• Title/Summary/Keyword: Fluorocarbon

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합성고무를 이용한 공업제품

  • Baek, Nam-Cheol
    • The tire
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    • s.18
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    • pp.3-10
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    • 1968
  • 화학공업사발행인 화학공업지 1968년 1월호에 고무에 대한 기본적인 개념과 아울러 현재 가장 댜량으로 사용되고 있는 합성고무들에 관한 성질, 용도 및 배합례를 소개한 일이 있다. 이번에는 특수한 용도에 사용되는 하이팔론(Hypalon, Chlorosulfonated polyethylene), 티오콜(Thiokol, Polysulfide, Polymers), 실리콘고무(Silicone rubbers) 및 비소고무(Fluorocarbon elastomers)에 대하여 기술하고자 한다.

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Effect of Washing and Subsequent Heat Treatment on Water Repellency and Mechanical Properties of Nylon 6, Triacetate and Silk Fabrics Treated with Hydrocarbon Resins

  • Park, Hyei-Ran;Lee, Mun-Cheul;Nishi, Kenji;Wakida, Tomiji
    • Textile Coloration and Finishing
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    • v.20 no.6
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    • pp.87-91
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    • 2008
  • It is commonly known that water repellency of the fabric treated with fluorocarbon resin brings about a decrease by the washing and recovers by the subsequent heat treatment. In this article, effect of the water repellency was investigated on the nylon 6, triacetate and silk fabrics treated with hydrocarbon and silicon resins. Hydrocarbon and silicon resins have been widely used in the textile finishing as the softening and water proofing agents. The fabrics were treated with hydrocarbon resins, Paragium JQ and RC (Ohara Paragium Chemical Co.) and a silicon resin, Poron MR (Shinetsu Chemical Co.), and then washed and subsequently heat treated. Although the water repellency increased by the resin treatment, it decreased by the washing apparently and recovered a little by the heat treatment. The effect of the heat treatment was small comparing with that of the fluorocarbon resin. Furthermore, as a mechanical property of the treated fabric, KES shearing and bending hysteresis parameters, modulus and hysteresis width of the hydrocarbon resin-treated nylon 6, triacetate and silk fabrics decreased by the heat treatment after washing. Therefore, the treatment is effective at improving the softening of the fabric in water repellent finish.

Comprehensive Review of Acute Respiratory Failure Following Inhalation Exposure to Waterproofing Agents (방수 스프레이 흡입 노출로 인한 급성 호흡기 중독 사례 및 원인 고찰)

  • Park, Donguk;Choi, Yeyong
    • Journal of Environmental Health Sciences
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    • v.38 no.6
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    • pp.451-459
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    • 2012
  • Background: In Korea, a healthy 36-year-old man developed acute interstitial pneumonitis soon after inhaling a waterproofing spray which he had applied at home to his outdoor jacket. Objectives: The objectives of this study were to review cases of varying degrees of respiratory toxicity and poisoning in connection with the use of waterproofing spray and summarize major reasons for cases of poisoning. Methods: We searched articles reporting on a combination of a waterproofing agent and/or respiratory symptoms, including acute respiratory syndrome, lung injury, pneumonia, pulmonary toxicity, and respiratory disease. Results: We reviewed a number of cases of varying degrees of respiratory toxicity and poisoning resulting from inhalation of waterproofing spray containing fluorocarbon co-polymer, solvents and propellants reported in a variety of countries. The literature searches concluded that among the ingredients of waterproofing agents, fluorinated polymer may cause acute respiratory health effects. Conclusion: Environmental policy should be implemented in order to prevent consumers from using household and industrial products including waterproofing agents. In addition, a national surveillance system should be created to collect cases of poisoning caused by the use of consumer products.

Hydrogen Effect Assessment of Fuel Supply Systems for Hydrogen Blended Natural Gas Vehicle (수소-천연가스 혼합연료 차량 연료 공급시스템 수소영향 평가)

  • Kang, SeungKyu;Kim, SangRyul
    • Journal of Energy Engineering
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    • v.26 no.4
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    • pp.1-6
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    • 2017
  • This study evaluated hydrogen effect of metal and non-metallic materials used in the hydrogen blended natural gas vehicle. Hydrogen penetrated concentration of 34Cr-Mo steel(850MPa tensile strength) for winter driving conditions was measured 0.0018ppm and summer driving conditions was 5.3ppm. The critical hydrogen concentration of high strength metal used in this study was measured 1.03ppm by CLT. Therefore, 34CrMo steel cas cause problems in the 30% HCNG(25MPa) environment. In case of the test for non-metallic materials, all materials met the criteria of the gas resistance test, but Fluorocarbon Rubber material had a significant change in the volume. So if it is used, extra care is needed.

Investigation on Suppression of Nickel-Silicide Formation By Fluorocarbon Reactive Ion Etch (RIE) and Plasma-Enhanced Deposition

  • Kim, Hyun Woo;Sun, Min-Chul;Lee, Jung Han;Park, Byung-Gook
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.13 no.1
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    • pp.22-27
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    • 2013
  • Detailed study on how the plasma process during the sidewall spacer formation suppresses the formation of silicide is done. In non-patterned wafer test, it is found that both fluorocarbon reactive ion etch (RIE) and TEOS plasma-enhanced deposition processes modify the Si surface so that the silicide reaction is chemically inhibited or suppressed. In order to investigate the cause of the chemical modification, we analyze the elements on the silicon surface through Auger Electron Spectroscopy (AES). From the AES result, it is found that the carbon induces chemical modification which blocks the reaction between silicon and nickel. Thus, protecting the surface from the carbon-containing plasma process prior to nickel deposition appears critical in successful silicide formation.

Surface Wettability in Terms of Prominence and Depression of Diverse Microstructures and Their Sizes (다양한 형태의 실리콘 미세 구조물을 이용한 초소수성 표면형상 구현)

  • Ha, Seon-Woo;Lee, Sang-Min;Jeong, Im-Deok;Jung, Phill-Gu;Ko, Jong-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.6 s.261
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    • pp.679-685
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    • 2007
  • Superhydrophobic surface, with a water contact angle greater than $150^{\circ}$, has a self-cleaning effect termed 'Lotus effect'. This surface is created by the combination of rough surface and the low surface energy. We proposed square pillar and square shapes to control surface roughness. Microstructure arrays are fabricated by DRIE(Deep Reactive Ion Etching) process and followed by PPFC(Plasma Polymerized Fluorocarbon) deposition. On the experimental result, contact angle at square pillar arrays is well matched with Cassie's model and largest contact angle is $173.37^{\circ}$. But contact angle of square pore shape arrays is lower than Cassie's theoretical contact angle about $5{\sim}10%$. Nevertheless, square pore arrays have more rigidity than square pillar arrays.

Wear Test for Rotary Compressor using Alternative Refrigerants (대체냉매를 사용한 로타리 압축기의 마모시험)

  • 좌성훈;백충국;장선태;오상경
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1995.06b
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    • pp.28-37
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    • 1995
  • To protect the ozone layer depeletion the CFC (chlorofluorocarbon). HCFC(hydrochlorofluorocarbon) refrigerants will be replaced with HFCs (hydro-fluorocarbon) as an alternative refrigerant. In recent years a good deal of effort has been made to develop new compressors which are compatible to the new referigent. This paper focused on developing accelerated screening test for predicting tribological characteristics of the rotary compressor in atmosphere of R407C as an alternative refrigerant with polyolester lubricant. Falex wear test machine with high pressure chamber has been used to simulate friction and wear behavior of the common contact geometries found in rotary compressors.

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Characteristics of ICP Fluorocarbon Thin Films (ICP를 이용한 불화 유기 박막의 특성 평가)

  • 차남구;박진구
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.72-72
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    • 2003
  • 반점착막으로 활용되고 있는 불화유기박막의 형성을 ICP를 이용하여 나노미터로 성장시키고 이를 기계적/화학적 관점에서 특성평가를 수행했다. 증착된 불차유기 박막은 알루미늄 시편위에서 110도 근처를 나타냈으며 30도 근처의 낮은 히스테리시스를 보이는 안정한 박막이 형성되었다. 극성과 비극성 용액을 사용하여 표면에너지를 검사한 결과 약 20 mN/m 이하의 낮은 표면에너지를 얻을 수 있었다. AFM을 이용한 실험결과 표면의 점착력이 약 4nN으로 매우 낮은 점착력을 가짐을 확인 할 수 있었다. FTIR 실험결과 표면에 CF$_2$ 와 같은 불화유기 그룹이 발견되었다.

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