results showed that there was 2% carbon deposition with La-added catalysts and 16% with La-free catalysts. It was found that the addition of La decreases the amount of carbon deposition and prevents catalyst deactivation.