• Environmental Engineering Research
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• v.21 no.4
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• pp.409-419
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• 2016

As a major energy consumption province, the issue about the carbon emissions in Hebei Province, China has been concerned by the government. The carbon emissions can be effectively reduced due to a more rational energy consumption structure. Thus, in this paper the constraint of low carbon emissions is considered as a foundation and four energies--coal, petroleum, natural gas and electricity including wind power, nuclear power and hydro-power etc are selected as the main analysis objects of the adjustment of energy structure. This paper takes energy cost minimum and carbon trading cost minimum as the objective functions based on the economic growth, energy saving and emission reduction targets and constructs an optimization model of energy consumption structure. And empirical research about energy consumption structure optimization in 2015 and 2020 is carried out based on the energy consumption data in Hebei Province, China during the period 1995-2013, which indicates that the energy consumption in Hebei dominated by coal cannot be replaced in the next seven years, from 2014 to 2020, when the coal consumption proportion is still up to 85.93%. Finally, the corresponding policy suggestions are put forward, according to the results of the energy structure optimization in Hebei Province.

• Bulletin of the Korean Chemical Society
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• v.29 no.10
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• pp.1951-1959
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• 2008

Pentamer cluster of azodicarbonamide (ADA) based on the crystalline structure was investigated for the equilibrium structure, the stabilization energies, and the vibrational properties at various levels of the density functional theory. Stretching force constants of N${\cdot}{\cdot}{\cdot}$H or O${\cdot}{\cdot}{\cdot}$H, and angle-bending force constants of N-H${\cdot}{\cdot}{\cdot}$N or N-H${\cdot}{\cdot}{\cdot}$O for intermolecular hydrogen bonds in the pentamer cluster were obtained in 0.2-0.5 mdyn/$\AA$ and 1.6-2.0 mdyn$\AA$, respectively. The geometry of central ADA molecule fully hydrogen bonded with other four molecules shows good coincidence to the crystalline structure except the bond distances of N-H. Calculated Raman and infrared spectra of central ADA molecule in cluster represent well the experimental spectra of ADA obtained in the solid state compared to a single molecule. Detailed structural and vibrational properties of central ADA molecule in the pentamer cluster are presented.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.4 s.97
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• pp.457-464
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• 2005

A three-dimensional (3-D) method of analysis is presented for determining the free vibration frequencies and mode shapes of thick, complete (not truncated) conical shells of revolution, Unlike conventional shell theories, which are mathematically two-dimensional (2-D). the present method is based upon the 3-D dynamic equations of elasticity. Displacement components $u_{r},\;u_{z},\;and\;u_{\theta}$ in the radial, axial, and circumferential directions, respectively, are taken to be sinusoidal in time, periodic in , and algebraic polynomials in the r and z directions. Potential (strain) and kinetic energies of the conical shells are formulated, the Ritz method is used to solve the eigenvalue problem, thus yielding upper bound values of the frequencies by minimizing the frequencies. As the degree of the polynomials is increased, frequencies converge to the exact values. Convergence to four-digit exactitude is demonstrated for the first five frequencies of theconical shells. Novel numerical results are presented for thick, complete conical shells of revolution based upon the 3-D theory. Comparisons are also made between the frequencies from the present 3-D Ritz method and a 2-D thin shell theory.

• Advances in concrete construction
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• v.9 no.4
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• pp.375-386
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• 2020

In the present study, the effect of basalt, glass, and hybrid glass-basalt fibers on mechanical properties and fracture behavior of self-compacting concrete (SCC) mixes have been assessed at room and elevated temperatures. To do so, twelve mix compositions have been prepared such that the proper workability, flowability, and passing ability have been achieved. Besides, to make comparison possible, water to binder ratio and the amount of solid contents were kept constant. Four fiber dosages of 0.5, 1, 1.5, and 2% (by concrete volume) were considered for monotype fiber reinforced mixes, while the total amount of fiber were kept 1% for hybrid fiber reinforced mixes. Three different portions of glass and basalt fiber were considered for hybridization of fibers to show the best cocktail for hybrid basalt-glass fiber. Test results indicated that the fracture energy of mix is highly dependent on both fiber dosage and temperature. Moreover, the hybrid fiber reinforced mixes showed the highest fracture energies in comparison with monotype fiber reinforced specimens with 1% fiber volume fraction. In general, hybridization has played a leading role in the improvement of mechanical properties and fracture behavior of mixes, while compared to monotype fiber reinforced specimens, hybridization has led to lower amounts of compressive strength.

• Proceedings of the Korean Society for Cognitive Science Conference
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• 2000.05a
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• pp.71-75
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• 2000

Conventional atom model must be criticized on the following four points. (1) Natural motions between positive and negative entities are not circular motions but linear going and returning ones, for examples sexual motion, tidal motion, day and night etc. (2) Potential energy generation was neglected when electron changes its orbit from outer one to inner one. The hv is the Kinetic energy of the photo-electron. The total energy difference between orbits comprises kinetic and potential energies. (3) The structure of the space must be taken into consideration because the properties of the electron do not change during the transition form outer orbit to inner one even though it produces photon. (4) Total energy conservation law applies to the energy flow between mind and matter because we daily experiences a interconnection between mind and body. New atomic model (the crystallizing $\pi$-bonding) was proposed in the journal of material processing technology since 1997 for the explanation of the mechanical behaviors in terms of physics. $\prod$-ray physics proved that the electrons can come out from in the nucleus and modern chemistry corresponds to the $\pi$-bonding by the nuclear electrons. The $\pi$-bonding structure of the protons outside the nucleus is that electrons move between protons of the different atoms. The perception step and the characteristic frequency in signal transduction is due to the accumulation of the $\pi$-rays outside fo the proton before their absorption to the nucleus.

• Proceedings of the Korean Society for Cognitive Science Conference
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• 2000.05a
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• pp.76-86
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• 2000

Conventional atom model must be criticized on the following four points. (1) Natural motions between positive and negative entities are not circular motions but linear going and returning ones, for examples sexual motion, tidal motion, day and night etc. (2) Potential energy generation was neglected when electron changes its orbit from outer one to inner one. The hv is the kinetic energy of the photo-electron. The total energy difference between orbits comprises kinetic and potential energies. (3) The structure of the space must be taken into consideration because the properties of the electron do not change during the transition from outer orbit to inner one even though it produces photon. (4) Total energy conservation law applies to the energy flow between mind and matter because we daily experiences a interconnection between mind and body. $\prod$-rays come out from the crystallizing $\pi$-bondings when they vibrate or deform. Gaston Naessens(1950) invented a microscope, which can visualize the $\pi$-rays in blood. Unordinarily agglomerated spores of $\pi$-rays may provoke poor immunity and bad illness. The agglomerated spores of $\pi$-rays can make closed type $\pi$-bondings in the case of carbohydrates and esters but proteins build open type $\pi$-bondings because the peptide bonds are planar, which principle produces a life.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.16 no.10 s.115
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• pp.1024-1035
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• 2006

A three-dimensional (3-D) method of analysis is presented for determining the free vibration frequencies and mode shapes of thick, complete (circumferentially closed), circular rings with an elliptical or circular cross-section. Displacement components $u_r,\;u_\theta\;and\;u_z$ in the radial, circumferential, and axial directions, respectively, are taken to be periodic in ${\theta}$ and in time, and algebraic polynomials in the r and z directions. Potential (strain) and kinetic energies of the circular rings are formulated, and upper bound values of the frequencies are obtained by minimizing the frequencies. As the degree of the polynomials is increased, frequencies converge to the exact values. Convergence to four-digit exactitude is demonstrated for the first five frequencies of the rings. Novel numerical results are presented for the circular rings having an elliptical cross-section based upon 3-D theory. Comparisons are also made between the frequencies from the present 3-D Ritz method and ones obtained from thin and thick ring theories, experiments, and another 3-D method.

• Bulletin of the Korean Chemical Society
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• v.29 no.9
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• pp.1755-1760
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• 2008

Energy minimization and conformational studies of molecular ions generated by ESI (electrospray ionization) tandem mass spectrometry (MS/MS) can be used for the discrimination of stereoisomeric permethylated and sodium cationized trisaccharides. Sets of fucose-containing trisaccharides having different internal and terminal linkages have been synthesized to analyze the reducing terminal linkage positions using BT and IT fusion approaches. A detailed investigation has been undertaken on the conformational behaviors of four trisaccharide fragments from human milk and blood group determinants of Type 1 and Type 2, namely Fuc($\alpha$1- 3)Gal($\beta$1-3)GalNAc and Fuc($\alpha$1-3)Gal($\beta$1-X)GlcNAc where X = 3, 4 and 6 using molecular modeling methods. Three dimensional rigid and adiabatic phi-psi-energy maps (Surfer program) describing the energy as a function of rotation around corresponding glycosidic linkages were calculated by SYBYL molecular modeling and MM4 force field programs conjunction with cleavage energies of ESI MS/MS for the side group orientations. This approach predicted conformational behaviors exhibited by isomer saccharides for future applications on biologically active glycoconjugates and to exploit a faster method of synthesizing a series of structural isomeric oligosaccharides.

• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1851-1853
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• 2006

We herein report a new analytical application of XPS to the identification of organic molecules in room temperature ionic liquid for the first time. An organic compound, propargylamine (1), produced in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][$PF_6$]), which is one of the room temperature ionic liquids (RTILs), via $A^3$ coupling reaction, is characterized by means of x-ray photoelectron spectroscopy (XPS) rather than using conventional organic compound analysis techniques. There are four non-equivalent carbons in RTILs and 1 each. The ratios of normalized integrated areas of the deconvoluted binding energy of core electron of carbon (C1s) peaks are well matched to the number of carbons in those compounds. The binding energies of C1s of the featured carbons in 1, C4 (sp carbons in acetylene group) and C5 ($sp^2$ carbons in benzene ring), are assigned 286.2 and 285.4 eV, respectively. These results will be able to provide an important tool and a new strategy for the analysis of organic molecules

• Proceedings of the KOSOMBE Conference
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• v.1996 no.11
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• pp.243-246
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• 1996

This study was peformed to characterize the physiological signal prior to develop an algorithm which quantifies EEGs evoked by tactile stimulation. The experiment was devised with four experimental conditions, which were control and two levels of pressures in tactile sensation. Twenty subjects were used to obtain EEGs while applying tactile stimulation using two types of textiles, soft towel and sand paper, to the right hand of each subject. EEGs were acquired for 20 seconds, and each trial was repeated five times randomly at the different levels of stimulus intensities. The index, $S_{n}$, was obtained by calculating the ratio of energy distribution in the time-frequency plot for each scored psychological state of the subject. The results showed that dominant aspects of the EEG signals have their maximal frequencies concentrated at a lower ranges for the resting and pleasant state, while the spectral energies were distributed to higher frequency ranges when subjects experience an unpleasant emotion.