• Title/Summary/Keyword: Free carbon

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Ag Nanowires와 혼합물을 이용한 ITO-free 유기태양전지 연구

  • Jang, So-Ra;Yang, Hye-Jin;Go, Geum-Jin;Choe, Cheol-Ho;Choe, Ju-Hwan;Sin, Jin-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.467.2-467.2
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    • 2014
  • 유기태양전지는 친환경 에너지 소스로써 저가 대량 생산이 가능하고 특히 유연한 기판에 적용이 가능하여 많은 관심을 받고 있다. 그럼에도 불구하고 기존에 사용되는 indium tin oxide (ITO)의 사용으로 인한 유연성 부족으로 대체되는 투명전극의 개발이 요구되어지고 있다. 이로 인해 carbon nanotubes, graphene, thin metals, metal grids, and conducting polymers 등이 연구되고 있으며, 이중 Silver nanowires (Ag NWs)를 이용한 방식도 많은 관심과 함께 전기광학적 특성에 대한 연구가 진행되고 있다. 하지만 유기전자소자에 사용되기에는 몇 가지 문제점이 발생하는데 이를 해결하기 위한 노력이 다양하게 이루어지고 있다. 특히 다양한 물질의 혼합을 통해 개선하고자 하는 노력이 증가하고 있는데 적층구조의 전도성필름 형성을 통해 ITO-free OPVs에서 Ag nanowire를 transparent conductive electrodes로 활용하였다. Ag NWs층과 PEDOT:PSS layer의 복합화를 통해 저가의 ITO-free OPVs용 transparent anodes가 가능해졌다.

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Disposable in-field electrochemical potable sensor system for free available chlorine (FAC) detection

  • Chang, Seung-Cheol;Park, Deog-Su
    • Journal of Sensor Science and Technology
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    • v.16 no.6
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    • pp.449-456
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    • 2007
  • The work described in this study concerns the development of a disposable amperometric sensor for the electrochemical detection of a well-known aqueous pollutant, free available chlorine (FAC). The FAC sensor developed used screen printed carbon electrodes (SPCEs) coupled with immobilised syringaldazine, commonly used as an indicator in photometric FAC detection, which was directly immobilised on the surface of SPCEs using a photopolymer PVA-SbQ. To enable in-field analysis of FAC, a prototype hand-held electrochemical analyzer has been developed to withstand the environment with its rugged design and environmentally sealed connections; it operates from two PP3 (9 volt) batteries and is comparable in accuracy and sensitivity to commercial bench top systems. The sensitivity of the FAC sensor developed was $3.5{\;}nA{\mu}M^{-1}cm^{-2}$ and the detection limit for FAC was found to be $2.0{\;}{\mu}M$.

Recent developments of manganese-aluminium as rare-earth-free magnets

  • Sirisathitkul, Chitnarong
    • Advances in materials Research
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    • v.9 no.4
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    • pp.323-335
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    • 2020
  • This article reviews findings and progresses in the past decade on manganese-aluminium (MnAl) based magnets as the interest has been revived to fulfill their potential as commercial magnets. The challenges in developments of these rare-earth-free magnets are to acquire a high remanence and coercivity from the ferromagnetic τ-phase in MnAl alloys. To this end, the phase transformation to this τ-MnAl with L10 body centered tetragonal structure has been promoted by a variety of methods and a few percents of carbon (C) is often added to prevent the phase decomposition. Magnetization and coercivity are not only influenced by the phase composition but also the microstructure. The fabrication processes and factors affecting the phase and microstructure are therefore covered. Finally, the productions of bulk MnAl magnets are addressed.

Non-linear free and forced vibration analysis of sandwich nano-beam with FG-CNTRC face-sheets based on nonlocal strain gradient theory

  • Arani, Ali Ghorbanpour;Pourjamshidian, Mahmoud;Arefi, Mohammad
    • Smart Structures and Systems
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    • v.22 no.1
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    • pp.105-120
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    • 2018
  • In this paper, the nonlinear free and forced vibration responses of sandwich nano-beams with three various functionally graded (FG) patterns of reinforced carbon nanotubes (CNTs) face-sheets are investigated. The sandwich nano-beam is resting on nonlinear Visco-elastic foundation and is subjected to thermal and electrical loads. The nonlinear governing equations of motion are derived for an Euler-Bernoulli beam based on Hamilton principle and von Karman nonlinear relation. To analyze nonlinear vibration, Galerkin's decomposition technique is employed to convert the governing partial differential equation (PDE) to a nonlinear ordinary differential equation (ODE). Furthermore, the Multiple Times Scale (MTS) method is employed to find approximate solution for the nonlinear time, frequency and forced responses of the sandwich nano-beam. Comparison between results of this paper and previous published paper shows that our numerical results are in good agreement with literature. In addition, the nonlinear frequency, force response and nonlinear damping time response is carefully studied. The influences of important parameters such as nonlocal parameter, volume fraction of the CNTs, different patterns of CNTs, length scale parameter, Visco-Pasternak foundation parameter, applied voltage, longitudinal magnetic field and temperature change are investigated on the various responses. One can conclude that frequency of FG-AV pattern is greater than other used patterns.

Vibration analysis of sandwich sectorial plates considering FG wavy CNT-reinforced face sheets

  • Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.28 no.5
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    • pp.541-557
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    • 2018
  • This paper presents the influence of carbon nanotubes (CNTs) waviness and aspect ratio on the vibrational behavior of functionally graded nanocomposite sandwich annular sector plates resting on two-parameter elastic foundations. The carbon nanotube-reinforced (CNTR) sandwich plate has smooth variation of CNT fraction along the thickness direction. The distributions of CNTs are considered functionally graded (FG) or uniform along the thickness and their mechanical properties are estimated by an extended rule of mixture. In this study, the classical theory concerning the mechanical efficiency of a matrix embedding finite length fibers has been modified by introducing the tube-to-tube random contact, which explicitly accounts for the progressive reduction of the tubes' effective aspect ratio as the filler content increases. Effects of CNT distribution, volume fraction, aspect ratio and waviness, and also effects of Pasternak's elastic foundation coefficients, sandwich plate thickness, face sheets thickness and plate aspect ratio are investigated on the free vibration of the sandwich plates with wavy CNT-reinforced face sheets. The study is carried out based on three-dimensional theory of elasticity and in contrary to two-dimensional theories, such as classical, the first- and the higher-order shear deformation plate theories, this approach does not neglect transverse normal deformations. The sandwich annular sector plate is assumed to be simply supported in the radial edges while any arbitrary boundary conditions are applied to the other two circular edges including simply supported, clamped and free.

The Effect of Gamma-Irradiation on Aqueous Solutions of Triglycine 3. Mechanism for Gamma-ray Induced Degradation Products (Triglycine 수용액에 미치는 감마선의 영향 3. 감마선에 의한 분해산물에 관하여)

  • ;LEONE, Charles A
    • The Korean Journal of Zoology
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    • v.7 no.2
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    • pp.1-5
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    • 1964
  • Carbonyl compounds, glycine, ammonia, carbon dioxide and hydrogen have been identified in gamma-irradiated oxygenated aqueous solutions of triglycine. The reactions occurring in this system are postulated only by representing the initial process and the final products. The triglycine molecule undergoes a reaction to form an intermediate giving rise to carbonyl compounds and acid amides. These compounds are decomposed to acetamide, glycine, glyoxylic acid, formic acid, oxalic acid, ammonia, and carbon dioxide by free radical attack in the primary and/or secondary reactions. It is also possible that the unrecognized reactions may give rise to products formed by radical-radical combinations. Satisfactory material balance for all the products have to wait until the completion of a study now in progress.ogress.

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Module of Carbon Nanotubes Backlight

  • Chou, Lin-En;Lin, Biing-Nan;Jiang, Yau-Chen;Tsou, Te-Hao;Fu, Chuan-Hsu;Hsiao, Ming-Chun;Chang, Yu-Yang;Lin, Wei-Yi;Lin, Ming-Hung;Lee, Cheng-Chung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.150-155
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    • 2006
  • Carbon nanotubes backlight unit (CNT-BLU) that lightened by field emission was developed into practicability. According to our novel structure, AC mode circuit design and simple printing process, CNT-BLU could achieve 85% of uniformity, 8000 nits of brightness and low material and fabrication cost. Based on these performances, this new planar backlight technology has chances to proceed to mass production and has the potential to replace traditional backlight technology because of its good properties, like the simple processes, easy to large scale, low surface temperature, low power consumption, optical film-free and Hg-free, etc.

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Synthesis of SiC Nano-powder from TEOS by RF Induction Thermal Plasma (RF 열플라즈마를 이용한 TEOS로 부터의 SiC 나노분말 합성)

  • Ko, Sang-Min;Koo, Sang-Man;Kim, Jin-Ho;Kim, Ji-Ho;Byeon, Myeong-Seob;Hwang, Kwang-Taek
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.1-5
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    • 2011
  • Silicon carbide (SiC) has recently drawn an enormous industrial interest because of its useful mechanical properties such as thermal resistance, abrasion resistance and thermal conductivity at high temperature. RF Thermal plasma (PL-35 Induction Plasma, Tekna CO., Canada) has been utilized for synthesis of high purity SiC powder from cheap inorganic solution (Tetraethyl Orthosilicate, TEOS). It is found that the powders by thermal plasma consist of SiC with free carbon and amorphous silica ($SiO_2$) and, by thermal treatment and HF treatment, the impurities are driven off resulting high purity SiC nano-powder. The synthesized SiC powder lies below 30 nm and its properties such microstructure, phase composition, specific surface area and free carbon content have been characterized by X-ay diffraction (XRD), field emission scanning electron microscopy (FE-SEM), thermogravimetric (TG) and Brunauer-Emmett-Teller (BET).

Free vibration and buckling analysis of elastically restrained FG-CNTRC sandwich annular nanoplates

  • Kolahdouzan, Farzad;Mosayyebi, Mohammad;Ghasemi, Faramarz Ashenai;Kolahchi, Reza;Panah, Seyed Rouhollah Mousavi
    • Advances in nano research
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    • v.9 no.4
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    • pp.237-250
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    • 2020
  • An accurate plate theory for assessing sandwich structures is of interest in order to provide precise results. Hence, this paper develops Layer-Wise (LW) theory for reaching precise results in terms of buckling and vibration behavior of Functionally Graded Carbon Nanotube-Reinforced Composite (FG-CNTRC) annular nanoplates. Furthermore, for simulating the structure much more realistic, its edges are elastically restrained against in-plane and transverse displacement. The nano structure is integrated with piezoelectric layers. Four distributions of Single-Walled Carbon Nanotubes (SWCNTs) along the thickness direction of the core layer are investigated. The Differential Quadrature Method (DQM) is utilized to solve the motion equations of nano structure subjected to the electric field. The influence of various parameters is depicted on both critical buckling load and frequency of the structure. The accuracy of solution procedure is demonstrated by comparing results with classical edge conditions. The results ascertain that the effects of different distributions of CNTs and their volume fraction are significant on the behavior of the system. Furthermore, the amount of in-plane and transverse spring coefficients plays an important role in the buckling and vibration behavior of the nano-structure and optimization of nano-structure design.

Proposal for the New Regeneration Energy Made by Converting Magnetic Force into Mechanical Energy (영구자석 자기력의 기계적 에너지 이용에 관한 유용성 고찰)

  • Shin, Hyun-Joon;Kim, Jung-Yup;Park, Byong-Jik;Lee, Su-Gak
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.4
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    • pp.158-164
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    • 2016
  • Currently, identifying a new carbon-free energy resource is important in order to resolve the global warming problem. Along the same line, this paper studied how to convert magnetic force into mechanical force and a new basic mechanism of converting magnetic force into mechanical force was identified. Long-term reliability test, around 15 million times, was also conducted at $-1^{\circ}C{\sim}27^{\circ}C$ to evaluate the durability of magnetic force. As a result, tests showed that the deviation of the mechanical force was within 0.8% of the initial force, and the relation between repulsive force (P) and ambient temperature (T) was formulated in a linear equation P = -0.175T+78.945.