• Title/Summary/Keyword: Free carbon

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Effect of Laser Heat-treatment on WC-CoFe Coated Surface by HVOF (초고속화염용사 WC-CoFe 코팅층의 레이저 표면 열처리 효과)

  • Joo, Yunkon;Yoon, Jaehong;Lee, Jehyun
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.52-58
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    • 2019
  • The microstructure, hardness, and wear behaviors of a High Velocity Oxygen Fuel(HVOF) sprayed WC-CoFe coating are comparatively investigated before and after laser heat treatments of the coating surface. During the spraying, the binder metal is melted and a small portion of WC is decomposed to $W_2C$. A porous coating is formed by evolution of carbon oxide gases formed by the reaction of the free carbon and the sprayed oxygen gas. The laser heat treatment eliminates the porosity and provides a more densified microstructure. After laser heat treatment, the porosity in the coating layer decreases from 1.7 % to 1.2 and the coating thickness decreases from $150{\mu}m$ to $100{\mu}m$. The surface hardness increases from 1440 Hv to 1117 Hv. In the wear test, the friction coefficient of coating decreases from 0.45 to 0.32 and the wear resistance is improved by the laser heat treatment. The improvement is likely due to the formation of oxide tribofilms.

Free vibration analysis of thick cylindrical MEE composite shells reinforced CNTs with temperature-dependent properties resting on viscoelastic foundation

  • Mohammadimehr, Mehdi;Arshid, Ehsan;Alhosseini, Seyed Mohammad Amin Rasti;Amir, Saeed;Arani, Mohammad Reza Ghorbanpour
    • Structural Engineering and Mechanics
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    • v.70 no.6
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    • pp.683-702
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    • 2019
  • The present study aims to analyze the magneto-electro-elastic (MEE) vibration of a functionally graded carbon nanotubes reinforced composites (FG-CNTRC) cylindrical shell. Electro-magnetic loads are applied to the structure and it is located on an elastic foundation which is simulated by visco-Pasternak type. The properties of the nano-composite shell are assumed to be varied by temperature changes. The third-order shear deformation shells theory is used to describe the displacement components and Hamilton's principle is employed to derive the motion differential equations. To obtain the results, Navier's method is used as an analytical solution for simply supported boundary condition and the effect of different parameters such as temperature variations, orientation angle, volume fraction of CNTs, different types of elastic foundation and other prominent parameters on the natural frequencies of the structure are considered and discussed in details. Design more functional structures subjected to multi-physical fields is of applications of this study results.

Fatigue evaluation and CFRP strengthening of diaphragm cutouts in orthotropic steel decks

  • Ke, Lu;Li, Chuanxi;He, Jun;Lu, Yongjun;Jiao, Yang;Liu, Yongming
    • Steel and Composite Structures
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    • v.39 no.4
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    • pp.453-469
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    • 2021
  • The cracking at the transverse diaphragm cutout is one of the most severe fatigue failures threatening orthotropic steel decks (OSDs), whose mechanisms and crack treatment techniques have not been fully studied. In this paper, full-scale experiments were first performed to investigate the fatigue performance of polished cutouts involving the effect of an artificial geometrical defect. Following this, comparative experimental testing for defective cutouts strengthened with carbon fiber-reinforced polymer (CFRP) was carried out. Numerical finite element analysis was also performed to verify and explain the experimental observations. Results show that the combinative effect of the wheel load and thermal residual stress constitutes the external driving force for the fatigue cracking of the cutout. Initial geometrical defects are confirmed as a critical factor affecting the fatigue cracking. The principal stress 6 mm away from the free edge of the cutout can be adopted as the nominal stress of the cutout during fatigue evaluation, and the fatigue resistance of polished cutouts is higher than Grade A in AASHTO specification. The bonded CFRP system is highly effective in extending the fatigue life of the defective cutouts. The present study provides some new insights into the fatigue evaluation and repair of OSDs.

A Study on the Adsorption Kinetics of 133Cs by Different Impregnations of Prussian Blue (프러시안 블루 고정화에 따른 133Cs의 흡착거동 모델링)

  • Choi, S.S.;Lee, Y.J.;Yun, K.J.;Cho, Y.J.;Lee, J.H.;Lee, S.H.
    • Journal of the Korean Society of Safety
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    • v.36 no.1
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    • pp.80-85
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    • 2021
  • Radionuclides, particularly radioactive cesium (Cs), are a concern of human health in some nuclear power accidents. It could lead to a high level of intracellular accumulation due to its high radioactivity and long half-life. Therefore, it is imperative to develop a method to remove Cs from wastewater. Herein, we synthesized activated carbon fibers (ACFs) doped with Prussian blue (PB) via in situ methods. We classified samples by their preparation method as either physical (PB-ACF-A) or physicochemical (PB-ACF-B) syntheses for comparison. The PB-ACF-B sample showed a significant surface loss compared to PB-ACF-A but a better 133Cs adsorption capacity. All samples fit well to Langmuir isotherms and the values of qmax were directly correlated to the amount of PB on the surface of the ACFs. Adsorption characteristics were further confirmed by the calculated free energy, enthalpy, and entropy.

Noncontact strain sensing in cement-based material using laser-induced fluorescence from nanotube-based skin

  • Meng, Wei;Bachilo, Sergei M.;Parol, Jafarali;Weisman, R. Bruce;Nagarajaiah, Satish
    • Structural Monitoring and Maintenance
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    • v.9 no.3
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    • pp.259-270
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    • 2022
  • This study explores the use of the recently developed "strain-sensing smart skin" (S4) method for noncontact strain measurements on cement-based samples. S4 sensors are single-wall carbon nanotubes dilutely embedded in thin polymer films. Strains transmitted to the nanotubes cause systematic shifts in their near-infrared fluorescence spectra, which are analyzed to deduce local strain values. It is found that with cement-based materials, this method is hampered by spectral interference from structured near-infrared cement luminescence. However, application of an opaque blocking layer between the specimen surface and the nanotube sensing film enables interference-free strain measurements. Tests were performed on cement, mortar, and concrete specimens with such modified S4 coatings. When specimens were subjected to uniaxial compressive stress, the spectral peak separations varied linearly and predictably with induced strain. These results demonstrate that S4 is a promising emerging technology for measuring strains down to ca. 30 𝜇𝜀 in concrete structures.

Service ability design of vibrating chiral SWCNTs: Validation and parametric study

  • Muzamal Hussain;Mohamed R. Ali;Abdelhakim Benslimane;Humaira Sharif;Mohamed A. Khadimallah;Muhammad Nawaz Naeem;Imene Harbaoui;Sofiene Helaili;Aqib Majeed;Abdelouahed Tounsi
    • Computers and Concrete
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    • v.32 no.4
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    • pp.393-398
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    • 2023
  • This paper provides the free vibrations of chiral carbon nanotubes. The governing equations of Flügge theory is considered for vibration frequencies of chiral single walled carbon nanotubes. The solution of frequency equation is obtained from a novel model for better representation of stubby and short vibration characteristics of chiral tubes with clamped-clamped and clamped-simply supported end conditions. For the harmonic response of this tube, the model displacement function is adopted. The variational approach Rayleigh-Ritz method with kinetic and strain energies are used. The Lagragian function is differentiated with respect to unknown functions. The frequency equation is written in compact form to solve with MATLAB software. The frequencies of chiral SWCNTs for first ten aspect ratios as small level are investigated. The results shown as for decreasing the aspect rations, the frequencies are increases. The presented results of this model are verified with experimental and numerical results, which found as an excellent agreement.

On the snap-buckling phenomenon in nanocomposite curved tubes

  • Dan Chen;Jun Shao;Zhengrong Xu;Hadi Babaei
    • Structural Engineering and Mechanics
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    • v.89 no.1
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    • pp.13-22
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    • 2024
  • The nonlinear snap-through buckling of functionally graded (FG) carbon nanotube reinforced composite (CNTRC) curved tubes is analytically investigated in this research. It is assumed that the FG-CNTRC curved tube is supported on a three-parameter nonlinear elastic foundation and is subjected to the uniformly distributed pressure and thermal loads. Properties of the curved nanocomposite tube are distributed across the radius of the pipe and are given by means of a refined rule of mixtures approach. It is also assumed that all thermomechanical properties of the nanocomposite tube are temperature-dependent. The governing equations of the curved tube are obtained using a higher-order shear deformation theory, where the traction free boundary conditions are satisfied on the top and bottom surfaces of the tube. The von Kármán type of geometrical non-linearity is included into the formulation to consider the large deflection in the curved tube. Equations of motion are solved using the two-step perturbation technique for nanocomposite curved tubes which are simply-supported and clamped. Closed-form expressions are provided to estimate the snap-buckling resistance of FG-CNTRC curved pipes rested on nonlinear elastic foundation in thermal environment. Numerical results are given to explore the effects of the distribution pattern and volume fraction of CNTs, thermal field, foundation stiffnesses, and geometrical parameters on the instability of the curved nanocomposite tube.

Sports balls made of nanocomposite: investigating how soccer balls motion and impact

  • Ling Yang;Zhen Bai
    • Advances in nano research
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    • v.16 no.4
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    • pp.353-363
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    • 2024
  • The incorporation of nanoplatelets in composite and polymeric materials represents a recent and innovative approach, holding substantial promise for diverse property enhancements. This study focuses on the application of nanocomposites in the production of sports equipment, particularly soccer balls, aiming to bridge the gap between theoretical advancements and practical implications. Addressing the longstanding challenge of suboptimal interaction between carbon nanofillers and epoxy resin in epoxy composites, this research pioneers inventive solutions. Furthermore, the investigation extends into unexplored territory, examining the integration of glass fiber/epoxy composites with nanoparticles. The incorporation of nanomaterials, specifically expanded graphite and graphene, at a concentration of 25.0% by weight in both the epoxy structure and the composite with glass fibers demonstrates a marked increase in impact resistance compared to their nanomaterial-free counterparts. The research transcends laboratory experiments to explore the practical applications of nanocomposites in the design and production of sports equipment, with a particular emphasis on soccer balls. Analytical techniques such as infrared spectroscopy and scanning electron microscopy are employed to scrutinize the surface chemical structure and morphology of the epoxy nanocomposites. Additionally, an in-depth examination of the thermal, mechanical, viscoelastic, and conductive properties of these materials is conducted. Noteworthy findings include the efficacy of surface modification of carbon nanotubes in preventing accumulation and enhancing their distribution within the epoxy matrix. This optimization results in improved interfacial interactions, heightened thermal stability, superior mechanical properties, and enhanced electrical conductivity in the nanocomposite.

Axially-compressed behavior of CFRP strengthening steel short columns having defects

  • Omid Yousefi;Amin Shabani Ammari
    • Structural Engineering and Mechanics
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    • v.91 no.1
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    • pp.49-61
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    • 2024
  • In recent decades, the majority of studies have concentrated on the utilization of Steel Square Hollow Section (SHS) columns, with minimal attention given to reinforcing columns exhibiting inherent defects. This study addresses this gap by introducing initial vertical and horizontal defects at three distinct locations (top, middle, and bottom) and employing Carbon-FRP for reinforcement. The research investigates the dimensional and positional impacts of these defects on the axial behavior of SHS columns. A total of 29 samples, comprising 17 with defects, 11 strengthened, and 1 defect-free control, underwent examination. The study employed ABAQUS modeling and conducted experimental testing. Results revealed that defects located at different positions significantly diminished the load-bearing capacity and initial performance of the steel columns. Axial loading induced local buckling and lateral rupture, particularly at the defect side, in short columns. Notably, horizontal (across the column's width) and vertical (along the column's height) defects in the middle led to the most substantial reduction in strength and load-bearing capacity. The axial compressive failure increased with the length-to-width ratio of the defect. Moreover, the application of four carbon fiber layers to strengthen the steel columns resulted in increased Energy Dissipation and a delayed onset of local buckling in the face of axial ruptures.

Mechanism and Effect of Corydalis ternata on the $CCl_4$-Induced$ Hepatotoxicity (사염화탄소에 의한 간손상에 미치는 현호색의 효과 및 그 기전)

  • 서인옥;정춘식;정기화
    • Journal of Food Hygiene and Safety
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    • v.15 no.3
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    • pp.226-234
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    • 2000
  • Protective effect of Corydalis ternata against the carbon tetrachloride-induced toxicity was investigated. Carbon tetrachloride($CCl_4$) induces hepatotoxicity due to the reactive free radical(CCl$_3$ . ) generated by cytochrome P-450 enzyme. We examined effects of hexane, chloroform, butanol and water fractions prepared from the Corydalis ternata methanol extract. Rats were treated with those for 3 days, and liver microsomes and cytosols were prepared at 24 hour after last treatment. Hepatoprotective activity of the water fraction was higher than that of other fractions. To examine mechanism of the hepatoprotective effect of Corydalis ternuta, we measured contents of malondialdehyde(MDA), cytochrome P46O(CYP), glutathione, calcium as well as the activities of NADPH-CYP reductase, glutathione S-transferase(GST), superoxide dismutase(SOD), glutathione peroxidase(GPX) and catalase. The fraction inhibited production of MDA, content of CYP and calcium in liver of water fractions - treated rats as compared with those of CCl4-treated rats. The GST activity was increased. We speculate that the O2 radical scavenging activities of the water fraction might play a key role in the mechanism opposing the progression of $CCl_4$-induced hepatotoxicity, but the activities of SOD, GPX, CAT were decreased. These results suggest that the mechanism might be mainly due to the decrease of CYP contents, act as calcium channel blocker and increase of GST activity rather than $O_2$ radical scavenging activities.

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