• Title/Summary/Keyword: Free carbon

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Free-standing graphene intercalated nanosheets on Si(111)

  • Pham, Trung T.;Sporken, Robert
    • Journal of IKEEE
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    • v.21 no.3
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    • pp.297-308
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    • 2017
  • By using electron beam evaporation under appropriate conditions, we obtained graphene intercalated sheets on Si(111) with an average crystallite size less than 11nm. The formation of such nanocrystalline graphene was found as a time-dependent function of carbon deposition at a substrate temperature of $1000^{\circ}C$. The structural and electronic properties as well as the surface morphology of such produced materials have been confirmed by reflection high energy electron diffraction, Auger electron spectroscopy, X-ray photoemission spectroscopy, Raman spectroscopy, scanning electron microscopy, atomic force microscopy and scanning tunneling microscopy.

Simultaneous Nitrification and Denitrification in a Fluidized Biofilm Reactor with a Hollow Fiber Double Layer Biofilm Media (이중층 중공사 생물막 담체를 이용한 유동층 생물막 반응기에서의 동시 질산화와 탈질)

  • 이수철;이현용;김동진
    • KSBB Journal
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    • v.15 no.5
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    • pp.514-520
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    • 2000
  • Simultaneous nitrification and denitrification of ammonia and organic compounds-containing wastewater were performed in a fluidized bed biofilm reactor with polysulfone(PS) hollow fiber as a double layer biomass carrier. The PS hollow fiber fragment has both aerobic and anoxic environments for the nitrifiaction and denitrification at the shell and lumen-side respectively. The reactor system showed about 80% nitrification efficiency stably throughout the ammonia load conditions applied in the experiment. Denitrification efficiency depended on organic load and C/N ratio. High free ammonia concentration and low dissolved oxygen resulted in nitrite accumulation which leads to enhance organic carbon efficiency in denitrification when compared to nitrate denitrification. The simultaneous nitrification and denitrification reactor system has an economic advantages in reduced chemical cost of organic carbon for denitrification as well as compact reactor configuration.

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Silicene on Other Two-dimensional Materials: Formation of Heterostructure

  • Kim, Jung Hwa;Lee, Zonghoon
    • Applied Microscopy
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    • v.44 no.4
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    • pp.123-132
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    • 2014
  • Silicene is one of the most interesting two-dimensional materials, because of not only the extraordinary properties similar to graphene, but also easy compatibility with existing silicon-based devices. However, non-existing graphitic-like structure on silicon and unstable free-standing silicene structure leads to difficulty in commercialization of this material. Therefore, substrates are essential for silicene, which affects various properties of silicene and supporting unstable structure. For maintaining outstanding properties of silicene, van der Waals bonding between silicene and substrate is essential because strong interaction, such as silicene with metal, breaks the band structure of silicene. Therefore, we review the stability of silicene on other two-dimensional materials for van der Waals bonding. In addition, the properties of silicene are reviewed for silicene-based heterostructure.

A study of the effect on variable generation cost by the variation of $CO_2$ emission trading price ($CO_2$ 거래비용 변화에 따른 발전원가(변동비) 영향 분석)

  • Jung, Young-Beom;Lee, Young-Eal;Yoon, Yong-Beum
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.822-823
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    • 2007
  • It is easily can be expected that Korea cannot be free under the regulation, because Korea is one of the major $CO_2$ emitter in the world. Even though Korea currently doesn't have any obligation to mitigate the carbon emission, power industry needs to study the effect of that. this paper aims to analyze the change of economic loading order for generation dispatch by various carbon price, looking at each plant's or generator's variable generation cost per unit electricity(kWh) that consists of basic generation price calculated by automatic generation system planning model, WASP 4.0, and $CO_2$ price per unit electricity generation.

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Comparison of spray characteristics for ammonia, ethanol, n-decane by using numerical simulation (시뮬레이션을 이용한 암모니아, 에탄올, 노말데케인 분무 특성 비교)

  • Lee, Jaejin;Yeom, Eunseop
    • Journal of the Korean Society of Visualization
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    • v.20 no.2
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    • pp.38-44
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    • 2022
  • Due to increasingly strict emission regulations for carbon-based fuels in the shipping industry, there is a significant motivation to investigate the alternative fuel. Ammonia is one of the attractive alternative fuels as a carbon-free fuel. Since ammonia has different properties such as high vapor pressure and low boiling point compared to conventional fuels, further research into ammonia spray behavior is important. In this work, the spray characteristics of ammonia and other fluids (ethanol, n-decane) were compared by using numerical simulation. The results show that the spray characteristics of ammonia differs from those of the others due to the occurrence of flash boiling. The narrow-dispersed spray with accelerated velocity at the center have been observed for ammonia. It is also found that droplets of ammonia achieve smaller diameter with more uniform distribution, leading to better atomization behavior compared to the others.

A nonlocal system for the identification of active vibration response of chiral double walled CNTs

  • Alghamdi, Sami;Hussain, Muzamal;Khadimallah, Mohamed A.;Asghar, Sehar;Ghandourah, Emad;Alzahrani, Ahmed Obaid M.;Alzahrani, M.A.
    • Steel and Composite Structures
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    • v.42 no.3
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    • pp.353-361
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    • 2022
  • In this study, an estimation regarding nonlocal shell model based on wave propagation approach has been considered for vibrational behavior of the double walled carbon nanotubes with distinct nonlocal parameters. Vibrations of double walled carbon nanotubes for chiral indices (8, 3) have been analyzed. The significance of small scale is being perceived by developing nonlocal Love shell model. The influence of changing mechanical parameter Poisson's ratio has been investigated in detail. The dominance of boundary conditions via nonlocal parameter is shown graphically. It is found that on increasing the Poisson's ratio, the frequencies increases. It is noted that the frequencies of clamped-clamped frequencies are higher than that of simply-supported and clamped-free edge conditions. The outcomes of frequencies are tested with earlier computations.

Recommendation for the modelling of Donnell shell: The relationship between non-local parameter and frequency

  • Mohamed A. Khadimallah;Muzamal Hussain;Elimam Ali;Sehar Asghar;Abdelouhed Tounsi
    • Computers and Concrete
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    • v.32 no.2
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    • pp.165-172
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    • 2023
  • The vibration analysis of armchair, zigzag and chiral double-walled carbon nanotubes has been developed by inserting the nonlocal theory of elasticity into thin shell theory. First Donnell shell theory is employed while exercising wave propagation approach. Scale effects are realized by using different values of nonlocal parameters under certain boundary conditions. The natural frequencies have been investigated and displayed for various non-local parameters. It is noticed that on increasing nonlocal parameter, the frequency curve tends to decrease. The frequency estimates of clamped-free boundary condition are less than those of clamped-clamped and simply supported computations. The frequency comparisons are presented for armchair, zigzag and chiral nanotubes. The software MATLAB is used to extract the frequencies of double walled carbon nanotubes.

Fabrication of Copper(II) Oxide Plated Carbon Sponge for Free-standing Resistive Type Gas Sensor and Its Application to Nitric Oxide Detection (프리스탠딩 저항형 가스 센서용 산화구리 무전해 도금 탄소스펀지 제조 및 일산화질소 감지)

  • Kim, Seokjin;Ha, Seongmin;Myeong, Seongjae;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.630-635
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    • 2022
  • Copper(II) oxide (CuO), electroless plated on a nitrogen-containing carbon sponge prepared by a melamine sponge thermal treatment, was developed as a nitric oxide (NO) gas sensor that operates without a wafer. The CuO content on the surface of the carbon sponge increased as the plating time increased, but the content of nitrogen known to induce NO gas adsorption decreased. The untreated carbon sponge showed a maximum resistance change (5.0%) at 18 min. On the other hand, the CuO plated sample (CuO30s-CS) showed a maximum resistance change of 18.3% in 8 min. It is considered that the improvement of the NO gas sensing capability was caused by the increase in hole carriers of the carbon sponge and improved movement of electrons due to CuO. However, the NO gas detection resistance of the CuO electroless plated carbon sponge for 60 s decreased to 1.9%. It is considered that the surface of the carbon sponge was completely plated with CuO, resulting in a decrease in the NO gas adsorption capacity and resistance change. Thus, CuO-plated carbon sponge can be used as an effective NO gas sensor because it has fast and excellent resistance change properties, but CuO should not be completely plated on the surface of the carbon sponge.

The preparation of ultra hard nitrogenated DLC film by $N_2^+$ implantation

  • Olofinjana, A.O.;Chen, Z.;Bell, J.M.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.165-166
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    • 2002
  • Hydrogen free diamond like carbon (DLC) films were prepared on steel substrates by using a single ion beam in a configuration that allowed sputtering of a graphite target and at the same time allowed to impact the substrate at a grazing angle. The DLC films so prepared have improved properties with increased disorder and with modest hardness that is slightly higher than previously reported values. We have studied the effects of $N_2^+$ ions implantation on such films. It is found that the implantations of nitrogen ions into DLC films lead to chemical modifications that allowed N atoms to be incorporated into the carbon network to produce a nitrogenated DLC. Nano-indentation experiments indicated that the nitrogenated films have consistently higher hardnesses ranging from 30 to 45GPa, which represents a considerable increase in surface hardness, compared with non-nitrogenated precursor films. The investigations by XPS and Raman spectroscopy suggests that the $N_2^+$ implanted DLCs had undergone both chemical and structural modifications through the incorporation of N atoms and the increased ratio of $sp^3/sp^2$ type bonding. The observed high hardness was therefore attributable to these structural and chemical modifications. This result has implication for the preparation of super hard wear resistant films required for tribological functions in devices.

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Effects of Pretreated Korean Red Ginseng on Carbon Tetrachloride and Galactosamine-induced Hepatotoxicity in Rats (홍삼의 전처리에 의한 사염화탄소 및 갈락토사민 유발 간독성에 대한 보호효과)

  • Lee, Chung-Kyu;Kim, Na-Young;Han, Yong-Nam;Choi, Jong-Won
    • Journal of Ginseng Research
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    • v.27 no.1
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    • pp.1-10
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    • 2003
  • In present study, we examined whether or not the pretreatment of Korean Red Ginseng (KRG) could protect hepatotoxicity induced by carbon tetrachloride (CCl$_4$) and D-galatosamine (GalN). For this study, we not only tested activity of various plasma enzymes (AST, ALT, SDH, LDH), which are used as indicators of liver disease, but also checked the change of liver components such as lipid, glutathione and cytochromes content, and several liver enzyme activity. Pretreatment of KRG for two weeks significantly reduced the elevated plasma enzyme activities induced by CCl$_4$ and GalN. Pretreatment of KRG also restored the hepatic enzymes, malonedialdehyde formation, and depletion of reduced glutathione content induced by CCl$_4$ and GalN to near normal level. However, ${\gamma}$-glutamylcysteine synthetase activity was lot affected by KRG. These results suggest that KRG shows the hepatoprotective effect by reducing lipid peroxidation, by reducing the activity of free radical generating enzymes, and by preserving the hepatic glutathione.