• 제목/요약/키워드: Forward Reaction

검색결과 153건 처리시간 0.024초

만성적 유기용제 폭로로 인한 조선업 도장공들의 신경행동학적 영향에 관한 연구 (Neurobehavioral Effects of Chronic Exposure to Organic Solvents among Dock Yard Painters)

  • 조영숙
    • 한국직업건강간호학회지
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    • 제6권1호
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    • pp.53-71
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    • 1997
  • Across sectional study was performed to evaluate the chronic effects on central nerve system(CNS) of cumulative exposure of complex organic solvents, using neurobehavioral test. Subjects were 66 (male) dock yard painters of some large ship industry which is located in Ulsan. The neurobehavioral test battery used in this study was NCTB (Neurabehavioral Core Test Battery recommended by WHO(World Health Organization), which consisted of 7 items-Profile of mood states (POMS), Simple reaction time, Santa Ana dexterity test. Digit span, Digit symbol, Benton visual retention test and Pursuit aiming. The subjects were classified by 3 groups according to duration of employment(group 1 ; less than 9 years, group 2 ; 10-14 years, group 3 ; more than 15 years). The results of performance were analyzed considering of work duration, age, educational level, alcohol drinking, smoking and testing time as confounding factors. Benton visual retention test, pursuit aiming correct dot and sum of dot showed significant differences among the groups, and decreased with increasing work duration. It indicated that the mean scores of performance ability were lowering according to work duration. Besides, the tests that didn't show statistical significances but showed linear trends were depression-dejection, vigor, fatigue of POMS, slowest time of simple reaction time and digit span forward. Most of the neurobehavioral test items were correlated with age and educational level. After controlling of confounding factors-age and educational level, the results followed ; digit span backward was different significantly. Tension-anxiety, depression-dejection, anger-hostility of POMS, SD and slowest time of simple reaction time, Santa Ana dexterity test non-preferred hand, digit span forward, Benton visual retention test and pursuit aiming correct dot decreased with increasing of work duration. The correlation analysis was done in order to find out the relationship between subjective symptom and the scores of neurobehavioral core test battery. According to the results of analysis there were no items that had statistical significant relationship(p<0.05).

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The Effects of Seat Surface Inclination on Forward Reaching in Children with Spastic Cerebral Palsy

  • Jeong, Jeong Yun;Lee, Ho-Cheol;Shin, Hwa-Kyung
    • The Journal of Korean Physical Therapy
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    • 제27권2호
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    • pp.106-111
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    • 2015
  • Purpose: Impaired reaching movement is commonly observed in children with cerebral palsy. The purpose of this study was to determine whether the inclination of seat surface can influence the reaching movement in children with spastic diplegic cerebral palsy (CP). Methods: The subjects were 31 children, 16 children with spastic bilateral CP and 15 typically developing (TD) children. The children performed static sitting and forward reaching under three conditions: a horizontal seat surface (Horizontal $0^{\circ}$), a seat surface inclined anterior 15 degrees (Ant $15^{\circ}$), and a seat surface inclined posterior 15 degrees (Post $15^{\circ}$). A 3-axis accelerometer ('ZSTAR3') was used for analysis of the reaching movement. A 3-axis accelerometer was attached on the manubrium of the sternum, lateral epicondyle of the humerus, and styloid process of the ulna. We measured the reaction time, movement time, and data amount during reaching the 8 cm target with an index finger on the three inclined seat surfaces. Results: Reaction time and movement time for CPs showed significant delay; comparing the TD's and CP's amount was significantly greater than the TD's during reaching task (p<0.05). In particular, CP's reaction time and movement time on a seat surface inclined Ant $15^{\circ}$ was significantly more delayed compared with the other seat surfaces (p<0.05). Conclusion: Our results suggest that seat-inclination intervention may provide an ergonomic approach for children with spastic cerebral palsy.

Effects of Reagent Rotation on Stereodynamics Information of the Reaction O(1D)+H2 (v = 0, j = 0-5) → OH+H: A Theoretical Study

  • Kuang, Da;Chen, Tianyun;Zhang, Weiping;Zhao, Ningjiu;Wang, Dongjun
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2841-2848
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    • 2010
  • Quasiclassical trajectory (QCT) method has been used to investigate stereodynamics information of the reaction $O(^1D)+H_2{\rightarrow}\;OH$+H on the DK (Dobbyn and Knowles) potential energy surface (PES) at a collision energy of 23.06 kcal/mol, with the initial quantum state of reactant $H_2$ being set for v = 0 (vibration quantum number) and j = 0-5 (rotation quantum number). The PDDCSs (polarization dependent differential cross sections) and the distributions of P($\theta_r$), P($\phi_r$), P($\theta_r$, $\phi_r$) have been presented in this work. The results demonstrate that the products are both forward and backward scattered. As j increases, the backward scattering becomes weaker while the forward scattering becomes slightly stronger. The distribution of P($\theta_r$) indicates that the product rotational angular momentum j' tends to align along the direction perpendicular to the reagent relative velocity vector k, but this kind of product alignment is found to be rather insensitive to j. Furthermore, the distribution of P($\phi_r$) indicates that the rotational angular momentum vector of the OH product is preferentially oriented along the positive direction of y-axis, and such product orientation becomes stronger with increasing j.

노인 건강운동 프로그램 개발 (The Development of Aquatic Health Exercise Program for the Old)

  • 최재청;한동욱;이정우
    • The Journal of Korean Physical Therapy
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    • 제17권2호
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    • pp.11-22
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    • 2005
  • Purpose: The purpose of this study was to investigate the effects of aquatic health exercise program for the old. Methods: 20 healthy female with an average age of 71years($71{\pm}4.2$), were participated in this study. The aquatic health exercise program that include warm-up, stretching, strengthening exercise, WATSU and cool-down was performed in the pool two times a week for eight weeks(40min per one session). Body composition, strength of the both knee flexors and extensors, balance ability(sway area and path), whole body reaction time and flexibility(forward reaching test in long sitting) were measured before and after exercise. The data was analyzed with paired t-test to determine significant differences of all suggested factors between pre and post-exercise by make use of the SPSS(ver 10.0) package program. Results: The strength of the both knee flexors and extensors were increased significantly(right knee; p<0.01, left knee; p<0.05). Anteroposterior sway area (p<0.01), and sway path (p<0.001) of both leg were reduced significantly with eyes closed and opened. Whole body reaction time by optical stimulation was increased significantly (p<0.01) but whole body reaction time by auditory stimulation was no significant difference. The flexibility was increased significantly (p<0.01). Conclusion: Aquatic health exercise program can improve muscle strength, balance, whole body reaction, and flexibility.

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The Effects of Shoe Type on Ground Reaction Force

  • Yi, Kyung-Ok
    • 한국운동역학회지
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    • 제21권1호
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    • pp.9-16
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    • 2011
  • The purpose of this study is to analyze the effects of both various shoe types and bare feet on ground reaction force while walking. Ten first-year female university students were selected. A force platform(Kistler, Germany) was used to measure ground reaction force. Six types of shoe were tested: flip flops, canvas shoes, running shoes, elevated forefoot walking shoes, elevated midfoot walking shoes, and five-toed shoes. The control group was barefooted. Only vertical passive/active ground reaction force variables were analyzed. The statistical analysis was carried out using the SAS 9.1.2 package, specifically ANOVA, and Tukey for the post hoc. The five-toed shoe had the highest maximum passive force value; while the running shoe had the lowest. The first active loading rate for running shoes was the highest; meanwhile, bare feet, the five-toed shoe, and the elevated fore foot walking shoe was the lowest. Although barefoot movement or movement in five toed shoes increases impact, it also allows for full movement of the foot. This in turn allows the foot arch to work properly, fully flexing along three arches(transverse, lateral, medial), facilitating braking force and initiating forward movement as the tendons, ligaments, and muscles of the arch flex back into shape. In contrast movement in padded shoes have a tendency to pound their feet into the ground. This pounding action can result in greater foot instability, which would account for the higher loading rates for the first active peak for padded shoes.

콤바인 예취장치(刈取裝置)의 절단현상(切斷現象) 및 동적특성(動的特性)에 관한 연구(硏究)(I) -왕복동(往復動) 예취장치(刈取裝置)의 동적특성(動的特性)- (Dynamic Characteristics of the Reciprocating Cutter-bar of Combine Harvester(I))

  • 정창주;이성범;노광모
    • Journal of Biosystems Engineering
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    • 제19권3호
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    • pp.163-174
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    • 1994
  • This study was conducted to investigate the dynamic motion of knife drive system of combine harvester. A computer program was developed to simulate the dynamic motion of the knife drive linkage and its algorithm was evaluated through experiments. The results are summarized as follows : 1. The theorectical horizontal (the direction of knife's reciprocating motion) reaction forces at the supporting point of rocker arm and crank arm were changed in the similar sinusoidal trends with the measured reaction forces. 2. The maximum values of shaking moment and reaction force per one revolution of crank arm followed polynomial trends as the rotational speed of crank shaft increased. The unbalanced force acting on the driving system increased at high speed. Therefore, the rotational speed of crank shaft should be maintained in proper range at increased forward speed to decrease vibration of the knife drive system. 3. The added mass to the crank arm increased the dynamic unbalanced force at the supporting point of rocker arm. It counterbalanced the reaction force at the supporting point of crank arm.

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Characteristics of Products in the Reaction 40 MeV/nucleon $^{14}N+Ag$

  • Chung, Yong-Hee;Porile, N. T.
    • Bulletin of the Korean Chemical Society
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    • 제15권11호
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    • pp.971-975
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    • 1994
  • Cross sections and recoil properties have been measured for the fragments produced in the interaction of silver with 40 MeV/nucleon $^{14}N$ ions using off-line ${\gamma}$-ray spectroscopy. The data were used to obtain the isobaric-yield distribution, the mass yield distribution, and the fractional momentum transfer. The values of forward-to-backward ratios were measured to be very large, indicating that substantial momentum transfer occurs at this energy regime. The results are compared with other studies of the interaction of silver with intermediate-energy heavy ions.

Trajectory Studies of Methyl Radical Reaction with Iodine Molecule

  • Lee, Sang-Kwon;Ree, Jong-Baik;Kim, Yoo-Hang;Shin, Hyung-Kyu
    • Bulletin of the Korean Chemical Society
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    • 제26권9호
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    • pp.1369-1380
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    • 2005
  • The reaction of methyl radical with iodine molecule on an attractive potential energy surface is studied by classical trajectory procedures. The reaction occurs over a wide range of impact parameters with the majority of reactive events occurring in the backward rebound region on a subpicosecond scale. A small fraction of reactive events take place in the forward hemisphere on a longer time scale. The ensemble average of reaction times is 0.36 ps. The occurrence of reactive events is strongly favored when the incident radical and the target molecule align in the neighborhood of collinear geometry. Since the rotational velocity of I2 is slow, the preferential occurrence of reactive events at the collinear configuration of $CH_3{\ldots}I{\ldots}$I leads to the reaction exhibiting an anisotropic dependence on the orientation of $I_2$. During the collision, there is a rapid flow of energy from the $H_3C{\ldots}$I interaction to the I-I bond. The $CH_3I$ translation and $H_3C$-I vibration share nearly all the energy released in the reaction, and the distribution of the vibrational energy is statistical. The reaction probability is $\cong$0.4 at the $CH_3$ and I2 temperatures maintained at 1000 K and 300 K, respectively. The probability is weakly dependent on the $CH_3\;and\;I_2$ temperatures between 300 K and 1500 K.

고압에서 β-glucosidase 반응속도론 및 평형에 관한 연구 (Kinetics and Equilibrium Study on β-glucosidase under High Hydrostatic Pressure)

  • 한진영;이승주
    • 산업식품공학
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    • 제15권3호
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    • pp.214-220
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    • 2011
  • 중고압 하에서 $\beta$-glucosidase효소반응을 물리화학적 관점에서 연구하였다. 모델 기질 (p-nitrophenyl-${\beta}$-D-glucopyranoside)에 대한 $\beta$-glucosidase 효소의 작용에 대한 압력 효과를 실험 하였다. 즉, 압력 조건(25MPa, 50 MPa, 75 MPa, 100 MPa)과 시간 (10분, 60분, 1시간, 6시간, 24시간, 40시간)의 처리 조건에서 효소 활성도를 분광학적인 표준방법에 따라 측정하였다. 효소-기질 반응의 단계를 크게 kinetic 구간과 평형 구간으로 구분하여 물리화학적 모델을 적용하여, 정 역반응속도 상수, 평형상수, 압력에 의한 부피 감소 등을 산출하였다. 대기압에서 100MPa까지 압력이 증가할수록 효소-기질 반응의 생성물이 더 많이 형성되었으며 전형적인 kinetic 구간과 평형 구간이 나타났다. 압력, 시간, 생성물농도 등의 데이터로부터 kinetic 구간과 평형에서의 생성물 예측 모델을 완성하였다. 결론적으로 중고압 처리에 의하여 효소-기질 반응이 촉진됨을 알 수 있었고, 임의의 압력 및 시간 조건에 따른 생성물의 농도를 예측할 수 있게 되었다.

Facilitated Transport of Cr(VI) through a Supported Liquid Membrane with a Carrier

  • Park, Sang-Wook;Lee, Jae-Wook;Kim, Sung-Soo;Choi, Byoung-Sik
    • 한국응용과학기술학회지
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    • 제20권2호
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    • pp.154-164
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    • 2003
  • This paper has applied a simple model to the mass transfer mechanism of Cr(VI) with crownether in a batch-type, supported liquid membrane module. Concentration at pH 3 are as follows : 0.012 kmol/$m^3{\le}$18-crown-6${\le}$0.036 kmol/$m^3$ and 20 g/$m^3{\le}$ Cr(VI)${\le}$500 g/$m^3$. The measured values of forward- and backward-reaction rate constants between Cr(VI) and 18-crown-6 were used to simulate the model with the mass conservation equation and associated boundary conditions. Comparison between the experimental and simulated facilitated factor of Cr(VI) transport led to classification of reaction regions.