• Title/Summary/Keyword: Free carbon

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Vibration analysis of carbon nanotubes with multiple cracks in thermal environment

  • Ebrahimi, Farzad;Mahmoodi, Fatemeh
    • Advances in nano research
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    • v.6 no.1
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    • pp.57-80
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    • 2018
  • In this study, the thermal loading effect on free vibration characteristics of carbon nanotubes (CNTs) with multiple cracks is studied. Various boundary conditions for nanotube are taken in to account. In order to take the small scale effect, the nonlocal elasticity of Eringen is employed in the framework of Euler-Bernoulli beam theory. This theory states that the stress at a reference point is a function of strains at all points in the continuum. A cracked nanotube is assumed to be consisted of two segments that are connected by a rotational spring which is located in the position of the cracked section. Hamilton's principle is used to achieve the governing equations. Influences of the nonlocal parameter, crack severity, temperature change and the number of cracks on the system frequencies are investigated. Also, it is found that at room or lower temperature the natural frequency for CNT decreases as the value of temperature change increases, while at temperature higher than room temperature the natural frequency of CNT increases as the value of temperature change increases. Various boundary conditions have been applied to the nanotube.

Nonlinear vibration analysis of an embedded multi-walled carbon nanotube

  • Wu, Chih-Ping;Chen, Yan-Hong;Hong, Zong-Li;Lin, Chia-Hao
    • Advances in nano research
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    • v.6 no.2
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    • pp.163-182
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    • 2018
  • Based on the Reissner mixed variational theorem (RMVT), the authors present a nonlocal Timoshenko beam theory (TBT) for the nonlinear free vibration analysis of multi-walled carbon nanotubes (MWCNT) embedded in an elastic medium. In this formulation, four different edge conditions of the embedded MWCNT are considered, two different models with regard to the van der Waals interaction between each pair of walls constituting the MWCNT are considered, and the interaction between the MWCNT and its surrounding medium is simulated using the Pasternak-type foundation. The motion equations of an individual wall and the associated boundary conditions are derived using Hamilton's principle, in which the von $K{\acute{a}}rm{\acute{a}}n$ geometrical nonlinearity is considered. Eringen's nonlocal elasticity theory is used to account for the effects of the small length scale. Variations of the lowest frequency parameters with the maximum modal deflection of the embedded MWCNT are obtained using the differential quadrature method in conjunction with a direct iterative approach.

Effects of Dissolved Humic Acid on Complexation and Activate Carbon Adsorption of PCB (Humic Acid가 PCB의 착화합과 활성탄 흡착특성에 미치는 영향)

  • Kim, Sung-Hyun;Beak, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.746-752
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    • 1993
  • Quantitative measurements have been made by using equilibrium dialysis techniques on the extent of complexation between PCB and dissoved humic acid(HA). This research investigates the effectiveness of activated carbon adsorption for the removal of PCB from organic free water and humid acid background solution by using bench-scale equilibrium and rate tests. It was found that the extent of complexation depended on the pH, calcium concentration, ionic strength, and the concentration of humic acid. When HA was present, activated carbon capacity was greatly reduced due to complexation and competitive adsorption effects and the adsorption characteristics became complicated by the presence of various species such as the unassociated HA, PCB, and PCB-HA complexes.

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Influence of Thyroxine on the Hepatotoxicity of Carbon Tetrachloride ($CC1_4$의 간장독작용(肝臟毒作用)에 미치는 Thyroxine의 영향(影響))

  • Hong, Ki-Sung;Cheon, Yun-Sook
    • The Korean Journal of Pharmacology
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    • v.16 no.2 s.27
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    • pp.31-38
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    • 1980
  • Calvert et al. formulated the hypothesis that carbon tetrachloride ($CCl_4$) acted on the central nervous system to produce and intensify sympathetic discharge which resulted in anoxic necrosis of the liver. Recknagel suggested that the essential feature of $CCl_4$ hepatotoxicity depended on the cleavage of it to $CCl_3$(free radical) and the peroxidative decomposition of cytoplasmic membrane structural lipids. And there are many reports which show the increase of adrenergic activity in hyperthyroidism. In this paper, the influence of thyroxine on the hepatotexicity of carbon tetrachloride was investigated in mice. The results obtained were summarized as follows; 1) Hepatic total lipid and lipid peroxide contents were slightly decreased by L-sodium thyroxine injection(4mg/kg/day for 4days or 6days), but hepatic glycogen content was significantly decreased. 2) Hepatic total lipid and lipid peroxide contents and serum lactic dehydrogenase activity were significantly increased by $CCl_4$ (4 ml/kg single dose or triple dose: 4ml/kg/day for 3days), but hepatic glycogen content was significantly decreased. 3) The increase of hepatic total lipid and lipid peroxide contents and serum lactic dehydrogenase activity induced by $CCl_4$ were significantly inhitited by the pretreatment of thyroxine. 4) The decrease of hepatic glycogen induced by $CCl_4$ was not affected by the pretreatment of thyroxine.

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Thermal Conductivity of Single-Walled Carbon Nanotube by Using Memory Function (메모리함수에 의한 단일 벽 탄소 나노튜브의 열전도도)

  • Park, Jung-Il;Cheong, Hai-Du
    • Journal of the Korean Vacuum Society
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    • v.22 no.3
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    • pp.144-149
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    • 2013
  • We use Memory function to examine the thermal conductivity as a function of the temperature in single-walled carbon nanotube (SWNT). We determine the Umklapp, normal and SWNT-substrate phonon scattering rate from the computed inverse spin relaxation time. Thermal conductivity increased as the diameter increased when we assumed that the zigzag (10,0) transition was a more dominant phonon scattering than the (9,0) transition.

Arabidopsis SIZ1 positively regulates alternative respiratory bypass pathways

  • Park, Bong-Soo;Kim, Sung-Il;Song, Jong-Tae;Seo, Hak-Soo
    • BMB Reports
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    • v.45 no.6
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    • pp.342-347
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    • 2012
  • Plant mitochondria possess alternative respiratory pathways mediated by the type II NAD(P)H dehydrogenases and alternative oxidases. Here, E3 SUMO ligase was shown to regulate alternative respiratory pathways and to participate in the maintenance of carbon and nitrogen balance in Arabidopsis. The transcript abundance of the type II NAD(P)H dehydrogenases NDA2 and NDB2 and alternative oxidases AOX1a and AOX1d genes was low in siz1-2 mutants compared to that in wild-type. The addition of nitrate or ammonium resulted in a decrease or an increase in the expression of the same gene families, respectively, in both wild-type and siz1-2 mutants. The amount of free sugar (glucose, fructose and sucrose) was lower in siz1-2 mutants than that in wild-type. These results indicate that low nitrate reductase activity due to the AtSIZ1 mutation is correlated with an overall decrease in alternative respiration and with a low carbohydrate content to maintain the carbon to nitrogen ratio in siz1-2 mutants.

Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Nam, Woo-Seok;Jung, Jae-Uk;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.388-391
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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Immobilization of α-amylase from Exiguobacterium sp. DAU5 on Chitosan and Chitosan-carbon Bead: Its Properties

  • Fang, Shujun;Chang, Jie;Lee, Yong-Suk;Hwang, Eun-Jung;Heo, Jae Bok;Choi, Yong-Lark
    • Journal of Applied Biological Chemistry
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    • v.59 no.1
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    • pp.75-81
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    • 2016
  • Glutaraldehyde was used as a cross-linking agent for immobilization of purified ${\alpha}$-amylase from Exiguobacterium sp. DAU5. Befitting concentration of glutaradehyde and cross-linking time is the key to preparation of cross-linking chitosan beads. Based on optimized immobilization condition for ${\alpha}$-amylase, an overall yield of 56% with specific activity of 2,240 U/g on chitosan beads and 58% with specific activity of 2,320 U/g on chitosan-carbon beads was obtained. The optimal temperature and pH of each immobilized enzyme activity were $50^{\circ}C$ and 50 mM glycine-NaOH buffer pH 8.5, respectively. Those retained more than 75 and 90% of its maximal enzyme activity at pH 7.0-9.5 and after incubation at $50^{\circ}C$ for 1 h, respectively. In addition, the immobilization product showed higher organic-solvent tolerance than free enzymes. The mode of hydrolyzing soluble starch revealed that the ${\alpha}$-amylase possessed high hydrolyzing activity. These results indicate that chitosan is good support and has broad application prospects of enzyme immobilization.

Adsorption Characteristics of Methylene Blue and Phenol from Aqueous Solution using Coal-based Activated Carbon (석탄계 활성탄에 의한 수중의 메틸렌블루와 페놀 흡착 특성)

  • Lee, Song-Woo;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.22 no.9
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    • pp.1161-1170
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    • 2013
  • The efficiency of coal-based activated carbon in removing methylene blue (MB) and phenol from aqueous solution was investigated in batch experiments. The batch adsorption kinetics were described by applying pseudo-first-order, pseudo-second-order, and first order reversible reaction. The results showed that the adsorption of MB and phenol occurs complexed process including external mass transfer and intraparticle diffusion. The maximum adsorption capacity obtained from Langmuir isotherm was 461.0 mg/g for MB and 194.6 mg/g for phenol, respectively. The values of activation parameters such as free energy (${\Delta}G^0$), enthalpy (${\Delta}H^0$), and entropy (${\Delta}S^0$) were also determined as -19.0~-14.9 kJ/mol, 25.4 kJ/mol, and 135.2 J/mol K for MB and 51.8~54.1 kJ/mol, -29.0 kJ/mol, and -76.4 kJ/mol K for phenol, respectively. The MB adsorption was found to be endothermic and spontaneous process. However, the CV adsorption was found to be exothermic and non-spontaneous process.

Improved Field Emission by Liquid Elastomer Modification of Screen-Printed CNT Film Morphology

  • Lee, Hyeon-Jae;Lee, Yang-Doo;Cho, Woo-Sung;Kim, Jai-Kyeong;Lee, Yun-Hi;Hwang, Sung-Woo;Ju, Byeong-Kwon
    • Journal of Information Display
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    • v.7 no.2
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    • pp.16-21
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    • 2006
  • The effect of improvement on the surface morphology of screen-printed carbon nanotube (CND) films was studied by using the optically clear poly-dimethylsiloxane (PDMS) elastomer for surface treatment. After the PDMS activation treatment was applied to the diode-type CNT cathode, the entangled carbon nanotube (CNT) bundles were broken up into individual free standing nanotubes to remarkably improve the field-emission characteristics over the as-deposited CNT film. Also, the cathode film morphology of a top gated triode-type structure can be treated by using the proposed surface treatment technique, which is a low-cost process, simple process. The relative uniform emission image showed high brightness with a high anode current. This result shows the possibility of using this technique for surface treatment of large-size field emission displays (FEDs) in the future.