• Title/Summary/Keyword: Free Area Ratio

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S-wave Velocity Derivation Near the BSR Depth of the Gas-hydrate Prospect Area Using Marine Multi-component Seismic Data (해양 다성분 탄성파 자료를 이용한 가스하이드레이트 유망지역의 BSR 상하부 S파 속도 도출)

  • Kim, Byoung-Yeop;Byun, Joong-Moo
    • Economic and Environmental Geology
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    • v.44 no.3
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    • pp.229-238
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    • 2011
  • S-wave, which provides lithology and pore fluid information, plays a key role in estimating gas-hydrate saturation. In general, P- and S-wave velocities increase in the presence of gas-hydrate and the P-wave velocity decreases in the presence of free gas under the gas-hydrate layer. Whereas there are very small changes, even slightly increases, in the S-wave velocity in the free gas layer because S-wave is not affected by the pore fluid when propagating in the free gas layer. To verify those velocity properties of the BSR (bottom-simulating reflector) depth in the gas-hydrate prospect area in the Ulleung Basin, P- and S-wave velocity profiles were derived from multi-component ocean-bottom seismic data which were acquired by Korea Institute of Geoscience and Mineral Resources (KIGAM) in May 2009. OBS (ocean-bottom seismometer) hydrophone component data were modeled and inverted first through the traveltime inversion method to derive P-wave velocity and depth model of survey area. 2-D multichannel stacked data were incorporated as an initial model. Two horizontal geophone component data, then, were polarization filtered and rotated to make radial component section. Traveltimes of main S-wave events were picked and used for forward modeling incorporating Poisson's ratio. This modeling provides S-wave profiles and Poisson's ratio profiles at every OBS site. The results shows that P-wave velocities in most OBS sites decrease beneath the BSR, whereas S-wave velocities slightly increase. Consequently, Poisson's ratio decreased strongly beneath the BSR indicating the presence of a free gas layer under the BSR.

Electrochemical Characteristics of EDLCs with Selectivity Factors for the Organic Electrolyte (유기용매전해질에 따른 전기이중층캐패시터의 전기화학적 특성)

  • Lee, Sun-young;Ju, Jeh-Beak;Sohn, Tae-Won;Cho, Won-Il;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.1-5
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    • 2005
  • Electric double layer capacitors(EDLCS) based on the charge stored at the interface between a hi팀 surface area carbon electrode and an organic electrolyte solution are widely used as a maintenance-free power source for IC memories and microcomputers. The achievement of the excellent performance of the capacitor requires an electrolyte solution which provides high conductivities over a wide temperature range and good electrochemical stabilities to allow the capacitor to be operated at high voltage. The electrochemical capacitor using a carbon material as electrodes and using an organic electrolyte with $1M-LiPF_6$ in PC-GBL-DEC(volume ratio 1:1:2) has specific capacitance of 64F/g.

Seismic Pre-processing and AVO analysis for understanding the gas-hydrate structure (가스 하이드레이트 부존층의 구조 파악을 위한 탄성파 전산처리 및 AVO 분석)

  • Chung Bu-Heung
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.634-637
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    • 2005
  • Multichannel seismic data acquired in Ulleung Basin of East Sea for gas hydrate exploration. The seismic sections of this area show strong BSR(bottom simulating reflections) associated with methane hydrate occurrence in deep marine sediments. Very limited information is available from deep sea drilling as the risk of heating and destabilizing the initial hydrate conditions during the processing of drilling is considerably high. Not so many advanced status of gas hydrate exploration in Korea, the most of information of gas hydrate characteristics and properties are inferred from seismic reflection data. In this study, The AVO analysis using the long offset seismic data acquired in Ulleung Basin used to explain the characteristics and structure of gas hydrate. It is used primarily P-wave velocity accessible from seismic data. To make a good quality of AVO analysis input data, seismic preprocessing including 'true gain correction', 'source signature deconvolution', twice velocity analysis and some kinds of multiple rejection and enhancing the signal to noise ratio processes is carried out very carefully. The results of AVO analysis, the eight kinds of AVO attributes are estimated basically and some others of AVO attributes are evaluated for interpretation of AVO analysis additionally. The impedance variation at the boundary of gas hydrate and free gas is estimated for investing the BSR characteristics and properties. The complex analysis is performed also to verifying the amplitude variation and phase shift occurrence at BSR. Type III AVO anomaly appearance at saturated free gas area is detected on BSR. It can be an important evidence of gas hydrate deposition upper the BSR.

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Hydrogen adsorption experiments with IRMOF-3 as a sorbent, and the molecular modeling studies on the functionalized MOFs (IRMOF-3 의 수소 흡착 실험 및 Organic Linker 의 작용기에 따른 분자모델링 연구)

  • Lee, Eungsung;Oh, Youjin;Yoon, Jihye;Kim, Jaheon;Kim, DaeJin;Lee, Tae-Bum;Choi, Seung-Hoon;Lee, Jun;Cho, Sung June
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.2
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    • pp.108-118
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    • 2004
  • To find out rational design and synthetic strategies toward efficient hydrogen storage materials, molecular modeling and quantum mechanical studies have been carried out on the MOFs(Metal-Organic Frameworks) having various organic linkers and nanocube frameworks. The calculation results about the free volume ratio, surface area, and electron density variation of the frameworks indicated that the capacity of the hydrogen storage of MOFs was largely dependent on the specific surface area and electron localization around benzene ring rather than the free volume of MOFs. The prediction of the modeling study could be supported by the hydrogen adsorption experiments using IRMOF-1 and -3, which showed more enhanced hydrogen storage capacities of IRMOF-3 compared with the IRMOF-1's at both experimental conditions, 77K, ∠ $H_2$ 1 atm and ambient temperature, ∠ $H_2$ 35 atm.

Survey of Antibiotic Resistant Bacteria in Ulleungdo, Korea (울릉도의 항생제 내성균 조사)

  • Jun Hyung Lee;Hye Won Hong;Dukki Han
    • Korean Journal of Environmental Agriculture
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    • v.41 no.4
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    • pp.344-354
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    • 2022
  • BACKGROUND: Although antibiotics have contributed to treatment of bacterial infection, the antibiotic abuse can lead to antibiotic resistant bacteria. Impact of human activities on distribution of antibiotic resistance has been intensively issued and occurrence of antibiotic resistant bacteria in contaminated environments would not be a surprise. Nonetheless, anthropogenic contamination with the dissemination of antibiotic resistance along uncontaminated environments has been less considered. The aim of this study is to investigate antibiotic resistant bacteria across Ulleungdo, known as antibiotic resistance free and anthropogenic pollution free environment in Rep. of Korea. METHODS AND RESULTS: Antibiotic resistant bacteria in coastal seawater of Ulleungdo were investigated in July 2021. Antibiotic susceptibility test using the disk diffusion method was applied with six drugs according to the Clinical and Laboratory Standards Institute (CLSI) guideline. Total 43 bacterial isolates were tested and 20 isolates among of them showed multidrug resistance. Particularly, the number and ratio of resistant bacteria were relatively high in a densely populated area of Ulleungdo. The bacterial communities were investigated using 16S rRNA gene metabarcoding approach in the coastal seawater and soils of Ulleungdo. In the bacterial communities, Firmicutes were selectively distributed only in seawater, suggesting the possibility of anthropogenic contamination in coastal seawater of Ulleungdo. CONCLUSION(S): We found antibiotic resistant bacteria in a populated area of Ulleungdo. The occurrence of antibiotic resistant bacteria in Ulleungdo seems to result from the recent anthropogenic impact. Consistent monitoring of antibiotic resistant bacteria in the uncontaminated environment needs to considered for future risk assessment of antibiotics.

A Study on the Cobalt Electrodeposition of High Aspect Ratio Through-Silicon-Via (TSV) with Single Additive (단일 첨가제를 이용한 고종횡비 TSV의 코발트 전해증착에 관한 연구)

  • Kim, Yu-Jeong;Lee, Jin-Hyeon;Park, Gi-Mun;Yu, Bong-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.140-140
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    • 2018
  • The 3D interconnect technologies have been appeared, as the density of Integrated Circuit (IC) devices increases. Through Silicon Via (TSV) process is an important technology in the 3D interconnect technologies. And the process is used to form a vertically electrical connection through silicon dies. This TSV process has some advantages that short length of interconnection, high interconnection density, low electrical resistance, and low power consumption. Because of these advantages, TSVs could improve the device performance higher. The fabrication process of TSV has several steps such as TSV etching, insulator deposition, seed layer deposition, metallization, planarization, and assembly. Among them, TSV metallization (i.e. TSV filling) was core process in the fabrication process of TSV because TSV metallization determines the performance and reliability of the TSV interconnect. TSVs were commonly filled with metals by using the simple electrochemical deposition method. However, since the aspect ratio of TSVs was become a higher, it was easy to occur voids and copper filling of TSVs became more difficult. Using some additives like an accelerator, suppressor and leveler for the void-free filling of TSVs, deposition rate of bottom could be fast whereas deposition of side walls could be inhibited. The suppressor was adsorbed surface of via easily because of its higher molecular weight than the accelerator. However, for high aspect ratio TSV fillers, the growth of the top of via can be accelerated because the suppressor is replaced by an accelerator. The substitution of the accelerator and the suppressor caused the side wall growth and defect generation. The suppressor was used as Single additive electrodeposition of TSV to overcome the constraints. At the electrochemical deposition of high aspect ratio of TSVs, the suppressor as single additive could effectively suppress the growth of the top surface and the void-free bottom-up filling became possible. Generally, copper was used to fill TSVs since its low resistivity could reduce the RC delay of the interconnection. However, because of the large Coefficients of Thermal Expansion (CTE) mismatch between silicon and copper, stress was induced to the silicon around the TSVs at the annealing process. The Keep Out Zone (KOZ), the stressed area in the silicon, could affect carrier mobility and could cause degradation of the device performance. Cobalt can be used as an alternative material because the CTE of cobalt was lower than that of copper. Therefore, using cobalt could reduce KOZ and improve device performance. In this study, high-aspect ratio TSVs were filled with cobalt using the electrochemical deposition. And the filling performance was enhanced by using the suppressor as single additive. Electrochemical analysis explains the effect of suppressor in the cobalt filling bath and the effect of filling behavior at condition such as current type was investigated.

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A Study on Structures and Properties of Liquid Crystal-UV Curable Resin Composite Materials (액정-UV경화 이크릴레이트 수지 복합재료의 구조와 물성에 관한 연구)

  • 김종원
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.59-69
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    • 2000
  • The characteristics of liquid crystal polymer composite(LCPC) films are possessed of large-area and flexible display, polarizer free, high contrast, wide angle of visual filed and high responsiveness. It is well known that the LCPC films consisting of a continuous LC phase embeded in a three-dimentional network of polymer matrix are formed by photopolymerization-induced phase separation. In this study, we have investigated the point that both liquid crystals and polymer having different properties have to coexiste as composed films. The purpose of this study has been the development of new application with liquid crystals and UV-curable monomers. In the results abtained on the miscibility of nematic liquid crystal and UV-curable resins, difunctional monomer HX-620 turned out to shows the best. From the results abtained on structures, electro-optical properties and dynamic visocoelasticity for LCPC films, the best mixing ratio of monomer to LC mixture were 3/7(photoinitiator; 4wt%) by weight, and this ratio has been provided the most thermal stability for LCPC films. In the results abtained on structure and discoloration properties of LCPC films, it has been demonstrated that consiste of a 8:2 mixture of chiral nematic liquid crystal and HX-620 has the greatest domain and it was the best discoloration.

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Gametophyte life-history dominance of Chondrus crispus (Gigartinaceae, Rhodophyta) along the Atlantic coast of Nova Scotia, Canada

  • Mclachlan, Jack L.;Blanchard, Wade;Field, Christopher;Lewis, Nancy I.
    • ALGAE
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    • v.26 no.1
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    • pp.51-60
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    • 2011
  • Similar to other species of Gigartinaceae Chondrus crispus has an alternation of perennial, isomorphic gametophytic and sporophytic generations. As these two generations co-exist independently within populations and obtain their resources in a similar manner, intraspecific competition is expected. In populations within the southern Gulf of St. Lawrence, fronds of both generations of C. crispus occur in similar numbers. This equivalency can be related to substratum instability, where the population is dynamic with a high turn-over rate of genets. These observations support a stochastic hypothesis to account for distribution of gametophytes and sporophytes in this area. Along the Atlantic coast of Nova Scotia, where the substratum is stable, gametophytes are overwhelmingly predominant. Gametophytic predominance is greatest in the lower littoral zone where C. crispus is abundant and space is limited. Under the fucoid canopy where "free-space" exists, the gametophyte to sporophyte ratio is lower. Gametophytic and sporophytic fronds are distributed equally among different size-classes and size-distribution is not considered a competitive factor. Previous studies have shown that sporophytic fronds of C. crispus are more susceptible to infections by endophytic algae and other pathogens, and are more heavily grazed by herbivores than are gametophytic fronds. Thus, mechanistic factors are strongly implied in the selection of gametophytes in the Atlantic population.

Development of Radiation Free Soft X-Ray Ionizer with Ion Control (완전차폐 및 이온조절형 연X선식 정전기제거장치의 개발)

  • Jeong, Phil Hoon;Lee, Dong Hoon
    • Journal of the Korean Society of Safety
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    • v.31 no.5
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    • pp.22-27
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    • 2016
  • The Electrostatic Charge Prevention Technology is a core factor that highly influences the yield of Ultra High Resolution Flat Panel Display and high-integrated semiconductor manufacturing processes. The corona or x-ray ionizations are commonly used in order to eliminate static charges during manufacturing processes. To develop such a revolutionary x-ray ionizer that is free of x-ray radiation and has function to control the volume of ion formation simultaneously is a goal of this research and it absolutely overcomes the current risks of x-ray ionization. Under the International Commission on Radiological Protection, it must have a leakage radiation level that should be lower than a recommended level that is $1{\mu}Sv/hour$. In this research, the new generation of x-ray ionizer can easily control both the volume of ion formation and the leakage radiation level at the same time. In the research, the test constraints were set and the descriptions are as below; First, In order not to leak x-ray radiation while testing, the shielding box was fully installed around the test equipment area. Second, Implement the metallic Ring Electrode along a tube window and applied zero to ${\pm}8kV$ with respect to manage the positive and negative ions formation. Lastly, the ion duty ratio was able to be controlled in different test set-ups along with a free x-ray leakage through the metallic Ring Electrode. In the result of experiment, the maximum x-ray radiation leakage was $0.2{\mu}Sv/h$. These outcome is lower than the ICRP 103 recommended value, which is $1{\mu}Sv/h$. When applying voltage to the metallic ring electrode, the positive decay time was 2.18s at the distance of 300 mm and its slope was 0.272. In addition, the negative decay time was 2.1s at the distance of 300 mm and its slope was 0.262. At the distance of 200 mm, the positive decay time was 2.29s and its slope was 0.286. The negative decay time was 2.35s and its slope was 0.293. At the distance of 100 mm, the positive decay time was 2.71s and its slope was 0.338. The negative decay time was 3.07s and its slope was 0.383. According to these research, the observation was shown that these new concept of ionizer is able to minimize the leakage radiation level and to control the positive and negative ion duty ratio while ionization.

A Study on the Microstructure of Melt-Quenched AISI 310 Stainless Steel (단롤법으로 제조한 AISI 310 스테인레스강의 급냉 조직에 관한 연구)

  • Choi, J.H.;Oh, M.S.;J., S.S.;Lee, Y.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.1
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    • pp.19-26
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    • 1996
  • Melt-quenching of steels leads to various metallographic effects such as refinement of grain size, extension of the solid solubility of carbon and alloying elements, and is expected to improve the mechanical properties of conventional steels. Furthermore, this technique is a useful method for producing sheet directly from liquid state. And it will lend itself to development as a continuous cast process which offers significant savings in energy and product costs. The purpose of this study is to present the microstructures of melt-quenched austenitic stainless steels. As the results of this study, the morphology of melt-quenched microstructure show that the roll contact area is columnar structure, and the free surface area is dendrite structure. As the line speed increases, the ratio of $d_{colunnar}/d_{total}$ increases from 0.12 to 0.60, but the ribbon thickness decreases from $150{\mu}m$ to $30{\mu}m$.

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