• 한국안전학회지
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• 제13권1호
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• pp.64-69
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• 1998

Three kinds of N-fluoroacyl carboxy pyridinium chlorides were synthesized by the reaction of pyridine-carboxylic acid such as pyridine-2-carboxylic, pyridine-3-carboxylic and pyridine-4-carboxylic acid with long chain perfluoroacyl chloride. The surface chemical properties including surface tension, foaming power, foam stability, effectiveness of wettability and solubilizing effect were measured. These compounds showed good surface activities as emulsifying agent, solubilizing agent and fire-fighting agent.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 추계 학술논문 발표대회
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• pp.19-20
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• 2018

As energy related problems continue to arise, Korea's thermal insulation market for the zero energy homes is also demanding major changes, but there are no realistic countermeasures. Also, interest in inorganic insulation is growing as damage from multifamily housing fire using flammable insulation materials is increasing. On the other hand, many studies have been conducted on lightweight foam concrete, which implies a sufficient possibility as an insulation material by generating a large amount of air bubbles. However, studies of existion bubble concrete are not quantified by the experimental difficulty of using bubbles when compared. Therefore, in this study, the change in strength due to air pressure using a bubble foam, one of the types of air bubbles for the development of light foam concrete.

• 한국염색가공학회지
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• 제4권3호
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• pp.82-90
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• 1992

To optimize the foam dyeing procedures for polyester and polyester/nylon blended non-woven fabrics, the effects of organic solvents and surfactants were investigated by measuring the foam heights and surface tensions of the foam dyeing solution. The results of the experiments can be summarized as follows: 1) Organic solvents and surfactants (sodium lauryl sulphate: SLS) solution lower the surface tension (ST) of the water, but ST lowering rate of SLS solution is greater than that of solvents. For a 0.25% SLS solution, the minimum surface tension was 30.3 dyne/cm, which is nearly the same value for organic solvents. 2) For 0.25% SLS solutions, additional adding of a 4.0% organic solvent makes the foam height (FH) be its maximum. 3) At 0.6 g/ι dye concentration, incorporation of 0.4% SLS makes the surface tension of the foam solution be its minimum. The foam height did not show any trend due to the dye type. 4) The effect of foam stabilizers (sodium alginate (Alg-Na) and hydroxy ethyl cellulose (HEC)) were also investigated. The foam height of the foaming solution with HEC was greater than that with Alg-Na. The foam stability of the foaming solution with Alg-Na was better than that with HEC.

• 한국응용과학기술학회지
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• 제32권1호
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• pp.72-77
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• 2015

고급지방산 메틸 에스테르류의 소포제를 합성하고 FT-IR과 $^1H-NMR$ 분석을 통해 확인하였다. FT-IR을 이용하여 합성된 물질의 특징인 -C=O기는 $1740cm^{-1}$ 부근에서, 그리고 C-O기는 $1175cm^{-1}$ 피크 값을 가지는 것을 확인하였다. 또한 $^1H-NMR$ 분석을 통해 에스테르의 -C=O의 Chemical shift가 2.29 ppm에서 나타나는 것을 확인하였다. 표면장력은 Surface Tensiometer CBVP-43을 이용하여 측정하였다. 표면장력은 17.7에서 21 dyne/cm 값을 가진다. SLS 수용액에서의 소포능은 Ross-Miles법을 통해 측정되었다. 4종류의 소포제 중 소포능은 스테아르산메틸을 이용하여 제조한 소포제가 가장 뛰어난 것으로 측정됐다.

• 콘크리트학회논문집
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• 제28권4호
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• pp.435-444
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• 2016

층간소음의 문제가 가장 크게 대두되고 있는 현재 층간소음 저감 방법으로 뜬바닥 구조에 적용되는 차음재등이 연구되고 있으나 이러한 방법의 경우 경량충격음에는 효과적이나 중량 충격음을 저감하기에는 재료 및 기술적 한계에 다다르고 있다. 중량충격음 저감을 위해서는 슬래브의 중량을 증가시켜 충격에 대해 바닥은 진동하기 어렵게 하여 충격에 의한 발생음을 저감시키거나, 슬래브의 강성을 높여 충격점의 유효 질량을 높여 중량충격음을 저감하는 것이 필요할 것으로 판단된다. 이에 본 연구에서는 중량 충격음을 저감하기 위한 한 방편으로 고중량, 고강성 기포콘크리트 제조함으로서 바닥충격음을 저감하기 위한 기술을 개발하고자 하였다. 연구 결과 기포제 종류 및 혼입량과 경량골재 종류 및 투입량과 관계없이 유동성은 190 mm이상으로 매우 우수한 것으로 나타났다. 밀도 및 압축강도 측정 결과 기포콘크리트의 경우 기포 혼입율 50%에서만, 경량골재 기포콘크리트의 경우 모든 배합에서 목표 밀도 및 압축강도를 만족하는 것으로 나타났다. 열전도율 측정 결과 기포콘크리트의 경우 VS50을 제외하고는 모두 만족하는 것으로 나타났으며, 경량골재 기포콘크리트의 경우 Type A 골재의 경우 대체율 25%, Type B의 경우 모든 배합에서 목표를 만족하는 것으로 나타났다.

• Composites Research
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• 제31권4호
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• pp.133-138
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• 2018

구조용 폼의 용도는 난연, 단열 기능이외에 구조적인 목적으로 공극부위를 충진시키는 용도로 사용되고 있다. 경량 소재 개발을 위해 CFRP와 구조용 폼이 이용되고 있으며, PUR, PIR, PVC, PET와 같은 대표적인 폼이 존재한다. 본 연구에서는 구조용 폼의 특성 중 강도 강화를 위한 목적으로 에폭시 폼을 개발하고자 하였다. 에폭시 조성 중 산무수물계 경화제는 기존의 폴리올과 반응을 하기 때문에 산무수물계 에폭시 수지에 발포제를 이용할 경우 폼이 형성되는지, 형성된다면, 압축특성과 포밍 형태를 관하는 연구를 진행하였다. 에폭시 폼을 형성시키기 위한 발포제의 종류에 따른 영향 및 발포재의 농도에 따라 변화되는 폼밍의 결과 차이를 분석하였으며, 산무수물계 수지의 조성차이에 따른 폼의 압축강도를 평가하였다. 궁극적으로 에폭시 폼을 최적의 발포제 선정으로 구조적 강도가 높은 폼을 형성시킬 수 있음을 확인하였으며, 기존의 구조용 폼 소재에 비해 높은 압축강도 및 비압축 강도를 가짐을 확인하였다.

• 산업기술연구
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• 제21권B호
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• pp.249-256
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• 2001

The purpose of this study was to remove the excessive air foaming which was produced in mixing the RSLMC(latex-modified concrete with rapid-setting cement) by choosing the best antifoam agent type. A series of RSLMM(latex-modified mortar with rapid-setting cement) experiments were carried out as a basic experiments for RSLMC with the main experimental variables such as antifiamer types(A, B, C, D), antifoamer contents(0, 1, 2, 3%), and latex contents(10, 15%). Air content test and compressive strength tests were carried out to measure the improved properties of RSLMM. SEM analysis, also, was carried to observe the formation of latex film. The results of RSLMM showed that the decrease of 50% air content was obtained by admixturing an antifoam agent by 1%. This made the strength enhanced and the workability be within the purposed. The best properties of compressive strengths was obtained at latex content of 15% and D antifoam agent of 1%. compressive strength increased about 32.6%. The analysis of SEM results no difference in a formation of later film.

• 한국염색가공학회지
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• 제30권2호
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• pp.107-116
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• 2018

Simplification of the manufacturing process in shoe making is essential to improve productivity and reduce production costs. To improve the adhesion of EVA foam used as a midsole, EVA/itaconated EPDM(EPDM-g-IA)(80/20wt%) blend was prepared using Torque Rheometer-Plasti-Corder, and 1,6-hexamethylenediamine/crosslinking agent/foaming agent/additive were mixed, followed by amidation reaction and foaming to prepare EVA/EPDM-g-IA foam for shoe midsole. In this study, we investigate the effect of the content of 1,6-hexamethylenediamine(0, 0.5, 1.0, 2.0, 3.0) on the mechanical properties, water-contact angle and adhesion of EVA/itaconated EPDM foam. As the content of 1,6-hexamethylenediamine increased, mechanical properties such as tensile strength, tear strength, tensile elastic modulus, hardness, and water-contact angle were lowered, but elongation at break and compression set(%) were increased. Both normal type and non-UV type adhesive strength increased with increasing diamine content. In particular, it was found that the adhesion strength of the non-UV type adhesion increased sharply with increasing diamine content. As a result, an adherend rupture occurs in a foam sample having a content of 1,6-hexamethylenediamine of 3phr. From this, it can be seen that the EVA/itaconated EPDM foam for shoe midsoles, which can be used for non-UV adhesion without primer and UV treatments, have been developed.

• 한국농공학회지
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• 제36권4호
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• pp.48-55
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• 1994

This study was performed to evaluate the engineering properties of the lightweight concrete using surlightweight aggregate foaming agent and high performance agent. The following conclusions were drawn. 1. The unit weight of type A, B and C concrete was 0.912t/m$^3$, 1.592t/m$^3$ and 1.070t/m$^3$, respectively. Specially, the unit weight of type A concrete was decreased 42% than that of the type B concrete. 2. The highest engineering property was measured in the lightweight concrete using high performance agent Also, the ratio of tensile and bending strength to compresive streng-th of the lightweight concrete was higher than that of the normal cement concrete. 3. The dynamic modulus of elasticity of the lightweight concrete was in the range of 2.86 x 10 5~9.86 x 10 5 kg/cm$^2$ which was approximately 300% than that of the normal cement concrete. 4. The ultrasonic pulse velocity of the lightweight concrete was in the range 2047~3394 n/sec, which was smaller than that of the normal cement concrete.

• Design & Manufacturing
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• 제11권2호
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• pp.1-8
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• 2017

In this study, we applied microcellular foaming injection molding process to improve the performance of system air-conditioner drain fan which had been produced by injection molding process and studied the optimization of process conditions through 6-sigma process and response surface method (RSM) to reduce weight and deformation of products. Additive type, melt temperature, mold temperature, and injection screw shape were selected as the factor affecting the weight and deformation of the products by carrying out analysis of trivial many through ANOVA and design of experiment (DOE) method. Among the effect factor, we set the addictive type to Long G/F and screw shape to foaming screw which had the highest level of weight reduction and deformation reduction. The amount of foaming agent gas was set at 60 ml, which was the limit beyond which the weight of product did not decrease any more. For melt temperature and mold temperature, we studied the conditions where both weight and deformation were minimized using the RSM. As a result, we set the melt temperature to $250^{\circ}C$, fixed mold temperature to $20^{\circ}C$, and moving mold temperature to $40^{\circ}C$. The improvement effect was analyzed by appling the selected optimal conditions to the production process using the microcellular foaming injection molding. The results showed that the mean weight of product was measured to be 1,420g which was 19% lower than that measured in the current process. The standard deviations of the weights were found to be similar to those in the current process and it showed a low dispersion. The mean deformation was measured to be 0.9237mm, which represented a 57% reduction compared to the mean deformation in the current process, and the standard deviation decreased from 0.3298mm to 0.1398mm. Moreover, we analyzed the process capability for deformation, and the results showed that the short-term process capability increased from 2.73 to 6.60 which was even higher than targeted level of 6.0.